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At least 1,783 records · Page 99

Transport and optical properties of the chiral semiconductor Ag 3 AuSe 2

Previous band structure calculations predicted Ag 3 AuSe 2 to be a semiconductor with a band gap of approximately 1 eV. Here, we report single crystal growth of Ag 3 AuSe 2 and its transport and optical properties. Single crystals of Ag 3 AuSe 2 were synthesized by slow-cooling from the melt, and grain sizes were confirmed to be greater than 2 mm using electron backscatter diffraction. Optical and transport measurements reveal that Ag 3 AuSe 2 is a highly resistive semiconductor with a band gap and activation energy around 0.3 eV. Our first-principles calculations show that the experimentally determined band gap lies between the predicted band gaps from GGA and hybrid functionals. We predict band inversion to be possible by applying tensile strain. The sensitivity of the gap to Ag/Au ordering, chemical substitution, and heat treatment merit further investigation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Morphology evolution of γ′ precipitates in a powder metallurgy Ni-base superalloy

Highlights: • The 3-D morphology of the γ′ precipitate for the Ni-base superalloy was characterized using the electronic etching. • Various morphologies of the γ′ precipitates, including cuboids, octet and dendritic shape, were observed. • Cooling rate has a significant influence on the morphology of the γ′ precipitate. • When the cooling rate was lower than 6 °C/min, the dendritic shape γ′ with eight-primary-branch pattern was observed. - Abstract: Effect of the cooling rate on the morphological evolution of the γ′ precipitate in a powder metallurgy Ni-base superalloy FGH96 was studied. Results showed that as the cooling rate decreased from 600 °C/min to 2 °C/min, the precipitate morphology transformed from sphere to cuboid, octet and dendrite. As the cooling rate increased, the mean size of the γ′ precipitates decreased while the nucleation density increased. When the cooling rate was lower than 6 °C/min, the precipitate would evolve from a sphere to cuboids with concave faces, octets, dendrite to final split-off branches. The morphological transition was driven by energy balance between coherent strain induced by the γ′/γ lattice misfit and interface energy. The dendritic shape γ′ exhibited an eight-primary-branch pattern with preferred growth direction along <111>, and secondary arms along <100>.

36 MATERIALS SCIENCE↗

Temperature dependence of the photo-induced inverse spin Hall effect in Au/InP hybrid structures

Photo-induced Inverse Spin Hall Effect (ISHE) measurements on Au/InP hybrid structures are performed over a temperature range of 45 to 300 K. Dependence of the spin current density on the degree of circular polarization and also on the angle of incidence of laser beam confirms the ISHE origin of measured signal. The magnitude of ISHE increases with sample cooling. A numerical model based on the spin relaxation of non-equilibrium spin-polarized electrons is proposed for predicting the temperature dependence of ISHE. Our results indicate that the proposed device can be used as a spin photodetector over a wide temperature range.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Study of the water dynamics near hydrophilic, nanostructured CuO surfaces by quasielastic and inelastic neutron scattering

We have used quasielastic and inelastic neutron scattering to investigate the structure, dynamics, and phase transitions of water interacting with superhydrophilic CuO surfaces that not only possess a strong affinity for water but also a “grass-like” topography that is rough on both micro- and nanoscales. Here, we report quasielastic neutron scattering (QENS) measurements on two samples differing in water content at five temperatures below 280 K. The QENS spectra show water undergoing two different types of diffusive motion near the CuO surfaces: a “slow” translational diffusion occurring on a nanosecond time scale and a faster rotational motion. Further from the surfaces, there is “fast” translational diffusion comparable in rate to that of bulk supercooled water and the rotational motion occurring in the interfacial water. Analysis of the QENS spectra supports wetting of water to the CuO blades as seen in electron microscopy images. In addition, we observe an anomalous temperature dependence of the QENS spectra on cooling from 270 to 230 K with features consistent with a liquid–liquid phase transition. We suggest that the solvent-like properties of the coexisting bulk-like water in our CuO samples are a significant factor in determining the temperature dependence of the interfacial water’s dynamics. Our results are compared with those obtained from two well-studied substrate classes: (1) silicas that contain ordered cylindrical nanopores but have weaker hydrophilicity and (2) nanoparticles of other transition-metal oxides, such as TiO 2 , which share the strong hydrophilicity of our samples but lack their porosity.

