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At least 1,783 records · Page 99

Understanding aerosol–cloud interactions using a single-column model for a cold-air outbreak case during the ACTIVATE campaign

Marine boundary layer clouds play a critical role in Earth's energy balance. Their microphysical and radiative properties are highly impacted by ambient aerosols and dynamic forcings. In this study, we evaluate the representation of these clouds and related aerosol–cloud interaction processes in the single-column version of the E3SM climate model (SCM) against field measurements collected during the NASA ACTIVATE campaign over the western North Atlantic, as well as intercompare results with high-resolution process level models. We show that E3SM SCM reproduces the macrophysical properties of post-frontal boundary layer clouds in a cold-air outbreak (CAO) case well. However, it generates fewer but larger cloud droplets compared to aircraft measurements. Further sensitivity tests show that the underestimation of both aerosol number concentration and vertical velocity variance contributes to this bias. Aerosol–cloud interactions are examined by perturbing prescribed aerosol properties in E3SM SCM with fixed dynamics. Higher aerosol number concentration or hygroscopicity leads to more numerous but smaller cloud droplets, resulting in a stronger cooling via shortwave cloud forcing. This apparent Twomey effect is consistent with prior climate model studies. The cloud liquid water path shows a weakly positive relation with cloud droplet number concentration due to precipitation suppression. This weak aerosol effect on cloud macrophysics may be attributed to the dominant impact of strong dynamical forcing associated with the CAO. Our findings indicate that the SCM framework is a key tool to bridge the gap between climate models, process level models, and field observations to facilitate process level understanding.

54 ENVIRONMENTAL SCIENCES↗

Experimental evaluation of a 600 lbf spacecraft rocket engine.

Experimental results are presented for a long-duration-capability (1000-sec), space-storable, bipropellant liquid rocket motor burning fluorine/hydrazine or FLOX/monomethylhydrazine. The interrelationship between injected mixture ratio and the per cent film cooling on vacuum specific impulse performance and chamber heat transfer is given. Experimental sea level measurements are used to predict space vacuum performance based upon simplified JANNAF reference procedures. Dynamic combustion stability is demonstrated over a wide range of operating conditions. Analytical results of char penetration, erosion, and ablative wall temperature distributions are presented for prototype chamber designs.

Hoehn, F. W.↗

Study of the potential for improving the economics of hydrogen liquefaction through the use of centrifugal compressors and the addition of a heavy water plant

An approach to the liquefaction of hydrogen was developed which permits the application of standard centrifugal compressors in place of reciprocating machines. A second fluid, such as propane, is added to the hydrogen prior to compression to form a mixture having a molecular weight much greater than that of hydrogen alone, so that a standard centrifugal compressor can be used. After compression, the mixture is cooled to cryogenic temperature levels where the propane condenses out of the mixture and is separated as a liquid. Since a small amount of deuterium is produced during hydrogen liquefaction, the potential of recovering deuterium and selling it as a co-product was investigated. Deuterium, in the form of heavy water, can be used in certain nuclear reactors as a neutron moderator to reduce the neutron velocity and enhance the probability of neutron collision with uranium nucleii.

Baker, C. R.↗

Multimegawatt Nuclear Power System for Lunar Base Applications

A multimegawatt nuclear power system for lunar surface applications is presented. The design requirements were to produce 3 MWe on the Moon for an operational lifetime of 10 years without human intervention. The system uses an inert-gas-cooled fuel pin reactor as the heat source, a regenerative Brayton cycle as the power converter and a liquid droplet radiator as the thermal management system, and has a specific power of 66 W/kg.

B Trueblood↗

Augmentation of blood circulation to the fingers by warming distant body areas

Future activities in space will require greater periods of time in extreme environments in which the body periphery will be vulnerable to chilling. Maintaining the hands and fingers in comfortable conditions enhances finger flexibility and dexterity, and thus effects better work performance. We have evaluated the efficacy of promoting heat transfer and release by the extremities by increasing the blood flow to the periphery from more distant parts of the body. The experimental garment paradigm developed by the investigators was used to manipulate the temperature of different body areas. Six subjects, two females and four males, were evaluated in a stage-1 baseline condition, with the inlet temperature of the circulating water in the liquid cooling/warming garment (LCWG) at 33 degrees C. At stage 2 the total LCWG water inlet temperature was cooled to 8 degrees C, and at stage 3 the inlet water temperature in specific segments of the LCWG was warmed (according to protocol) to 45 degrees C, while the inlet temperature in the rest of the LCWG was maintained at 8 degrees C. The following four body-area-warming conditions were studied in separate sessions: (1) head, (2) upper torso/arm, (3) upper torso/arm/head, and (4) legs/feet. Skin temperature, heat flux and blood perfusion of the fingers, and subjective perception of thermal sensations and overall physical comfort were assessed. Finger temperature (T(fing)) analyses showed a statistically significant condition x stage interaction. Post-hoc comparisons (T(fing)) indicated that at stage 3, the upper torso/arm/head warming condition was significantly different from the head, upper torso/arm and legs/feet conditions, showing an increase in T(fing). There was a significant increase in blood perfusion in the fingers at stage 3 in all conditions. Subjective perception of hand warmth, and overall physical comfort level significantly increased in the stage 3 upper torso/arm/head condition. The findings indicate that physiological methods to enhance heat transfer by the blood to the periphery within protective clothing provide an additional tool for increasing total and local human comfort in extreme environments.

