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At least 19 records

An interface facet driven Rayleigh instability in high-aspect-ratio bimetallic nanolayered composites

One limitation hindering the structural and electrical applications of nanostructured metals is the loss of their nanostructure and strength under elevated temperatures. Nanostructured metals often have grain structures that contain a high density of triple junctions, where thermally induced instabilities commonly initiate. Prior work has resulted in fabrication of nanolayered two-phase composites that possess high-aspect ratio grains, a scarcity of triple junctions, and a thermally stable microstructure. In this work, transmission electron microscopy is used to investigate how these composites could eventually breakdown during heating. We reveal an unconventional thermal instability mechanism in this class of materials, which operates without the assistance of triple junctions. The mechanism can be rationalized by that thermally induced pinch off occurs as the result of bimetal interface faceting and can trigger a classic Rayleigh instability.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Fabrication of hard x-ray zone plates with high aspect ratio using metal-assisted chemical etching

Fresnel zone plates are widely used as nanofocusing optics for x-ray microscopy, where the spatial resolution is set by the width of the finest rings while the efficiency is set by their thickness. This leads to the requirement for high aspect ratio nanofabrication. Metal-assisted chemical etching and atomic layer deposition has already been used to produce high aspect ratio zone plate structures on un-thinned silicon wafers. We demonstrate here a substantial improvement on the achieved aspect ratio up to a value of 500:1, by producing 16 nm wide platinum zones with thicknesses up to 8 µm. At the same time, the silicon substrate was thinned to 15 µm as required for a practically useful optic. First tests have shown 4.8% diffraction efficiency using 20 keV X rays. This x-ray focusing efficiency is higher than most Fresnel zone plates for this photon energy and near what has been achieved with multilayer-coated Kirkpatrick-Baez mirrors, and multilayer Laue lenses. Hard x-ray zone plates offer the advantages of easy alignment, energy tunability, and one can make many zone plates in a batch on a single silicon chip.

Fresnel zone plates↗

Characteristics of Ultralow Aspect Ratio Toroidal Plasmas and Non-Solenoidal Startup and Edge Stability Studies at Near-Unity Aspect Ratio (Final Report)

