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At least 19 records

Analysis and Recommendation of Tritium Gas Continuous Air Monitor Alarm Setpoints for the RPL Stack Exhaust

The Radiochemical Processing Laboratory (RPL) tritium continuous air monitor (CAM) is used for near real-time detection of tritium gas (i.e., elemental tritium [HT] and tritiated water vapor [HTO]) in the stack exhaust. The CAM interfaces with software developed by the Pacific Northwest National Laboratory (PNNL)—called the “PNNL OS3700 Tritium Monitoring Software”—that provides near real-time estimates of tritium gas air concentrations and integrated daily activities that are calculated from measured CAM counts. The OS3700 software implements alarm setpoints to alert the facility of larger tritium gas releases that if allowed to persist, could begin to challenge permitted emission and established dose constraints. This report performs a detailed review of historical and current tritium alarm setpoints used at RPL, including discussion of the technical basis used in their development, analysis of alarm frequencies using measured historical data, and performs a detailed dose assessment using more realistic release scenarios and meteorology. Based on the results, the tritium air concentration and integrated daily tritium activity alarm setpoints will remain 2.0 × 10 -5 µCi/ml and 25 Ci/day, respectively. These setpoints achieve the right operational balance in identifying larger releases from planned tritium work at RPL, without being overly conservative so as to cause nuisance alarming. Furthermore, implied doses associated with these setpoints are well below defined and regulatory limits.

325RPL↗

Analysis and Recommendation of Alpha-Beta Continuous Air Monitor Alarm Setpoints for the RPL Stack Exhaust

The Radiochemical Processing Laboratory (RPL) alpha-beta continuous air monitor (CAM) is used for real-time detection of “artificial” alpha-beta particulates from the stack exhaust. The CAM interfaces with software developed by the Pacific Northwest National Laboratory—called the “PNNL OS3300 Alpha-Beta Monitoring Software”—that provides real-time estimates of alpha-beta air concentrations and integrated activities that are calculated from measured CAM counts. The OS3300 software has alarm setpoints that can be used to provide an early indication of larger releases, that if allowed to persist, could approach defined dose limits. This report performs a detailed review of historical and current alarm setpoints used at RPL, including discussion of the technical basis used in their development, analysis of alarm frequencies using measured historical data, and performs a detailed dose assessment using more realistic release scenarios, meteorology, and adjustment factors used in estimating released stack activity. Based on the results, the alpha and beta air concentration alarm setpoints will remain 1.77 × 10 -8 µCi/ml and 3.47 × 10 -8 µCi/ml, respectively; and the alpha and beta integrated activity alarm setpoints will remain 70.22 µCi and 137.63 µCi, respectively. These setpoints achieve the right operational balance in identifying larger releases from planned radiological work at RPL, without being overly conservative so as to cause nuisance alarming. Furthermore, implied doses associated with these setpoints are below defined and regulatory limits.

325RPL↗

Argonne News Brief: First Sensors for Chicago’s “City Fitness Tracker”

This week in Chicago, the Array of Things team installed its first 50 nodes on city streets to kick off the groundbreaking urban sensing project. Array of Things is designed as a “fitness tracker” for the city, collecting new streams of data on Chicago’s environment, infrastructure, and activity. This hyper-local, open data can help researchers, city officials, and software developers study and address critical city challenges, such as preventing urban flooding, improving traffic safety and air quality, and assessing the nature and impact of climate change.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

R&D to Market Success: BTO-Supported Technologies Commercialized from 2010-2015

Technology commercialization plays an essential role in almost every facet of the U.S. economy. It spurs private sector funding that supports innovative breakthroughs, drives growth through increased productivity and product development, increases American competitiveness, and creates domestic jobs. The BTO Technology Commercialization report is an annual publication offering the latest information on successfully commercialized technologies resulting in part from BTO’s research partnerships. This report defines a “commercialized technology” as a process, technique, design, machine, tool, material, or software that was developed with funds provided at least in part by BTO, and that has resulted in domestic sales or is in use in the U.S. This definition also applies to open-source software products developed with support from BTO, all of which are currently distributed freely but are actively used for commercial purposes.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Open-air Demolition: Validation of EPA Approved Alternative Method for Emission Estimation - 19397