NASA Discipline Life Sciences Technologies↗

Optical Fiber Distributed Sensing Structural Health Monitoring (SHM) Strain Measurements Taken During Cryotank Y-Joint Test Article Load Cycling at Liquid Helium Temperatures

This paper outlines cryogenic Y-joint testing at Langley Research Center (LaRC) to validate the performance of optical fiber Bragg grating strain sensors for measuring strain at liquid helium temperature (-240 C). This testing also verified survivability of fiber sensors after experiencing 10 thermal cool-down, warm-up cycles and 400 limit load cycles. Graphite composite skins bonded to a honeycomb substrate in a sandwich configuration comprised the Y-joint specimens. To enable SHM of composite cryotanks for consideration to future spacecraft, a light-weight, durable monitoring technology is needed. The fiber optic distributed Bragg grating strain sensing system developed at LaRC is a viable substitute for conventional strain gauges which are not practical for SHM. This distributed sensing technology uses an Optical Frequency Domain Reflectometer (OFDR). This measurement approach has the advantage that it can measure hundreds of Bragg grating sensors per fiber and the sensors are all written at one frequency, greatly simplifying fiber manufacturing. Fiber optic strain measurements compared well to conventional strain gauge measurements obtained during these tests. These results demonstrated a high potential for a successful implementation of a SHM system incorporating LaRC's fiber optic sensing system on the composite cryotank and other future cryogenic applications.

Allison, Sidney G.↗

Cryogenic System for Interferometric Measurement of Dimensional Changes at 40 K: Design and Performance

This report describes the facility, experimental methods, characterizations, and uncertainty analysis of the Cryo Distortion Measurement Facility (CDMF) at the Goddard Space Flight Center (GSFC). This facility is designed to measure thermal distortions of structural elements as the temperature is lowered from 320K to below 40 K over multiple cycles, and is capable of unattended running and data logging. The first measurement is to be the change in length and any bending of composite tubes with Invar end-fittings. The CDMF includes a chamber that is efficiently cooled with two cryo-coolers (one single-stage and one two-stage) rather than with liquid cryogens. Five optical ports incorporate sapphire radiation shields - transparent to the interferometer - on each of two shrouds and a fused silica vacuum-port window. The change in length of composite tubes is monitored continuously with displacement-measuring interferometers; and the rotations, bending, and twisting are measured intermittently with theodolites and a surface-figure interferometer. Nickel-coated invar mirrors and attachment mechanisms were developed and qualified by test in the CDMF. The uncertainty in measurement of length change of 0.4 m tubes is currently estimated at 0.9 micrometers.

Blake, Peter↗

Method of Manufacturing a Humidity Sensing Material

A method is provided for manufacturing a humidity sensing material. Particles of a trivalent rare earth hydroxide or oxide (such as lanthanum hydroxide) are mixed with particles of barium oxide and titanium dioxide in specified proportions. The particle mixture is heated to generate a sintered mixture that is milled. The resulting milled particles are mixed with glass particles, an organic surfactant, a solvent, an organic vehicle, and an alkali hydroxide. The resulting liquid mixture is deposited as a layer thereof onto a substrate. The substrate and layer thereon are processed to remove liquid portions of the liquid mixture. Such liquid removal processing includes at least one cycle of heating the layer followed by a corresponding cycle of cooling the layer in a nitrogen atmosphere containing less than 25 parts per million of oxygen.

