Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “element”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,783 records · Page 99
All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

Substitution of Nd with other rare earth elements in melt spun Nd{sub 2}Fe{sub 14}B magnets

This is a contemporary study of rapidly quenched Nd{sub 1.6}X{sub 0.4}Fe{sub 14}B magnetic materials (where X= Nd, Y, Ce, La, Pr, Gd and Ho). A 20% substitution of the Nd component from Nd{sub 2}Fe{sub 14}B can bring about some commercial advantage. However, there will be some compromise to the magnetic performance. Light rare earth elements are definitely more abundant (Y, Ce, La) than the heavier rare earth elements, but when they are included in RE{sub 2}Fe{sub 14}B magnets they tend to lower magnetic performance and thermal stability. Substituting heavy rare earth elements (Gd, Ho) for Nd in Nd{sub 2}Fe{sub 14}B improves the thermal stability of magnets but causes a loss in magnet remanence.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2016

The investigation of ferromagnetic resonance linewidth in Ni{sub 80}Fe{sub 20} films with submicron rectangular elements

Patterned magnetic films with nano-scaled dots exhibit some special magnetic properties. In this paper, we investigate the in-plane shape anisotropy and the magnetization dynamic damping in permalloy (Ni{sub 80}Fe{sub 20}) arrays of submicron rectangular elements using ferromagnetic resonance (FMR). The FMR linewidth exhibits a dependence on the element size, and mainly comes from the contribution of the intrinsic damping. Also the contribution of two-magnon scattering plays an important role and is reduced with increasing aspect ratio. The damping coefficient decreases from 0.0129 to 0.0118 with the element length increasing from 300 nm to 1200 nm, and the theoretical calculation suggests that the change of damping results from the longitudinal and transverse interlayer spin current due to the spatially inhomogeneous magnetization dynamics.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Controlling ZnSe/GaAs interface properties: The role of elemental exposure and photon irradiation during growth initiation

Incorporating dissimilar semiconductors into a single platform can offer additional degrees of freedom for optoelectronic device design. However, bonding of elements with mixed valence at heterovalent interfaces often leads to defect formation and poor material quality. In this work, using ZnSe/GaAs as a model system, we investigate the use of above-bandgap photon irradiation in combination with elemental surface treatments as a route to modify the interface properties. We find that this approach produces large changes in the behavior of the interfaces. Specifically, treating the GaAs surface with light and a short exposure to Se flux results in strong excitonic emission from both layers and an abrupt interface between them. We propose that these improvements arise from controlled desorption of As atoms from the GaAs surface and the subsequent Se enrichment of the interface. In conclusion, these results suggest that illumination with above-bandgap photons and proper choice of elemental exposure prior to heterovalent epitaxial layer growth may aid the synthesis of heterovalent semiconductor heterostructures.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Cluster ion source for external injection and high capacity filling of light elements into the relativistic heavy ion collider electron beam ion source

An advanced Electron Beam Ion Source (EBIS) is the primary ion source to supply highly charged ion beams of different elements to the Relativistic Heavy Ion Collider (RHIC) and to the NASA Space Radiation Laboratory (NSRL). Intense beams of highly charged ions of various elements of the periodic table, ranging from helium to uranium, have been demonstrated since EBIS became operational in 2010. EBIS routinely provides ion beams to RHIC and NSRL quasisimultaneously with about 1 s switching time between different ion species. Such unique flexibility and rapid switching between ion species are based on external injection of singly charged ions into the EBIS trap either in “fast” or “slow” injection modes. At present, a Laser Ion Source (LIS) provides most of the ion species of solid materials using the “fast” injection mode into the EBIS trap and a Hollow Cathode Ion Source (HCIS) provides most of the ion species of gaseous elements using the “slow” injection mode into the EBIS trap. Gas injection into the EBIS trap is also possible and has been used but imposes some restrictions for the simultaneous generation of highly charged ions such as Au 32+ ions for RHIC and ions of gaseous species for NSRL. Because light ions have relatively high velocity inside the EBIS trap, efficient injection of hydrogen and helium ions and filling of the EBIS trap to high capacity is difficult from either LIS or HCIS. To overcome this restriction and enhance EBIS operational capability, we suggest injecting beams of hydrogen and helium cluster ions into the EBIS trap. Required parameters of cluster ion beam injection into the EBIS trap are estimated, and advantages of such an injection are highlighted. A cluster ion source with required high intensity is visible and will be designed, built, optimized, and tested.