This grant supported a long-term research and development program to explore the physics and technology of spherical tokamak (ST) plasma behavior at near-unity aspect ratio ( A ). The PEGASUS Toroidal Experiment is a university-scale ( R ) ~ 0.40 m, α ~ .35 m, I p ≤ 0.3 MA, B T ≤ 0.15 T) experiment that accesses A → 1, to provide large values of the normalized plasma current, I N = I p /α B T , or equivalently the toroidal field utilization factor I p / I TF . The research activities focused on: 1) developing the technique of Local Helicity Injection (LHI) as a viable means of initiating and growing an ST plasma without the use of a central solenoid; 2) exploring the equilibrium and stability properties of spherical tokamak plasmas at extremely low aspect ratio; and 3) obtaining new insights in the properties of the enhanced confinement H-mode regime at A ~ 1. The initial (Phase I) facility employed a unique high-stress central solenoid Ohmic for current drive and heating with simple magnet current waveforms. A subsequent major upgrade (Phase II) offered more flexible control of the plasma evolution along with a powerful LHI system for plasma initiation, heating and sustainment. The LHI technique consists of injection of high-density current streams into vacuum toroidal and vertical magnetic fields. These streams become unstable and support magnetic reconnection to allow the system to relax into a tokamak-like magnetic configuration. This program focused on: 1) development of electron current sources that provide sufficiently high injection currents in the challenging edge plasma region; 2) validation of theoretical limits to achievable I p arising from magnetic helicity and energy conservation plus absolute limits arising from relaxation to a minimal energy states; 3) tests of a power balance model to describe the evolution of the plasma current I p (t); and 4) study of magnetic fluctuations and their role in the I p evolution. This culminated in the production of toroidal currents of I p ≥ 0.2 MA with only ~8 kA of injected current. Operation with Ohmic induction alone in Phase I created plasmas with soft limits on the achievable I p and field utilization ( I p / I TF ~ 1) due to the onset of large low-order (2/1 or 3/2) internal resonant tearing modes. With the expanded capabilities in Phase II operation, methods employed to mitigate those modes and achieve I p / I TF > 1 were: 1) I TF ramp-downs; 2) non-solenoidal startup via LHI; and 3) extremely low I TF Ohmic operations assisted by LHI current injector pre-ionization. Extensive use of LHI-driven startup and drive for non-solenoidal operation produced favorable current profiles to stably operate tokamak plasmas with unprecedentedly high I N = I p / aB T ~ 15 and I p / I TF > 2. With strong reconnection-driven anomalous ion heating, this in turn provided access to tokamak plasmas with B t up to 100%, a world record 2 times higher than that previously achieved in advanced or spherical tokamaks. This high B t regime had a large fraction (~50%) of the plasma volume in a region of an absolute minimum- B configuration. The MHD stability limit in this regime was the ideal external kink mode without a stabilizing wall. These results provided the first demonstration of access to tokamak plasmas with very high B t , high i N , high elongation κ, and low internal inductance ℓ i , and as such served as a proof-ofprinciple for access to this long-sought ST regime. The naturally low B T needed for stability at A ≤ 1.2 reduces the L-H mode power threshold, P LH , so that H-mode plasmas were achieved with Ohmic heating alone. The power threshold for the transition to the H-mode regime was found to be 10× the accepted values from the ITER international scaling, confirming initial trends indicated by experiments on MAST and NSTX, and suggesting that the physics behind this transition is not yet fully understood. The density dependence of the transition and the observed insensitivity to whether the plasma is bounded by a limiter or magnetic divertor are consistent with the recent FM 3 model. Multiple unstable toroidal magnetic modes were measured during ELM (Edge Localized Mode) crashes, with generally lower toroidal mode numbers than seen at higher A , which was attributed to the larger peeling mode instability drive at low A . First-ever edge current profile measurements through an ELM crash showed current-carrying filaments were generated, as seen in ELM simulations and in electromagnetic blob transport theory.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Investigation of Gas Turbine Internal Cooling Using Supercritical CO 2 —Effect of Surface Roughness and Channel Aspect Ratio

In this paper, an experimental and numerical investigation of internal cooling channels with rib turbulators is presented with sCO 2 as the working fluid at process conditions (pressure-20.7 MPa and temperature up to 150 °C). The effect of channel aspect ratio up to 2:1 on thermal-hydraulic performance is explored in additively manufactured rectangular channels and square channels, both with and without 60 deg ribs on the top and bottom sides. The Wilson-plot method is employed to experimentally measure channel-averaged Nusselt number over a Reynolds number range up to 370,000. The friction factor is calculated from pressure drop and mass flow rate and additionally, the overall thermal performance factor (TPF) is reported. A companion computational fluid dynamics (CFD) simulation is performed for the rib turbulated cooling configurations reported in the experiments using the Reynolds average Navier–Stokes-based turbulence model. The objective of the numerical study is to gain insight into the local heat transfer augmentation in the ribbed channels as a result of varying the aspect ratio, channel configuration (square versus rectangular), operating conditions (Reynolds number) and the surface roughness, an inherent outcome of the additive manufacturing process. Surface roughness is simulated using sand grain roughness height (K S ) calculated from the experimental data, and a comparison is presented with the corresponding channel configuration with varying surface roughness heights starting from smooth surfaces (K S = 0). Experimental results indicate that the heat transfer augmentation is negligible in the rectangular channels with ribs on the long side compared to the square channel. However, it is enhanced by 60% in comparison to placing ribs on the shorter side. The TPF remains constant at around 1 for the entire range of Reynolds numbers consistent with prior work at the National Energy Technology Laboratory (NETL). Here, the simulation results highlight that increased surface roughness can have a favorable considerable influence on Nusselt number and overall thermal performance enhancement.

