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Results for “PHASE SHIFT”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,783 records · Page 99
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Pressure-induced shift of effective Ce valence, Fermi energy and phase boundaries in CeOs 4 Sb 12

Abstract CeOs 4 Sb 12 , a member of the skutterudite family, has an unusual semimetallic low-temperature L -phase that inhabits a wedge-like area of the field H —temperature T phase diagram. We have conducted measurements of electrical transport and megahertz conductivity on CeOs 4 Sb 12 single crystals under pressures of up to 3 GPa and in high magnetic fields of up to 41 T to investigate the influence of pressure on the different H – T phase boundaries. While the high-temperature valence transition between the metallic H -phase and the L -phase is shifted to higher T by pressures of the order of 1 GPa, we observed only a marginal suppression of the S -phase that is found below 1 K for pressures of up to 1.91 GPa. High-field quantum oscillations have been observed for pressures up to 3.0 GPa and the Fermi surface of the high-field side of the H -phase is found to show a surprising decrease in size with increasing pressure, implying a change in electronic structure rather than a mere contraction of lattice parameters. We evaluate the field-dependence of the effective masses for different pressures and also reflect on the sample dependence of some of the properties of CeOs 4 Sb 12 which appears to be limited to the low-field region.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2015

Effect of sintering time on structural, microstructural and chemical composition of Ni-doped lanthanum gallate perovskites

This work reports the effect of two different sintering times, 6 and 48 h on the structural, microstructural, and chemical features of Ni-doped La{sub 0.90}Sr{sub 0.10}GaO{sub 3.00−δ}. Independently of the sintering time, La{sub 0.90}Sr{sub 0.10}Ga{sub 1−x}Ni{sub x}O{sub 3.00−δ} (where x=0.10, and 0.20 (mol)) presents a rhombohedral symmetry with a lattice volume that decreases when NiO dopant increases. Besides the perovskite, LaSrGa{sub 3.00}O{sub 7.00} (nominal composition) is present as second phase in all cases. When the samples are doped with NiO, the peaks of this second phase are shifted with respect to the peaks of the pure phase. These shifts suggest that this second phase could admit some Ni ions in its structure. According to the XRD patterns, the amount of the latter phase is larger when sintering time is increased. Electron probe microanalysis (EPMA) indicated that the matrix of the samples sintered for 6 h is constituted by a perovskite with an experimental composition very close to the nominal one. However, when the samples are sintered for 48 h the matrix of each sample is constituted by two perovskites; both with compositional deviations with respect to their nominal one. In particular, a significant Sr depletion compensated by a La increment in the A site is observed. Those compositional deviations could be mainly due to the diffusion of the cations in the bulk and/or from the bulk to the surface of the samples. That diffusion can favour the formation, not only, of a second perovskite with a different composition in relation with the first one formed, but also, the formation of second phases. In addition, a very slight broadening of Bragg peaks of the perovskites sintered for 48 h is observed by XRD and can be related to the presence of two different perovskites in each sample according to EPMA results. By BSEM and EPMA analyses La{sub 4.00}Ga{sub 2.00}O{sub 9.00} (nominal composition) is also observed as second phase when samples are treated for 48 h. - Graphical abstract: Typical microstructures, observed by FEG-SEM, of La{sub 0.90}Sr{sub 0.10}Ga{sub 1−x}Ni{sub x}O{sub 3.00−δ} materials with x=0.00 and 0.10 (nominal compositions) and sintered at 1450 °C for 48 h after polishing and thermal etching are shown. Lighter grey grains with a bimodal grain size are observed and according to XEDS analysis correspond to two perovskites with different experimental compositions (labelled as 1 and 2 for x=0.00 and labelled as 4 and 5 for x=0.10, respectively), meanwhile the darker grey phases correspond to LaSrGa{sub 3.00}O{sub 7.00} (labelled as 3 for x=0.00) and LaSr(Ga{sub 1−y′},Ni{sub y′}){sub 3.00}O{sub 7.00} (labelled as 6 for x=0.10), respectively. - Highlights: • When NiO is introduced into La{sub 0.90}Sr{sub 0.10}GaO{sub 3.00−δ} a change in symmetry is produced. • A significant Sr depletion in the A-site of perovskites treated for 48 h is observed. • Compositional deviations could be due to a thermally-activated diffusional process. • The phase purity of these materials is deteriorated when the sintering time is extended.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1992