43 PARTICLE ACCELERATORS↗
DOE OSTI2022

A new generation of effective core potentials from correlated and spin–orbit calculations: Selected heavy elements

We introduce new correlation consistent effective core potentials (ccECPs) for the elements I, Te, Bi, Ag, Au, Pd, Ir, Mo, and W with 4d, 5d, 6s, and 6p valence spaces. These ccECPs are given as a sum of spin-orbit averaged relativistic effective potential (AREP) and effective spin–orbit (SO) terms. The construction involves several steps with increasing refinements from more simple to fully correlated methods. The optimizations are carried out with objective functions that include weighted many-body atomic spectra, norm-conservation criteria, and SO splittings. Transferability tests involve molecular binding curves of corresponding hydride and oxide dimers. The constructed ccECPs are systematically better and in a few cases on par with previous effective core potential (ECP) tables on all tested criteria and provide a significant increase in accuracy for valence-only calculations with these elements. Our study confirms the importance of the AREP part in determining the overall quality of the ECP even in the presence of sizable spin–orbit effects. The subsequent quantum Monte Carlo calculations point out the importance of accurate trial wave functions that, in some cases (mid-series transition elements), require treatment well beyond a single-reference.

Wang, Guangming (ORCID:0000000231327925)↗
DOE OSTI2023

Downward quantum learning from element 118: Automated generation of Fermi–Löwdin orbitals for all atoms

A new algorithm based on a rigorous theorem and quantum data computationally mined from element 118 guarantees automated construction of initial Fermi–Löwdin-Orbital (FLO) starting points for all elements in the Periodic Table. It defines a means for constructing a small library of scalable FLOs for universal use in molecular and solid-state calculations. The method can be systematically improved for greater efficiency and for applications to excited states such as x-ray excitations and optically silent excitations. FLOs were introduced to recast the Perdew–Zunger self-interaction correction (PZSIC) into an explicit unitarily invariant form. The FLOs are generated from a set of N quasi-classical electron positions, referred to as Fermi-Orbital descriptors (FODs), and a set of N-orthonormal single-electron orbitals. FOD positions, when optimized, minimize the PZSIC total energy. However, creating sets of starting FODs that lead to a positive definite Fermi orbital overlap matrix has proven to be challenging for systems composed of open-shell atoms and ions. The proof herein guarantees the existence of a FLOSIC solution and further guarantees that if a solution for N electrons is found, it can be used to generate a minimum of N – 1 and a maximum of 2 N – 2 initial starting points for systems composed of a smaller number of electrons. As a result, applications to heavy and super-heavy atoms are presented. All starting solutions reported here were obtained from a solution for element 118, Oganesson.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Comparing the kinetics of ionized and neutral atoms from single and multi-element laser-produced plasmas

In this work, kinetics of ion and neutral atom emission features were compared for nanosecond laser-produced plasmas generated from several metal targets (i.e., Al, Ti, Zr, Nb, Ta) and an alloy containing all of these as principal alloying elements. Plasmas were produced by focusing 6 ns, 1064 nm pulses from an Nd:YAG laser on the targets of interest in a vacuum. A Faraday cup was used for collecting ion temporal features while spatially and temporally resolved emission spectroscopy was used for measuring the optical time of flight of various neutral atomic transitions. Our results highlight that most probable ion and atom velocities decay with increasing atomic mass. Trends for ions from the alloy target represent a weighted average where all ions contribute. For both ions and atoms, velocities decrease with increasing heat of vaporization and melting temperature, consistent with the thermal mechanisms that contribute to nanosecond laser ablation. Kinetic energies for neutral atoms from pure metal targets have some variability with atomic mass, whereas kinetic energies for atoms from the alloy target are more similar. These more similar kinetic energies observed for neutral atoms in the multi-element plasma may be attributed to collisions between species from all elements in the Knudsen layer.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

