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All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

First experimental determination of the ⁴⁰Ar(𝑛, 2𝑛)³⁹Ar reaction cross section and ³⁹Ar production in Earth’s atmosphere

The cosmogenic ³⁹Ar(t1∕2 = 268 years) isotope of argon is used for geophysical dating and tracing of underground and ocean water, as well as ice owing to its appropriate half-life and chemical inertness as a noble gas; ³⁹Ar serves also in nuclear weapon test monitoring. We measured for the first time the total cross section of the main ³⁹Ar cosmogenic production reaction in the atmosphere, namely ⁴⁰Ar(𝑛, 2𝑛)39 Ar, using 14.8 ± 0.3 MeV neutrons. The neutrons, produced by a deuterium-tritium generator, impinged on a stainless steel sphere filled with Ar gas highly enriched in the ⁴⁰Ar isotope and were monitored by a stack of fast-neutron activation foils. The reaction yield was measured by atom counting of long-lived ³⁹Ar with noble gas accelerator mass spectrometry and, independently, by decay counting relative to atmospheric argon (³⁹Ar/Ar= 8.12 × 10−16 ). A total ⁴⁰Ar(𝑛, 2𝑛)39 Ar cross section of 610 ± 100 mb was determined at 14.8 ± 0.3 MeV incident neutron energy. This result serves as a benchmark for recent theoretical calculations and evaluations, found to reproduce well the experimental total cross section. We use these energy-dependent theoretical cross sections together with experimental spectra of cosmogenic neutrons at different altitudes to calculate the global average rate of neutron-induced ³⁹Ar atmospheric production, resulting in 770 ± 240 39 Ar atoms/cm²/day. The secular equilibrium between the ³⁹Ar calculated production rate and radioactive decay rate leads to a partial isotopic abundance ³⁹Ar/Ar = (5.9 ± 1.8) × 10−16 , showing that ≈73% of atmospheric ³⁹Ar is produced by cosmogenic neutrons, the remaining part believed to be induced by muons and high-energy 𝛾 rays. The ⁴⁰Ar(𝑛, 2𝑛)³⁹Ar cross section at 14 MeV is also a key parameter for quantifying the anthropogenic contribution to atmospheric 39 Ar produced during the thermonuclear tests of the 1960s. We estimate that anthropogenic ³⁹Ar accounts for roughly 20% of the present atmospheric inventory.

39 Ar atmospheric production↗
DOE OSTI2026

A comparison of long-term 37 Ar and 39 Ar transport and implications for 39 Ar as a persistent indicator of underground nuclear explosions

Measurements were first made in 2016 of legacy 39 Ar gas from the decades-old Barnwell underground nuclear explosion site within the Nevada National Security Site. This has raised the question of the ubiquity of the radionuclide 39 Ar following underground nuclear explosions in general locations. This article presents a high-level evaluation of the scientific case for using 39 Ar as a long-term indicator of underground nuclear explosions. Assessment is made based on a broad set of assumptions to reasonably estimate the persistence of 39 Ar in the subsurface environment following an explosion to establish potential detectability years to decades after the originating event.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
DOE OSTI2025

First Measurement of $π^+$-Ar and $p$-Ar Total Inelastic Cross Sections in the Sub-GeV Energy Regime with ProtoDUNE-SP Data

The ProtoDUNE-SP detector, a kiloton-scale prototype for the Deep Underground Neutrino Experiment (DUNE), is the largest liquid argon time projection chamber built to date. Operated at CERN from 2018 to 2020, it collected both cosmic-ray data and a beam consisting of positively-charged particles with discrete momentum settings across a range of 0.3 GeV/$c$ to 7 GeV/$c$. In this letter, we report the total inelastic cross section measurements for $π^+$-Ar and $p$-Ar interactions using selected $π^+$ and proton samples from the 1 GeV/$c$ beam data. These results provide the first measurement of the total inelastic cross sections for $π^+$-Ar in the 500-900 MeV kinetic energy range and for $p$-Ar below 450 MeV, both of which are directly relevant to the DUNE energy range. The measured cross sections are consistent with predictions and provide a dataset that was previously unavailable for argon targets. These measurements are essential for constraining neutrino-argon interaction models, which are crucial for the precision physics goals of the upcoming DUNE experiment.

