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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,783 records · Page 99
All sourcesNASA NTRSDOE OSTI
NASA NTRS2021

Effect of High Temperature Storage on AC Characteristics of Polymer Tantalum Capacitors

Replacement of MnO2 with conductive polymers as cathode materials in chip tantalum capacitors allows for a substantial reduction of the equivalent series resistance (ESR), improvement of frequency characteristics, and elimination of the possibility of ignition during failures. One of the drawbacks of chip polymer tantalum capacitors (CPTCs) is a relatively poor long-term stability at high temperatures. In this work, variations of capacitance, dissipation factor, and ESR in different types of capacitors including automotive grade parts from three manufacturers have been monitored during storage at temperatures from 100 ºC to 175 ºC for up to 18,000 hours. Results show that ESR is the most and capacitance the least sensitive to degradation parameter. Times to parametric failures have been simulated using a Weibull-Arrhenius model that allowed for assessments of activation energies of the degradation and prediction of times to failure at the use temperature. Degradation of CPTCs was explained by thermo-oxidative processes in conductive polymers that result in exponential increasing of the resistivity with time of ageing. This process starts after a certain incubation period that depends on packaging materials and design and corresponds to the time that is necessary to form delamination between the encapsulating molding compound and lead frame. The effectiveness of the existing qualification procedures to assure stable operation of CPTCs is discussed.

Alexander A Teverovsky↗
NASA NTRSDate not supplied

Effect of High Temperature Storage on AC Characteristics of Polymer Tantalum Capacitors

Replacement of MnO2 with conductive polymers as cathode materials in chip tantalum capacitors allows for a substantial reduction of the equivalent series resistance (ESR), improvement of frequency characteristics, and elimination of the possibility of ignition during failures. One of the drawbacks of chip polymer tantalum capacitors (CPTCs) is a relatively poor long-term stability at high temperatures. In this work, variations of capacitance, dissipation factor, and ESR in different types of capacitors including automotive grade parts from three manufacturers have been monitored during storage at temperatures from 100 ºC to 175 ºC for up to 18,000 hours. Results show that ESR is the most and capacitance the least sensitive to degradation parameter. Times to parametric failures have been simulated using a Weibull-Arrhenius model that allowed for assessments of activation energies of the degradation and prediction of times to failure at the use temperature. Degradation of CPTCs was explained by thermo-oxidative processes in conductive polymers that result in exponential increasing of the resistivity with time of ageing. This process starts after a certain incubation period that depends on packaging materials and design and corresponds to the time that is necessary to form delamination between the encapsulating molding compound and lead frame. The effectiveness of the existing qualification procedures to assure stable operation of CPTCs is discussed.

Aging↗
NASA NTRSDate not supplied

Effect of High Temperature Storage on AC Characteristics of Polymer Tantalum Capacitors

Replacement of MnO2 with conductive polymers as cathode materials in chip tantalum capacitors allows for a substantial reduction of the equivalent series resistance (ESR), improvement of frequency characteristics, and elimination of the possibility of ignition during failures. One of the drawbacks of chip polymer tantalum capacitors (CPTCs) is a relatively poor long-term stability at high temperatures. In this work, variations of capacitance, dissipation factor, and ESR in different types of capacitors including automotive grade parts from three manufacturers have been monitored during storage at temperatures from 100 ºC to 175 ºC for up to 18,000 hours. Results show that ESR is the most and capacitance the least sensitive to degradation parameter. Times to parametric failures have been simulated using a Weibull-Arrhenius model that allowed for assessments of activation energies of the degradation and prediction of times to failure at the use temperature. Degradation of CPTCs was explained by thermo-oxidative processes in conductive polymers that result in exponential increasing of the resistivity with time of ageing. This process starts after a certain incubation period that depends on packaging materials and design and corresponds to the time that is necessary to form delamination between the encapsulating molding compound and lead frame. The effectiveness of the existing qualification procedures to assure stable operation of CPTCs is discussed.