Emissions from open-air demolition of US Department of Energy (DOE) facilities are regulated by the US Environmental Protection Agency (EPA) under 40 CFR 61 subpart H. This regulation requires that facilities estimate emissions using an EPA approved method from activities such as open-air demolition prior to commencing the activity. Should those emissions exceed certain thresholds, the facility may be required to obtain an Approval to Construct or Modify the facility and/or installed monitoring methods meeting methods acceptable to EPA. There are no EPA approved methods that are specific to open-air demolition methods. For this project the DOE and CH2M Hill BWXT elected to prepare an alternative method specific to open-air demolition. EPA conditionally approved the method but required validation of the method during the demolition of the Vitrification Facility at the West Valley Demonstration Project (WVDP) before use for open-air demolition at other WVDP structures. The validation method included detailed source characterization, close-in ambient samplers, and a comparison of measured results to predicted emissions using AERMOD (American Meteorological Society (AMS) and U.S. Environmental Protection Agency (EPA) Regulatory Model). The methods evaluated include hydraulic hammers, mechanical shears, load out of waste and handling of the debris piles. The validation method involved the collection and analysis of ambient air samples from air samplers located at strategic locations within the projected plume path of the demolition activities. The analytical results from the air samplers were then compared to ambient air concentrations predicted at the sampler locations with the EPA model AERMOD. The input to the AERMOD software is a source term developed weekly using the alternative method and material at risk disturbed during each week. To account for the building wake effects of the surrounding structures, virtual point sources were developed in the AERMOD model and placed at the locations of the demolition, debris piles, debris handling and load out areas. It was found that the factors used for hydraulic hammering were extremely conservative and that emissions from the debris pile were not only the primary emission source, but that the moisture content of the debris pile and the wind speed were critical factors that must be considered in future open-air demolition projects. Based on the results of the validation process, adjustments were made to the alternative method. The final validated alternative method provides an approach for estimating airborne emissions from open-air demolition methods and techniques. The method will be used in lieu of 40 CFR 61 Appendix D to estimate emissions from future open-air demolition projects at the WVDP. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Heat pump concepts for nZEB Technology developments, design tools and testing of heat pump systems for nZEB in the USA: Country report IEA HPT Annex 40 Task 2, Task 3 and Task 4 of the USA

The IEA HPT Annex 40 "Heat pump concepts for Nearly Zero Energy Buildings" deals with the application of heat pumps as a core component of the HVAC system for Nearly or Net Zero energy buildings (nZEB). This report covers Task 2 on the system comparison and optimisation and Task 3 dedicated to the development of adapted technologies for nZEB and field monitoring results of heat pump systems in nZEB. In the US team three institutions are involved and have worked on the following projects: The Oak Ridge National Laboratory (ORNL) will summarize development activities through the field demonstration stage for several integrated heat pump (IHP) systems electric ground-source (GS-IHP) and air-source (AS-IHP) versions and an engine driven AS-IHP version. The first commercial GS-IHP product was just introduced to the market in December 2012. This work is a contribution to Task 3 of the Annex. The University of Maryland will contribute a software development project to Task 2 of the Annex. The software ThermCom evaluates occupied space thermal comfort conditions accounting for all radiative and convective heat transfer effects as well as local air properties. The National Institute of Standards and Technology (NIST) is working on a field study effort on the NIST Net Zero Energy Residential Test Facility (NZERTF). This residential building was constructed on the NIST campus and officially opened in summer 2013. During the first year, between July 2013 and June 2014, baseline performance of the NZERTF was monitored under a simulated occupancy protocol. The house was equipped with an air-to-air heat pump which included a dedicated dehumidification operating mode. Outdoor conditions, internal loads and modes of heat pump operation were monitored. Field study results with respect to heat pump operation will be reported and recommendations on heat pump optimization for a net zero energy building will be provided. This work is a contribution to Task 3 of the Annex.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Nuclear waste calorimeter for very large drums with 385 litres sample volume

Calorimetry is a very precise and well adapted tool for the classification of drums containing nuclear waste material depending on their level of activities (low, medium, high). A new calorimeter has been developed by SETARAM Instrumentation and the CEA Valduc in France. This new calorimeter is designed for drums having a volume bigger than 100 liters. It guarantees high operator safety by optimizing drum handling and air circulation for cooling, and optimized software for direct measurement of the quantity of nuclear material. The LVC1380 calorimeter makes it possible to work over the range 10 to 3000 mW, which corresponds to approximately 0.03 to 10 g of tritium or 3 to 955 g of {sup 241}Pu in a volume up to 385 liters. This calorimeter is based on the heat flow measurement using Peltier elements which surround the drum in the 3 dimensions and therefore measure all the heat coming from the radioactive stuff whatever its position inside the drum. Calorimeter's insulating layers constitute a thermal barrier designed to filter disturbances until they represent less than 0.001 Celsius degrees and to eliminate long term disturbances associated, for example, with laboratory temperature variations between day and night. A calibration device based on Joule effect has also been designed. Measurement time has been optimized but remains long compared with other methods of measurement such as gamma spectrometry but its main asset is to have a good accuracy for low level activities.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Voltron Compatible Whole Building Root-Fault Detection and Diagnosis

