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At least 1,783 records · Page 99

Modification of the Structure and Magnetic Properties of Cobalt-Doped Ferrihydrite Nanoparticles Under Heat Treatment

Nanoparticles of antiferromagnetic materials acquire the magnetic moment due to the surface effects and structural defects. According to the Neel hypothesis, magnetic moment μ{sub P} of a particle containing N magnetically active atoms with magnetic moment J can be estimated as μ{sub P} ∼ J · N{sup n} or μ{sub P} ∼ V{sup n}, where V is the particle volume. Numerous studies of the magnetic properties of ferrihydrite 5Fe{sub 2}O{sub 3}⋅9H{sub 2}O and ferritin revealed a value of n ≈ 1/2 for this material, in which Fe atoms have the octahedral surrounding of anions. We investigate the effect of low-temperature annealing of cobalt-doped ferrihydrite nanoparticles on their average size and magnetic properties. Using the Mössbauer spectroscopy study, we demonstrate that doping with Co makes Fe atoms enter the anion tetrahedra which leads to an increase in the exponent n〉1/2 in the expression μ{sub P} ∼ J · N{sup n}.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Intrafraction Bladder Motion in Radiation Therapy Estimated From Pretreatment and Posttreatment Volumetric Imaging

Purpose: The use of image guidance protocols using soft tissue anatomy identification before treatment can reduce interfractional variation. This makes intrafraction clinical target volume (CTV) to planning target volume (PTV) changes more important, including those resulting from intrafraction bladder filling and motion. The purpose of this study was to investigate the required intrafraction margins for soft tissue image guidance from pretreatment and posttreatment volumetric imaging. Methods and Materials: Fifty patients with muscle-invasive bladder cancer (T2-T4) underwent an adaptive radiation therapy protocol using daily pretreatment cone beam computed tomography (CBCT) with weekly posttreatment CBCT. A total of 235 pairs of pretreatment and posttreatment CBCT images were retrospectively contoured by a single radiation oncologist (CBCT-CTV). The maximum bladder displacement was measured according to the patient's bony pelvis movement during treatment, intrafraction bladder filling, and bladder centroid motion. Results: The mean time between pretreatment and posttreatment CBCT was 13 minutes, 52 seconds (range, 7 min 52 sec to 30 min 56 sec). Taking into account patient motion, bladder centroid motion, and bladder filling, the required margins to cover intrafraction changes from pretreatment to posttreatment in the superior, inferior, right, left, anterior, and posterior were 1.25 cm (range, 1.19-1.50 cm), 0.67 cm (range, 0.58-1.12 cm), 0.74 cm (range, 0.59-0.94 cm), 0.73 cm (range, 0.51-1.00 cm), 1.20 cm (range, 0.85-1.32 cm), and 0.86 cm (range, 0.73-0.99), respectively. Small bladders on pretreatment imaging had relatively the largest increase in pretreatment to posttreatment volume. Conclusion: Intrafraction motion of the bladder based on pretreatment and posttreatment bladder imaging can be significant particularly in the anterior and superior directions. Patient motion, bladder centroid motion, and bladder filling all contribute to changes between pretreatment and posttreatment imaging. Asymmetric expansion of CTV to PTV should be considered. Care is required in using image-guided radiation therapy protocols that reduce CTV to PTV margins based only on daily pretreatment soft tissue position.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

Predictors of Individual Tumor Local Control After Stereotactic Radiosurgery for Non-Small Cell Lung Cancer Brain Metastases

