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NASA NTRSDate not supplied

An Updated Model for the Effect of Atmospheric Absorption on Sounding Rockets

A very high-resolution R > 20,000 Far Ultraviolet full-disk, solar spectrograph will be launched in the Spring of 2023. This paper describes the in-flight wavelength calibration techniques and the fortuitous retrieval of Earth’s thermospheric information during the flight. Building and calibration of the Full-sun Ultraviolet Rocket Spectrograph (FURST) is currently underway. The purpose of this instrument is to obtain the highest resolution and most complete Far Ultra-Violet (FUV) spectra of the full disk Sun. This so-called "Sun-as-a-star" spectra will allow direct comparisons between our Sun and other stars measured by the Hubble Space Telescope(HST) and the upcoming James Webb Space Telescope (JWST). The Solar Physics groups at NASA Marshall Space Flight Center (MSFC) and Montana State University (MSU) have been developing the tools and procedures necessary to achieve the high spectral resolution goal. These include, among other things, improved tracking of error propagation, in-situ monitoring of the camera gain with a radioactive Fe-55 source, and the development of a simulated spectral calibration map under a noisy diagnostic-lamp signal. This mapping introduces a clocked CCD in order to obtain sub-pixel spectral resolution and overcome the Nyquist limit by about a factor of 2. Aside from the main purpose of FURST, we have been investigating the effect of absorption in the upper atmosphere at sounding-rocket altitudes (about 100-300 km). We present here an improved model of the optical depth caused by the thermospheric Oxygen cross-section and H and O self-absorption. This data-based model uses concentric spherical shells to account for the curvature of the Earth’s atmosphere and refraction. Using these calculations, we present the anticipated effect on the signal received by FURST, how that signal changes over the course of the flight-path These absorption peaks would provide wavelength fiducials at line-center that might add to in-flight calibration of the instrument. Many studies have found ways to correct for these so-called "Telluric" lines. However, it may be that these lines can in fact be a useful tool to further improve our calibration, rather than simply a nuisance to be corrected for! Finally, we discuss the inversion problem: how we could take actual flight data and back-out the atmospheric data (such as density and temperature) from any such sounding rocket flight that shows evidence of atmospheric absorption.

Nicolas Donders↗
NASA NTRSDate not supplied

Mitigating the Impact of Momentum Unloads on Station Keeping Around Libration Point Orbits

The Space Weather Follow On (SWFO) observatory will observe the Sun from L1, collecting solar wind data and coronal imagery, while providing early warning for space weather events. SWFO is a ride-share mission on SpaceX Falcon9 that is carrying IMAP. The spacecraft will be operated by NOAA and is expected to launch in February 2025. In order to meet NOAA’s operational requirements SWFO must maintain a Sun-Earth-Vehicle (SEV) angle between 4 and 13 degrees for at least 5 years. This constraint drives the size of the Lissajous orbit. SWFO is required keep a Sun pointing attitude in order to perform the Sun observations. Frequent Momentum Unloads are required to desaturate its reaction wheals. Station-keeping maneuvers are required to stay in orbit around L1, they are planned to be performed every 30 days.