Abbaslu, Saeed [IPM, Tehran] (ORCID:00000003356771↗
DOE OSTI2026

Plasma decay of nanosecond pulsed laser-produced Ar and Ar–H 2 O sparks at atmospheric pressure

Time-resolved diagnostics were applied to investigate free-electron properties in nanosecond laser-produced discharges generated in atmospheric pressure Ar and in Ar–3%H 2 O. The discharges were generated using 23 ns, 1064 nm laser pulses. Broadband plasma imaging and laser Thomson scattering were combined with optical emission spectroscopy, with particular emphasis on the Stark broadening of the H α and H β lines. The plasma exhibited a bright emission that persists for up to 30–40 µs after breakdown. Plasma emission was then followed by a very weak glow emission that persisted for up to 19 ms after breakdown. Peak electron number density of ∼2 × 10 17 cm −3 and electron temperature of ∼7 eV were measured. An excellent agreement between both techniques was obtained regarding absolute electron number densities. The inferred free-electron temporal decay dynamics are consistent with processes dominated by hydrodynamic expansion and two- and three-body electron–ion recombination. These results provide benchmark data for modeling nanosecond laser discharges and demonstrate the reliability of combining Thomson scattering with Stark broadening in atmospheric laser sparks.

Thomson scattering↗
DOE OSTI2024

Subsurface cosmogenic and radiogenic production of 42 Ar

Radioactive decays from 42 Ar and its progeny 42 K are potential background sources in large-scale liquid-argon-based neutrino and dark matter experiments. In the atmosphere, 42 Ar is produced primarily by cosmogenic activation on 40 Ar. The use of low radioactivity argon from cosmogenically shielded underground sources can expand the reach and sensitivity of liquid-argon-based rare event searches. We estimate 42 Ar production underground by nuclear reactions induced by natural radioactivity and cosmic-ray muon-induced interactions. At 3,000 mwe, 42 Ar production rate is 1.8×10 -3 atoms per ton of crust per year, 7 orders of magnitude smaller than the 39 Ar production rate at a similar depth in the crust. In conclusion, by comparing the calculated production rate of 42 Ar to that of 39 Ar for which the concentration has been measured in an underground gas sample, we estimate the activity of 42 Ar in gas extracted from 3,000 mwe depth to be less than two decays per ton of argon per year.

07 ISOTOPE AND RADIATION SOURCES↗
DOE OSTI2026

Dynamics of argon metastables in Ar–CH 4 radio frequency capacitively-coupled plasma: real-time monitoring with neural network-augmented broadband optical emission spectroscopy

In moderate-pressure radio frequency (RF) capacitively coupled plasmas generated in argon–methane mixtures, the density of argon metastable atoms (Ar 1 s 5 ) exhibits a non-monotonic dependence on methane (CH 4 ) concentration. Laser-induced fluorescence (LIF) was used to measure and compare local Ar 1 s 5 densities in Ar and Ar–CH 4 plasmas at 2.6 Torr and RF powers of 17–117 W. The addition of 1% CH 4 increases the metastable density, and 2% CH 4 triggers a strong depletion by an order of magnitude, compared to 1% CH 4 case. This non-monotonic behavior demonstrates the sensitivity of metastable populations to small gas admixtures, which is critical for processes where metastables drive precursor dissociation. For real-time monitoring of metastable population, broadband optical emission spectroscopy (OES) is augmented with a feedforward neural network (NN) to predict Ar s1 5 densities from spectral features. When trained on LIF data, the NN replicates the absolute densities and the dynamic trends of Ar 1 s 5 density variation. The NN-augmented broadband OES approach can be used as a simple and cost-effective tool for tracking Ar metastables in Ar-rich plasmas, facilitating industrial-scale optimization.

Yatom, Shurik [Princeton Plasma Physics Laboratory↗
DOE OSTI2025

Energy resolution and gain measurements in Argon-based gas mixtures: Exploring Ar:CF 4 for low energy measurements with TPCs

Time Projection Chambers (TPCs) are among the most advanced charged-particle detectors. Gas-filled TPCs have tracking capabilities that provide 3D-imaging of charged particles with a good energy resolution for spectroscopy. Different gas mixtures have different properties that determine the energy resolution as well as the spatial resolution. Therefore, optimization of operating conditions is required to simultaneously obtain adequate gain, energy resolution, spatial/track resolution, as well as higher drift velocities for high counting rates applications. Ar:CF 4 gas mixture has higher electron drift velocities and lower electron diffusion, which makes it an attractive candidate for TPC filling gas for low energy nuclear physics applications as compared to commonly used Ar:CH 4 and Ar:CO 2 gas mixtures, namely when tracking information is needed. However, other properties, including energy resolution and gain, remain largely unexplored in Ar:CF 4 especially at pressures and other operating conditions relevant for low-energy nuclear physics applications. Here, in this paper we report on gain and energy resolution measurements, using Gas Electron Multipliers (GEMs), in the less explored Ar:CF 4 mixture (Alfonsi et al., 2006), as well as in the more commonly used gas mixtures Ar:CH 4 and Ar:CO 2 . In addition to obtaining energy resolution and gain, we provide results from Garfield++ simulations for gain fluctuations, and their impact on energy resolution is discussed.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2025