Purpose: To evaluate local control rates and predictors of individual tumor local control for brain metastases from non-small cell lung cancer (NSCLC) treated with stereotactic radiosurgery (SRS). Methods and Materials: Between June 1998 and May 2011, 401 brain metastases in 228 patients were treated with Gamma Knife single-fraction SRS. Local failure was defined as an increase in lesion size after SRS. Local control was estimated using the Kaplan-Meier method. The Cox proportional hazards model was used for univariate and multivariate analysis. Receiver operating characteristic analysis was used to identify an optimal cutpoint for conformality index relative to local control. A P value <.05 was considered statistically significant. Results: Median age was 60 years (range, 27-84 years). There were 66 cerebellar metastases (16%) and 335 supratentorial metastases (84%). The median prescription dose was 20 Gy (range, 14-24 Gy). Median overall survival from time of SRS was 12.1 months. The estimated local control at 12 months was 74%. On multivariate analysis, cerebellar location (hazard ratio [HR] 1.94, P=.009), larger tumor volume (HR 1.09, P<.001), and lower conformality (HR 0.700, P=.044) were significant independent predictors of local failure. Conformality index cutpoints of 1.4-1.9 were predictive of local control, whereas a cutpoint of 1.75 was the most predictive (P=.001). The adjusted Kaplan-Meier 1-year local control for conformality index ≥1.75 was 84% versus 69% for conformality index <1.75, controlling for tumor volume and location. The 1-year adjusted local control for cerebellar lesions was 60%, compared with 77% for supratentorial lesions, controlling for tumor volume and conformality index. Conclusions: Cerebellar tumor location, lower conformality index, and larger tumor volume were significant independent predictors of local failure after SRS for brain metastases from NSCLC. These results warrant further investigation in a prospective setting.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

Crystal structure, magnetism, and specific heat of lightly depleted layered honeycomb oxides, Na$_2$(Ni$_{2-x}$D$_x$)TeO$_6$ ($D$ = Mg, Ga, Co; 0.10 ≤ $x$ ≤ 0.25)

Layered oxides, in which transition metal atoms form a honeycomb lattice, are known for complex magnetic phase diagrams. In this work we study the doped compounds, Na$_2$(Ni$_{2-x}$D$_x$)TeO$_6$, $D$ = Mg, Ga, and Co (0.10 ≤ $x$ ≤ 0.25), to understand how chemical dilution at the nickel site influences the stability of magnetic exchanges within the honeycomb layer of the parent, Na$_2$ Ni$_2$ TeO$_6$. Here, the studied compounds were found to crystallize in $P6_3/mcm$ space group common to P2 type layered oxides. In general, the lattice parameters and the unit cell volume expanded with increased doping. The oxidation states determined from X-ray photoelectron spectroscopy were consistent with bond valence sum estimates, that confirmed the presence of Ni$^{2+}$, Mg$^{2+}$, Ga$^{3+}$, Co$^{2+}$ in our samples. Irrespective of magnetic or non-magnetic doping, the magnetic phase transition temperature ($T_N$) of the doped compounds were reduced from that of Na$_2$ Ni$_2$ TeO$_6$ or Na$_2$ Co$_2$ TeO$_6$, and lay between 21.7 K and 26.8 K. The effective paramagnetic moments extracted from Curie–Weiss analysis were in the range 3.17 μ B to 3.84 μ B and the Weiss temperatures were between $-15$ K and $-25$ K, suggesting antiferromagnetism. Mg- and Ga-doped compounds showed free spin formation, indicated by Curie–Weiss tails in their magnetic susceptibility. Our results suggest emergence of short-range magnetic correlations in Na$_2$(Ni$_{2-x}$D$_x$)TeO$_6$, enhanced due to the depletion of the Ni honeycomb lattice.

75 - CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY A↗

Modeling of the merging of two colliding field reversed configuration plasmoids

The field reversed configuration (FRC) is one of the candidate plasma targets for the magneto-inertial fusion, and a high temperature FRC can be formed by using the collision-merging technology. Although the merging process and mechanism of FRC are quite complicated, it is thinkable to build a simple model to investigate the macroscopic equilibrium parameters including the density, the temperature and the separatrix volume, which may play an important role in the collision-merging process of FRC. It is quite interesting that the estimates of the related results based on our simple model are in agreement with the simulation results of a two-dimensional magneto-hydrodynamic code (MFP-2D), which has being developed by our group since the last couple of years, while these results can qualitatively fit the results of C-2 experiments by Tri-alpha energy company. On the other hand, the simple model can be used to investigate how to increase the density of the merged FRC. It is found that the amplification of the density depends on the poloidal flux-increase factor and the temperature increases with the translation speed of two plasmoids.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