Libration Point Orbits↗
NASA NTRSDate not supplied

Lander Lighting Solution to Reduce Pilot & Autonomous Approach Errors

The south pole lighting environment will have harsh low inclination sunlight, making overhead judgement of surface features difficult. Autonomous solutions are great, however, the need for visual monitoring and independent go/no-go decisions remain. Our project proposes that lunar landing systems will be better served by including a powerful landing light system that improves visibility of surfaces from overhead by illuminating the ground at critical distances for the crew to make last minute decisions regarding an approach. The project utilized computer-based optical modeling software to predict requirements for a potential landing light system. The analysis based the lamp prediction from commercially available LED chip sets and lamp optics. The goal was to illustrate a method to raise the surface contrast of a landing site within an acceptable contrast threshold for most camera systems and human observers to recognize hazards that would not be noticed with low inclination sunlight alone. The Apollo lunar landings benefitted from overhead sun or dark conditions. The surface lighting at the Lunar South Pole is a harsh environment where surfaces are lit from a low inclination angle by the sun (from the side). This change in lighting condition precipitates a need for updated lunar landing systems that facilitate improved recognition of landing sites, and thereby increase pilot awareness of landing hazards. The reliance on LIDAR and other autonomous mechanisms alone is risky given the known usage of visual monitoring for operator concurrence on current spacecraft programs and present-day autonomous land-based vehicles. Visual monitoring via cameras or windows requires the surface contrast to be within 3 orders of magnitude for reasonable recognition of objects. Artificial overhead illumination, when sufficiently sized, provides a means to even out contrast problems created by low inclination sunlight, potentially reducing piloting errors. Current vehicle requirements do not specify this type of guidance for the purpose of increasing mission success. An optical ray-trace simulation model was developed in Zemax Optics Studio to predict the best combination of LED power, LED optics, lamp quantity, and lamp location to raise the surface contrast to within 2 orders of magnitude from 3 orders required to further increased visibility and reduce risk. The project considered the following design constraints: potential base diameter of lander, approach distance(s) for a go-no-go decision point (200 meter), solar inclination angle (2-7), lunar surface reflectance (10%), LED chip sets, LED focusing optics, LED power, lamp quantity, lamp locations, and illumination diameter of lunar surface landing zone. The results can be used to establish minimum design constraints for vehicle landing light systems. With a solar inclination angle ranging from 2-7 degrees, the horizontal illumination of the lunar surface is attenuated by about 10% when compared to overhead illumination from the Sun. This modifies the sun's maximum of 130,000 lux to 13,000 lux horizontal illuminance. The artificial lighting system was designed to provide an 18-meter-wide illumination zone, to create viewing clearances around a 6-meter-wide lander. The system provides an average illuminance of 300 lux, meeting the 2 orders of magnitude criteria. The solution utilized modern Chip On Board LEDs, that each utilized 17 watts, with focusing Total Internal Reflection (TIR) lenses. A lighting system of 300 LEDs was arrayed along the "bottom" of a “lander”. With 17 watts per LED, the system is estimated to require 5100 watts. This is a large amount of power, but it would only be needed during critical phases during the landing. LED lighting systems can be dimmed, and it is assumed that as the lander arrives closer to the landing site, the lighting system power can be adjusted as needed to produce the necessary surface illuminance. The designed reduction of contrast improves reliability of safety assessments using real time visible light camera systems and out the window viewing by the crew.

T A Clark↗
NASA NTRS2023

ICARUS: in-Situ Studies of the Solar Corona Beyond Parker Solar Probe and Solar Orbiter

The primary scientific goal of ICARUS (Investigation of Coronal AcceleRation and heating of solar wind Up to the Sun), a mother-daughter satellite mission, proposed in response to the ESA “Voyage 2050” Call, will be to determine how the magnetic field and plasma dynamics in the outer solar atmosphere give rise to the corona, the solar wind, and the entire heliosphere. Reaching this goal will be a Rosetta Stone step, with results that are broadly applicable within the fields of space plasma physics and astrophysics. Within ESA’s Cosmic Vision roadmap, these science goals address Theme 2: “How does the Solar System work?” by investigating basic processes occurring “From the Sun to the edge of the Solar System”. ICARUS will not only advance our understanding of the plasma environment around our Sun, but also of the numerous magnetically active stars with hot plasma coronae. ICARUS I will perform the first direct in situ measurements of electromagnetic fields, particle acceleration, wave activity, energy distribution, and flows directly in the regions in which the solar wind emerges from the coronal plasma. ICARUS I will have a perihelion altitude of 1 solar radius and will cross the region where the major energy deposition occurs. The polar orbit of ICARUS I will enable crossing the regions where both the fast and slow winds are generated. It will probe the local characteristics of the plasma and provide unique information about the physical processes involved in the creation of the solar wind. ICARUS II will observe this region using remote-sensing instruments, providing simultaneous, contextual information about regions crossed by ICARUS I and the solar atmosphere below as observed by solar telescopes. It will thus provide bridges for understanding the magnetic links between the heliosphere and the solar atmosphere. Such information is crucial to our understanding of the plasma physics and electrodynamics of the solar atmosphere. ICARUS II will also play a very important relay role, enabling the radio-link with ICARUS I. It will receive, collect, and store information transmitted from ICARUS I during its closest approach to the Sun. It will also perform preliminary data processing before transmitting it to Earth. Performing such unique in situ observations in the area where presumably hazardous solar energetic particles are energized, ICARUS will provide fundamental advances in our capabilities to monitor and forecast the space radiation environment. Therefore, the results from the ICARUS mission will be extremely crucial for future space explorations, especially for long-term crewed space missions.