36 MATERIALS SCIENCE↗

CORONAL LOOP OSCILLATIONS OBSERVED WITH ATMOSPHERIC IMAGING ASSEMBLY-KINK MODE WITH CROSS-SECTIONAL AND DENSITY OSCILLATIONS

A detailed analysis of a coronal loop oscillation event is presented, using data from the Atmospheric Imaging Assembly on board the Solar Dynamics Observatory (SDO) for the first time. The loop oscillation event occurred on 2010 October 16, 19:05-19:35 UT and was triggered by an M2.9 GOES-class flare, located inside a highly inclined cone of a narrow-angle coronal mass ejection. This oscillation event had a number of unusual features: (1) excitation of kink-mode oscillations in vertical polarization (in the loop plane), (2) coupled cross-sectional and density oscillations with identical periods, (3) no detectable kink amplitude damping over the observed duration of four kink-mode periods (P=6.3 minutes), (4) multi-loop oscillations with slightly ({approx}10%) different periods, and (5) a relatively cool loop temperature of T {approx} 0.5 MK. We employ a novel method of deriving the electron density ratio external and internal to the oscillating loop from the ratio of Alfvenic speeds deduced from the flare trigger delay and the kink-mode period, i.e., n{sub e} /n{sub i} = (v{sub A} /v{sub Ae}){sup 2} = 0.08 {+-} 0.01. The coupling of the kink mode and cross-sectional oscillations can be explained as a consequence of the loop length variation in the vertical polarization mode. We determine the exact footpoint locations and loop length with stereoscopic triangulation using STEREO/EUVI/A data. We model the magnetic field in the oscillating loop using Helioseismic and Magnetic Imager/SDO magnetogram data and a potential-field model and find agreement with the seismological value of the magnetic field, B{sub kink} = 4.0 {+-} 0.7 G, within a factor of two.

79 ASTRONOMY AND ASTROPHYSICS↗

Tungsten control in long pulse operation: feedback from WEST to ITER

The full W environment that is now foreseen for ITER puts strong emphasis on experimental results obtained in present devices in similar conditions. In this context, the WEST tokamak is well equipped to bring key contributions to the preparation of ITER operation, thanks to its capability to perform long pulses in dominant electron heating, torque-free scheme based on RF systems, and its ITER-grade actively cooled divertor. Recent results of interest cover the understanding of tungsten contamination and the evaluation of conditioning methods, the feedback on the current ramp-up phase, and the ageing of the ITER divertor components in L-mode attached condition. Further, new directions are being explored, in particular low divertor temperature operation that should be the normal operating regime of ITER. We also report on tungsten peaking physics, and the role of light impurity content.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

X-ray Diffuse Scattering Study of Local Distortions in Fe{1plusx}Te Induced by Excess Fe

We report x-ray diffuse scattering studies of the iron chalcogenide Fe{sub 1+x}Te as a function of doping and temperature for x = 0.03, 0.08, and 0.12. In all cases, remarkably strong, characteristic diffuse scattering is observed. This scattering extends throughout the Brillouin zone and exhibits a nonmonotonic decay away from the fundamental Bragg peaks, with a peaklike structure at a reduced q {approx} (0.3,0,0.6). We interpret this scattering as Huang diffuse scattering resulting from distortions induced by the interaction between the excess Fe and the FeTe layers. The form of the scattering indicates that this interaction is strong and extends a number of unit cells away from the interstitial Fe site. Further, the diffuse scattering shows a sudden decrease on cooling through the structural and magnetic phase transition, reflecting the first-order change of the electronic structure of FeTe.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Ferromagnetic domain behavior and phase transition in bilayer manganites investigated at the nanoscale

Understanding the underlying mechanism and phenomenology of colossal magnetoresistance in manganites has largely focused on atomic and nanoscale physics such as double exchange, phase separation, and charge order. Here in this article, we consider a more macroscopic view of manganite materials physics, reporting on the ferromagnetic domain behavior in a bilayer manganite sample with a nominal composition of La 2-2x Sr 1+2x Mn 2 O 7 with x = 0:38, studied using in-situ Lorentz transmission electron microscopy. The role of magnetocrystalline anisotropy on the structure of domain walls was elucidated. On cooling, magnetic domain contrast was seen to appear first at the Curie temperature within the a - b plane. With further reduction in temperature, the change in area fraction of magnetic domains was used to estimate the critical exponent describing the ferromagntic phase transition. Lastly, the ferromagnetic phase transition was accompanied by a distinctive nanoscale granular contrast close to the Curie temperature, which we infer to be related to the presence of ferromagnetic nanoclusters in a paramagnetic matrix, which has not yet been reported in bilayer manganites.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Hybrid-Electric Turbocharger and High-Speed SiC Variable-Frequency Drive Using Sensorless Control Algorithm