Buildings consume more than 40% of primary energy in the U.S. Malfunctioning sensors, components, and control systems, as well as degrading components in Heating, Ventilating and Air-conditioning (HVAC) and lighting systems are main reasons for energy waste and unsatisfactory indoor environment. Field studies have shown that an energy saving of 5-30% of total building energy consumption and improved indoor air quality can be achieved by simply applying automated fault detection and diagnosis (AFDD), followed by corrections even if these are not done in real time. Extensive research has been made on the development of component level AFDD tools in the past two decades. However, in recent years, the development of method for a whole building level AFDD has received much attention. Here, a whole building fault refers to a fault happening in one subsystem but impact on more than one subsystems, or has a significant impact on building performances, such as building’s energy consumption. Existing component level AFDD tools could fail to detect or give false alarm for faults that trigger abnormalities in multiple subsystems. Isolating such whole building faults, which have impacts on multiple subsystems, is also challenging by simply using component based AFDD solutions. On the other hand, it might be more cost-effective for medium- or small-sized commercial buildings that have subsystems (e.g. primary cooling subsystem, air loop subsystem, heating subsystem, lighting subsystem, etc.) to install one whole building level AFDD tool, rather than many component level AFDD tools, to focus on significant faults. The focus of this project is firstly to provide training opportunities in building AFDD research area for undergraduate students and to develop a workforce pipeline in building sciences. The objective of the proposed research activities is to develop cost-effective and scalable AFDD solutions for whole building level faults. The developed AFDD solution is VOLTTRONTM compatible to further increase its plug-n-play capacity and the market penetration. VOLTTRONTM is an open-source innovative distributed control and sensing software platform developed by the Pacific Northwest National Laboratory. A VOLTTRONTM compatible AFDD tool brings the benefits such as low-cost deployment, and better building to grid integration, etc. The performance of the developed whole building AFDD tools is evaluated using data collected from a mixed-use medium-sized university campus building. Another significant goal of this project is to engage undergraduate students in research activities and expose them to building control and AFDD fields. A demonstration building – Nesbitt Hall at Drexel University is identified for this study. This demonstration building has a typical HVAC system configuration, which includes a water-cooled chiller system, three variable air volume (VAV) air handling unit (AHU) systems, and a hydronic heating system. Faults, that are expected to have a whole building level impact, are artificially implemented in this demonstration building for three different seasons. Building data have been collected in this project, which include fault free building automation system (BAS) data and BAS data that contain system behaviors caused by artificially implemented and naturally occurred faults. These collected data are used to evaluate the developed whole building AFDD tools. A data-driven method, which includes a weather and schedule-based pattern matching (WPM) method and Feature based Principal Component Analysis (FPCA) method, is developed for whole building level fault detection. Parameter sensitivity tests, including snapshot window size, data sample searching pool size, etc., are implemented to evaluate the impacts of various WPM-FPCA parameters. A data-driven and expert knowledge/rule-based method using Bayesian Network (BN) and WPM is developed for whole building level fault diagnosis. The developed WPM-BN method, which includes a two-layer BN structure model and BN parameters, are either learned from baseline data or developed from expert knowledge. The developed whole building AFDD tools are evaluated using BAS data collected from the demonstration building. Using the evaluation data set, the WPM-FPCA fault detection method is evaluated under two different Principle Component (PC) retention rates, i.e., 0.65 retention rate and 0.95 retention rate. It is observed that when using 0.65 PC retention rate, the WPM-FPCA fault detection method achieves a 79% fault detection rate (this rate reaches to 85% when including the six make-up fault test cases discussed in the next bullet), while when using 0.95 PC retention rate, the WPM-FPCA fault detection method achieves 100% fault detection rate (this rate remains to be 100% when including the six make-up fault test cases). Under both PC retention rates, the WPM-FPCA fault detection method demonstrates 0% false alarm rates. Using the evaluation data set, the developed WPM-BN fault diagnosis method has successfully diagnosed thirteen (13) faults out of the fourteen (14) fault test cases. The one mis-diagnosed case exhibits fewer fault symptoms in different subsystems, when compared with other fault test cases. Overall speaking, the developed whole building AFDD solutions demonstrate satisfactory fault detection/diagnosis accuracy with very low false alarm rate. Lastly, a survey and market study has been performed to understand the existing AFDD market, including its gaps and needs.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Prediction of Performance of a Pilot-Scale Dual Fluidized Bed System for Chemical Looping with Oxygen Uncoupling

Chemical looping with oxygen uncoupling (CLOU) is a variant of chemical looping combustion that involves spontaneous release of gaseous oxygen in the fuel reactor, which enables efficient combustion of solid fuel char. The University of Utah has constructed a 200 kW pilot-scale chemical looping process development unit (PDU) consisting of two fluidized beds. The CLOU oxygen carrier uses copper as the active metal, cycling between cupric (CuO) and cuprous (Cu2O) oxides. As an aid for design, troubleshooting and evaluation of the pilot system, a CFD model has been developed using CPFD Software’s Barracuda VR software. The 3D model includes both reactors, as well as loop seals and cyclone separators. Mechanisms describing CLOU reaction kinetics for cuprous oxide oxidation in the air reactor and cupric oxide reduction in the fuel reactor were adapted from previously reported experimental work. Coal char kinetics were based on the carbon-hydrogen-nitrogen-oxygen-sulfur, CHNOS, method. Submodels for devolatilization, gasification, and homogenous gas-phase reactions used preexisting relationships in the literature. Three different simulations were performed, analyzing the influence of particle properties (a base carrier and an alternate carrier referred to as cariact) and coal feeding rate (100kW, 200kW). Increased coal feeding rate caused significant increase in cuprious oxide oxidation in the air reactor as well as higher temperature. The alternate carrier predicted CO2 capture below 90%, in contrast to the other cases.

