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NASA NTRS1994

Experimental study of lunar and SNC (Mars) magmas

The overall objectives of this research were to evaluate the role of C-O-S-Cl degassing processes in explaining vesiculation, oxidation state and fire-fountaining of lunar magmas by analysis of individual lunar glass spherules, and by experimental determination of equilibrium abundances and diffusion rates of C, S and Cl melt species in lunar glass compositions; and to determine possible primitive SNC magma compositions and the mineralogy of the mantle from which they were derived, and to evaluate P, T, XH2O etc. conditions at which they crystallize to form the SNC meteorites. After funding for one year, a project on the A15 volcanic green glass has been completed to the point of writing a first manuscript. Carbon-oxygen species C-O and CO2 are below detection limits (20 ppm) in these glasses, but there is up to 500 ppm S with concentrations both increasing and decreasing toward the spherule margins. Calculations and modeling indicate that C species could have been present in the volcanic gases, however. In a second project, experiments with low PH2O have resulted in refined estimates of the early intercumulus melt composition in the Chassigny meteorite which is generally accepted as a sample from Mars.

Rutherford, Malcolm J.↗

NASA NTRS1993

Aspects of modelling the tectonics of large volcanoes on the terrestrial planets

Analytic solutions for the response of planetary lithospheres to volcanic loads have been used to model faulting and infer elastic plate thicknesses. Predictions of the distribution of faulting around volcanic loads, based on the application of Anderson's criteria for faulting to the results of the models, do not agree well with observations. Such models do not give the stress state and stress history within the edifice. The effects of episodic load growth can also be treated. When these effects are included, models give much better agreement with observations.

Mcgovern, Patrick J.↗

NASA NTRS1993

Magmatic volatiles and the weathering of Mars

The sources for volatiles on Mars have been the subject of many hypotheses for exogenous influences including late accretion of volatile-enriched material, impact devolatilization to create massive early atmospheres, and even major bombardment by comets. However, the inventory of chemically active volatiles observable at the contemporary surface of Mars is consistent with domination by endogenous, subsequent planetary processes, viz., persistent magmatic outgassing. Volcanism on Mars has been widespread in both space and time. Notwithstanding important specific differences between the mantles of Earth and Mars, the geochemical similarities are such that the suite of gases emitted from Martian volcanic activity should include H2O, CO2, S-containing gases (e.g. H2S and/or SO2), and Cl-containing gases (e.g., Cl2 and/or HCl). H2O and CO2 exist in the atmosphere of Mars. Both are also present as surface condensates. However, spectroscopic observations of the Martian atmosphere clearly show that the S- and Cl-containing gases are severely depleted, with upper limits of less than or equal to 10(exp -7) the abundance of CO2. Likewise, there is no evidence of polar condensates of compounds of these elements as there is for CO2 and H2O. Within the soil, on the other hand, there has been direct measurement of incorporated H2O and abundant compounds containing S and Cl. Barring some as yet implausible geochemical sequestering process, the S/Cl ratio of about 6:1 in Martian soils implies a limit of 5% on the contribution of matter of solarlike composition (e.g., carbonaceous chondrite or cometary material) to these volatiles. Hence, exogenous sources are minor or not yet observed. From analysis of elemental trends in Martian soils, it has been recently shown that a simple two-component model can satisfy the Viking in situ measurements. Component A includes Si and most or all the Al, Ca, Ti, and Fe. Component B, taken as 16 +/- 3% by weight of the total, contains S and most or all the Cl and Mg. These results constrain several models of Martian soil mineralogy but are consistent with a mixture of silicates (such as Fe-rich clays and accessory minerals and soluble salts). The overall element profile is notably like shergottites, with significant incorporation of chemically reactive atmospheric gases from magmatic degassing.