Electrically assisted engine boosting systems lend themselves to better throttle response, wider effective operating ranges, and can provide the ability to extract excess energy during deceleration and high-load events (and store it in a vehicle's onboard batteries). This can lead to better overall vehicle performance, emissions, and efficiency while allowing for further engine downsizing and increased power density. In this research effort, a hybrid-electric turbocharger, variable-frequency drive (VFD), and novel sensorless control algorithm were developed. An 11 kW permanent-magnet (PM) machine was coupled to a commercial turbocharger via an in-line, bolt-on housing attached to the compressor inlet. A high-efficiency, high-temperature VFD, consisting of custom control and power electronics, was also developed. The VFD uses SiC MOSFETS to achieve high-switching frequency and can be cooled using an existing engine coolant loop operating at up to 105 °C at an efficiency greater than 98%. A digital sliding mode-observer sensorless speed control algorithm was created to command and regulate speed and achieved ramp rates of over 68,000 rpm/s. A two-machine benchtop motor/generator test stand was constructed for initial testing and tuning of the VFD and sensorless control algorithm. A gas blow-down test stand was constructed to test the mechanical operation of the hybrid-electric turbocharger and speed control using the VFD. In addition, a liquid-pump cart was assembled for high-temperature testing of the VFD. Initial on-engine testing is planned for later this year. This paper intends to present a design overview of the in-line, hybrid-electric device, VFD, and performance characterization of the electronics and sensorless control algorithm.

Engineering↗

Micro-Bubble Experiments at the Van de Graaff Accelerator

In order to test and verify the experimental designs at the linear accelerator (LINAC), several micro-scale bubble ("micro-bubble") experiments were conducted with the 3-MeV Van de Graaff (VDG) electron accelerator. The experimental setups included a square quartz tube, sodium bisulfate solution with different concentrations, cooling coils, gas chromatography (GC) system, raster magnets, and two high-resolution cameras that were controlled by a LabVIEW program. Different beam currents were applied in the VDG irradiation. Bubble generation (radiolysis), thermal expansion, thermal convection, and radiation damage were observed in the experiments. Photographs, videos, and gas formation (O 2 + H 2 ) data were collected. The micro-bubble experiments at VDG indicate that the design of the full-scale bubble experiments at the LINAC is reasonable.

43 PARTICLE ACCELERATORS↗

Constituent Redistribution in U-Zr Metallic Fuel Using the Advanced Fuel Performance Code BISON

Previous work done by Galloway, et. al. on EBR-II ternary (U-Pu-Zr) fuel constituent redistribution yielded accurate simulation data for the limited data sets of Zr redistribution. The data sets included EPMA scans of two different irradiated rods. First, T179, which was irradiated to 1.9 at% burnup, was analyzed. Second, DP16, which was irradiated to 11 at% burnup, was analyzed. One set of parameters that most accurately represented the zirconium profiles for both experiments was determined. Since the binary fuel (U-Zr) has previously been used as the driver fuel for sodium fast reactors (SFR) as well as being the likely driver fuel if a new SFR is constructed, this same process has been initiated on the binary fuel form. From limited binary EPMA scans as well as other fuel characterization techniques, it has been observed that zirconium redistribution also occurs in the binary fuel, albeit at a reduced rate compared to observation in the ternary fuel, as noted by Kim et. al. While the rate of redistribution has been observed to be slower, numerous metallographs of U-Zr fuel show distinct zone formations.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Results of thermal test of metallic molybdenum disk target and fast-acting valve testing

This report describes the irradiation conditions for thermal testing of helium-cooled metallic disk targets that was conducted on March 9, 2016, at the Argonne National Laboratory electron linac. The four disks in this irradiation were pressed and sintered by Oak Ridge National Laboratory from molybdenum metal powder. Two of those disks were instrumented with thermocouples. Also reported are results of testing a fast-acting-valve system, which was designed to protect the accelerator in case of a target-window failure.

36 MATERIALS SCIENCE↗

Hot ion plasma production in HIP-1 using water-cooled hollow cathodes

A steady-state ExB plasma was formed by applying a strong radially inward dc electric field near the mirror throats. Most of the results were for hydrogen, but deuterium and helium plasmas were also studied. Three water-cooled hollow cathodes were operated in the hot-ion plasma mode with the following results: (1) thermally emitting cathodes were not required to achieve the hot-ion mode; (2) steady-state operation (several minutes) was attained; (3) input powers greater than 40 kW were achieved; (4) cathode outside diameters were increased from 1.2 cm (uncooled) to 4.4 cm (water-cooled); (5) steady-state hydrogen plasma with ion temperatures from 185 to 770 eV and electron temperatures from 5 to 21 eV were produced. Scaling relations were empirically obtained for discharge current, ion temperature, electron temperature, and relative ion density as a function of hydrogen gas feed rate, magnetic field, and cathode voltage. Neutrons were produced from deuterium plasma, but it was not established whether thay came from the plasma volume or from the electrode surfaces.