First results from COPSS: The CO power spectrum survey

We present constraints on the abundance of carbon monoxide in the early universe from the CO Power Spectrum Survey. We utilize a data set collected between 2005 and 2008 using the Sunyaev–Zel’dovich Array (SZA), which was previously used to measure arcminute-scale fluctuations of the cosmic microwave background. This data set features observations of 44 fields, covering an effective area of 1.7 square degrees, over a frequency range of 27–35 GHz. Using the technique of intensity mapping, we are able to probe the CO(1–0) transition, with sensitivity to spatial modes between k = 0.5–2 h Mpc{sup −1} over a range in redshift of z = 2.3–3.3, spanning a comoving volume of 3.6 × 10{sup 6} h{sup −3} Mpc{sup 3}. We demonstrate our ability to mitigate foregrounds, and present estimates of the impact of continuum sources on our measurement. We constrain the CO power spectrum to P{sub CO} < 2.6 × 10{sup 4} μK{sup 2} (h{sup −1} Mpc){sup 3}, or Δ{sup 2}{sub CO}(k = 1 h Mpc{sup −1}) < 1.3 × 10{sup 3} μK{sup 2}, at 95% confidence. This limit resides near optimistic predictions for the CO power spectrum. Under the assumption that CO emission is proportional to halo mass during bursts of active star formation, this corresponds to a limit on the ratio of CO(1–0) luminosity to host halo mass of A{sub CO} < 1.2 × 10{sup −5} L{sub ⊙} M{sub ⊙}{sup −1}. Further assuming a Milky Way-like conversion factor between CO luminosity and molecular gas mass (α{sub CO} = 4.3 M{sub ⊙} (K km s{sup −1} pc{sup −2}){sup −1}), we constrain the global density of molecular gas to ρ{sub z∼3}(M{sub H{sub 2}})⩽2.8×10{sup 8} M{sub ⊙} Mpc{sup −3}.

79 ASTRONOMY AND ASTROPHYSICS↗

Road exposure and the detectability of birds in field surveys

Road ecology, the study of the impacts of roads and their traffic on wildlife, including birds, is a rapidly growing field, with research showing effects on local avian population densities up to several kilometres from a road. However, in most studies, the effects of roads on the detectability of birds by surveyors are not accounted for. This could be a significant source of error in estimates of the impacts of roads on birds and could also affect other studies of bird populations. Using road density, traffic volume and bird count data from across Great Britain, we assess the relationships between roads and detectability of a range of bird species. Of 51 species analysed, the detectability of 36 was significantly associated with road exposure, in most cases inversely. Across the range of road exposure recorded for each species, the mean positive change in detectability was 52% and the mean negative change was 36%, with the strongest negative associations found in smaller‐bodied species and those for which aural cues are more important in detection. These associations between road exposure and detectability could be caused by a reduction in surveyors’ abilities to hear birds or by changes in birds’ behaviour, making them harder or easier to detect. We suggest that future studies of the impacts of roads on populations of birds or other taxa, and other studies using survey data from road‐exposed areas, should account for the potential impacts of roads on detectability.

Cooke, Sophia C.↗

Microstructural Changes to Thermally Sprayed Materials Subjected to Dynamic Compression

Dynamic compression of materials can induce a variety of microstructural changes. As thermally-sprayed materials have highly complex microstructures, the expected pressure at which changes occur cannot be predicted a priori. In addition, typical in-situ measurements such as velocimetry are unable to adequately diagnose microstructural changes such as failure or pore collapse. Quasi-isentropic compression experiments with sample recovery were conducted to examine microstructural changes in thermally sprayed tantalum and tantalum-niobium blends up to 8 GPa pressure. Spall fracture was observed in all tests, and post-shot pore volume decreased relative to the initial state. The blended material exhibited larger spall planes with fracture occurring at interphase boundaries. An estimate of the pressure at which pore collapse is complete was determined to be ~26 GPa for pure tantalum and ~19 GPa for the tantalumniobium blend under these loading conditions.

