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DOE OSTI2023

Editorial: Advanced water splitting technologies development: Best practices and protocols

As the level of deployment and utilization of renewable energy sources, including wind and solar, continues to rise, large-scale, long-term energy storage technologies that could accommodate weekly and seasonal energy fluctuations will play a significant role in the overall deployment of renewable energies in the future. Harnessing and storing renewable energy resources via electrochemical, photoelectrochemical, or thermochemical processes by converting renewable energy into sustainable (energy storage) fuels have the potential to meet the long-term, terawatt scale energy storage challenge. Renewable hydrogen production is the cornerstone for sustainable fuel production and deep decarbonization of multiple sectors in our society. Cost-competitive clean hydrogen provides value to applications, such as 1) in the transportation sector for fuel cell vehicles, 2) in the electric grid sector for system stability and load balancing, and 3) in the industrial sector with metal refineries, cement production, and biomass upgrading (carbon-free fertilizer production). In addition, coupling clean renewable hydrogen with the carbon and nitrogen cycles enables known and well-established thermal-chemical processes to generate renewable hydrocarbon fuels and ammonia. The Advanced Water Splitting Technologies (AWST): low temperature electrolysis (LTE), high temperature electrolysis (HTE), photoelectrochemical (PEC) and solar thermo-chemical hydrogen (STCH) provide four unique and parallel approaches to produce low cost, low greenhouse gas (GHG) emission hydrogen at scale (Figure 1). Cost competitive clean hydrogen production using these four technologies is a current high priority focus for governments and industry. In June of 2022, the U.S. Department of Energy (DOE) launched the first in a series of Earthshot Initiatives. The Hydrogen Shot, “1 1 1” aims to reduce the cost of clean hydrogen by more than 80% to one dollar per one kilogram in 1 decade ($\$$1/kg H 2 ). The European Green Deal and the International Energy Agency (IEA) have implemented a strong focus on green hydrogen production for a clean and secure energy future.

benchmarking, low temperature electrolysis↗

DOE OSTI2023

Predicting Short-Term Deformation in the Central Valley Using Machine Learning

Land subsidence caused by excessive groundwater pumping in Central Valley, California, is a major issue that has several negative impacts such as reduced aquifer storage and damaged infrastructures which, in turn, produce an economic loss due to the high reliance on crop production. This is why it is of utmost importance to routinely monitor and assess the surface deformation occurring. Two main goals that this paper attempts to accomplish are deformation characterization and deformation prediction. The first goal is realized through the use of Principal Component Analysis (PCA) applied to a series of Interferomtric Synthetic Aperture Radar (InSAR) images that produces eigenimages displaying the key characteristics of the subsidence. Water storage changes are also directly analyzed by the use of data from the Gravity Recovery and Climate Experiment (GRACE) twin satellites and the Global Land Data Assimilation System (GLDAS). The second goal is accomplished by building a Long Short-Term Memory (LSTM) model to predict short-term deformation after developing an InSAR time series using LiCSBAS, an open-source InSAR time series package. The model is applied to the city of Madera and produces better results than a baseline averaging model and a one dimensional convolutional neural network (CNN) based on a mean squared error metric showing the effectiveness of machine learning in deformation prediction as well as the potential for incorporation in hazard mitigation models. The model results can directly aid policy makers in determining the appropriate rate of groundwater withdrawal while maintaining the safety and well-being of the population as well as the aquifers’ integrity.

58 GEOSCIENCES↗

DOE OSTI2022

PLA Renewable Bio Polymer Based Solid-State Gamma Radiation Detector-Dosimeter for Biomedical and Nuclear Industry Applications