Reinking, Zachary↗

Prediction of Performance of a Pilot Scale Dual Fluidized Bed System for Chemical Looping with Oxygen Uncoupling

Chemical looping with oxygen uncoupling (CLOU) is a variant of chemical looping combustion that involves spontaneous release of gaseous oxygen in the fuel reactor, which enables efficient combustion of solid fuel char. The University of Utah has constructed a pilot-scale dual fluidized bed chemical looping process development unit (PDU) with a nominal thermal input of 200 kW. The CLOU oxygen carrier uses copper as the active metal, cycling between cupric (CuO) and cuprous (Cu2O) oxides. As an aid for design, troubleshooting and evaluation of the pilot system, a CFD model has been developed using CPFD Software’s Barracuda VR software. The 3D model includes both reactors, as well as loop seals and cyclone separators. Mechanisms describing CLOU reaction kinetics for cuprous oxide oxidation in the air reactor and cupric oxide reduction in the fuel reactor were adapted from previously done experimental work. Coal char kinetics were based on the carbon-hydrogen-nitrogen-oxygen-sulfur, CHNOS, method. Submodels for devolatilization, gasification, and homogenous gas-phase reactions used preexisting relationships in the literature. Results predict temperature profiles, concentration profiles, product gas composition, and CO¬2 capture efficiency. This paper presents results of a parametric study in which key operational variables were adjusted to determine the influence on simulated performance of the PDU. The adjusted variables include fuel feed rate, fuel particle size, total oxygen carrier inventory, oxygen carrier copper oxide loading, and oxygen carrier particle physical properties.

Reinking, Zachary↗

Climate data, analysis and models for the study of natural variability and anthropogenic change