Solar wind↗
DOE OSTI2022

Modeling the Effect of the Interplanetary Magnetic Field on Cosmic Ray Muon Shadows

Cosmic ray (CR) muon shadows were located using muon data from the MINOS Far Detector in Northern Minnesota. The shadows were located independently across 3 time periods; near solar minimum, solar maximum, and over the entire 13 year span of the data. A muon distribution for each shadow was then sampled to simulate CR motions near the Sun using the Parker Spiral model of the Sun’s IMF and a dipole model of the Earth’s GMF. The resulting particle distributions were then compared to their position with respect to the Sun. An analytical relationship between the primary CR cutoff energy E0 and the associated shadow deflections was observed. The minimum cutoff energy of the primary CR energy spectrum consistent with the Parker Spiral model was determined to be $E_0 = 22.8 \pm 1.2$~TeV. This value is 2-3 times higher than the experimentally determined value. Complexities that can be added to the Parker Spiral Model and affect the overall shift of the the Sun’s cosmic ray shadow are discuss ed to explain discrepancies. Results show that the Parker Spiral model is most consistent with the the solar minimum shadow and least consistent with the solar maximum shadow, as expected.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2026

Modeling the Effect of the Heliospheric Magnetic Field on Cosmic Ray Muon Shadows

Shadows cast in the cosmic ray (CR) muon sky by the Sun were located using muon data from the MINOS far detector in Northern Minnesota. The shadows were observed independently across three time periods; near solar minimum, near solar maximum, and over the entire 13 year span of the data. A distribution of muon positions for each shadow was then sampled to simulate CR motions near the Sun using the Parker spiral model of the Heliospheric Magnetic Field (HMF) and a dipole model of the Geomagnetic Field (GMF). The resulting particle distributions were then compared to their position with respect to the Sun. Results show that the Parker spiral model is most consistent with the solar minimum shadow and least consistent with the solar maximum shadow, as expected. The simple Parker spiral is more consistent with the data for a harder CR spectrum than is actually present, indicating the need for a more detailed HMF model. Plausible modifications to the Parker spiral model which would affect the overall shift of the Sun's CR shadow are discussed.

Adamson, P. [Fermilab]↗
NASA NTRS2012

The Height of a White-Light Flare and its Hard X-Ray Sources

We describe observations of a white-light (WL) flare (SOL2011-02-24T07:35:00, M3.5) close to the limb of the Sun, from which we obtain estimates of the heights of the optical continuum sources and those of the associated hard X-ray (HXR) sources. For this purpose, we use HXR images from the Reuven Ramaty High Energy Spectroscopic Imager and optical images at 6173 Ang. from the Solar Dynamics Observatory.We find that the centroids of the impulsive-phase emissions in WL and HXRs (30 -80 keV) match closely in central distance (angular displacement from Sun center), within uncertainties of order 0".2. This directly implies a common source height for these radiations, strengthening the connection between visible flare continuum formation and the accelerated electrons. We also estimate the absolute heights of these emissions as vertical distances from Sun center. Such a direct estimation has not been done previously, to our knowledge. Using a simultaneous 195 Ang. image from the Solar-Terrestrial RElations Observatory spacecraft to identify the heliographic coordinates of the flare footpoints, we determine mean heights above the photosphere (as normally defined; tau = 1 at 5000 Ang.) of 305 +/- 170 km and 195 +/- 70 km, respectively, for the centroids of the HXR and WL footpoint sources of the flare. These heights are unexpectedly low in the atmosphere, and are consistent with the expected locations of tau = 1 for the 6173 Ang and the approx 40 keV photons observed, respectively.