Reinmann, J. J.↗

Hot ion plasma production in HIP-1 using water-cooled hollow cathodes

The paper reports on hot-ion plasma experiments conducted in a magnetic mirror facility. A steady-state E x B plasma was formed by applying a strong radially inward dc electric field near the mirror throats. Most of the results were for hydrogen, but deuterium and helium plasmas were also studied. Three water-cooled hollow cathodes were operated in the hot-ion plasma mode with the following results: (1) thermally emitting cathodes were not required to achieve the hot-ion mode; (2) steady-state operation (several minutes) was attained; (3) input powers greater than 40 kW were achieved; (4) cathode outside diameters were increased from 1.2 cm (uncooled) to 4.4 cm (water-cooled); (5) steady-state hydrogen plasmas with ion temperatures from 185 to 770 eV and electron temperatures from 5 to 21 eV were produced. Scaling relations were empirically obtained for discharge current, ion temperature, electron temperature, and relative ion density as a function of hydrogen gas feed rate, magnetic field, and cathode voltage.

Reinmann, J. J.↗

The plasma line revisited as an aeronomical diagnostic - Suprathermal electrons, solar EUV, electron-gas thermal balance

Spectra of plasma wave intensities in the ionosphere over Arecibo are calculated and compared with those from observations of the plasma line intensity. This approach involving directly observed quantities avoids the uncertainties that have plagued past comparisons with photoelectron theory. In addition, careful comparisons in physically relevant segments of the spectra show that any significant increase in the magnitude of the solar EUV flux would lead to a contradiction of the observed plasma wave intensities. Further, the comparisons indicate that resolution of the thermal electron-gas heat balance problem must be sought through better heat transfer rates (e.g., heating and cooling rates, etc.), rather than in the solar EUV. This approach utilizes more fully the potential of the plasma line experiment as a diagnostic tool for aeronomical studies, (e.g., photoelectrons, auroral secondaries, ionosphere-modification experiments, etc.).

Carlson, H. C., Jr.↗

Space shuttle main engine digital controller

The controller provides responsive control of engine thrust and mixture ratio through the digital computer in the controller, updating the instructions to the engine control elements 50 times per second (every 20 milliseconds). Additionally, precise engine performance is achieved through closed loop control, utilizing 16 bit computation, 10 bit input/output resolution, and self calibrating analog-to-digital conversion. Engine reliability is enhanced by a dual redundant control system that allows normal operation after the first failure and a fail-safe shutdown after a second failure. The digital computer is programmable, allowing modification of engine control equations and constants by change of the stored program (software). The controller is packaged in a sealed, pressurized chassis with cooling provided by convection heat transfer through pin fins as part of the main chassis. The electronics are distributed on functional modules having special provisions for thermal and vibrational protection.

Mitchell, W. T.↗

Bulk formation of a metallic glass - Pd40Ni40P20

Molten spheroids of Pd40Ni40P20, of up to 0.53-cm minor diameter, were slowly cooled (1.4 K/s) on a fused silica surface under 10 to the -6 torr vacuum to a form which was entirely glassy except for some superficial crystallinity comprising less than 0.5% of the volume. The occurrence of crystallization was eliminated by subjecting the specimens to surface etching followed by a succession of heating and cooling cycles. The absence of crystallization in bulk was confirmed by X-ray diffraction, transmission electron microscopy, and calorimetry. Using the last technique, the heat of crystallization of the glass was measured to be 5.3 + or - 0.3 kJ/g atom.

Drehman, A. J.↗

Interaction of the solar wind with interstellar neutral hydrogen - Three-fluid model

It is commonly assumed in models of the solar wind-interstellar neutral hydrogen interaction that the ionized interstellar particles are quickly assimilated into the solar wind proton population and 'become indistinguishable' from the original solar wind. This assumption leads to the prediction that the solar wind proton temperature should increase with radius in the outer heliosphere. This temperature increase has not been observed. It is pointed out that assimilation of the interstellar particles to the point of indistinguishability takes place on the very long Coulomb collision time scale, and is not expected to occur within the heliosphere. Results are presented of a three-fluid model of the solar wind which consists of comoving thermal populations of protons of solar origin, protons produced by ionization of interstellar hydrogen, and electrons. The steady-state results yield a solar wind with a 'core' proton distribution which cools adiabatically, and a 'halo' of interstellar pickup protons which is maintained near 10 to the 7th K by the energy input of continued ionization and pickup. Such a distribution will not be observed to manifest the temperature increase at large heliocentric distances which is predicted from a one-fluid analysis. Further time-dependent calculations show a strong correlation between the densities of the solar wind and the interstellar pickup protons. It is suggested that the interstellar pickup population may be observable by the Voyager plasma instruments in low resolution mode during periods of high solar wind density and low solar wind temperature.

Isenberg, P. A.↗