Coded 16-CPFSK for downlink applications

A bandwidth-efficient constant-envelope Proof-of-Concept (POC) modem is described. The modem was developed on an Advanced Modulation Techniques Development contract for the NASA/Lewis Research Center. The POC modem employs 16-ary Continuous Phase Frequency Shift Keying (16-CPFSK) modulation. The 16 frequencies are spaced every 1/16th baud rate which produces a compact spectrum allowing 2 bits/sec/Hz operation. The modem is designed for 200 mb/s Time Division Multiple Access (TDMA) application with 100 MHz adjacent channel spacing. Overall rate 3.4 convolutional coding is incorporated. The demodulator differs significantly from typical quadrature phase detector approaches in that phase is coherently measured by processing the baseband output of a frequency discriminator. Baud rate phase samples for the baseband processor are subsequently decoded to yield the original data stream. The method of encoding onto the 16-ary symbol-ending phase nodes, together with convolutional coding gain, results in near Quadrature Phase Shift Keying (QPSK) theoretical performance. The modulated signal is of constant envelope; thus the power amplifier can be saturated for peak performance. The spectrum is inherently bandlimited and requires no RF filter for sidelobe containment. Two novel theoretical techniques are used in this 16-CPFSK modem: (1) coherent phase measurements are obtained by processing an FM discriminator baseband output; and (2) modulation is accomplished via a closed-loop-linearized voltage controlled oscillator (VCO).

Davis, Robert↗
DOE OSTI2018

Laboratory Strategies for Hydrate Formation in Fine‐Grained Sediments

Abstract Fine‐grained sediments limit hydrate nucleation, shift the phase boundary, and hinder gas supply. Laboratory experiments in this study explore different strategies to overcome these challenges, including the use of a more soluble guest molecule rather than methane, grain‐scale gas‐storage within porous diatoms, ice‐to‐hydrate transformation to grow lenses at predefined locations, forced gas injection into water saturated sediments, and long‐term guest molecule transport. Tomographic images and thermal and pressure data provide rich information on hydrate formation and morphology. Results show that hydrate formation is inherently displacive in fine‐grained sediments; lenses are thicker and closer to each other in compressible, high specific surface area sediments subjected to low effective stress. Temperature and pressure trajectories follow a shifted phase boundary that is consistent with capillary effects. Exo‐pore growth results in freshly formed hydrate with a striped and porous structure; this open structure becomes an effective pathway for gas transport to the growing hydrate front. Ice‐to‐hydrate transformation goes through a liquid stage at premelt temperatures; then, capillarity and cryogenic suction compete, and some water becomes imbibed into the sediment faster than hydrate reformation. The geometry of hydrate lenses and the internal hydrate structure continue evolving long after the exothermal response to hydrate formation has completely decayed. Multiple time‐dependent processes occur during hydrate formation, including gas, water and heat transport, sediment compressibility, reaction rate, and the stochastic nucleation process. Hydrate formation strategies conceived for this study highlight the inherent difficulties in emulating hydrate formation in fine‐grained sediments within the relatively short time scale available for laboratory experiments.

Lei, L.↗
NASA NTRS1967

Wideband array antenna system

Distortion of radiation pattern of 96-element phased array with matching dielectric sheet at each face of phase shifter matrix

RADIATION DISTRIBUTION↗
DOE OSTI2014

Effects of non-local exchange on core level shifts for gas-phase and adsorbed molecules

Density functional theory calculations are often used to interpret experimental shifts in core level binding energies. Calculations based on gradient-corrected (GC) exchange-correlation functionals are known to reproduce measured core level shifts (CLS) of isolated molecules and metal surfaces with reasonable accuracy. In the present study, we discuss a series of examples where the shifts calculated within a GC-functional significantly deviate from the experimental values, namely the CLS of C 1s in ethyl trifluoroacetate, Pd 3d in PdO and the O 1s shift for CO adsorbed on PdO(101). The deviations are traced to effects of the electronic self-interaction error with GC-functionals and substantially better agreements between calculated and measured CLS are obtained when a fraction of exact exchange is used in the exchange-correlation functional.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

SU-G-JeP3-14: Positioning and Dosimetric Uncertainties in Image-Guided Radiation Therapy with Respiratory Gating