Characterization of superconducting through-silicon vias as capacitive elements in quantum circuits

The large physical size of superconducting qubits and their associated on-chip control structures presents a practical challenge toward building a large-scale quantum computer. In particular, transmons require a high-quality-factor shunting capacitance that is typically achieved by using a large coplanar capacitor. Other components, such as superconducting microwave resonators used for qubit state readout, are typically constructed from coplanar waveguides, which are millimeters in length. Here, we use compact superconducting through-silicon vias to realize lumped-element capacitors in both qubits and readout resonators to significantly reduce the on-chip footprint of both of these circuit elements. We measure two types of devices to show that through-silicon vias are of sufficient quality to be used as capacitive circuit elements and provide a significant reduction in size over existing approaches.

Physics↗
DOE OSTI2024

A new generation of effective core potentials: Selected lanthanides and heavy elements

Here, we construct correlation-consistent effective core potentials (ccECPs) for a selected set of heavy atoms and ƒ-elements that are of significant current interest in materials and chemical applications, including Y, Zr, Nb, Rh, Ta, Re, Pt, Gd, and Tb. As is customary, ccECPs consist of spin orbit averaged relativistic effective potential (AREP) and effective spin-orbit (SO) terms. For the AREP part, our constructions are carried out within a relativistic coupled-cluster framework while also taking into account objective function one-particle characteristics for improved convergence in optimizations. The transferability is adjusted using binding curves of hydride and oxide molecules. We address the difficulties encountered with ƒ-elements, such as the presence of large cores and multiple near-degeneracies of excited levels. For these elements, we construct ccECPs with core valence partitioning that includes 4ƒ-subshell in the valence space. The developed ccECPs achieve an excellent balance between accuracy, size of the valence space, and transferability and are also suitable to be used in plane wave codes with reasonable energy cutoffs.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Violation of the Cauchy–Born rule in multi-principal element alloys

Multi-principal element alloys are a novel class of materials that are formed by combining multiple elements in high concentrations and show exceptional properties compared to conventional alloys. These alloys have high configurational entropy due to inherent atomic disorder. The Cauchy–Born rule is a popular homogenization method for linking atomistic to continuum length scales. In this Letter, we use ab initio density functional theory calculations to report that the Cauchy–Born rule, which holds in conventional alloys in the absence of defects, is not valid in multi-principal element alloys. Further, the violation of the Cauchy–Born rule in these alloys is attributed to the presence of atomic disorder due to which the deformations are inhomogeneous. Our results also show the deviations in deformation are related to the magnitude of the stretch and shear by power laws.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Thin-rod active elements for amplification of femtosecond pulses

To study the possibility of amplifying the radiation of femtosecond fibre lasers in thin-rod active elements, amplifying modules based on thin rods made of broadband Yb : CaF{sub 2} and Yb : Y{sub 2}O{sub 3} materials are developed. It is shown that the gain in Yb : YAG and Yb : Y{sub 2}O{sub 3} elements is limited because only part of the broadband signal is amplified, while amplification in Yb : CaF{sub 2} elements occurs in a wider spectral range but is weak due to a small emission cross section. Amplification from submicrojuole to submillijoule level in the regenerative amplification regime is demonstrated. The new broadband Yb : CaF{sub 2} and Yb : Y{sub 2}O{sub 3} materials can amplify radiation with a considerably broader spectrum than Yb : YAG. (paper)