High-Power Impulse Magnetron Sputter Deposition of Boron Carbide with Full-Face Erosion Magnetron and Mixed Ar-Ne Plasma

Boron carbide (B 4 C) is an attractive inertial confinement fusion ablator material. The fabrication of B4C ablators by magnetron sputtering requires process optimization. To increase process flexibility, here we explore high-power impulse magnetron sputter (HiPIMS) deposition of B 4 C in pure Ar and mixed Ar-Ne plasmas. Here, the results show that higher plasma discharge currents can be reached with a mixed Ar-Ne plasma in the entire working pressure range studied (5 𝑡𝑜 50 mTorr). At 45 mTorr with 10% of Ne in the Ar-Ne mix, high peak target current densities of ~1 A cm −2 were demonstrated. Films deposited with such a mixed Ar-Ne plasma with a full-face erosion magnetron source on substrates biased at −25 V exhibited higher density and improved mechanical properties, albeit with higher compressive residual stresses compared to the case of HiPIMS deposition in a pure Ar plasma. This work demonstrates additional process flexibility of the HiPIMS discharge mode for the deposition of B 4 C coatings.

Ablator capsule↗
DOE OSTI2026

Synthetic Atmospheric River Ensembles Generated by Deep-AR

This dataset contains 35,850 synthetic landfalling atmospheric river (AR) realizations generated by the Deep-AR two-stage deep-learning framework over the Northeast Pacific and U.S. West Coast. The archive contains 25 stochastic ensemble members for each of 1,434 held-out observed seed events. Each synthetic realization is initialized from conditions 48 hours before the corresponding observed AR landfall and is generated autoregressively at 6-hour intervals over a 144-hour period. Deep-AR combines a deterministic residual network (ResNet) that advances the large-scale atmospheric state with a Wasserstein generative adversarial network (WGAN) that produces stochastic, high-resolution fields. Each HDF5 file contains 0.25° gridded synthetic integrated vapor transport components (qu, qv), 10 m wind components (u10, v10), and 6-hour accumulated precipitation on a common 200 × 480 grid. The files also include coordinate and datetime arrays. This dataset supports AR hazard analysis, ensemble-based uncertainty characterization, precipitation-extremes research, and regional stress testing. Synthetic files follow the naming convention deepar.model.YYYYMMDD.HHMMSS.vNN.h5. YYYYMMDD.HHMMSS identifies the UTC initial-condition timestamp, which occurs 48 hours before the diagnosed observed landfall, and vNN identifies the zero-padded ensemble member, ranging from v01 through v25. Each synthetic file can be paired with its corresponding observed file by matching the initial-condition timestamp. The paired observed file follows the naming convention deepar.obs.YYYYMMDD.HHMMSS.h5 and is available in the separately registered oracle/deepar.obs dataset at https://wdh.energy.gov/ds/oracle/deepar.obs (DOI: https://doi.org/10.21947/3377671).

17 WIND ENERGY↗
DOE OSTI2025

Si–Cl 2 –Ar + Atomic Layer Etching Window: A Fundamental Study Using Molecular Dynamics Simulations and a Reduced Order Model

Silicon (Si) atomic layer etching (ALE) by alternating exposure to chlorine gas (Cl 2 ) and argon ions (Ar + ) is studied by using molecular dynamics (MD) simulations and a reduced order model (ROM). Here, the purpose of this study is to elucidate the properties of the ALE window, a range of ion energies where the amount of Si etched over a series of cycles is nonzero and nearly independent of ion energy. Experimental studies of the Si–Cl 2 –Ar + ALE system report contradictory results related to the ALE window’s ion energy range. Both MD simulations and the ROM show that there is an ALE window present from approximately 15 to 20 eV for normal incidence argon ions. The Si–Cl 2 –Ar + system, therefore, exhibits a narrow ALE window. The amount of Si etched per cycle is less than one atomic layer because of the higher etch yield of Cl atoms relative to atomic Si and silicon chlorides. A modified version of the ROM with an artificially increased Si physical sputtering threshold energy expands the ALE window, illustrating the importance of the difference in chemical and physical sputtering threshold energies in the ALE window energy range. The ROM is also used to examine the dependence of the EPC on the Ar + ion fluence.