Clark, B. C.↗

NASA NTRS1994

Characteristics of civil aviation atmospheric hazards

Clear air turbulence, wake vortices, dry hail, and volcanic ash are hazards to civil aviation that have not been brought to the forefront of public attention by a catastrophic accident. However, these four hazards are responsible for major and minor injuries, emotional trauma, significant aircraft damage, and in route and terminal area inefficiency. Most injuries occur during clear air turbulence. There is significant aircraft damage for any volcanic ash encounter. Rolls induced by wake vortices occur near the ground. Dry hail often appears as an area of weak echo on the weather radar. This paper will present the meteorological, electromagnetic, and spatiotemporal characteristics of each hazard. A description of a typical aircraft encounter with each hazard will be given. Analyzed microwave and millimeter wave sensor systems to detect each hazard will be presented.

Marshall, Robert E.↗

NASA NTRS1994

Cerberus Plains: A most excellent Pathfinder landing site

The Cerberus Plains in southeastern Elysium and western Amazonis cover greater than 10(exp 5) sq km, extending an east-west distance of approximately 3000 km and a north-south distance of up to 700 km near 195 deg. Crater numbers are 89 plus or minus 15 craters greater than 1 km/10(exp 6) sq km, indicating a stratigraphic age of Upper Amazonian and an absolute age of 200-500 Ma. The material forming the surface is referred to as the Cerberus Formation. The two ideas postulated about the unit's origin are fluvial and volcanic. Regardless of which interpretation is correct, the Cerberus Plains is an important candidate for a pathfinder landing site because it represents the youngest major geologic event (be it fluvial or volcanic) on Mars.

Plescia, Jeff B.↗

NASA NTRS1994

D/H ratios and H2O contents of mantle-derived amphibole megacrysts from Dish Hill, California

D/H ratios are, in principle, useful in characterizing reservoirs of mantle hydrogen and as tracers of volatile transfer processes in Earth's interior. In practice, however, interpretation of isotopic measurements on mantle derived H is complicated by surface processes such as contamination and degassing which may alter the primary D/H ratio. Although there are indications that water associated with subduction zones and certain chemically enriched basalts is enriched in D relative to 'typical' upper mantle water, the extent of isotopic heterogeneity of mantle H remains uncertain. Kaersutitic amphibole megacrysts in alkaline basalts are one of the most widespread sources of mantle water and are therefore potentially useful for large-scale regional studies of D/H variation. However, D/H ratios of these amphiboles vary widely (from plus 8 to minus 113 percent), even in samples from the same locality, so that this potential has yet to be realized. In order to investigate the origin of this variability, and to explore the possibility that primary mantle D/H ratios may be deduced from these amphiboles, we analyzed the D/H ratios and chemical compositions of a suite of 17 kaersutitic amphiboles from Dish Hill, California. This work contrasts with previous studies in which sampling is widespread, but representatives from any given locality are few. Samples were collected from a restricted area on the southern flank of the volcanic center and are associated with the basal volcanic breccia. Fourteen of the samples were large single crystals or crystal fragments (megacrysts, 0.4 to 30 grams), believed to derive from pegmatitic veins crystallized from melts in the mantle. Two were coarse-grained intergrowths of amphibole with olivine and spinel, and one was a thin (2 mm) selvage on a peridotite xenolith.

Bell, David R.↗

NASA NTRS1993

Application of MAC-Europe AVIRIS data to the analysis of various alteration stages in the Landdmannalauger Hydrothermal Area (South Iceland)