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2020

Diffractive optical elements for multiplexing structured laser beams

We consider methods for obtaining a multitude of structured laser beams (multiplexing) from an illuminating beam (both structured and unstructured) with the help of diffractive optical elements (DOEs). An approach of ‘intelligent multiplexing’ is proposed to describe and develop the methods. A DOE is calculated that forms a set of five diffraction orders located in a line. An example of focusing a set of doughnut-shaped azimuthally polarised laser beams using a diffraction beam splitter is presented. Efficient multiplexing of first-order vortex beams in a two-dimensional region is implemented by a two-dimensional diffraction grating. An approach is proposed and realised in which the transmission functions of a two-dimensional diffraction beam splitter and the elements forming structured laser beams with specified parameters are combined into the transmission function of one element. Such DOEs can be used in optical communication systems for encoding and decoding data. The possibility of using binary curved fork-shaped gratings for the formation of doughnut-shaped three-dimensional vortex beams, which are detected outside the focal plane, is demonstrated. This approach provides additional advantages for safe data transmission; it can be used in laser processing of materials and in laser manipulation applications. (paper)

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2013

Systems of elements preserving measure on varieties of groups

It is proved that for any l, 1≤l≤r, a system of elements (v{sub 1},…,v{sub l}) of a free metabelian group S of rank r≥2 is primitive if and only if it preserves measure on the variety of metabelian groups A{sup 2}. From this we obtain the result that a system of elements (v{sub 1},…,v{sub l}) is primitive in the group S if and only if it is primitive in its profinite completion S-hat . Furthermore, it is proved that there exist a variety M and a nonprimitive element v∈F{sub r}(M) such that v preserves measure on M. Bibliography: 13 titles.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2020

The uncharacterized gene EVE contributes to vessel element dimensions in Populus

The radiation of angiosperms led to the emergence of the vast majority of today’s plant species and all our major food crops. Their extraordinary diversification occurred in conjunction with the evolution of a more efficient vascular system for the transport of water, composed of vessel elements. The physical dimensions of these water-conducting specialized cells have played a critical role in angiosperm evolution; they determine resistance to water flow, influence photosynthesis rate, and contribute to plant stature. However, the genetic factors that determine their dimensions are unclear. Here we show that a previously uncharacterized gene, ENLARGED VESSEL ELEMENT ( EVE ) , contributes to the dimensions of vessel elements in Populus , impacting hydraulic conductivity. Our data suggest that EVE is localized in the plasma membrane and is involved in potassium uptake of differentiating xylem cells during vessel development. In plants, EVE first emerged in streptophyte algae, but expanded dramatically among vessel-containing angiosperms. The phylogeny, structure and composition of EVE indicates that it may have been involved in an ancient horizontal gene-transfer event.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2013

The TRUSPEAK Concept: Combining CMPO and HDEHP for Separating Trivalent Lanthanides from the Transuranic Elements

Combining octyl(phenyl)-N,N-diisobutyl-carbamoylmethyl-phosphine oxide (CMPO) and bis-(2-ethylhexyl) phosphoric acid (HDEHP) into a single process solvent for separating transuranic elements from liquid high-level waste is explored. Co-extraction of americium and the lanthanide elements from nitric acid solution is possible with a solvent mixture consisting of 0.1-M CMPO plus 1-M HDEHP in n-dodecane. Switching the aqueous-phase chemistry to a citrate-buffered solution of diethylene triamine pentaacetic acid (DTPA) allows for selective stripping of americium, separating it from the lanthanide elements. Potential strategies for managing molybdenum and zirconium (both of which co-extract with americium and the lanthanides) have been developed. The work presented here demonstrates the feasibility of combining CMPO and HDEHP into a single extraction solvent for recovering americium from high-level waste and its separation from the lanthanides.

actinide separation↗
DOE OSTI2019

Elemental Characterization of Neutron-Irradiated Tungsten Using the GD-OES Technique