Aging↗
NASA NTRS1985

Effects of a finite plasma temperature on electron-cyclotron maser emission

Auroral kilometric radiation, Jupiter's decametric radio emission, and microwave spike bursts have all been attributed to the semirelativistic maser instability. The effect of a finite plasma temperature on the emission from this instability is investigated. Temperature effects reduce the frequency of the x mode and thereby enable fundamental x-mode radiation to occur at higher omega sub p/Omega sub e (where omega sub p is the plasma frequency and Omega sub e is the electron-cyclotron frequency). When the plasma frequency is sufficiently high to suppress x-mode growth, z-mode growth then dominates. The z-mode radiation is, however, subject to electron-cyclotron damping, and this damping can cause heating of the plasma in the vicinity of the source region. In this case, x-mode radiation can be generated even though initial conditions might favor z-mode growth.

Winglee, R. M.↗
NASA NTRS1973

The meteorological effects on microwave apparent temperatures looking downward over a smooth sea

The effects of clouds and rain on microwave apparent temperatures for a flat sea surface are examined. The presence of clouds and rain can be expressed as a change of absorption coefficient and the total absorption is computed as the sum of individual effects. Various cloud and rain models proposed by meteorologists are employed to compute the microwave apparent temperature when viewing downward through these model atmospheres. It is shown that stratus, cumulus, overcast, and rain all contribute significantly to the observed temperature. Larger sensitivities to clouds and rain are observed for horizontally polarized apparent temperature at large nadir angles than for vertically polarized apparent temperature.

Wu, S.↗
NASA NTRS1995

Considerations for modeling thin cirrus effects via brightness temperature differences

Brightness temperature difference (BTD) values are calculated for selected Geostationary Operational Environmental Satellite (GOES-6) channels (3.9, 12.7 micrometer) and Advanced Very High Resolution Radiometer channels (3.7, 12.0 micrometer). Daytime and nighttime discrimination of particle size information is possible given the infrared cloud extinction optical depth and the BTD value. BTD values are presented and compared for cirrus clouds composed of equivalent ice spheres (volume, surface area) versus randomly oriented hexagonal ice crystals. The effect of the hexagonal ice crystals is to increase the magnitude of the BTD values calculated relative to equivalent ice sphere (volume, surface area) BTDs. Equivalent spheres (volume or surface area) do not do a very good job of modeling hexagonal ice crystal effects on BTDs; however, the use of composite spheres improves the simulation and offers interesting prospects. Careful consideration of the number of Legendre polynomial coefficients used to fit the scattering phase functions is crucial to realistic modeling of cirrus BTDs. Surface and view-angle effects are incorporated to provide more realistic simulation.

Schmidt, E. O.↗
NASA NTRS1988

Effects of a temperature-dependent rheology on large scale continental extension

The effects of a temperature-dependent rheology on large-scale continental extension are investigated using a thin viscous sheet model. A vertically-averaged rheology is used that is consistent with laboratory experiments on power-law creep of olivine and that depends exponentially on temperature. Results of the calculations depend principally on two parameters: the Peclet number, which describes the relative rates of advection and diffusion of heat, and a dimensionless activation energy, which controls the temperature dependence of the rheology. At short times following the beginning of extension, deformation occurs with negligible change in temperature, so that only small changes in lithospheric strength occur due to attenuation of the lithosphere. However, after a certain critical time interval, thermal diffusion lowers temperatures in the lithosphere, strongly increasing lithospheric strength and slowing the rate of extension. This critical time depends principally on the Peclet number and is short compared with the thermal time constant of the lithosphere. The strength changes cause the locus of high extensional strain rates to shift with time from regions of high strain to regions of low strain. Results of the calculations are compared with observations from the Aegean, where maximum extensional strains are found in the south, near Crete, but maximum present-day strain rates are largest about 300 km further north.

Sonder, Leslie J.↗
DOE OSTI2024

Interpreting test temperature and loading rate effects on the fracture toughness of polymer-metal interfaces via time–temperature superposition

Here, in this letter, we present interfacial fracture toughness data for a polymer-metal interface where tests were conducted at various test temperatures T and loading rates $\dot{δ}$. An adhesively bonded asymmetric double cantilever beam (ADCB) specimen was utilized to measure toughness. ADCB specimens were created by bonding a thinner, upper adherend to a thicker, lower adherend (both 6061 T6 aluminum) using a thin layer of epoxy adhesive, such that the crack propagated along the interface between the thinner adherend and the epoxy layer. The specimens were tested at T from 25 to 65 °C and $\dot{δ}$ from 0.002 to 0.2 mm/s. The measured interfacial toughness Γ increased as both T and $\dot{δ}$ increased. For an ADCB specimen loaded at a constant $\dot{δ}$, the energy release rate G increases as the crack length a increases. For this reason, we defined rate effects in terms of the rate of change in the energy release rate $\dot{G}$. Although not rigorously correct, a formal application of time–temperature superposition (TTS) analysis to the Γ data provided useful insights on the observed dependencies. In the TTS-shifted data, Γ decreased and then increased for monotonically increasing $\dot{G}$. Thus, the TTS analysis suggests that there is a minimum value of Γ. This minimum value could be used to define a lower bound in Γ when designing critical engineering applications that are subjected to T and $\dot{δ}$ excursions.