In June 1991 extensive airborne remote sensing data-sets have been acquired over Iceland in the framework of the joint NASA/ESA Multisensor Airborne Campaign Europe (MAC-Europe). The study area is located within the Torfajokull central volcanic complex in South Iceland. This complex is composed by anomalously abundant rhyolitic acid volcanics, which underwent intensive hydrothermal alteration. Detailed studies of surface alteration of rhyolitic rocks in the area showed that all the major elements are leached as the rock is affected by complex mineralogical changes. Montmorillonite appears during the earliest stages of alteration. In the ultimate alteration product montmorillonite is absent and the rock consists mostly of amorphous silica, anatase, up to a volume of 50% kaolinite and variable amounts of native sulphur and pyrite. The case study presented shall endeavor to assess the potential of MAC-Europe AVIRIS and TMS data in determining a possible zonation of hydrothermal alteration in relationship to the active geo-thermal fields and structural features. To this end, the airborne data is analysed in comparison with laboratory spectral measurements of characteristics rock, soil, and vegetation samples collected in the study areaduring the summer of 1992. Various spectral mapping algorithms as well as unmixing approaches are tested and evaluated. Detailed geological and structural mapping as well as geochemical analysis of the main rock and soil types were performed to underpin the analysis of the airborne data.

Sommer, S.↗

NASA NTRS1993

Current and future use of TOPSAR digital topographic data for volcanological research

In several investigations of volcanoes, high quality digital elevation models (DEM's) are required to study either the geometry of the volcano or to investigate temporal changes in relief due to eruptions. Examples include the analysis of volume changes of a volcanic dome, the prediction of flow paths for pyroclastic flows, and the quantitative investigation of the geometry of valleys carved by volcanic mudflows. Additionally, to provide input data for models of lava flow emplacement, accurate measurements are needed of the thickness of lava flows as a function of distance from the vent and local slope. Visualization of volcano morphology is also aided by the ability to view a DEM from oblique perspectives. Until recently, the generation of these DEM's has required either high resolution stereo air photographs or extensive field surveying using the Global Positioning System (GPS) and other field techniques. Through the use of data collected by the NASA/JPL TOPSAR system, it is now possible to remotely measure the topography of volcanoes using airborne radar interferometry. TOPSAR data can be collected day or night under any weather conditions, thereby avoiding the problems associated with the derivation of DEM's from air photographs that may often contain clouds. Here we describe some of our initial work on volcanoes using TOPSAR data for Mt. Hekla (Iceland) and Vesuvius (Italy). We also outline various TOPSAR topographic studies of volcanoes in the Galapagos and Hawaii that will be conducted in the near future, describe how TOPSAR complements the volcanology investigations to be conducted with orbital radars (SIR-C/X-SAR, JERS-1 and ERS-1), and place these studies into the broader context of NASA's Global Change Program.

Mouginis-Mark, Peter J.↗

NASA NTRS1995

Quantitative remote sensing of ammonium minerals, Cedar Mountains, Esmeralda County, Nevada

Mineral-bound ammonium (NH4+) was discovered by the U.S. Geological Survey in the southern Cedar Mountains of Esmeralda County, Nevada in 1989. At 10 km in length, this site is 100 times larger than any previously known occurrence in volcanic rocks. The ammonium occurs in two hydrothermally altered, crystal-rich rhyolitic tuff units of Oligocene age, and is both structurally and stratigraphically controlled. This research uses Advanced Visible/Infrared Imaging Spectrometer (AVIRIS) data to quantitatively map the mineral-bound ammonium (buddingtonite) concentration in the altered volcanic rocks. Naturally occurring mineral-bound ammonium is fairly rare; however, it has been found to occur in gold-bearing hydrothermal deposits. Because of this association, it is thought that ammonium may be a useful too in exploration for gold and other metal deposits. Mineral-bound ammonium is produced when an ammonium ion (NH4+) replaces the alkali cation site (usually K+) in the crystal structure of silicate minerals such as feldspars, micas and clays. Buddingtonite is an ammonium feldspar. The ammonium originates in buried organic plant matter and is transported to the host rock by hydrothermal fluids. Ammonium alteration does not produce visible changes in the rock, and it is barely detectable with standard x-ray diffraction methods. It is clearly identified, however, by absorption features in short wave-infrared (SWIR) wavelengths (2.0 - 2.5 micrometers). The ammonium absorption features are believed to be caused by N-H vibrational modes and are analogous to hydroxyl (O-H) vibrational modes, only shifted slightly in wavelength. Buddingtonite absorption features in the near- and SWIR lie at 1.56, 2.02 and 2.12 micrometers. The feature at 2.12 micrometer is the strongest of the three and is the only one used in this study. The southern Cedar Mountains are sparsely vegetated and are an ideal site for a remote sensing study.