In reactor-relevant fusion divertor conditions, tungsten (W) will be used as an armor material due to its excellent thermal properties. It will be exposed to impurities from numerous sources, including ion implantation and mixing, neutron transmutation, low-Z plasma-facing-component (PFC) redeposition and codeposition of deuterium and tritium fuel, and trapped helium bubbles. The impurity plasma material–interaction effects are a concern because they can cause gradual degradation of the material and of plasma performance due to dust formation, fuel retention, and even changes to the thermal and mechanical properties of the W armor. It is crucial to measure the amount of impurities in W, and the glow discharge–optical emission spectroscopy (GD-OES) technique is exceptionally well suited for analysis of irradiated samples. GD-OES can measure a sample’s elemental composition by sputtering the surface of the sample, ionizing the eroded material, and measuring the optical emission of the excited atoms. In order for the GD-OES technique to be applied to neutron-irradiated tungsten samples, a mounting system for miniature samples was designed. The sample mounting and centering procedure was successful in measuring the depth distribution of control W and W alloy sample elemental concentrations. These control depth spectra will be used as elemental references for postirradiated samples. The residence time of surface layers was measured, a comparison of signals from different anodes was completed, and the influence of initial surface roughness or nonuniformity was understood. The depth distribution of an arc-welded W-0.4% rhenium (Re) alloy was measured to have a stable Re signal that was distributed evenly in the W matrix. Here, the methods developed here will allow for quantification of impurities and transmutation amounts in neutron-irradiated W. GD-OES is a powerful tool but requires calibration and careful optimization of the parameters to obtain meaningful results.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2014

Diffusion of magnetic elements in a supergranular cell

Small scale magnetic fields (magnetic elements) are ubiquitous in the solar photosphere. Their interaction can provide energy to the upper atmospheric layers, and contribute to heat the solar corona. In this work, the dynamic properties of magnetic elements in the quiet Sun are investigated. The high number of magnetic elements detected in a supergranular cell allowed us to compute their displacement spectrum ((Δr){sup 2})∝τ{sup γ} (with γ > 0, and τ the time since the first detection), separating the contribution of the network (NW) and the internetwork (IN) regions. In particular, we found γ = 1.27 ± 0.05 and γ = 1.08 ± 0.11 in NW (at smaller and larger scales, respectively), and γ = 1.44 ± 0.08 in IN. These results are discussed in light of the literature on the topic, as well as the implications for the build-up of the magnetic network.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2014

Five-minute oscillation power within magnetic elements in the solar atmosphere

It has long been known that magnetic plage and sunspots are regions in which the power of acoustic waves is reduced within the photospheric layers. Recent observations now suggest that this suppression of power extends into the low chromosphere and is also present in small magnetic elements far from active regions. In this paper we investigate the observed power suppression in plage and magnetic elements, by modeling each as a collection of vertically aligned magnetic fibrils and presuming that the velocity within each fibril is the response to buffeting by incident p modes in the surrounding field-free atmosphere. We restrict our attention to modeling observations made near the solar disk center, where the line-of-sight velocity is nearly vertical and hence, only the longitudinal component of the motion within the fibril contributes. Therefore, we only consider the excitation of axisymmetric sausage waves and ignore kink oscillations as their motions are primarily horizontal. We compare the vertical motion within the fibril with the vertical motion of the incident p mode by constructing the ratio of their powers. In agreement with observational measurements we find that the total power is suppressed within strong magnetic elements for frequencies below the acoustic cut-off frequency. However, further physical effects need to be examined for understanding the observed power ratios for stronger magnetic field strengths and higher frequencies. We also find that the magnitude of the power deficit increases with the height above the photosphere at which the measurement is made. Furthermore, we argue that the area of the solar disk over which the power suppression extends increases as a function of height.

79 ASTRONOMY AND ASTROPHYSICS↗