Gridded Temperature Under prior/current support, we completed and published (Jones et al., 2012) the fourth major update to our global land dataset of near-surface air temperatures, CRUTEM4. This is one of the most widely used records of the climate system, having been updated, maintained and further developed with DoE support since the 1980s. We have continued to update the CRUTEM4 (Jones et al., 2012) database that is combined with marine data to produce HadCRUT4 (Morice et al., 2012). The emphasis in our use of station temperature data is to access as many land series that have been homogenized by National Meteorological Services (NMSs, including NCDC/NOAA, Asheville, NC). Unlike the three US groups monitoring surface temperatures in a similar way, we do not infill areas that have no or missing data. We can only infill such regions in CRUTEM4 by accessing more station temperature series. During early 2014, we have begun the extensive task of updating as many of these series as possible using data provided by some NMSs and also through a number of research projects and programs around the world. All the station data used in CRUTEM4 have been available since 2009, but in Osborn and Jones (2014) we have made this more usable using a Google Earth interface (http://www.cru.uea.ac.uk/cru/data/crutem/ge/ ). We have recently completed the update of our infilled land multi-variable dataset (CRU TS 3.10, Harris et al., 2014). This additionally produces complete land fields (except for the Antarctic) for temperature, precipitation, diurnal temperature range, vapour pressure and sunshine/cloud. Using this dataset we have calculated sc-PDSI (self-calibrating Palmer Drought Severity Index) data and compared with other PDSI datasets (Trenberth et al., 2014). Also using CRU TS 3.10 and Reanalysis datasets, we showed no overall increase in global temperature variability despite changing regional patterns (Huntingford et al., 2013). Harris et al. (2014) is an update of an earlier dataset (Mitchell and Jones, 2005) which also had earlier DoE support. The earlier dataset has been cited over 1700 times according to ResearcherID on 31/July/2014 and the recent paper has already been cited 22 times. Analyses of Temperature Data Using the ERA-Interim estimate of the absolute surface air temperature of the Earth (instead of in the more normal form of anomalies) we compared the result against estimates we produced in 1999 with earlier DoE support. The two estimates are surprisingly close (differing by a couple of tenths of a degree Celsius), with the average temperature of the world (for 1981-2010) being very close to 14°C (Jones and Harpham, 2013). We have assessed ERA-Interim against station temperatures from manned and automatic weather station measurements across the Antarctic (Jones and Lister, 2014). Agreement is generally excellent across the Antarctic Peninsula and the sparsely sampled western parts of Antarctica. Differences tend to occur over eastern Antarctica where ERA-Interim is biased warm (up to 6°C) in the interior of the continent and biased cool (up to 6°C) for some of the coastal locations. Opportunities presented themselves during 2012 for collaborative work with a couple of Chinese groups. Three papers develop new temperature series for China as a whole and also for the eastern third of China (Wang et al., 2014, Cao et al., 2013 and Zhao et al., 2014). A dataset of ~400 daily Chinese temperature stations has been added to the CRU datasets. The latter paper finds that urban effects are generally about 10% of the long-term warming trend across eastern China. A fourth paper (Wang et al., 2013) illustrates issues with comparisons between reanalyses and surface temperatures across China, a method that has been widely used by some to suggest urban heating effects are much larger in the region. ERA-Interim can be used but NCEP/NCAR comparisons are very dependent on the period analysed. Earlier a new temperature dataset of homogenized records was developed for China (Li et al., 2009). Urbanization has also been addressed for London (Jones and Lister, 2009) where two rural sites have not warmed more than a city centre site since 1900. Additionally, in Ethymiadis and Jones (2010) we show that land air temperatures agree with marine data around coastal areas, further illustrating that urbanization is not a major component of large-scale surface air temperature change. Early instrumental data (before the development of modern thermometer screens) have always been suspected of being biased warm in summer, due to possible direct exposure to the sun. Two studies (Böhm et al., 2010 and Brunet et al., 2010) show this for the Greater Alpine Region (GAR) and for mainland Spain respectively. The issue is important before about 1870 in the GAR and before about 1900 in Spain. After correction for the problems, summer temperature estimates before these dates are cooler by about 0.4°C. In Jones and Wigley (2010), we discussed the importance of the biases in global temperature estimation. Exposure and to a lesser extent urbanization are the most important biases for the land areas, but both are dwarfed by the necessary adjustments for bucket SST measurements before about 1950. Individual station homogeneity is only important at the local scale. This was additionally illustrated by Hawkins and Jones (2013) where we replicated the temperature record developed by Guy Stewart Callendar in papers in 1938 and 1961. Analyses of Daily Climate Data Work here indicates that ERA-Interim (at least in Europe, Cornes and Jones, 2013, discussed in more detail in this proposal) can be used to monitor extremes (using the ETCCDI software – see Zhang et al., 2011). Additionally, also as a result of Chinese collaboration, a new method of daily temperature homogenization has been developed (Li et al., 2014). In Cornes and Jones (2011) we assessed storm activity in the northeast Atlantic region using daily gridded data. Even though the grid resolution is coarse (5° by 5° lat/long) the changes in storm activity are similar to those developed from the pressure triangle approach with station data. Analyses of humidity and pressure data In Simmons et al. (2010) we showed a reduction in relative humidity over low-latitude and mid-latitude land areas for the 10 years to 2008, based on monthly anomalies of surface air temperature and humidity from ECMWF reanalyses (ERA-40 and ERA-Interim) and our earlier land-only dataset (CRUTEM3) and synoptic humidity observations (HadCRUH). Updates of this station-based humidity dataset (now called HadISDH) extend the record, showing continued reductions (Willett et al., 2013). Analyses of Proxy Temperature Data In Vinther et al. (2010), relationships between the seasonal stable isotope data from Greenland Ice Cores and Greenland and Icelandic instrumental temperatures were investigated for the past 150-200 years. The winter season stable isotope data are found to be influenced by the North Atlantic Oscillation (NAO) and very closely related to SW Greenland temperatures. The summer season stable isotope data display higher correlations with Icelandic summer temperatures and North Atlantic SST conditions than with local SW Greenland temperatures. In Jones et al. (2014) we use these winter isotope reconstructions to show the expected inverse correlation (due to the NAO) with winter-season documentary reconstructions from the Netherlands and Sweden over the last 800 years. Finally, in this section Jones et al. (2013) shows the agreement between tree-ring width measurements from Northern Sweden and Finland and an assessment of the link to explosive volcanic eruptions. An instrumental record for the region in the early 19th century indicates that the summer of 1816 was only slightly below normal, explaining why this year has normal growth for both ring width and density. GCM/RCM/Reanalysis Evaluation In this section we have intercompared daily temperature extremes across Europe in Cornes and Jones (2013) using station data, E-OBS and ERA-Interim. We have additionally considered the impact of the urban issue on the global scale using the results of the Compo et al. (2011) Reanalyses, 20CR. These only make use of SST and station pressure data. Across the world’s land areas, they indicate similar warming since 1900 to that which has occurred (Compo et al., 2013), again illustrating that urbanization is not the cause of the long-term warming. Changes in HadCRUH global land surface specific humidity and CRUTEM3 surface temperatures from 1973 to 1999 were compared to the CMIP3 archive of climate model simulations with 20th Century forcings (Willett et al., 2010). The models reproduce the magnitude of observed interannual variance over all large regions. Observed and modelled trends and temperature-humidity relationships are comparable with the exception of the extra-tropical Southern Hemisphere where observations exhibit no trend but models exhibit moistening.