Baugh, William M.↗

NASA NTRS1995

Lithologic controls on AIRSAR signatures of bedrock and alluvium, at Lunar Crater, Nevada

Radar backscatter intensity as measured by calibrated synthetic aperture radar (SAR) systems is primarily controlled by three factors: local incidence angle, wavelength-scale roughness, and dielectric permittivity of surface materials. In order to make adequate use of radar observations for geological investigations of surface type, the relationships between lithology and the above characteristics must be adequately understood. In arid terrains weathering signatures (e.g. fracturing, debris grain size and shape, slope characteristics) are controlled to some extent by lithologic characteristics of the parent bedrock. These textural features of outcrops and their associated debris control radar backscatter to varying degrees. The quad-polarization JPL AIRSAR system allows sampling of textures at three distinct wavelength scales: C-band (5.66 cm), L-band (23.98 cm), and P-band (68.13 cm). This paper presents a discussion of AIRSAR data using recent field observations of weathered felsic and basaltic volcanic rock units exposed in the southern part of the Lunar Crater Volcanic Field, in the Pancake Range of central Nevada. The focus is on the relationship of radar backscatter at multiple wavelengths to weathering style and parent bedrock lithology.

Rivard, Benoit↗

NASA NTRS1994

Global temperature monitoring from space

Global and regional temperature variations in the lower troposphere and lower stratosphere are examined for the period 1979-92 from Microwave Sounder Unit (MSU) data obtained by the Television Infrared Observation Satellite (TIROS)-N series of National Oceanic and Atmospheric Administration (NOAA) operational satellites. In the lower troposphere, globally-averaged temperature variations appear to be dominated by tropical El Nino (warm) and La Nina (cool) events and volcanic eruptions. The Pinatubo volcanic eruption in June 1991 appears to have initiated a cooling trend which persisted through the most recent data analyzed (July, 1992), and largely overwhelmed the warming from the 1991-92 El Nino. The cooling has been stronger in the Northern Hemisphere than in the Southern Hemisphere. The temperature trend over the 13.5 year satellite record is small (+0.03 C) compared to the year-to-year variability (0.2-0.4 C), making detection of any global warming signal fruitless to date. However, the future global warming trend, currently predicted to be around 0.3 C/decade, will be much easier to discern should it develop. The lower stratospheric temperature record is dominated by warm episodes from the Pinatubo eruption and the March 1982 eruption of El Chichon volcano.

Spencer, R. W.↗

NASA NTRS1994

The global distribution of giant radiating dike swarms on Venus: Implications for the global stress state

Magellan radar data of Venus reveal 163 large radial lineament systems composed of graben, fissure, and fracture elements. On the basis of their structure, plan view geometry, and volcanic associations, at least 72% are interpreted to have formed primarily through subsurface dike swarm emplacement, the remainder through uplift or a combination of these two mechanisms. The population of swarms is used to determine regional and global stress orientation. The stress configuration recorded from 330-210 deg E (Aphrodite Terra) is best explained by isostatic compensation of existing long wavelength topography or coupling between mantle flow and the lithosphere. The rest are correlated with concentrations of rifting and volcanism in the Beta-Atla-Themis region. The global stress field on Venus is different than that of Earth, where plate boundary forces dominate.