Rolin, Terry D.↗

Heat Transfer Measurements of NASA Liquid Kerosene/Oxygen Rotating Detonation Rocket Engine

The RDRE has been identified as a viable high performance propulsion system with numerous advantages over the state-of-the-art (SOA) liquid rocket engine. NASA has been investigating this combustion device for applications ranging from lander, upper stage, thruster, and hypersonics. All of the activities funded to date have been focused on closing major technology gaps preventing the RDRE from being used more broadly by industry. One of those gaps include the prediction and management of heat transfer to the walls from the extreme combustion environment. This work overviews the heat transfer measurements made using new and existing hardware. A liquid oxygen / liquid RP-1 RDRE was tested utilizing a calorimeter outer body and outer body nozzle extension. An actively cooled inner body with axial running cooling channels was also used. A bimetallic GRCop-42 / Monel K500 injector was developed and demonstrated to be a viable technology for RDRE environments. Trends in bulk heat loads are discussed along with a direct comparison to constant pressure theory predictions of wall heat transfer. The experimental data obtained in this investigation showed similar heat fluxes to constant pressure theory indicating deflagration may have dominated the flow field. Only a single detonation wave was observed in all tests which imparted a significant dynamic load (vibration) on the test article making measurement of combustor performances extremely challenging. Both accelerometer and load cell data corroborate the extreme G-forces measured. The single wave mode yielded relatively low performances compared with other hot fire test data sets available. This leads to the conclusion that a single detonation wave in this geometry is not sufficient for high performance. Wave multiplicity, or rather, a specific number of waves may yield higher performances.

Thomas Teasley↗

Method for removing a foulant from a gas stream without external refrigeration

A process for removing a foulant from a gas stream is disclosed. The gas stream, containing a foulant, is cooled across a first heat exchanger and a second heat exchanger, producing a solid foulant entrained in cryogenic liquid as a foulant slurry, and a foulant-depleted gas stream. The foulant-depleted gas stream is passed through a cryogenic turbine and a first separation vessel, producing a light gas stream and further solid foulant. The solid foulants are recovered by a combination of pressurization, melting, and distillation to produce a liquid foulant product. Heat is recovered from the various streams in the various heat exchangers and the melter.

Baxter, Larry↗

Monitoring of Liquid Metal Reactor Heater Zones with Recurrent Neural Network Learning of Temperature Time Series

Advanced high-temperature fluid reactors (ARs), such as sodium fast reactors (SFRs) and molten salt cooled reactors (MSCRs) utilize high-temperature fluids at ambient pressure. To melt the fluid during reactor startup and prevent fluid freezing during cooldown, the thermal–hydraulic systems of such ARs include heater zones consisting of specific heaters with controllers, temperature sensors, and thermal insulation. The failure of heater zones due to insulation material degradation or improper installation, resulting in parasitic heat losses, can lead to fluid freezing. The detection of faults using a heat-transfer model is difficult because of a lack of knowledge of the experimental details. Data-driven machine learning of heater zone temperature time series offers a viable alternative. In this study, we benchmarked the performance of recurrent neural networks (RNNs) in an analysis of heat-up transient temperature time series of heater zones installed on a liquid sodium vessel. The RNN models include long short-term memory (LSTM) and gated recurrent unit (GRU) networks, as well as their bi-directional variants, BiLSTM and BiGRU. Anomalous temperature points were designated using a percentile-based threshold applied to residual fluctuations in the detrended temperature time series. Additionally, the impact of the exponentially weighted moving average (EWMA) method on detection accuracy was examined. The RNN models’ performance was assessed using precision, recall, and F 1 score metrics. Results demonstrated that RNN models effectively detect anomalies in temperature time series with the best models for each heater zone achieving F 1 scores of over 93%. To explain the variations in RNN model performance across different heater zones, we used Kullback–Leibler (KL) divergence to quantify the relative entropy between training and testing data, and the Detrended Fluctuation Analysis (DFA) to assess long-range temporal correlations. For datasets with strong long-range correlations and minimal relative entropy between training and testing data, GRU is the best-performing model. When the data exhibits weaker long-term correlations and a significant relative entropy between training and testing distributions, BiGRU shows the best performance. For the data sets with intermediate values of both KL divergence and DFA, the best performance is obtained with LSTM and BiLSTM, respectively.

gated recurrent unit↗

Containerless Liquid to Solid Nucleation Pathways in Two Representative Grades of Commercially Available Zirconium

Experimental measurements were conducted to determine the solid metal nucleation pathways of radiatively cooling, molten zirconium spheres of two different commercially available purity grades in a high-vacuum, high-temperature electrostatic levitator. The ensemble distribution of maximum undercooling temperatures was interpreted using Poisson statistics to determine the temperature dependence of the solid metal nucleation rate. For a sample of nominally 99.95% pure zirconium, the results are consistent with heterogeneous solid metal nucleation either on static catalyst particles at least approx. 30 nm diameter or on a surface coating. For a sample of nominally 99% pure zirconium, however, it appears that heterogeneous solid metal nucleation occurred either on a polydispersion of approx. 10 nm (mean diameter) static catalyst particles or on dynamic catalyst particles that precipitated from a solution that became supersaturated as the melt cooled.