42 ENGINEERING↗

Time-resolved PIV measurements in a low-aspect ratio facility of randomly packed spheres and flow analysis using modal decomposition

This work experimentally investigated the flow characteristics in a facility with randomly packed spheres at a low-aspect ratio of 4.4. Velocity fields in the near-wall region and in the pores between spheres were obtained by employing the matched-index-of-refraction (MIR) and time-resolved particle image velocimetry (TR-PIV) techniques for Reynolds numbers of 340, 520, and 720. From the obtained TR-PIV velocity vector fields, flow characteristics including first- and second-order statistics, such as mean velocity, root-mean-square fluctuating velocity, and Reynolds stress profiles, were computed. The effects of the wall enclosure and Reynolds numbers on the flow patterns were investigated by comparing the computed flow statistics and evaluating two-point cross correlations of the velocities measured adjacent to and far from the wall. Comparisons of the mean velocities, root-mean-square fluctuating velocities, and Reynolds stress component showed an increase in flow mixing and turbulent intensity in the gaps between spheres in the packed bed. The re-circulation-region sizes, however, were found to be independent from an increase in Reynolds numbers. Finally, flow modal decompositions, such as the proper orthogonal decomposition (POD) and dynamic mode decomposition (DMD), were applied to the vorticity fields extracted from sub-regions located near and far from the wall to reveal the most dominant POD and DMD flow structures.

42 ENGINEERING↗

Finite orbit width effects in large aspect ratio stellarators

New orbit-averaged equations for low collisionality neoclassical fluxes in large aspect ratio stellarators with mirror ratios close to unity are derived. The equations retain finite orbit width effects by employing the second adiabatic invariant $J$ as a velocity-space coordinate and they have been implemented in the orbit-averaged neoclassical code KNOSOS (Velasco et al. , J. Comput. Phys. , vol. 418, 2020, 109512; Velasco et al. , Nucl. Fusion , vol. 61, 2021, 116013). The equations are used to study the $1/\nu$ regime and the lower collisionality regimes. For generic large aspect ratio stellarators with mirror ratios close to unity, as the collision frequency decreases, the $1/\nu$ regime transitions directly into the $\nu$ regime, without passing through a $\sqrt {\nu }$ regime. An explicit formula for the neoclassical fluxes in the $\nu$ regime is obtained. The formula includes the effect of particles that transition between different types of wells. While these transitions produce stochastic scattering independent of the value of the collision frequency in velocity space, the diffusion in real space remains proportional to the collision frequency. The $\sqrt {\nu }$ regime is only recovered in large aspect ratio stellarators close to omnigeneity: large aspect ratio stellarators with large mirror ratios and optimized large aspect ratio stellarators with mirror ratios close to unity. Neoclassical transport in large aspect ratio stellarators with large mirror ratios can be calculated with the orbit-averaged equations derived by Calvo et al. ( Plasma Phys. Control. Fusion , vol. 59, 2017, 055014). In these stellarators, the $\sqrt {\nu }$ regime exists in the collisionality interval $(a/R) \ln (R/a) \ll \nu _{ii} R a/\rho _i v_{ti} \ll R/a$ . In optimized large aspect ratio stellarators with mirror ratios close to unity, the $\sqrt {\nu }$ regime occurs in an interval of collisionality that depends on the deviation from omnigeneity $\delta$ : $\delta ^{2} |\ln \delta | \ll \nu _{ii} R a/\rho _i v_{ti} \ll 1$ . Here, $\nu _{ii}$ is the ion–ion collision frequency, $\rho _i$ and $v_{ti}$ are the ion gyroradius and thermal speed, and $a$ and $R$ are the minor and major radii.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

What Can We Conclude about the Real Aspect Ratios of Ice Particle Aggregates from Two-Dimensional Images?