Grosfils, Eric B.↗

NASA NTRS1994

Two-dimensional simulation of Pinatubo aerosol and its effect on stratospheric ozone

This paper presents time-dependent simulations of the response of the stratosphere to the injection into the atmosphere of massive amounts of sulfur during the eruption of Mt. Pinatubo (The Philippines) in June 1991. The study is based on a coupled two-dimensional chemical-dynamical-radiative model to which a microphysical model for sulfate aerosol formation and fate has been added. The study suggests that, during the first year (July 1991 to June 1992) following the volcanic eruption, the observed changes in the ozone amount integrated between 65 deg S and 65 deg N were caused primarily by changes in the meridional circulation (associated with heating by the volcanic cloud in the tropics) and in the photolysis rate of molecules such as ozone (associated with backscattering of light by the cloud). During the second year after the eruption, as the aerosol was dispersed at all latitudes and, in particular, reached the polar region, the largest contribution to ozone reduction resulted from the heterogeneous chemical conversion of N2O5 and ClONO2 on the surface of the aerosol particles. The conversion of the latter compound, and hence the magnitude of the calculated ozone depletion, is highly dependent on the temperature in the lower stratosphere. Despite the fact that the surface area provided by aerosol particles decreased during the second year following the eruption, the calculated ozone depletion remained significant because the conversion of N2O5 is insensitive to the aerosol surface area density for values larger than 1-10 sq microns/cu cm (depending on latitude). The predicted reduction in ozone at 20 km in March during the third year (July 1993 to June 1994) of the model integration is smaller by a factor of 2 than it was during the second year.

Tie, Xuexi↗

NASA NTRS1994

Topography of Valles Marineris: Implications for erosional and structural history

Compilation of a simplified geologic/geomorphic map onto digital terrain models of the Valles Marineris permitted an evaluation of elevations in the vicinity of the troughs and the calculation of depth of troughs below surrounding plateaus, thickness of deposits inside the troughs, volumes of void spaces above geologic/geomorphic units, and volumes of deposits. The central troughs north Ophir, north and central Candor, and north Melas Chasmata lie as much as 11 km below the adjacent plateaus. In Ophir and Candor chasmata, interior layered deposits reach 8 km in elevation. If the deposits are lacustrine and if all troughs were interconnected, lake waters standing 8 km high would have spilled out of Coprates Chasma onto the surrounding plateaus having surface elevations of only 4-5 km. On the other hand, the troughs may not have been interconnected at the time of interior-deposit emplacement; they may have formed isolated ancestral basins. The existence of such basins is supported by independent structural and stratigraphic evidence. The ancestral basins may have eventually merged, perhaps through renewed faulting, to form northern subsidiary troughs in Ophir and Candor Chasmata and the Coprates/north Melas/Ius graben system. The peripheral troughs are only 2-5 km deep, shallower than the central troughs. Chaotic terrain is seen in the peripheral troughs near a common contour level of about 4 km on the adjacent plateaus, which supports the idea of release of water under artesian pressure from confined aquifers. The layered deposits in the peripheral troughs may have formed in isolated depressions that harbored lakes and predated the formation of the deep outflow channels. (If these layered deposits are of volcanic origin, they may have been emplaced beneath ice in the manner of table mountains.) Areal and volumetric computations show that erosion widened the troughs by about one-third and that deposits occupy one-sixth of the interior space. Even though the volume eroded is larger than the volume deposited, topographic and geologic considerations imply that material eroded from trough walls was probably part of the interior layered deposits but not their sole source. Additional material may have come from subterranean piping, from reworking of local disintegration products on the floors, such as chaotic materials, or from eolian influx. But overall it is likely that the additional material is volcanic and that it forms mostly the upper, more diversely bedded layers of the interior deposits.

Lucchitta, B. K.↗

NASA NTRS1994

Banded structures in stratospheric aerosol distributions

Zonal bands of stratospheric aerosol optical depth are observed by various sensors under both volcanic and non-volcanic conditions. Maximum optical depths occur within the tropics and at high latitudes, while minima are found between latitudes of approximately 15 deg and 45 deg. This structure is shown to result from a reservoir of aerosol over the tropics, poleward transport, and the departure of the tropopause from isentropic surfaces.