36 MATERIALS SCIENCE↗

Data from: Leaching losses of dissolved organic carbon and nitrogen from agricultural soils in the upper US Midwest

Leaching losses of dissolved organic carbon (DOC) and nitrogen (DON) from agricultural systems are important to water quality and carbon and nutrient balances but are rarely reported; the few available studies suggest linkages to litter production (DOC) and nitrogen fertilization (DON). In this study we examine the leaching of DOC, DON, NO3-, and NH4+ from no-till corn (maize) and perennial bioenergy crops (switchgrass, miscanthus, native grasses, restored prairie, and poplar) grown between 2009 and 2016 in a replicated field experiment in the upper Midwest U.S. Leaching was estimated from concentrations in soil water and modeled drainage (percolation) rates. DOC leaching rates (kg ha-1 yr-1) and volume-weighted mean concentrations (mg L-1) among cropping systems averaged 15.4 and 4.6, respectively; N fertilization had no effect and poplar lost the most DOC (21.8 and 6.9, respectively). DON leaching rates (kg ha-1 yr-1) and volume-weighted mean concentrations (mg L-1) under corn (the most heavily N-fertilized crop) averaged 4.5 and 1.0, respectively, which was higher than perennial grasses (mean: 1.5 and 0.5, respectively) and poplar (1.6 and 0.5, respectively). NO3- comprised the majority of total N leaching in all systems (59-92%). Average NO3- leaching (kg N ha-1 yr-1) under corn (35.3) was higher than perennial grasses (5.9) and poplar (7.2). NH4+ concentrations in soil water from all cropping systems were relatively low (<0.07 mg N L-1). Perennial crops leached more NO3- in the first few years after planting, and markedly less after. Among the fertilized crops, the leached N represented 14-38% of the added N over the study period; poplar lost the greatest proportion (38%) and corn was intermediate (23%). Requiring only one third or less of the N fertilization compared to corn, perennial bioenergy crops can substantially reduce N leaching and consequent movement into aquifers and surface waters.

09 BIOMASS FUELS↗

DOD/NASA system impact analysis (study 2.1). Volume 2: Study results

Results of the tug turnaround cost study and the space transportation system (STS) abort modes and effects study are presented for DOD/NASA system impact analysis. Cost estimates are given for tug turnabout; and vehicle description, abort assessment, and abort performance capability are given for the STS.

Source record↗

Systems theoretic model of stratospheric pollution on ozone

Discrete state space analysis is applied to the development of a model for predicting the reduction in the amount of stratospheric ozone due to stratospheric pollution. The modeling approach is to segment the stratosphere into a number of altitudinal bands and to associate state variables with the state of ozone reduction in each band due to NO(x) injections. The ozone reductions in each band are then combined into an estimate of total global ozone reduction. The model proposed predicts changes in stratospheric ozone based on altitude of pollutant injection and volume of pollutant injected at that altitude. The present approach is not a detailed analysis of stratospheric constituents and their interactions, but rather an analysis procedure for modeling the results of other researchers in the field.

Wilkins, R. D.↗

EDIN design study alternate space shuttle booster replacement concepts. Volume 1: Engineering analysis

The use of a recoverable liquid rocket booster (LRB) system to replace the existing solid rocket booster (SRB) system for the shuttle was studied. Historical weight estimating relationships were developed for the LRB using Saturn technology and modified as required. Mission performance was computed using February 1975 shuttle configuration groundrules to allow reasonable comparison of the existing shuttle with the study designs. The launch trajectory was constrained to pass through both the RTLS/AOA and main engine cut off points of the shuttle reference mission 1. Performance analysis is based on a point design trajectory model which optimizes initial tilt rate and exoatmospheric pitch profile. A gravity turn was employed during the boost phase in place of the shuttle angle of attack profile. Engine throttling add/or shutdown was used to constrain dynamic pressure and/or longitudinal acceleration where necessary. Four basic configurations were investigated: a parallel burn vehicle with an F-1 engine powered LRB; a parallel burn vehicle with a high pressure engine powered LRB; a series burn vehicle with a high pressure engine powered LRB. The relative sizes of the LRB and the ET are optimized to minimize GLOW in most cases.