36 MATERIALS SCIENCE↗
NASA NTRS1985

Heat transfer characteristics within an array of impinging jets. Effects of crossflow temperature relative to jet temperature

Spanwise average heat fluxes, resolved in the streamwise direction to one stream-wise hole spacing were measured for two-dimensional arrays of circular air jets impinging on a heat transfer surface parallel to the jet orifice plate. The jet flow, after impingement, was constrained to exit in a single direction along the channel formed by the jet orifice plate and heat transfer surface. The crossflow originated from the jets following impingement and an initial crossflow was present that approached the array through an upstream extension of the channel. The regional average heat fluxes are considered as a function of parameters associated with corresponding individual spanwise rows within the array. A linear superposition model was employed to formulate appropriate governing parameters for the individual row domain. The effects of flow history upstream of an individual row domain are also considered. The results are formulated in terms of individual spanwise row parameters. A corresponding set of streamwise resolved heat transfer characteristics formulated in terms of flow and geometric parameters characterizing the overall arrays is described.

Florschuetz, L. W.↗
NASA NTRS2015

Differences Between the HUT Snow Emission Model and MEMLS and Their Effects on Brightness Temperature Simulation

Microwave emission models are a critical component of snow water equivalent retrieval algorithms applied to passive microwave measurements. Several such emission models exist, but their differences need to be systematically compared. This paper compares the basic theories of two models: the multiple-layer HUT (Helsinki University of Technology) model and MEMLS (Microwave Emission Model of Layered Snowpacks). By comparing the mathematical formulation side-by-side, three major differences were identified: (1) by assuming the scattered intensity is mostly (96) in the forward direction, the HUT model simplifies the radiative transfer (RT) equation into 1-flux; whereas MEMLS uses a 2-flux theory; (2) the HUT scattering coefficient is much larger than MEMLS; (3 ) MEMLS considers the trapped radiation inside snow due to internal reflection by a 6-flux model, which is not included in HUT. Simulation experiments indicate that, the large scattering coefficient of the HUT model compensates for its large forward scattering ratio to some extent, but the effects of 1-flux simplification and the trapped radiation still result in different T(sub B) simulations between the HUT model and MEMLS. The models were compared with observations of natural snow cover at Sodankyl, Finland; Churchill, Canada; and Colorado, USA. No optimization of the snow grain size was performed. It shows that HUT model tends to under estimate T(sub B) for deep snow. MEMLS with the physically-based improved Born approximation performed best among the models, with a bias of -1.4 K, and an RMSE of 11.0 K.

Pan, Jinmei↗
DOE OSTI2023

Remote effects of Tibetan Plateau spring land temperature on global subseasonal to seasonal precipitation prediction and comparison with effects of sea surface temperature: the GEWEX/LS4P Phase I experiment

The prediction skill for precipitation anomalies in late spring and summer months—a significant component of extreme climate events—has remained stubbornly low for years. This paper presents a new idea that utilizes information on boreal spring land surface temperature/subsurface temperature (LST/SUBT) anomalies over the Tibetan Plateau (TP) to improve prediction of subsequent summer droughts/floods over several regions over the world, East Asia and North America in particular. The work was performed in the framework of the GEWEX/LS4P Phase I (LS4P-I) experiment, which focused on whether the TP LST/SUBT provides an additional source for subseasonal-to-seasonal (S2S) predictability. The summer 2003, when there were severe drought/flood over the southern/northern part of the Yangtze River basin, respectively, has been selected as the focus case. With the newly developed LST/SUBT initialization method, the observed surface temperature anomaly over the TP has been partially produced by the LS4P-I model ensemble mean, and 8 hotspot regions in the world were identified where June precipitation is significantly associated with anomalies of May TP land temperature. Consideration of the TP LST/SUBT effect has produced about 25–50% of observed precipitation anomalies in most hotspot regions. The multiple models have shown more consistency in the hotspot regions along the Tibetan Plateau-Rocky Mountain Circumglobal (TRC) wave train. The mechanisms for the LST/SUBT effect on the 2003 drought over the southern part of the Yangtze River Basin are discussed. For comparison, the global SST effect has also been tested and 6 regions with significant SST effects were identified in the 2003 case, explaining about 25–50% of precipitation anomalies over most of these regions. This study suggests that the TP LST/SUBT effect is a first-order source of S2S precipitation predictability, and hence it is comparable to that of the SST effect. With the completion of the LS4P-I, the LS4P-II has been launched and the LS4P-II protocol is briefly presented.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1988