Rulison, A. J.↗

Containerless Liquid to Solid Nucleation Pathways in Two Representative Grades of Commercially Available Zirconium

Experimental measurements were conducted to determine the solid metal nucleation pathways of radiatively cooling, molten zirconium spheres of two different commercially available purity grades in a high-vacuum, high-temperature electrostatic levitator. The ensemble distribution of maximum undercooling temperatures was interpreted using Poisson statistics to determine the temperature dependence of the solid metal nucleation rate. For a sample of nominally 99.95% pure zirconium, the results are consistent with heterogeneous solid metal nucleation either on static catalyst particles at least ~30 nm diameter or on a surface coating. For a sample of nominally 99% pure zirconium, however, it appears that heterogeneous solid metal nucleation occurred either on a polydispersion of ~10 nm (mean diameter) static catalyst particles or on dynamic catalyst particles which precipitated from a solution which became supersaturated as the melt cooled. A quantitative analysis of the compositions of both samples suggests that the catalysts probably consisted of one or more of the following elements: niobium, molybdenum, hafnium, and oxygen.

containerless, nucleation, zirconium↗

Validation study of sodium pool fire modeling efforts in $\mathrm{MELCOR}$ and $\mathrm{SPHINCS}$ codes

Discharge of sodium coolant into containment from a sodium-cooled fast reactor vessel can occur in the event of a pipe leak or break. In this situation, some of the liquid sodium droplets discharged from the coolant system will react with oxygen in the air before reaching the containment. This phase of the event is normally termed the sodium spray fire phase. Unreacted sodium droplets pool on the containment floor where continued reaction with containment atmospheric oxygen occurs. This phase of the event is normally termed the sodium pool fire phase. Both phases of these sodium-oxygen reactions (or fires) are important to model because of the heat addition and aerosol generation that occur. Any fission products trapped in the sodium coolant may also be released during this progression of events, which if released from containment could pose a health risk to workers and the public. The paper describes progress of an international collaborative research in the area of the sodium fire modeling in the sodium-cooled fast reactors between the United States and Japan under the framework of the Civil Nuclear Energy Research and Development Working Group. In this collaboration between Sandia National Laboratories and Japan Atomic Energy Agency, the validation basis for and modeling capabilities of sodium spray and pool fires in MELCOR of Sandia National Laboratories and SPHINCS of Japan Atomic Energy Agency are being enhanced. Here this study documents MELCOR and SPHINCS sodium pool fire model validation exercises against the JAEA’s sodium pool fire experiments, F7-1 and F7-2. The proposed enhancement of the sodium pool fire models in MELCOR through addition of thermal hydraulic and sodium spreading models that enable a better representation of experimental results is also described.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Neutron Spin–Echo Studies of the Structural Relaxation of Network Liquid ZnCl 2 at the Structure Factor Primary Peak and Prepeak

Using neutron spin-echo spectroscopy, we studied the microscopic structural relaxation of a prototypical network ionic liquid ZnCl 2 at the structure factor primary peak and pre-peak. The results show that the relaxation at the primary peak is faster than the pre-peak and the activation energy is ≈33% higher. Stretched exponential relaxation is observed even at temperatures well above the melting point T m . Surprisingly, the stretching exponent shows a rapid increase upon cooling, especially at the primary peak, where it changes from stretched exponential to simple exponential on approaching T m . Furthermore, these results suggest that the appearance of glassy dynamics typical of the supercooled state even in the equilibrium liquid state of ZnCl 2 as well as the difference of activation energy at the two investigated length scales are related to the formation of network structure on cooling.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Vitrification of Hanford Tank 241-AP-101 Waste and Simulant