Sun: photosphere↗
NASA NTRS2010

Characterization of MODIS Solar Diffuser On-Orbit Degradation

MODIS reflective solar bands (RSB) are calibrated using a solar diffuser (SD). The SD on-orbit degradation is determined by a solar diffuser stability monitor (SDSM) at 9 wavelengths from 0.41 to 0.94 microns via alternate observations of its sunlight reflected from the SD (SD view) and direct sunlight through an attenuation screen (Sun view). For each SDSM detector, a time series of ratios of its SD view to its Sun view responses tracks on-orbit changes in the SD bidirectional reflectance factor (BRF) at its wavelength. Due to an SDSM component design error, however, there exist large ripples in its Sun view responses, which have made it extremely difficult to use the original ratio approach for accurate characterization of SD on-orbit degradation. In order to mitigate the impact due to unexpected ripples, MODIS Characterization Support Team (MCST) developed a normalization approach. It relies on the fact that all SDSM detectors (D1 to D9) experience similar ripples and assumes that the SD degradation at its D9 wavelength (0.94 micron) is extremely small and can be ignored. As mission continues, the normalization approach becomes inadequate since the accumulated SD degradation at 0.94[tm can no longer be ignored. This paper presents a new approach to further improve on-orbit characterization of SD degradation. It uses a took-up table (LUT) with parameters derived from D9 observations made over a short period. Compared to other approaches, this approach can significantly reduce the impact due to ripples and that due to accumulated SD degradation at the reference detector wavelength.

Xiong, X.↗
NASA NTRS2012

Atmospheric Dust Modeling from Meso to Global Scales with the Online NMMB/BSC-Dust Model Part 2: Experimental Campaigns in Northern Africa

The new NMMB/BSC-Dust model is intended to provide short to medium-range weather and dust forecasts from regional to global scales. It is an online model in which the dust aerosol dynamics and physics are solved at each model time step. The companion paper (Perez et al., 2011) develops the dust model parameterizations and provides daily to annual evaluations of the model for its global and regional configurations. Modeled aerosol optical depth (AOD) was evaluated against AERONET Sun photometers over Northern Africa, Middle East and Europe with correlations around 0.6-0.7 on average without dust data assimilation. In this paper we analyze in detail the behavior of the model using data from the Saharan Mineral dUst experiment (SAMUM-1) in 2006 and the Bodele Dust Experiment (BoDEx) in 2005. AOD from satellites and Sun photometers, vertically resolved extinction coefficients from lidars and particle size distributions at the ground and in the troposphere are used, complemented by wind profile data and surface meteorological measurements. All simulations were performed at the regional scale for the Northern African domain at the expected operational horizontal resolution of 25 km. Model results for SAMUM-1 generally show good agreement with satellite data over the most active Saharan dust sources. The model reproduces the AOD from Sun photometers close to sources and after long-range transport, and the dust size spectra at different height levels. At this resolution, the model is not able to reproduce a large haboob that occurred during the campaign. Some deficiencies are found concerning the vertical dust distribution related to the representation of the mixing height in the atmospheric part of the model. For the BoDEx episode, we found the diurnal temperature cycle to be strongly dependant on the soil moisture, which is underestimated in the NCEP analysis used for model initialization. The low level jet (LLJ) and the dust AOD over the Bodélé are well reproduced. The remaining negative AOD bias (due to underestimated surface wind speeds) can be substantially reduced by decreasing the threshold friction velocity in the model.

photometers↗
NASA NTRS2015

Venus: The First Habitable World of Our Solar System?