Abstract A simple numerical experiment was performed to investigate the result published in many papers that measurements indicate that aggregates may be well represented as oblate spheroids with mean aspect ratio (semiminor axis to semimajor axis length) of 0.6. The aspect ratio measurements are derived from two-dimensional projections of complex three-dimensional aggregates. Here, aggregates were modeled as ellipsoids with semiprincipal axes of length a, b, and c, which include oblate spheroids (a = b) as a class, and the projected aspect ratios of large numbers of two-dimensional projections of them were sampled. When sampling oblate spheroids with aspect ratio 0.6 over random orientations, the mean projected aspect ratio is 0.746. A mean projected aspect ratio of 0.6 is obtained for an oblate spheroid with aspect ratio of 0.33. When sampling randomly oriented ellipsoids with semiminor axes (b, c) varying from 0.10 to 1.00 in steps of 0.01, representing many complex shapes, the mean projected aspect ratio is 0.595, close to the measured mean projected aspect ratio of aggregates of 0.6. These experiments demonstrate that the conclusion one may safely draw from the projected aspect ratio measurements is that the mean aspect ratio of aggregates is lower than 0.6. Moreover, the projected aspect ratio distributions from measurements suggest a mixture of aggregate shapes, rather than only oblate spheroids as is often assumed.

Jiang, Zhiyuan↗

Aspect ratio control and photocatalytic properties analysis of anatase TiO2 nanoparticles

Highlights: • TiO{sub 2} nanoparticles with different aspect ratio were prepared and characterized. • Their aspect ratio is tuned by varying surfactants molar ratio and concentration. • TiO{sub 2} nanoparticles show photocatalytic activities in degradation of methylene blue. - Abstract: Anatase TiO{sub 2} nanoparticles with tuning size and aspect ratio were successfully prepared by a simple solvothermal method, using ethanol as a solvent, titanium butoxide as a precursor, and oleic acid and oleylamine as anionic and cationic capping agents, respectively. The average size and aspect ratio of these nanoparticles can be greatly regulated by varying the oleic acid/oleylamine molar ratio while keeping their total molar content constant and finely adjusted by increasing the total capping agents molar concentration in solvent at constant molar ratio (oleic acid/oleylamine molar ratio = 1:1). The variation of molar ratio or molar concentration enables a manipulation of the growth rate along different facets of TiO{sub 2} nanoparticles and, consequently, a control of the aspect ratio of these nanoparticles. Moreover, the photocatalytic degradation rate of methyl blue for sample prepared with molar ratio of oleic acid to oleylamine at 6:24 is over 11% higher than that for the other samples.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Synthesis of high aspect ratio ZnO nanowires with an inexpensive handcrafted electrochemical setup

In this work, high aspect ratio zinc oxide nanowires are synthesized using templated one-step electrodeposition technique. Electrodeposition of the nanowires is done using a handcrafted electronic system. Nuclear track-etched polycarbonate membrane is used as a template to form the high aspect ratio nanowires. The result of X-ray diffraction and scanning electron microscopy shows that nanowires with a good crystallinity and an aspect ratio of more than 30 can be achieved in a suitable condition. The height of electrodeposited nanowires reaches to about 11 μm. Based on the obtained results, high aspect ratio ZnO nanowires can be formed using inexpensive electrodeposition setup with an acceptable quality.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Effect of aspect ratio on plasma response to resonant magnetic perturbations in tokamak devices

A systematic numerical study is carried out, computing and comparing the plasma response to the resonant magnetic perturbation (RMP) field, applied for controlling edge localized modes (ELMs), in a series of tokamak plasmas with varying aspect ratio and utilizing the MARS-F code. The aspect ratio is scanned either by varying the plasma major radius at a fixed minor radius or by varying the latter while fixing the former. Both approaches yield similar results when compared in terms of quantities with proper normalizations. In general, a non-monotonic dependence of the resonant response field (normalized by the vacuum counterpart) near the plasma edge is found with varying aspect ratio, indicating that a given ELM control coil current configuration strongly favors plasmas with a certain aspect ratio. This optimal aspect ratio, on the other hand, depends on the toroidal as well as poloidal (i.e., coil phasing) spectra of the applied RMP field. The equilibrium (edge) safety factor, the plasma shape, and the plasma toroidal flow are all fixed to ensure that the effects identified here are predominantly due to the plasma aspect ratio.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Ultra-high aspect ratio pores milled in diamond via laser, ion and electron beam mediated processes