Hanford tank 241-AP-101 (referred to herein as AP-101) is the second Hanford radioactive tank waste planned to be processed and vitrified. A simulant version of AP 101 waste was formulated from the best-basis inventory (BBI) for the Hanford Tank 241-AP-101 liquid with an assumed target dilution of the waste from the BBI sodium molarity of 8.61 M to the desired 5.5 M Na. After the addition of glass-forming chemicals (GFCs), the simulant melter feed was processed in a non-radioactive, continuous laboratory-scale melter (CLSM) system. The AP-101 simulant melter feed was charged into the CLSM for 6.11 h of processing, which produced 6.55 kg of glass, for an average glass production rate of 2275 kg m 2 d -1 . Since there were no processing issues with the AP-101 simulant melter feed, AP-101 melter feed made with actual waste was then processed in a CLSM system built into a contamination area in a radioactive environment. The melting behavior characteristics appeared similar for both the simulant and waste melter feeds. The AP-101 waste melter feed was charged into the CLSM for 12.14 h of processing, which produced 8.75 kg of glass, for an average glass production rate of 1530 kg m 2 d -1 . During the AP-101 waste melter feed charging, the pump used to move the feed reached a maximum and it is believed that if the pump had a greater capacity, a greater average glass production rate could have been achieved. A constituent of interest present in low quantities in the AP-101 waste is 99 Tc or its non-radioactive surrogate, Re, added to the AP-101 simulant. Analysis for the quantities of 99 Tc and Re in the AP-101 glass product resulted in an average single-pass retention from the melter feed during relative chemical steady state of 55 ± 2 % for 99 Tc and 45 ± 2 % for Re. Compared to the processing of other melter feeds, the retention of 99 Tc in the AP-101 glass was greater than in both AP-107 and AP-105 glass, while the retention of Re in the AP-101 was less than in the AP-107 glass, but greater than in the AP-105 glass. A spike of I was added into the AP-101 melter feed that could be detected above the analysis detection limits. However, the iodine was only detectable above the ~6 ppm limit in one glass pour: the pour immediately following the burn off of the cold cap, where the I level reached ~30 ppm. This event was significant because the glass was poured immediately after burn off and thus it is presumed that the iodine had yet to volatilize from the glass melt while idling. It is recommended to perform future tests with I spikes at greater levels so that it can be detected in additional glass pours to determine if the expected 50 % retention of I used in the Kim et al. glass models can be confirmed. Offgas liquid samples were analyzed for acetonitrile, which was present at greater concentrations in CLSM liquids than in other scaled melter systems. This result was expected based on unique conditions with the CLSM system including a small plenum space leading to low residence time for offgas and the rapidity of offgas cooling upon exiting the CLSM vessel due to the location and environment. About 90 % of the total acetonitrile captured during both the AP-101 simulant and waste CLSM runs was found in the offgas condensate and demister liquids, thus it is recommended that only those liquids be sent for analysis if future testing to study the presence of acetonitrile in offgas products is desired.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Inhomogeneities of stratocumulus liquid water

There is a growing body of observational evidence on inhomogeneous cloud structure, most recently from the extensive measurements of the FIRE field program. Knowledge of cloud structure is important because it strongly influences the cloud radiative properties, one of the major factors in determining the global energy balance. Current atmospheric circulation models use plane-parallel radiation, so that the liquid water in each gridbox is assumed to be uniform, which gives an unrealistically large albedo. In reality cloud liquid water occupies only a subset of each gridbox, greatly reducing the mean albedo. If future climate models are to treat the hydrological cycle in a manner consistent with energy balance, a better treatment of cloud liquid is needed. FIRE concentrated upon two cloud types of special interest: cirrus and marine stratocumulus. Cirrus tend to be high and optically thin, thus reducing the effective radiative temperature without increasing the albedo significantly, leading to an enhanced greenhouse heating. In contrast, marine stratocumulus are low and optically thick, thus producing a large increase in reflected radiation with a small change in emitted radiation, giving a net cooling which could potentially mitigate the expected greenhouse warming. The FIRE measurements in California stratocumulus during June and July of 1987 show variations in cloud liquid water on all scales. Such variations are associated with inhomogeneous entrainment, in which entrained dry air, rather than mixing uniformly with cloudy air, remains intact in blobs of all sizes, which decay only slowly by invasion of cloudy air. Two important stratocumulus observations are described, followed by a simple fractal model which reproduces these properties, and finally, the model radiative properties are discussed.

Cahalan, Robert F.↗

Experimental modeling of jet-ring turbine disk cooling

The experimental facility and some early results are described from a current research program modeling turbine disk cooling with multiple impinging jets, such as employed on the Space Shuttle Main Engine oxygen turbopump. The study is designed to obtain detailed local convection heat transfer rates on specially constructed turbine disk models that employ either multiple cooling jet impingement near the disk outer radius from a jet ring, or alternatively, single entrance coolant supply into the center of the disk cavity. Jet impingement is an effective scheme for cooling of turbine disks at or near the blade attachment region, but the heat transfer mechanisms and merits relative to other schemes are not well understood. The present study employs two specially constructed full scale plastic model disks, contoured and plane, together with the corresponding stators. Local heat transfer rates are determined by a computer vision system from the response of thin liquid crystal coatings applied to the disk test faces. The present results indicate that multiple jet impingement directed at the blade attachment region results in higher cooling rates in that region than does the same flow supplied to the disk center, but this conclusion must be regarded as tentative.

Metzger, D. E.↗