Polylactic acid (PLA) as a “green,” renewable corn-soy based polymer resin was assessed as a novel solid-state detector for rapid-turnaround gamma radiation dosimetry in the 1–100 kGy range–of significant interest in biomedical and general nuclear industry applications. Co-60 was used as the source of gamma photons. It was found that PLA resin responds well in terms of rheology and porosity metrics with an absorbed gamma dose (Dg). In this work, rheological changes were ascertained via measuring the differential mass loss ratio (MLR) of irradiated PLA placed within PTFE-framed (40 mm × 20 mm × 0.77 mm) cavities bearing ~0.9 g of PLA resin and pressed for 12–16 min in a controlled force hot press under ~6.6 kN loading and platens heated to 227 °C for the low Dg range: 0–11 kGy; and to 193 °C for the extended Dg range: 11–120 kGy. MLR varied quadratically from 0.05 to ~0.2 (1σ ~ 0.007) in the 0–11 kGy experiments, and from 0.05 to ~0.5 (1σ ~0.01) in the 0–120 kGy experiments. Rheological changes from gamma irradiation were modeled and simultaneously correlated with void-pocket formations, which increase with Dg. A single PLA resin bead (~0.04 g) was compressed 5 min at 216 °C in 0–16 kGy experiments, and compressed 2 min at 232 °C in the 16–110 kGy experiments, to form sturdy ~100 µm thick wafers in the same press. Aggregate coupon porosity was then readily measurable with conventional optical microscope imaging and analyzed with standard image processing; this provided complementary data to MLR. Average porosity vs. dose varied quadratically from ~0 to ~15% in the 0–16 kGy range and from ~0 to ~18% over the 16–114 kGy range. These results provide evidence for utilizing “green”/renewable (under $0.01) PLA resin beads for rapid and accurate (+/-5–10%) gamma dosimetry over a wide 0–120 kGy range, using simple to deploy mass and void measuring techniques using common laboratory equipment.

61 RADIATION PROTECTION AND DOSIMETRY↗

NASA NTRS1974

RM2: Transform operations

The two-dimensional transform used in the research TV source encoder, RM2 is discussed. It is shown that both conceptually and in terms of the number of required computations, the RM2 transform is considerably simpler than the Fast Hadamard Transform. The latter can in fact be generated by extending the RM2 transform.

Rice, R. F.↗

NASA NTRS1976

On the mathematical conditions for the existence of periodic fluctuations in non-uniform media

The assumption that periodic excitations result in periodic responses for the case of waves propagating through nonuniform media is examined by investigating the periodic solutions of linear hyperbolic differential equations whose coefficients vary with position and whose solution must satisfy periodic boundary or source data. It is shown that the nature of the coefficients of undifferentiated terms of the differential system is crucial in determining whether the solution is periodic. Particular attention is paid to the propagation of infinitesimal pressure waves through the nonuniform steady flow of a lossless fluid.

Gunzburger, M. D.↗

NASA NTRS1977

Variations in eddy diffusion and associated transport processes

Variation in the eddy diffusion coefficient constitutes a momentum source. This variation near the turbopause affects both the composition and the wind and temperature fields of the thermosphere. Two types of calculations are carried out, for horizontal winds considered self-consistently in a three-dimensional dynamic model and horizontal winds artificially suppressed to simulate a one-dimensional model. Momentum transfer associated with variations in eddy diffusion coefficients represents the source function in the analysis presented. It is shown that for long-term variations in the thermosphere, the compositional dependence on variations in eddy diffusion coefficients can be entirely different in one and three dimensional models with horizontal winds included. Horizontal winds can greatly reduce the effects of eddy diffusion in general and the ratio between He and O amplitudes in particular.

Mayr, H. G.↗

NASA NTRS1977

The signature of parallel electric fields in a collisionless plasma

The presence of a parallel electric field in the magnetosphere should be apparent through its effect on particles. An analysis is made of particle trajectories in phase space for a steady state collisionless plasma. The analysis utilizes the concepts of distribution function, total energy, and magnetic moment because all three quantities are conserved in a steady state situation in the absence of collisions. Two methods are presented for using particle data to gain information on the potential distribution. The first method involves the use of measurements of both ion and electron distribution functions and invokes the principle of quasi-neutrality. The second method involves the observation of discontinuities in velocity space which can be interpreted in terms of the effect of the electric field on the apparent loss or source cone.

Whipple, E. C., Jr.↗

NASA NTRS1977

Flight-test measurements of ground effect - STOL airplanes

Powered-lift STOL aircraft exhibit special aerodynamic characteristics that necessitate changes in established procedures of flight testing. Methods used in ground-effect flight testing of STOL-configured aircraft are described, with special emphasis on results obtained from tests of the YC-15 AMST prototype aircraft. Ground effect on lift and on drag is theoretically analyzed in terms of trailing vortices, bound vortex, and flight-path angle. Airspeed static source position errors are induced by ground constraint and must be considered in the data reduction. Flight-test results show a positive lift increment due to ground proximity.