Demakes, P. T.↗

Satellite services system analysis study. Volume 2, part 2: Study results

The development of an effective satellite services system was investigated. Satek Satellite user market, design reference missions, satellite service functions, service equipment, and cost estimates are discussed. Extensive program plans for a satellite service system implementation are included.

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Remote sensing of cloud-top pressure using reflected solar radiation in the oxygen A-band

An algorithm has been developed for using the reflection of solar radiation in the oxygen A-band to determine cloud-top altitude. Because of multiple scattering and molecular absorption inside the cloud, the reflection of clouds is substantially modified in comparison with a mirror cloud, which is assumed to have a 100 percent reflection. To infer true cloud-top altitude, therefore, it is necessary to accurately estimate the amount of 'photon penetration'. Theoretical calculations indicate that the amount of photon penetration depends on the altitude, the scaled volume scattering coefficient, and the scaled optical thickness of the cloud. Algorithms using the reflection in the oxygen A-band to determine the cloud-top pressure have been applied to an aircraft field experiment in conjunction with CCOPE, 1981. Results of this study are very encouraging, especially for extended clouds.

Wu, M.-L. C.↗

A study of backscattering and emission from closely packed inhomogeneous media

The effects of close spacing between small scattering spheres were examined by keeping the distance-dependent terms in the expressions for the transverse scattered fields. The phase matrix was then derived from these fields and was used in the radiative transfer formulation to model scattering and emission from a densely populated, inhomogeneous layer. Computed results were compared with those obtained when the phase matrix was specialized to the far-field condition. It was found that the use of the far-zone condition tended to underestimate both the level of the copolarized backscattering and the cross-polarized backscattering. In emission computations, the use of the far-zone condition overestimated the level of the brightness temperature. These effects decreased with a decrease in the volume fraction or an increase in the exploring frequency, as expected. An improvement on the snow parameter (density and crystal size) estimation was shown to be possible when this new phase matrix was used.

Fung, A. K.↗

Size distribution and scattering phase function of aerosol particles retrieved from sky brightness measurements

Ground-based measurements of the solar transmission and sky radiance in a horizontal plane through the Sun are taken in several geographical regions and aerosol types: dust in a desert transition zone in Israel, sulfate particles in Eastern and Western Europe, tropical aerosol in Brazil, and mixed continental/maritime aerosol in California. Stratospheric aerosol was introduced after the eruption of Mount Pinatubo in June 1991. Therefore measurements taken before the eruption are used to analyze the properties of tropospheric aerosol; measurements from 1992 are also used to detect the particle size and concentration of stratospheric aerosol. The measurements are used to retrieve the size distribution and the scattering phase function at large scattering angles of the undisturbed aerosol particles. The retrieved properties represent an average on the entire atmospheric column. A comparison between the retrieved phase function for a scattering angle of 120 deg, with phase function predicted from the retrieved size distribution, is used to test the assumption of particle homogeneity and sphericity in radiative transfer models (Mie theory). The effect was found to be small (20% +/- 15%). For the stratospheric aerosol (sulfates), as expected, the phase function was very well predicted using the Mie theory. A model with a power law distribution, based on the spectral dependence of the optical thickness, alpha, cannot estimate accurately the phase function (up to 50% error for lambda = 0.87 microns). Before the Pinatubo eruption the ratio between the volumes of sulfate and coarse particles was very well correlated with alpha. The Pinatubo stratospheric aerosol destroyed this correlation. The aerosol optical properties are compared with analysis of the size, shape, and composition of the individual particles by electron microscopy of in situ samples. The measured volume size distribution before the injection of stratospheric aerosol consistently show two modes, sulfate particles with r(sub m) less than 0.2 microns and coarse paritcles with r(sub m) greater than 0.7 microns. The 'window' in the tropospheric aerosol in this radius range was used to observe a stable stratospheric aerosol in 1992, with r(sub m) approximately 0.5 microns. A combination of such optical thickness and sky measurements can be used to assess the direct forcing and the climatic impact of aerosol. Systematic inversion for the key aerosol types (sulfates, smoke, dust, and maritime aerosol) of the size distribution and phase function can give the relationship between the aerosol physical and optical properties that can be used to compute the radiative forcing. This forcing can be validated in dedicated field experiments.