Trepte, Charles R.↗

NASA NTRS1994

Assimilation by lunar mare basalts: Melting of crustal material and dissolution of anorthite

We discuss techniques for calculating the amount of crustal assimilation possible in lunar magma chambers and dikes based on thermal energy balances, kinetic rates, and simple fluid mechanical constraints. Assuming parent magmas of picritic compositions, we demonstrate the limits on the capacity of such magmas to melt and dissolve wall rock of anorthitic, troctolitic, noritic, and KREEP (quartz monzodiorite) compositions. Significant melting of the plagioclase-rich crustal lithologies requires turbulent convection in the assimilating magma and an efficient method of mixing in the relatively buoyant and viscous new melt. Even when this occurs, the major element chemistry of the picritic magmas will change by less than 1-2 wt %. Diffusion coefficients measured for Al2O3 from an iron-free basalt and an orange glass composition are 10(exp -12) sq m/s at 1340 C and 10(exp -11) sq m/s at 1390 C. These rates are too slow to allow dissolution of plagioclase to significantly affect magma compositions. Picritic magmas can melt significant quantities of KREEP, which suggests that their trace element chemistry may still be affected by assimilation processes; however, mixing viscous melts of KREEP composition with the fluid picritic magmas could be prohibitively difficult. We conclude that only a small part of the total major element chemical variation in the mare basalt and volcanic glass collection is due to assimilation/fractional crystallization processes near the lunar surface. Instead, most of the chemical variation in the lunar basalts and volcanic glasses must result from assimilation at deeper levels or from having distinct source regions in a heterogeneous lunar mantle.

Finnila, A. B.↗

NASA NTRS1993

Airborne brightness temperature measurements of the polar winter troposphere as part of the Airborne Arctic Stratosphere Experiment 2 and the effect of brightness temperature variations on the diabatic heating in the lower stratosphere

In this paper we report radiometric measurements of tropospheric brightness temperatures obtained during the AASE 2 experiment. These measurements represent the first attempt to characterize effective radiative temperatures as seen from above the troposphere during the Arctic winter. The reported measurements include brightness temperatures at 6.7 and 10.5 microns as seen from the NASA DC-8 aircraft flying at about 11 km altitude. We also present radiative transfer calculations to estimate the effect of tropospheric brightness temperature on the lower stratospheric heating rates. Because of the recent massive eruption of the Pinatubo volcano, we also discuss the effects of a volcanic aerosol layer. It is concluded that small particles like the volcanic aerosol or polar stratospheric clouds (PSCs) type 1 do not affect stratospheric heating rates by much; on the other hand, larger particles, PSCs types 2 and 3, may have significant effects on heating rates and consequently on dynamics of the lower stratosphere. The dynamical effects of local stratospheric temperature variations are briefly discussed.

Valero, Francisco P. J.↗

NASA NTRS1993

Assumptions about the presence of natural glasses on Mars

Natural glasses occur not only on Earth but also in lunar rocks and in some meteorites. On geological grounds, natural glasses could be expected on the surface of Mars and their presence would have important implications for the weathering and alteration of the near-surface layer. Ultramafic and mafic magmatism rich in iron and some volatiles appears to have been important on Mars as has been impact cratering, volcanism, and possibly hydrothermal alteration. Available data indicate that we can presume the past or present existence of volcanic basaltic glasses, impact glasses formed by thermal fusion of meteorite-impact targets, and diaplectic (mainly maskelynite) glasses. Conditions appear unsuitable for the formation of tektites on the Martian surface, and the production of measurable amounts of fulgurite or combustion glass seems improbable. Prospects for the remote and in-situ identification of Martian glasses and their subsequent weathering products are discussed and include orbital reflectance and thermal emission spectroscopic measurements and Mossbauer spectroscopy from a surface lander.

Bouska, Vladimir↗