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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Intrinsic anisotropy versus effective pinning anisotropy in YBa 2 Cu 3 O 7 thin films and nanocomposites

The intrinsic and effective anisotropies, both in the liquid and solid vortex regimes, of YBa 2 Cu 3 O 7 (YBCO) pristine and nanocomposite thin films have been investigated in this paper. Angular resistivity measurements under varying fields and temperatures were performed to characterize the intrinsic vs effective anisotropy of samples in the regime of long-range vortex displacements. The effective anisotropy γ eff was determined from the scaling of the irreversibility line, applying the Blatter approach developed for uniaxial anisotropic superconductors. Resistive measurements in flux flow were utilized, in addition to H c2 measurements in ultrahigh-fields, to determine the intrinsic anisotropy mass γ , enabling the study of a large number of samples with varied nanoparticle compositions. In order to access the intrinsic anisotropy in the vortex solid phase, complex impedance measurements at high microwave frequencies were performed, allowing us to access the flux-flow intrinsic anisotropy in the regime of very short vortex oscillations within the pinning potential wells. Results show that while the effective anisotropy γ eff decays as the nanoparticles-induced nanostrain in the YBCO films increases, the intrinsic anisotropy γ (determined both in dc and at microwave frequency) remains unaltered.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Effective anisotropy due to the surface of magnetic nanoparticles

Analytical solution has been discovered for the second-order effective anisotropy of magnetic nanoparticles of a cubic shape due to the surface anisotropy (SA) of the Néel type. Similarly to the spherical particles, for the simple cubic lattice the grand-diagonal directions (±1,±1,±1) are favored by the effective cubic anisotropy but the effect is twice as strong. Uniaxial core anisotropy and applied magnetic field cause screening of perturbations from the surface at the distance of the domain-wall width and reduce the effect of SA near the energy minima. Yet, screening disappears near the uniaxial energy barrier, and the uniform barrier state of larger particles may become unstable. For these effects the analytical solution is obtained as well, and the limits of the additive formula with the uniaxial and effective cubic anisotropies for the particle are established. Thermally-activated magnetization-switching rates have been computed by the pulse-noise technique for the stochastic Landau-Lifshitz equation for a system of spins.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Tuning Noncollinear Spin Structure and Anisotropy in Ferromagnetic Nitride MXenes

Recent experimental success in the realization of two-dimensional magnetism has invigorated the search for low-dimensional material systems with tunable magnetic anisotropy that exhibit intrinsic long-range ferromagnetic order. Here in this paper, we report that modifying the surface termination and transition metal in monolayer M 2 NT x nitride MXenes gives rise to a rich diversity of noncollinear spin structures and finely tunable magnetocrystalline anisotropy. Based on first-principles simulations, we predict that manipulating the strength of the spin–orbit interaction and electron localization via the chemical degrees of freedom can induce sufficient anisotropy to counteract thermal fluctuations that suppress long-range magnetic order. We find that Ti 2 NO 2 and Mn 2 NF 2 MXenes have continuous O(3) and O(2) spin symmetries, respectively, that may be broken by an applied field, while Cr 2 NO 2 and Mn 2 NO 2 are intrinsic Ising ferromagnets with out-of-plane easy axes and magnetic anisotropy energies up to 63 μeV/atom. These systems also exhibit both gapped and gapless Dirac points near the Fermi level. Our study suggests that nitride MXenes offer a promising avenue for achieving both practical spintronic devices and investigating fundamental spin processes in two-dimensional materials.