54 ENVIRONMENTAL SCIENCES↗

Collaborative Research On Ecophysiological Controls on Amazonian Precipitation Seasonality And Variability

We developed and deployed a robust and accurate instrumentation package for measurement of solar induced chlorophyll fluorescence (SIF) from above a plant canopy. The sensor collects light from identical up and down facing hemispheric collectors. A fiber optic transmits the collected light (selected by a rotatable prism) to spectrometers located at the base of the tower. Spectra of the down welling and upwelling light were collected alternatively and stored for later analysis. SIF was retrieved by a spectral unmixing approach using high resolution spectra in the 730-760 nm band. Most other ground-based sensors base their analysis on O 2 -alpha band (760-780 nm) for SIF retrieval. We found that the former gave identical results when the atmosphere was clear, but the former was more stable in the cloudy conditions that often prevailed in the Amazon. The mechanical design and software developed for the system are available on request. The sensor was mounted near the top of an 80 m tower at K34 near Manaus in the Brazilian Amazon Forest. The sensor system proved weather-tight and functioned flawlessly over the time of deployment. Our experiment was cut short at 6 months by failure of air conditioning infrastructure at the tower. We found that SIF emitted by canopy was remarkably stable when scaled by the downwelling photosynthetically active radiation or the upwelling near infrared light. We detected a 3.4% increase in SIF over the course of the dry season. This finding is consistent with the observation that several trees in the field of view flushed new leaves in the dry season. We saw no evidence of drought stress or photo damage of the forest canopy during our study.

54 ENVIRONMENTAL SCIENCES↗

Methods to Account for CAP-88 PC-Omitted Nuclides in Radioactive Air Emissions From DOE Facilities

Routine research and development activities at US Department of Energy facilities can result in the release of radioactive emissions, potentially exposing the public and the environment. Such emissions are subject to certain Clean Air Act regulations, specifically those outlined in 40 CFR Part 61, Subpart H, which are enforced by the US Environmental Protection Agency. Compliance is determined in part with a dose standard. Doses to members of the public from most US Department of Energy facility airborne emissions are modeled using CAP-88 PC software, the latest version of which contains more than 1,200 radionuclides. Radioactive effluents from US Department of Energy facilities may contain radioisotopes that are not available in CAP-88 PC, and those radioisotopes must still be evaluated to determine whether doses to members of the public are below established limits. CAP-88 PC-omitted radionuclides can be accounted for using alternate methods, including the use of surrogate radionuclides. Here, this paper elucidates the process of accounting for CAP-88 PC-omitted radionuclides by providing criteria and rationale for surrogate selection, a compilation of surrogate radionuclides used in the past by US Department of Energy facilities, a discussion of alternate methods used to account for CAP-88 PC-omitted radionuclides and a comparison of methods and impacts on receptor doses. Ultimately, this paper aims to aid in the process of surrogate selection and consequently to simplify and expedite compliance with Clean Air Act regulations.

61 RADIATION PROTECTION AND DOSIMETRY↗

Economic and Jobs Impacts of Point-Source Carbon Capture in Cement Industry – Case Study

The cement industry accounts for an estimated 8% of global CO2 emissions, which surpasses that of the entire aviation sector. In contrast with other industries, where CO2 emissions can be drastically reduced via electrification or fuels substitution, cement production releases CO2 as part of its process, during the calcination of carbonates to yield oxides. Thus, point-source carbon capture has become a key technology in the cement industry’s decarbonization. Apart from the expected environmental benefits, point-source carbon capture in the cement industry can yield important economic benefits and create jobs. The objective of this study was to perform a preliminary assessment of the economic and workforce impacts associated with the construction and operation of a point-source carbon capture retrofit of an existing cement production facility, using as a basis the data from a front-end engineering design (FEED) study to install a 3.9 million metric tons per year (Mtpy) CO2 capture facility at Holcim Ste Genevieve cement plant in Missouri, United States of America. The advanced carbon capture technology used in this FEED study was Air Liquide’s Cryocap™ FG carbon capture technology. The study evaluated the direct, indirect, and induced economic impacts of the construction, operation, and maintenance activities of the project over its lifespan. It also covered how the project will generate new jobs, their nature, and quantity, along with strategies to prepare the workforce. To perform this study, construction, operation, and maintenance cost estimates, as well as construction and operation staffing plans from the FEED study were input into IMPLAN version 7.5 software, licensed by IMPLAN Group LLC (Huntersville, VC), to predict the direct, indirect and induced economic impacts of the project using industry multipliers from the software. Additionally, recruitment strategies were developed for hiring individuals who belong to groups that are historically underserved or underrepresented, as well as anticipated recruitment of workers from the local community (whether training will be required or if the skills are associated with an existing labor force). The analysis estimated that the construction and operation of the carbon capture at Holcim Ste. Genevive will result in over 24 thousand work-years of job opportunities, close to USD 10 billion of economic impacts, including over USD 460 million of tax revenue. These results encompass the direct, indirect, and induced effects. A strategy to maximize hiring from the project and neighboring counties was developed, leveraging training agreements with local trade groups and universities. The result of this study can be used for a strategic preliminary assessment of the potential regional economic and job impacts of retrofitting existing cement plants with point source carbon systems, and its methodology can be replicated to individual projects to aid in planning and workforce development.