energy↗
DOE OSTI2025

Calculation of ion–ion mutual neutralization rate constants using Landau–Zener theory coupled with trajectory simulations for Ar + –Cl − , Br − , I −

In this computational study, we self-consistently calculate the rate constants of mutual neutralization reactions by incorporating the electron transfer probability, using Landau–Zener state transition theory with inputs derived from ab initio quantum chemistry calculations, into classical trajectory simulations. Electronic structure calculations are done using correlation consistent basis sets with multi-reference configuration interaction to map all the molecular electronic states below the ion-dissociation limit as a function of the distance between the reacting species. Our electronic structure calculations have been significantly improved from our previous work through improved selection of molecular electronic configurations maintaining a fine grid of 1a 0 over a wide range of bond lengths and accurate treatment of spin–orbit couplings. Non-adiabatic coupling matrix elements are calculated with the three-point central difference method near each avoided crossing to estimate the exact crossing point R x and coupling parameter H if , which are inputs to the multi-channel Landau–Zener theory to calculate the electron transition probability. Our approach is applied to estimate the mutual neutralization rate constants for the following ion pairs: Ar + –Cl − , Ar + –Br − , Ar + –I − at ∼133 Pa. Furthermore, our predictions are compared against the experimental data reported. It is seen that the improvement in the electronic structure calculation results in excellent agreement between the simulation results and the available experimental data to within a factor of ∼2 or ∼±50%.

Complete-active space self-consistent field↗
DOE OSTI2026

$K^{*}(892)^0$ production and the time between freeze-outs in $^{40}$Ar+$^{45}$Sc collisions by NA61/SHINE at the CERN SPS

The analysis of the production of strange $K^{*}(892)^0$ resonances allows us to better understand the temporal evolution of high-energy nucleus--nucleus collisions. In particular, the ratio of $K^{*}(892)^0$ to charged kaon yields is used to determine the time interval between chemical and kinetic freeze-outs. In this paper, the first measurements of $K^{*}(892)^0$ production in central $^{40}$Ar+$^{45}$Sc collisions at the CERN Super Proton Synchrotron are reported. They were performed by NA61/SHINE at collision center-of-mass energies per nucleon pair $\sqrt{s_\mathrm{NN}}$ = 8.8, 11.9, 16.8 GeV. The obtained $\langle K^{*}(892)^0 \rangle/\langle K^{+} \rangle $ and $\langle K^{*}(892)^0 \rangle/\langle K^{-} \rangle$ mean multiplicity ratios are compared with corresponding results in $p$+$p$ collisions, allowing for an estimate of the time interval between chemical and thermal freeze-outs in the $^{40}$Ar+$^{45}$Sc system. These are the first such results reported for $^{40}$Ar+$^{45}$Sc collisions.

Adrich, P. [NCBJ, Warsaw] (ORCID:0000000270195451)↗
DOE OSTI2024

First application of a liquid argon time projection chamber for the search for intranuclear neutron-antineutron transitions and annihilation in 40 Ar using the MicroBooNE detector

We present a novel methodology to search for intranuclear neutron-antineutron transition (n→n̅) followed by n̅-nucleon annihilation within an 40 Ar nucleus, using the MicroBooNE liquid argon time projection chamber (LArTPC) detector. A discovery of n→n̅ transition or a new best limit on the lifetime of this process would either constitute physics beyond the Standard Model or greatly constrain theories of baryogenesis, respectively. The approach presented in this paper makes use of deep learning methods to select n→n̅ events based on their unique features and differentiate them from cosmogenic backgrounds. The achieved signal and background efficiencies are (70.22 ± 6.04)% and (0.0020 ± 0.0003)%, respectively. A demonstration of a search is performed with a data set corresponding to an exposure of 3.32 ×10 26 neutron-years, and where the background rate is constrained through direct measurement, assuming the presence of a negligible signal. With this approach, no excess of events over the background prediction is observed, setting a demonstrative lower bound on the n→n̅ lifetime in 40 Ar of τ m ≳ 1.1×10 26 years, and on the free n→n̅ transition time of τ n→n̅ ≳ 2.6×10 5 s, each at the 90% confidence level. This analysis represents a first-ever proof-of-principle demonstration of the ability to search for this rare process in LArTPCs with high efficiency and low background.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2026