Effect of spatial inlet temperature and pressure distortion on turbofan engine stability

The effects of circumferential and radial inlet temperature distortion, circumferential pressure distortion, and combined temperature and pressure distortion on the stability of an advanced turbofan engine were investigated experimentally at simulated altitude conditions. With circumferential and radial inlet temperature distortion, a flow instability generated by the fan operating near stall caused the high-pressure compressor to surge at, or near, the same time as the fan. The effect of combined distortion was dependent on the relative location of the high-temperature and low-pressure regions; high-pressure compressor stalls occurred when the regions coincided, and fan stalls occurred with the regions separated.

Mehalic, Charles M.↗
NASA NTRS1988

Effect of spatial inlet temperature and pressure distortion on turbofan engine stability

The effects of circumferential and radial inlet temperature distortion, circumferential pressure distortion, and combined temperature and pressure distortion on the stability of an advanced turbofan engine were investigated experimentally at simulated altitude conditions. With circumferential and radial inlet temperature distortion, a flow instability generated by the fan operating near stall caused the high-pressure compressor to surge at, or near, the same time as the fan. The effect of combined distortion was dependent on the relative location of the high-temperature and low-pressure regions; high-pressure compressor stalls occurred when the regions coincided, and fan stalls occurred with the regions separated.

Mehalic, Charles M.↗
DOE OSTI2023

Effect of Surface Temperature on the Distribution and Reactivity of Rh Active Sites for CO Oxidation

Single–atom catalysts are a fast–emerging area in which late–transition metal atoms are supported on oxides, metals, and carbonaceous supports. They show great promise for selective chemical reactions due to their well–defined active sites, and significantly reduce precious metal loading. However, oxide–supported single–atom catalysts have drawbacks such as deactivation due to sintering, and there are on–going debates about the exact nature of the active sites. Herein we report a model system where the surface temperature during Rh deposition on a copper oxide support dictates the Rh size distribution. Here our temperature–programmed desorption experiments reveal that Rh clusters perform CO oxidation at lower temperature than single atoms, and isotopic labelling demonstrates differences in the mechanism in that the C–O bond is broken and reformed on clusters, as opposed to a pure Mars van Krevelen mechanism for CO oxidation at the single–atom Rh sites. We further examine the cluster size distributions with scanning tunneling microscopy and X–ray photoelectron spectroscopy which confirm the presence of both clusters and single atoms for the lower temperature deposition and only single atoms for the higher temperature deposition. Together, these results provide a fundamental understanding of the differences in the CO oxidation mechanism on Rh atoms and clusters.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Modeling Microstructural Effects on Heterogeneous Temperature Fields within Polycrystalline Explosives

The paper addresses the role of crystal anisotropy on the evolution of heterogeneous temperature fields in plastic-bonded explosives (PBXs) under conditions of weak shock. The modeling approach is based on simplified idealizations of PBX microstructure including RDX grains and estane binder regions subjected to velocity boundary conditions representative of impact conditions in situ. The constitutive description of the microstructure constituents includes a dislocation-based, anisotropic, single crystal plasticity model for the explosive grains and a linear viscoelastic model to represent the estane binder. Large suites of simulations were used to systematically study the correlation in heating of the grains with local wave dynamics, crystal orientation, and the microstructural neighborhood. These correlations were identified through the selection of characteristics of crystal anisotropy including oriented wave speeds and Taylor factor. A key observation is that the wave dispersion within a certain distance from the impact interface plays a dominant role in the temperature field. Beyond this distance, individual crystal orientations play a more dominant role, but cannot entirely account for the observed heterogeneity without consideration of the local microstructure neighborhood.

42 ENGINEERING↗