01 COAL, LIGNITE, AND PEAT↗

Improved Hybrid Modeling of Spent Fuel Storage Facilities

This work developed a new computational method for improving the ability to calculate the neutron flux in deep-penetration radiation shielding problems that contain areas with strong streaming. The “gold standard” method for radiation transport is Monte Carlo (MC) as it samples the physics exactly and requires few approximations. Historically, however, MC was not useful for shielding problems because of the computational challenge of following particles through dense shields. Instead, deterministic methods, which are superior in term of computational effort for these problems types but are not as accurate, were used. Hybrid methods, which use deterministic solutions to improve MC calculations through a process called variance reduction, can make it tractable from a computational time and resource use perspective to use MC for deep-penetration shielding. Perhaps the most widespread and accessible of these methods are the Consistent Adjoint Driven Importance Sampling (CADIS) and Forward-Weighted CADIS (FW-CADIS) methods. For problems containing strong anisotropies, such as power plants with pipes through walls, spent fuel cask arrays, active interrogation, and locations with small air gaps or plates embedded in water or concrete, hybrid methods are still insufficiently accurate. In this work, a new method for generating variance reduction parameters for strongly anisotropic, deep penetration radiation shielding studies was developed. This method generates an alternate form of the adjoint scalar flux quantity, Φ Ω , which is used by both CADIS and FW-CADIS to generate variance reduction parameters for local and global response functions, respectively. The new method, called CADIS-Ω, was implemented in the Denovo/ADVANTG software. Results indicate that the flux generated by CADIS-Ω incorporates localized angular anisotropies in the flux more effectively than standard methods. CADIS-Ω outperformed CADIS in several test problems. This initial work indicates that CADIS- may be highly useful for shielding problems with strong angular anisotropies. This is a benefit to the public by increasing accuracy for lower computational effort for many problems that have energy, security, and economic importance.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Theory of Carbon Dioxide Absorption by Hanford Waste - 18208

Hanford nuclear waste has a very high pH, and Hanford tanks are ventilated with air. Air has CO{sub 2(g)} in it, which is an acid, so it has some affinity for the waste. The absorption of CO{sub 2} by the waste is important because CO{sub 2} absorption consumes hydroxide at the liquid-air interface, and the hydroxide is important for inhibiting tank corrosion. NaOH is periodically added to some tanks in order to mitigate the surface acidification. The NaOH added then becomes part of the waste and must be treated as waste, increasing the cost of the mission. The Hobbs Equation, developed at the Savannah River site, is used at Hanford to predict CO{sub 2} absorption from the tank ventilation system. In this study, the Hobbs Equation functional form is theoretically evaluated from thermodynamic calculations of CO{sub 2} absorption, and diffusion rates in the waste surface. This study theoretically justifies the empirical equation reported by Hobbs. Thermodynamic calculations performed using the Environmental Simulation Program (ESP) software on a typical double-shell tank waste composition indicate that essentially 100 % of CO{sub 2} that contacts the waste will react with the waste whenever the pH is above 10. In the 1990's, a substantial amount of data was collected on the concentration of CO{sub 2} in the off-gas of ventilated double-shell tanks at Hanford. This historic data was mined in order to determine the quantity of CO{sub 2} absorbed by the waste. The results of this data mining activity determined that tanks below approximately pH 10 (i.e., tank 241-AN-107) will show limited CO{sub 2} absorption, consistent with both the Hobbs model and the theory developed here. Two other tank with higher pH showed contrasting CO{sub 2} absorption. One showed substantial CO{sub 2} absorption, and the other showed minimal CO{sub 2} absorption despite the high waste pH in one tank, presumably because there was minimal contact between the waste surface and most of the air flow. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Supply Chain-Based Solution to Prevent Fuel Tax Evasion: Final Report