Electron temperature relations and the direct N, O, Ne, S, and Ar abundances of 49 959 star-forming galaxies in DESI data release 2

We present the largest direct-method abundance catalogue of galaxies to date, containing measurements of 49 959 star-forming galaxies at z<0.96 from DESI (Dark Energy Spectroscopic Instrument) data release 2. By directly measuring electron temperatures across multiple ionization zones, we provide constraints on a number of electron temperature relations. Using the temperature measurements, we derive reliable abundances for N, O, Ne, S, and Ar, and measure the evolution of abundances and abundance ratios of as a function of metallicity and other galaxy properties. Our measurements include direct oxygen abundances for 49 507 galaxies, leading to the discovery of the two most metal-poor galaxies in the nearby Universe, with oxygen abundances of 12+log⁡(O/H)=6.77−0.03+0.03 dex (1.2 per cent Z⊙⁠) and 12+log⁡(O/H)=6.81−0.04+0.04 dex (1.3 per cent Z⊙⁠). We identify a rare outlier population of 24 galaxies with high-N/O ratios at low metallicity, reminiscent of galaxy abundances observed in the early Universe. We find the Ne/O ratio is constant at low metallicity but increases gradually at 12+log(O/H)>8.105±0.004 dex. We show that the S/O and Ar/O abundance ratios are strongly correlated, consistent with the expected additional Type Ia enrichment channel for S and Ar. In this work, we present an initial survey of the key properties of the sample, with this data set serving as a foundation for extensive future work on galaxy abundances at low redshift.

Scholte, D. [Edinburgh U., Inst. Astron.] (ORCID:0↗
DOE OSTI2025

Measurement of magnetic dipole strength in 40 Ar between 9.3 and 10.3 MeV excitation energy and impact on neutral current neutrino interaction

The magnetic dipole strength 𝐵⁡(𝑀⁢1 ↑) of 40 Ar was measured in the excitation energy range between 9.3 and 10.3 MeV. The nuclear resonance fluorescence technique was used with monoenergetic, linearly polarized incident photon beams. The new data increase the known 𝐵⁡(𝑀⁢1 ↑) strength in this important excitation energy range by a factor of 2, resulting in an equivalent increase of the calculated neutral current neutrino cross section of 40 Ar . This observation is of special interest for liquid-argon (LAr)-based neutrino detectors. 𝐵⁡(𝑀⁢1 ↑) strength has not been found between 10.3 and 11.7 MeV excitation energy. In conclusion, with the new data, a more reliable detection capability of the large Deep Underground Neutrino Experiment LAr detectors can be derived for potential core-collapse supernova neutrinos via the neutral current interaction.

Energy levels↗
DOE OSTI2024

Reactor wall effects in Si–Cl 2 –Ar atomic layer etching

This work complements our previous manuscript [J. Vac. Sci. Technol. A41, 062602 (2023)] where predictions from molecular dynamics (MD) simulations of silicon–chlorine–argon (Si–Cl 2 –Ar) atomic layer etching (ALE) are compared to experiments. When etch product distributions for atomic chlorine (Cl) and silicon chlorides were initially compared to optical emission spectroscopy (OES) signals, it appeared that there was a discrepancy between the MD predictions and experimental results at higher ion fluences. Experiments showed a relatively long period of nearly constant Cl-containing etch products released from the ion-bombarded surface (referred to as the “plateau”) but this effect was not observed in MD simulations. In this report, we demonstrate that the “plateau” observed in the OES signals is most likely due to the desorption of Cl-containing etch products from the walls of the reactor and subsequent adsorption on the Si substrate. Experiments varying the gas residence time in the chamber while keeping incoming gas concentrations and pressure constant support this interpretation. We also conducted experiments with an additional Ar-only flow in the chamber to reduce the concentration of Cl-containing species on the chamber walls. For both sets of flow modification experiments, we observe results consistent with the hypothesis that Cl-containing species desorbing from chamber walls are a significant cause of the observed discrepancy between MD predictions and experimental observations. If the measured OES signals are corrected for this “additional” source of Cl-containing species at the surface, the MD predictions and measured OES signals are in excellent agreement. This further supports the predictive capability of MD simulations to accurately capture the relevant physical and chemical processes in plasma-assisted ALE processes. We provide an order of magnitude estimate of the required density of Cl-containing species that would account for the additional etch products observed. Finally, we discuss the implications of this effect on ALE in plasma nanofabrication.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