A great deal of effort in the search for life off-Earth in the past 20+ years has focused on Mars via a plethora of space and ground based missions. While there is good evidence that surface liquid water existed on Mars in substantial quantities, it is not clear how long such water existed. Most studies point to this water existing billions of years ago. However,those familiar with the Faint Young Sun hypothesis for Earth will quickly realize that this problem is even more pronounced for Mars. In this context recent simulations have been completed with the GISS 3-D GCM (1) of paleo Venus (approx. 3 billion years ago) when the sun was approx. 25 less luminous than today. A combination of a less luminous Sun and a slow rotation rate reveal that Venus could have had conditions on its surface amenable to surface liquid water. Previous work has also provided bounds on how much water Venus could have had using measured DH ratios. It is possible that less assumptions have to be made to make Venus an early habitable world than have to be made for Mars, even thoughVenus is a much tougher world on which to confirm this hypothesis.

surface water↗
NASA NTRS2014

Aerosol Remote Sensing in Polar Regions

Multi-year sets of ground-based sun-photometer measurements conducted at 12 Arctic sites and 9 Antarctic sites were examined to determine daily mean values of aerosol optical thickness tau(lambda) at visible and near-infrared wavelengths, from which best-fit values of Ångström's exponent alpha were calculated. Analyzing these data, the monthly mean values of tau(0.50 micrometers) and alpha and the relative frequency histograms of the daily mean values of both parameters were determined for winter-spring and summer-autumn in the Arctic and for austral summer in Antarctica. The Arctic and Antarctic covariance plots of the seasonal median values of alpha versus tau(0.50 micrometers) showed: (i) a considerable increase in tau(0.50 micrometers) for the Arctic aerosol from summer to winter-spring, without marked changes in alpha; and (ii) a marked increase in tau(0.50 micrometer) passing from the Antarctic Plateau to coastal sites, whereas alpha decreased considerably due to the larger fraction of sea-salt aerosol. Good agreement was found when comparing ground-based sun-photometer measurements of tau(lambda) and alpha at Arctic and Antarctic coastal sites with Microtops measurements conducted during numerous AERONET/MAN cruises from 2006 to 2013 in three Arctic Ocean sectors and in coastal and off-shore regions of the Southern Atlantic, Pacific, and Indian Oceans, and the Antarctic Peninsula. Lidar measurements were also examined to characterize vertical profiles of the aerosol backscattering coefficient measured throughout the year at Ny-Ålesund. Satellite-based MODIS, MISR, and AATSR retrievals of tau(lambda) over large parts of the oceanic polar regions during spring and summer were in close agreement with ship-borne and coastal ground-based sun-photometer measurements. An overview of the chemical composition of mode particles is also presented, based on in-situ measurements at Arctic and Antarctic sites. Fourteen log-normal aerosol number size-distributions were defined to represent the average features of nuclei, accumulation and coarse mode particles for Arctic haze, summer background aerosol, Asian dust and boreal forest fire smoke, and for various background austral summer aerosol types at coastal and high-altitude Antarctic sites. The main columnar aerosol optical characteristics were determined for all 14 particle modes, based on in-situ measurements of the scattering and absorption coefficients. Diurnally averaged direct aerosol-induced radiative forcing and efficiency were calculated for a set of multimodal aerosol extinction models, using various Bidirectional Reflectance Distribution Function models over vegetation-covered, oceanic and snow-covered surfaces. These gave a reliable measure of the pronounced effects of aerosols on the radiation balance of the surface-atmosphere system over polar regions.