Parks, E. K.↗

NASA NTRS1979

Synchronous rotation in magnetic X-ray binaries

AM Herculis is thought to be a binary stellar system that contains an accreting magnetic degenerate dwarf whose rotation is synchronous with the orbital period. This synchronism is remarkable, particularly because of the small moment of inertia of a degenerate dwarf and the large specific angular momentum of the accreted matter. This paper demonstrates that ohmic dissipation from the magnetic interaction of the stars is capable of bringing about exact synchronism, provided that some other process has brought the rotation period of the degenerate dwarf to the same order of magnitude as the orbital period. It is also shown that magnetostatic interaction in the synchronous state leads to oscillatory drifts in phase about exact synchronism with periods of approximately 1-10 yr. These phase drifts could manifest themselves in long-term periodic variability in the X-ray or optical properties of the source. Accretion torques could excite such oscillatory motions but need not disrupt synchronism once it has been established.

Joss, P. C.↗

NASA NTRS1984

Far-infrared and submillimeter survey of the galactic plane from l = 11.5 deg to l = 17.5 deg

Medium resolution (11 min) maps of the galactic plane are presented from l = 11.5 deg to l = 17.5 deg at wavelengths of 93 microns, 154 microns, and 190 microns. The maps are interpreted in terms of the temperature and spatial structure of diffuse far-infrared/submillimeter sources associated with evolved H II regions and a continuous ridge of galactic emission. The emission regions are found to be more extended at the longer wavelengths which implies that there must be a range of dust temperatures in the sources. The properties of the galactic ridge are similar to those of the sources.

Campbell, M. F.↗

NASA NTRS1984

Methods for Cloud Cover Estimation

Several methods for cloud cover estimation are described relevant to assessing the performance of a ground-based network of solar observatories. The methods rely on ground and satellite data sources and provide meteorological or climatological information. One means of acquiring long-term observations of solar oscillations is the establishment of a ground-based network of solar observatories. Criteria for station site selection are: gross cloudiness, accurate transparency information, and seeing. Alternative methods for computing this duty cycle are discussed. The cycle, or alternatively a time history of solar visibility from the network, can then be input to a model to determine the effect of duty cycle on derived solar seismology parameters. Cloudiness from space is studied to examine various means by which the duty cycle might be computed. Cloudiness, and to some extent transparency, can potentially be estimated from satellite data.

Glackin, D. L.↗

NASA NTRS1987

Operating envelopes of particle sizing instrumentation used for icing research

The Forward Scattering Spectrometer Probe and the Optical Array Probe are analyzed in terms of their ability to make accurate determinations of water droplet size distributions. Sources of counting and sizing errors are explained. The paper describes ways of identifying these errors and how they can affect measurement.

Hovenac, Edward A.↗

NASA NTRS1988

Operating envelopes of particle sizing instrumentation used for icing research

Hovenac, Edward A.↗

NASA NTRS1988

The field lines of an axisymmetric magnetic field

The equations of Willis and Young (1987) for the field lines of an arbitrary axisymmetric multipole are generalized to an arbitrary linear combination of multipoles, i.e., to an arbitrary axisymmetric magnetic field B outside a sphere of radius a, S(a), centered on the origin, and containing all the sources of B. For this field, axisymmetric Stokes stream function is expressed in terms of the Gauss coefficients. It is shown that if only one Gauss coefficient is nonzero, the field line equations are identical to those obtained by Willis and Young.

Backus, George E.↗

NASA NTRS1990

Preliminary greenhouse design for a Martian colony: Structural, solar collection, and light distribution systems

The design of a greenhouse that will be a component of a long-term habitat on Mars is presented. The greenhouse will be the primary food source for people stationed on Mars. The food will be grown in three identical underground modules, pressurized at 1 atm to allow a shirt-sleeve environment within the greenhouse. The underground location will support the structure, moderate the large environmental variations on the surface, and protect the crops from cosmic radiation. The design effort is concentrated on the outer structure and the lighting system for the greenhouse. The structure is inflatable and made of a Kevlar 49/Epoxy composite and a pipe-arched system that is corrugated to increase stiffness. This composite is pliable in an uncured state, which allows it to be efficiently packaged for transport. The lighting system consists of several flat-plate fiber optic solar collectors with dual-axis tracking systems that will continually track the sun. This design is modeled after the Himawari collector, which was designed by Dr. Kei Mori and is currently in use in Japan. The light will pass through Fresnel lenses that filter out undesirable wavelengths and send the light into the greenhouses by way of fiber optic cables. When the light arrives at the greenhouse, it is dispersed to the plants via a waveguide and diffuser system.