The primary source of funding for the United States transportation system is derived from motor fuel and other highway use taxes. Loss of revenue attributed to fuel-tax evasion has been assessed to be somewhere between 1 billion and 3 billion per year. Any solution that addresses this problem needs to include not only the tax-collection agencies and auditors, but also the carriers transporting oil products and the carriers customers. This report presents a system developed by the Oak Ridge National Laboratory (ORNL) for the Federal Highway Administration which has the potential to reduce or eliminate many fuel-tax evasion schemes. The solution balances the needs of tax-auditors and those of the fuel-hauling companies and their customers. The system has three main components. The on-board subsystem combined sensors, tracking and communication devices, and software (the on-board Evidential Reasoning System, or obERS) to detect, monitor, and geo-locate the transfer of fuel among different locations. The back office sub-system (boERS) used self-learning algorithms to determine the legitimacy of the fuel loading and offloading (important for tax auditors) and detect potential illicit operations such as fuel theft (important for carriers and their customers, and may justify the deployment costs). The third sub-system, the Fuel Distribution and Auditing System or FDAS, is a centralized database, which together with a user interface allows tax auditors to query the data submitted by the fuel-hauling companies and correlate different parameters to quickly identify any anomalies. Industry partners included Barger Transport of Weber City, Virginia (fleet); Air-Weigh, of Eugene, Oregon (and their wires and harnesses); Liquid Bulk Tank (LBT) of Omaha, Nebraska (three five-compartment trailers); and Innovative Software Engineering (ISE) of Coralville, Iowa(on-board telematics device and back-office system). ORNL conducted a pilot test with the three instrumented vehicles collecting real-world data during an eight-month period (October 2014 to June 2015). The vehicles logged a total of 375,000 miles and transported more than 7.5 million gallons of fuel. The drivers entered information on the telematics device about 77% of the time, with about 15% (10%) of the data showing at least one compartment with loading (offloading) valve activity, but not driver information entry for that compartment. Seven events (or about 0.7% of the trips) were identified by the boERS as having a missing fuel diversion number. The solution developed and tested in the pilot test had federal- and state-level tax auditors as its main audience. Nonetheless, the technology has to be adopted by the fuel carriers and therefore the solution had to address the needs of fuel-hauling companies and their customers (i.e., fuel theft and cocktailing). Sensors in the hatches allowed the obERS recognize when one of those were opened (always a suspicious activity, unless it happens at locations where maintenance is performed on the vehicle). The fuel-theft issue was addressed by a self-learning algorithm deployed on the boERS that continuously processed the data from the field to construct probability distributions of measures such as elapsed time of fuel loading and offloading by driver, vehicle, and compartment, valve actuation sequence, elapsed time between the first two valve actuations (by driver, compartment, and location), and other parameters. Probability thresholds, which can be set up by the carrier, determined how to classify the observed events. The boERS also kept track of valve sequencing at a given location and analyzed these actuations to help identify any suspicious activities. Technical and economic recommendations include: a) simplification of the driver data-entry task; b) reduction of system deployment cost; c) addition of capabilities that make the system more appealing to industry (i.e., identify and avoid fuel misdelivery); and d) incorporation of additional capabilities to the FDAS. Path to commercialization recommendations include: a) identify a company willing to further develop, test, and certify a hardened system with a price point the market will bear; b).transfer ERS to licensee; c) establish a fleet or fleets who want this technology for carrier benefits or trailer manufacturer who wants to offer it as optional technology; and d) identify a location for the deployment of FDAS.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Integrated PEV Charging Solutions and Reduced Energy for Occupant Comfort [Brochure]

Brochure on Vehicle Testing and Integration Facility, featuring the Vehicle Modification Facility, Vehicle Test Pad and ReCharge Integrated Demonstration System. Plug-in electric vehicles (PEVs) offer the opportunity to shift transportation energy demands from petroleum to electricity, but broad adoption will require integration with other systems. While automotive experts work to reduce the cost of PEVs, fossil fueled cars and trucks continue to burn hundreds of billions of gallons of petroleum each year - not only to get from point A to point B, but also to keep passengers comfortable with air conditioning and heat. At the National Renewable Energy Laboratory (NREL), three installations form a research laboratory known as the Vehicle Testing and Integration Facility (VTIF). At the VTIF, engineers are developing strategies to address two separate but equally crucial areas of research: meeting the demands of electric vehicle-grid integration and minimizing fuel consumption related to vehicle climate control. Part of NREL's Center for Transportation Technologies and Systems (CTTS), the VTIF is dedicated to renewable and energy efficient solutions. This facility showcases technology and systems designed to increase the viability of sustainably powered vehicles. NREL researchers instrument every class of on-road vehicle, conduct hardware and software validation for electric vehicle (EV) components and accessories, and develop analysis tools and technology for the Department of Energy, other government agencies and industry partners. Research conducted at the VTIF examines the interaction of building energy systems, utility grids, renewable energy sources and PEVs, integrating energy management solutions, and maximizing potential greenhouse gas (GHG) reduction, while smoothing the transition and reducing costs for EV owners. NREL's collaboration with automakers, charging station manufacturers, utilities and fleet operators to assess technologies using VTIF resources is designed to enable PEV communication with the smart grid and create opportunities for vehicles to play an active role in building and grid management. Ultimately, this creates value for the vehicle owner and will help renewables be deployed faster and more economically, making the U.S. transportation sector more flexible and sustainable.

02 PETROLEUM↗