Sun-photometer measurements↗
NASA NTRS2016

Distance to the IBEX Ribbon Source Inferred From Parallax

Maps of energetic neutral atom (ENA) fluxes obtained from observations made by the Interstellar Boundary Explorer (IBEX) revealed a bright structure extending over the sky, subsequently dubbed the IBEX ribbon. The ribbon had not been expected from the existing models and theories prior to IBEX, and a number of mechanisms have since been proposed to explain the observations. In these mechanisms, the observed ENAs emerge from source plasmas located at different distances from the Sun. Since each part of the sky is observed by ibex TWICE DURING THE YEAR FROM OPPOSTIE SIDE OF THE Sun, the apparent position of the ribbon as observed in the sky is shifted due to parallax. To determine the ribbons parallax, we found the precise location of the maximum signal of the ribbon observed in each orbital arc. The apparent positions obtained were subsequently corrected for the Compton-Getting effect, gravitational deflection, and radiation pressure. Finally, we selected a part of the ribbon where its position is similar in the different IBEX ENERGY PASSBANDS. We compared the apparent positions obtained from the viewing locations on the opposite sides of the Sun, and found that they are shifted by a parallax angle of 0 41 0 15, which corresponds to a distance of AU. This finding supports models of the ribbon with the source located just outside the heliopause.

ISM: atoms↗
NASA NTRS1995

(abstract) Ulysses Orbit Determination at High Declinations

The trajectory of the Ulysses spacecraft carries it over the South polar region of the Sun in mid-1994, albeit at a great distance from the Sun itself. During this time the South Solar latitude of Ulysses' orbit reaches a maximum value of 80.2 degrees, and the geocentric declination reaches a magnitude of over 75 degrees. As a result, a number of unique and interesting events occur, not the least of which being that Ulysses never sets over the Canberra tracking station of the DSN for more than two months. A less obvious aspect of the Sun-spacecraft-Earth geometry during this time is the return of solar-induced nutation to the spin-stabilized Ulysses spacecraft, and the consequent use of active nutation control. Both of these events have significant implications for theory and practice of Ulysses' orbit determination during this period, which is the subject of the proposed paper.

orbit↗
NASA NTRS2023

Chapter Fourteen - Space Photovoltaics for Extreme High-Temperature Missions

Solar arrays in space are subjected to a daunting set of environmental hazards, including extreme temperature cycles, particulate and ultraviolet radiation in space, micrometeoroid damage, and exposure to a flux of atomic oxygen in low-Earth orbit. Over the years since the first solar cells were sent into space on Vanguard 1 in 1958, space solar array technology has advanced to develop photovoltaic materials, cells, and arrays resistant to these degradation mechanisms. This chapter highlights approaches to solar array design for near-Sun missions including thermal management at the systems level, to optimize efficiency at elevated temperature, or the use of novel device design to reduce the incident solar energy to limit operating temperature. Several of these have been successfully demonstrated to enable solar-powered spacecraft to explore the near-Sun planets such as Mercury and Venus as well as the Sun itself.

Space photooltaics↗
DOE OSTI2021

A transmissive concentrator photovoltaic module with cells directly cooled by silicone oil for solar cogeneration systems

Hybrid concentrator photovoltaic-thermal systems can cogenerate electricity and heat by beam-splitting incoming concentrated light onto photovoltaic cells and a thermal receiver to increase total conversion efficiency and potentially reduce system cost. To demonstrate this, we have designed and prototyped a transmissive spectrum-splitting concentrator photovoltaic module that maximizes solar energy conversion by utilizing the entire solar spectrum. Visible light is collected using infrared-transmissive triple-junction photovoltaic cells to achieve an in-band module efficiency of 43.3% for light of wavelength λ < 873 nm, while 44.2% of out-of-band light with λ > 873 nm is transmitted through for collection by a thermal receiver. During testing on a dual-axis tracked parabolic concentrator dish at up to 166 suns, cell temperatures were maintained at 119 °C or below via a novel active cooling method. This cooling system strictly flows silicone oil directly across both sides of the cells, without inhibiting optical transmission, as verified through experimentation and simulation. The module was validated outdoors for 572 sun·hrs, and achieved a maximum thermal receiver temperature of 180 °C. 86.1% of incident solar power is collected at 166 suns average concentration collectively among the electrical, cooling, and thermal receiver subsystems. The remaining 13.9% is lost to mirror reflectivity, dish shadowing, receiver reflection, and thermal losses. The ability to directly cool the cells with an inert silicone oil offers the potential for reduced system cost relative to previous transmissive hybrid concentrator photovoltaic-thermal systems, including microfluidic-cooled designs. This solar cogeneration capability is valuable in a wide range of commercial and industrial applications.