Source record↗

NASA NTRS1991

Solar cycle variation in the subauroral electron temperature enhancement - Comparison of AE-C and DE 2 satellite observations

The elevation of the subauroral electron temperature is one of the phenomena showing the energy transfer from the magnetosphere and the response of the ionosphere. This study addresses solar cycle variations in the subauroral Te peak by comparing observations of the subauroral peak by the Atmosphere Explorer C (AE-C) satellite near solar minimum (1974 and 1977) with similar observations by the Dynamics Explorer 2 (DE 2) satellite near solar maximum (1981-1982). Te peaks with magnitudes sufficient to produce observable stable auroral red arc emissions occurred more frequently during solar maximum than in solar minimum, but the variation in the magnitudes and positions of these peaks with magnetic activity did not change significantly with solar cycle. These results are discussed in terms of the solar cycle changes in the ionosphere and the magnetospheric energy source.

Fok, M.-C.↗

NASA NTRS2012

GX 3+1: The Stability of Spectral Index as a Function of Mass Accretion Rate

We present an analysis of the spectral and timing properties observed in X-rays from neutron star (NS) binary GX 3+1 (4U 1744-26) during long-term transitions between the faint and bright phases superimposed on short-term transitions between lower banana (LB) and upper banana (UB) branches in terms of its color-color diagram, We analyze all observations of this source obtained with the Rossi X-ray Timing Explorer and BeppoSAX satellites, We find that the X-ray broadband energy spectra during these spectral transitions can be adequately reproduced by a composition of a low-temperature blackbody component, a Comptonized component (COMPTB), and Gaussian component We argue that the electron temperature kTe of the Compton cloud monotonically increases from 2.3 keY to 4.5 keY, when GX 3+1 makes a transition from UB to LB. We also detect an evolution of noise components (a very low frequency noise and a high-frequency noise) during these LB-UB transitions. Using a disk seed photon normalization of COMPTB, which is proportional to the mass accretion rate, we find that the photon power-law index Gamma is almost constant (Gamma = 2.00 +/- 0.02) when mass accretion rate changes by factor four. In addition, we find that the emergent spectrum is dominated by the strong Comptonized component We interpret this quasi-stability of the index Gamma and a particular form of the spectrum in the framework of a model in which the energy release in the transition layer located between the accretion disk and NS surface dominates that in the disk. Moreover, this index stability effect now established for GX 3+ I was previously found in the atoll source 4U 1728-34 and suggested for a number of other low-mass X-ray NS binaries. This intrinsic behavior of NSs, in particular for atoll sources, is fundamentally different from that seen in black hole binary sources where the index monotonically increases during spectral transition from the low state to the high state and then finally saturates at high values of mass accretion rate.

Seifana, Elena↗

NASA NTRS2012

All Sky Search for Gravitational-Wave Bursts in the Second Joint LIGO-Virgo Run

We present results from a search for gravitational-wave bursts in the data collected by the LIGO and Virgo detectors between July 7, 2009 and October 20, 2010: data are analyzed when at least two of the three LIGO-Virgo detectors are in coincident operation, with a total observation time of 207 days. The analysis searches for transients of duration approx. < 1 s over the frequency band 64-5000 Hz, without other assumptions on the signal wa.veform, polarization, direction or occurrence time. All identified events are c.onsistent with the expected accidental background. We set frequentist upper limits on the rate of gravitational-wave bursts by combining this search with the previous LIGOVirgo search on the data collected "between November 2005 and October 2007. The upper limit on the rate of strong gravita.tional-wave bursts at the Earth is 1.3 events per year at 90% confidence. We also present upper limits on source rate density per yea.r and Mpc3 for sample popula.tions of standard-candle sources. As in the previous joint run, typical sensitivities of the search in terms of the root-sum-squared strain amplitude for these waveforms lie in the range approx 5 x 10(exp -22 Hz(exp-1/2) approx 1 X 10(exp -20) Hz(exp -1/2) . The combination of the two joint runs entails the most sensitive all-sky search for generic gravitational-wave bursts and synthesizes the results achieved by the initial generation of interferometric detectors.

Abadie, J.↗