Kaufman, Y. J.↗

Martian Surface Properties: Inferences from Resolved Differences in Crater Geometries

Impact craters are a natural probe of planetary sub-surfaces, both from the excavated material and from crater geometries, which are sensitive to material properties of the target. One of the most intriguing aspects of Martian craters is the morphology of the ejecta blankets. All fresh and many older Martian craters larger than a few km are surrounded by ejecta blankets which appear fluidized, with morphologies believed to form by entrainment of liquid water. In addition to the ejecta morphology, quantitative information about the subsurface composition may be derived from geometrical measurements, e.g., rim uplift height and ejecta blanket volumes. In order to use craters to derive subsurface composition or test rampart morphology formation hypotheses, accurate measurements with quantified error estimates are required. We have developed and tested a toolkit for measurements of crater geometry using the MOLA altimetry data. Here, we present the results from geometry measurements on fresh craters in Lunae Planum and Utopia Planitia.

Valiant, G. J.↗

Characteristics and Influence of Biosmoke on the Fine-Particle Ionic Composition Measured in Asian Outflow during the Transport and Chemical Evolution Over the Pacific (TRACE-P) Experiment

We investigate the sources, prevalence, and fine-particle inorganic composition of biosmoke over the western Pacific Ocean between 24 February and 10 April 2001. The analysis is based on highly time-resolved airborne measurements of gaseous and fine- particle inorganic chemical composition made during the NASA Transport and Chemical Evolution over the Pacific (TRACE-P) experiment. At latitudes below approximately 25 deg. N, relatively pure biomass burning plumes of enhanced fine-particle potassium, nitrate, ammonium, light-absorbing aerosols, and CO concentrations were observed in plumes that back trajectories and satellite fire map data suggest originated from biomass burning in southeast Asia. Fine-particle water-soluble potassium (K+) is confirmed to be a unique biosmoke tracer, and its prevalence throughout the experiment indicates that approximately 20% of the TRACE-P Asian outflow plumes were influenced, to some extent, by biomass or biofuel burning emissions. At latitudes above 25 deg. N, highly mixed urban/industrial and biosmoke plumes, indicated by SO(sup 2, sub 4) and K+, were observed in 5 out of 53 plumes. Most plumes were found in the Yellow Sea and generally were associated with much higher fine-particle loadings than plumes lacking a biosmoke influence. The air mass back trajectories of these mixed plumes generally pass through the latitude range of between 34 deg. and 40 deg. N on the eastern China coast, a region that includes the large urban centers of Beijing and Tianjin. A lack of biomass burning emissions based on fire maps and high correlations between K+ and pollution tracers (e.g., S(sup 2, sub 4) suggest biofuel sources. Ratios of fine-particle potassium to sulfate are used to provide an estimate of relative contributions of biosmoke emissions to the mixed Asian plumes. The ratio is highly correlated with fine-particle volume (r(sup 2) = 0.85) and predicts that for the most polluted plume encounter in TRACE-P, approximately 60% of the plume is associated with biosmoke emissions. On average, biosmoke contributes approximately 35-40% to the measured fine inorganic aerosol mass in the mixed TRACE-P plumes intercepted north of 25% latitude.

Ma, Y.↗