14 SOLAR ENERGY↗
DOE OSTI2025

Soil fertility management for sustainable Miscanthus × giganteus production: Increased tiller weight from nitrogen management explains yield gains in aged miscanthus

Aging-related yield decline in Miscanthus × giganteus (miscanthus) remains a major constraint to sustainable biomass production. This study evaluated how nitrogen (N) management and soil fertility influence yield-component traits and productivity in aging miscanthus. Trials were conducted at two sites established in 2008 at the University of Illinois Energy Farm, Urbana, IL. (i) The Sun Grant trial received 0, 60, and 120 kg N ha −1 annually until 2015. Starting 2021, half of each plot received 60 or 120 kg N ha −1 , resulting in six legacy-contemporary treatments: 0N–0N, 0N–120N, 60N–0N, 60N–60N, 120N–0N, 120N–120N. (ii) The Energy Farm trial remained unfertilized until 2014, when one half of each plot received 56 kg N ha −1 , forming two treatments: 0N–0N, 0N–56N. Sun Grant trial results showed N fertilization increased tiller density (tillers m −2 ) and tiller weight (g tiller −1 ) in juvenile to early-mature miscanthus (2011–2015). After N withdrawal, both traits declined (20 % and 40 %), though legacy effects persisted in tiller weight in the aging stands (2020–2023). Contemporary N had little effect on tiller density but increased tiller weight by 34 %–77 %, resulting in 23 %–106 % higher machine-harvested biomass yield in 0–120N, 60-60N, and 120-120N plots. At the Energy Farm trial, 0N–56N plots yielded 59 %–108 % more biomass than 0N–0N. Soil total N increased (Sun Grant: 47 % by 2020; Energy Farm: 58 % by 2023), while Mehlich-3 P (42 %–44 %) and K (21 %–46 %) declined. These findings identify tiller weight as a key determinant of biomass yield in aging miscanthus and highlight the need for P and K management for long-term productivity.

09 BIOMASS FUELS↗
DOE OSTI2023

Recycling the Energy of Indoor Light: Highly Efficient Organic Photovoltaics via a Ternary Strategy

A ternary approach in organic photovoltaics (OPV) is simple and reliable to effectively tune the optical, electrical and morphological properties of the photoactive layer for high efficiency as well as long-term stability under 1 sun. However, there have been few papers reporting spectra and weak illumination compared to outdoor light. In this study, by using two compatible 16 structures, we demonstrate a simultaneous modulation of light absorption and molecular donor polymers (PM7 and PM7 D1) with slightly-different band gaps and similar chemical packing under ambient conditions, which resulted in efficient indoor OPVs exhibiting power conversion efficiency (PCE) over 20% under 1000 lux of warm white light-emitting diode (2900 K). From morphological analysis, we infer that PM7 serves to seed nucleation of PM7 D1 in the ternary blend, templating its crystallization and alignment along the PM7 backbone. Such templating effect leads to increased domain spacing and relative degree of crystallinity (rDoC) compared to those of each binary system. We further show that higher rDoC helps suppress both bimolecular and trap-assisted recombination of photogenerated charges in the ternary devices. As a result, the complementary absorption and synergistic molecular assembly of the two donor polymers enhance the short-circuit current density as to increase the average PCEs from 9.6 to 10.3% under 1 sun and from 18.7 to 20.0% under 1000 lux. We envision that our strategy of incorporating both a planar and a flexible donor polymer with similar chemical structures can be generally applicable to attain a high performance ternary OPV under both 1 sun and indoor light.

14 SOLAR ENERGY↗