Microfabrication techniques are critical for the rapid prototyping and development of applications for cutting edge materials. Recently diamond has gained considerable interest for quantum photonic, biosensing, inertial confinement fusion and magnetometer applications. In this article, ultra-high aspect ratio milling of diamond micropores by photon, ion and electron based methods is reported. A multiphoton absorption laser ablation approach is revealed to rapidly produce sub-10 μm diameter micropores in diamond with an aspect ratio of 14:1 and a tapered profile at the surface interface. Chemically active, oxygen focused ion beam milling produces high-aspect ratio pores in diamond with an aspect ratio of 65:1 and minimal tapering over the length of the pore, overcoming the physical interaction volume limitations imposed in conventional gallium based focused ion beam milling and laser ablation methods. Oxygen-mediated electron beam induced etching is revealed to negate the limitations imposed by physical sputtering mechanisms utilized in focused ion beam milling via the direct initiation of chemical reactions at the receding surface, producing aspect ratios on the order of 200:1. Numerical simulations reveal the physical basis for the superior aspect-ratio pore milling of the oxygen focused ion beam milling and electron beam induced etching methods. Our results demonstrate direct-write methods for the fabrication of ultra-high aspect micropores in diamond and provide insight into the underlying mechanisms of these physical processes. The three methods demonstrated here can be interchanged for applications based on the desired characteristic aspect ratio and process throughput.

36 MATERIALS SCIENCE↗

One-pot rapid synthesis of high aspect ratio silver nanowires for transparent conductive electrodes

Highlights: • We improved a method of preparation of silver nanowires. • The effects of PVP molecular weight and concentration on the morphology and aspect ratio of AgNWs were investigated. • The preferred orientation growth mechanism of AgNWs was also discussed briefly. • We got transparent conductive films by spin-coating silver nanowires dispersion which is compared to ITO films. • The effects of silver nanowires density and heating time on the sheet resistance and transmittance were investigated. - Abstract: Silver nanowires (AgNWs) with high aspect ratio were rapidly one-pot synthesized by a polyol process in the presence of polyvinylpyrrolidone (PVP) as a stabilizer as well as the anisotropic agent, and the corresponding transparent conductive films were prepared by spin-coating method. The effects of PVP molecular weight and concentration on the morphology and aspect ratio of AgNWs were investigated in detail, and the optoelectrical properties of the transparent conductive films were briefly introduced. The presence of PVP induces the growth of silver directed to form high aspect-ratio nanowires by a high anisotropic mode. Appropriate PVP molecular weight and concentration allows the rapid synthesis of AgNWs with the diameter of about 78.2 nm, the length of 79.52 μm and the aspect ratio as high as 1009.2. The as-prepared AgNWs films possess a transmittance of 81.6% and a sheet resistance of 11.36 Ω/sq. The resultant AgNWs with high aspect ratio can be applied to prepare transparent conductive electrodes.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

High- β equilibrium and ballooning stability of the low aspect ratio CNT stellarator

In the paper, the existence and ballooning-stability of low aspect ratio stellarator equilibria is predicted for the Columbia Neutral Torus (CNT) with the aid of 3D numerical tools. In addition to having a low aspect ratio, CNT is characterized by a low magnetic field and small plasma volume. Also, highly overdense plasmas were recently heated in CNT by means of microwaves. These characteristics suggest that CNT might attain relatively high values of plasma beta and thus be of use in the experimental study of stellarator stability to high-beta instabilities such as ballooning modes. As a first step in that direction, here the ballooning stability limit is found numerically. Depending on the particular magnetic configuration we expect volume-averaged β limits in the range 0.9%–3.0%, and possibly higher, and observe indications of a second region of ballooning stability. As the aspect ratio is reduced, stability is found to increase in some configurations and decrease in others. Energy-balance estimates using stellarator scaling laws indicate that the lower β limit may be attainable with overdense heating at powers of 40 to 100 kW. The present study serves the additional purpose of testing VMEC and other stellarator codes at high values of β and at low aspect ratios. For this reason, the study was carried out both for free boundary, for maximum fidelity to experiment, as well as with a fixed boundary, as a numerical test.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