2D materials↗
DOE OSTI2023

An Efficient High-Order Solver for Diffusion Equations with Strong Anisotropy on Non-Anisotropy-Aligned Meshes

This paper concerns numerical solution of the diffusion equation with strong anisotropy on meshes not aligned with the anisotropic vector field. In order to resolve the numerical pollution for simulations on a non-anisotropy-aligned mesh and reduce the associated high computational cost we propose an effective preconditioner, extending our previous work. Similar to the anisotropy-aligned mesh case, we apply the auxiliary space preconditioning framework to design a preconditioner where a continuous finite element space is used as the auxiliary space for the discontinuous finite element space. The key component is an effective line smoother that can mitigate the high-frequency errors perpendicular to the magnetic field. We design a graph-based approach to find such a line smoother that is approximately perpendicular to the vector fields when the mesh does not align with the anisotropy. Finally, numerical experiments for several benchmark problems are presented, demonstrating the effectiveness and robustness of the proposed preconditioner when applied to Krylov iterative methods.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2019

Surface-Engineered MXenes: Electric Field Control of Magnetism and Enhanced Magnetic Anisotropy

Controlling magnetism in two-dimensional (2D) materials via electric fields and doping enables robust long-range order by providing an external mechanism to modulate magnetic exchange interactions and anisotropy. Here in this report, we predict that transition metal carbide and nitride MXenes are promising candidates for controllable magnetic 2D materials. The surface terminations introduced during synthesis act as chemical dopants that influence the electronic structure, enabling controllable magnetic order. We show ground-state magnetic ordering in Janus M 2 XO x F 2–x (M is an early transition metal, X is carbon or nitrogen, and x = 0.5, 1, or 1.5) with asymmetric surface functionalization, where local structural and chemical disorder induces magnetic ordering in some systems that are nonmagnetic or weakly magnetic in their pristine form. The resulting magnetic states of these noncentrosymmetric structures can be robustly switched and stabilized by tuning the interlayer exchange couplings with small applied electric fields. Furthermore, bond directionality is enhanced by Janus functionalization, resulting in improved magnetic anisotropy, which is essential to stable 2D magnetic ordering. The mixed termination-induced anisotropy leads to robust Ising ferromagnetism with an out-of-plane easy axis over the full range of relevant termination compositions for Janus Mn 2 N. Janus Cr 2 C, V 2 C, and Ti 2 C were found to be robustly antiferromagnetic. Our results provide a strategy for exploiting asymmetric surface functionalization to achieve room-temperature nanoscale magnetism under ambient conditions in MXenes with currently available synthesis techniques.

2D materials↗
DOE OSTI2023

T 1 Anisotropy Elucidates Spin Relaxation Mechanisms in an S = 1 Cr(IV) Optically Addressable Molecular Qubit

Paramagnetic molecules offer unique advantages for quantum information science owing to their spatial compactness, synthetic tunability, room-temperature quantum coherence, and potential for optical state initialization and readout. However, current optically addressable molecular qubits are hampered by rapid spin–lattice relaxation ( T 1 ) even at sub-liquid nitrogen temperatures. Here, we use temperature- and orientation-dependent pulsed electron paramagnetic resonance (EPR) to elucidate the negative sign of the ground state zero-field splitting (ZFS) and assign T 1 anisotropy to specific types of motion in an optically addressable S = 1 Cr(o-tolyl) 4 molecular qubit. The anisotropy displays a distinct sin 2 (2θ) functional form that is not observed in S = 1/2 Cu(acac) 2 or other Cu(II)/V(IV) microwave addressable molecular qubits. The Cr(o-tolyl) 4 T 1 anisotropy is ascribed to couplings between electron spins and rotational motion in low-energy acoustic or pseudoacoustic phonons. Our findings suggest that rotational degrees of freedom should be suppressed to maximize the coherence temperature of optically addressable qubits.

magnetic properties↗
NASA NTRS2009

Microstructural, Magnetic Anisotropy, and Magnetic Domain Structure Correlations in Epitaxial FePd Thin Films with Perpendicular Magnetic Anisotropy

L1(sub 0)-ordered FePd epitaxial thin films were prepared using dc magnetron sputter deposition on MgO (001) substrates. The films were grown with varying thickness and degree of chemical order to investigate the interplay between the microstructure, magnetic anisotropy, and magnetic domain structure. The experimentally measured domain size/period and magnetic anisotropy in this high perpendicular anisotropy system were found to be correlated following the analytical energy model proposed by Kooy and Enz that considers a delicate balance between the domain wall energy and the demagnetizing stray field energy.

Skuza, J. R.↗
DOE OSTI2024

Temperature-Dependent Mechanical Anisotropy in Textured Zircaloy Cladding

This work evaluates deformation activity in textured zircaloy-4 cladding with the aim of elucidating the mechanisms that govern mechanical behavior across a temperature range anticipated in reactor service. In particular, the dependence of mechanical anisotropy on temperature and stress state (ratio of applied stresses) is examined via uniaxial and biaxial tensile experiments at room temperature and 400 °C. The mechanical behavior was interpreted based on micro-texture and dominant slip system activity. Thermal activation of basal systems is found as a key mechanism affecting mechanical behavior across the temperature range. The biaxial stress states produce resolved shear stresses contrasting to uniaxial stress states. As a result, mechanical testing and implications for reactor pellet-cladding mechanical interaction stress conditions are discussed.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2018

Time for anisotropy: The significance of mechanical anisotropy for the development of deformation structures

The forty-year history of the Journal of Structural Geology has recorded an enormous increase in the description, interpretation and modelling of deformation structures. Amongst factors that control deformation and the resulting structures, mechanical anisotropy has proven difficult to tackle. Using a Fast Fourier Transform-based numerical solver for viscoplastic deformation of crystalline materials, we illustrate in this paper how mechanical anisotropy has a profound effect on developing structures, such as crenulation cleavages, porphyroclast geometry and the initiation of shear bands and shear zones.

58 GEOSCIENCES↗
DOE OSTI2018

Measurement of the azimuthal anisotropy of charged particles produced in $\sqrt{s_{_\text {NN}}}$ = 5.02 TeV Pb+Pb collisions with the ATLAS detector

Measurements of the azimuthal anisotropy in lead–lead collisions at $\sqrt{s_{_\text {NN}}}$ = 5.02 TeV are presented using a data sample corresponding to 0.49 nb -1 integrated luminosity collected by the ATLAS experiment at the LHC in 2015. The recorded minimum-bias sample is enhanced by triggers for “ultra-central” collisions, providing an opportunity to perform detailed study of flow harmonics in the regime where the initial state is dominated by fluctuations. The anisotropy of the charged-particle azimuthal angle distributions is characterized by the Fourier coefficients, v 2 - v 7 , which are measured using the two-particle correlation, scalar-product and event-plane methods. The goal of the paper is to provide measurements of the differential as well as integrated flow harmonics v n over wide ranges of the transverse momentum, 0.5 < p T < 60 GeV, the pseudorapidity, |η|< 2.5, and the collision centrality 0–80%. Results from different methods are compared and discussed in the context of previous and recent measurements in Pb+Pb collisions at $\sqrt{s_{_\text {NN}}}$ = 2.76 TeV and 5.02 TeV . In particular, the shape of the p T dependence of elliptic or triangular flow harmonics is observed to be very similar at different centralities after scaling the v n and p T values by constant factors over the centrality interval 0–60% and the p T range 0.5 < p T < 5 GeV.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS1991

A millimeter-wave anisotropy experiment (MAX) to search for anisotropy in the cosmic background radiation on medium angular scales

We report preliminary results from two balloon flights of a millimeter-wave telescope designed to measure anisotropy in the cosmic microwave background (CMB) on angular scales from 0.3 to 3 degrees. The receiver used in the first flight, in November 1989, was a dichroic, He-3-cooled bolometric photometer with passbands centered at 3, 6, 9, and 12/cm. The second flight, in July 1990, employed improved bolometric detectors. The 3/cm band was removed in order to increase the efficiency of the remaining bands. Preliminary analysis of the data gives a factor of 3 improvement in sensitivity over the first flight in the 6/cm band. Future plans include a new receiver to provide an additional factor of 5 improvement in sensitivity and a new balloon-borne telescope which is optimized for low-background bolometric detectors at millimeter wavelengths.

Fischer, M. L.↗