Purpose: To investigate quantitatively positioning and dosimetric uncertainties due to 4D-CT intra-phase motion in the internal-target-volume (ITV) associated with radiation therapy using respiratory-gating for patients setup with image-guidance-radiation-therapy (IGRT) using free-breathing or average-phase CT-images. Methods: A lung phantom with an embedded tissue-equivalent target is imaged with CT while it is stationary and moving. Four-sets of structures are outlined: (a) the actual target on CT-images of the stationary-target, (b) ITV on CT-images for the free-moving phantom, (c) ITV’s from the ten different phases (10–100%) and (d) ITV on the CT-images generated from combining 3 phases: 40%–50%–60%. The variations in volume, length and center-position of the ITV’s and their effects on dosimetry during dose delivery for patients setup with image-guidance are investigated. Results: Intra-phase motion due to breathing affects the volume, center position and length of the ITVs from different respiratory-phases. The ITV’s vary by about 10% from one phase to another. The largest ITV is measured on the free breathing CT images and the smallest is on the stationary CT-images. The ITV lengths vary by about 4mm where it may shrink or elongated depending on the motion-phase. The center position of the ITV varies between the different motion-phases which shifts upto 10mm from the stationary-position which is nearly equal to motion-amplitude. This causes systematic shifts during dose delivery with beam gating using certain phases (40%–50%–60%) for patients setup with IGRT using free-breathing or average-phase CT-images. The dose coverage of the ITV depends on the margins used for treatment-planning-volume where margins larger than the motion-amplitudes are needed to ensure dose coverage of the ITV. Conclusion: Volume, length, and center position of the ITV’s change between the different motion phases. Large systematic shifts are induced by respiratory-gating with ITVs on certain phases when patients are setup with IGRT using free-breathing or average-phase CT-images.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2015

SU-E-J-26: A Novel Technique for Markerless Self-Sorted 4D-CBCT Using Patient Motion Modeling: A Feasibility Study

Purpose: To develop an automatic markerless 4D-CBCT projection sorting technique by using a patient respiratory motion model extracted from the planning 4D-CT images. Methods: Each phase of onboard 4D-CBCT is considered as a deformation of one phase of the prior planning 4D-CT. The deformation field map (DFM) is represented as a linear combination of three major deformation patterns extracted from the planning 4D-CT using principle component analysis (PCA). The coefficients of the PCA deformation patterns are solved by matching the digitally reconstructed radiograph (DRR) of the deformed volume to the onboard projection acquired. The PCA coefficients are solved for each single projection, and are used for phase sorting. Projections at the peaks of the Z direction coefficient are sorted as phase 1 and other projections are assigned into 10 phase bins by dividing phases equally between peaks. The 4D digital extended-cardiac-torso (XCAT) phantom was used to evaluate the proposed technique. Three scenarios were simulated, with different tumor motion amplitude (3cm to 2cm), tumor spatial shift (8mm SI), and tumor body motion phase shift (2 phases) from prior to on-board images. Projections were simulated over 180 degree scan-angle for the 4D-XCAT. The percentage of accurately binned projections across entire dataset was calculated to represent the phase sorting accuracy. Results: With a changed tumor motion amplitude from 3cm to 2cm, markerless phase sorting accuracy was 100%. With a tumor phase shift of 2 phases w.r.t. body motion, the phase sorting accuracy was 100%. With a tumor spatial shift of 8mm in SI direction, phase sorting accuracy was 86.1%. Conclusion: The XCAT phantom simulation results demonstrated that it is feasible to use prior knowledge and motion modeling technique to achieve markerless 4D-CBCT phase sorting. National Institutes of Health Grant No. R01-CA184173 Varian Medical System.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2017

Heat Treatment of Iron-Carbon Alloys in a Magnetic Field (Phase 2)

Thermomagnetic processing was shown to shift the phase transformation temperatures and therefore microstructural evolution in the high performance engine valve spring 9254 steel alloy by applying a high magnetic field during cooling. These effects would be anticipated to improve performance such as high cycle fatigue as demonstrated in prior projects. Thermomagnetic processing of gears and crank shafts was constrained by the size of the prototype equipment currently available at ORNL. However, the commercial procurement viability of production scale 9-Tesla, 16-inch diameter bore thermomagnetic processing equipment for truck idler gears up to ~11-inch diameter and potential crank shaft applications was shown, as multiple superconducting magnet manufacturing companies (in conjunction with an induction heat treating company, AjaxTOCCO Magnethermic) offered cryogen-free or cryocooler equipment designs to Cummins.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Measurement of toroidal variation in conducted heat loads in locked mode induced disruptions on DIII-D

Locked mode disruptions with controlled toroidal phase are produced in the DIII-­D tokamak by locking to large non-­axisymmetric applied magnetic perturbations with different toroidal phases. Additionally, the disruption conducted heat loads are found to go almost completely to the outer divertor region, possibly due to strong inner leg detachment, but possibly also due to plasma motion and limiting on the outer divertor leg shelf. The outer leg conducted heat loads are found to have a significant toroidal variation of order ±30%, with a dominantly n = 1 structure. The heat load phase is shifted from initial locked mode phase in a way that is approximately consistent with heat loss into the scrape-­off layer being enhanced at the mode island O-­point outer midplane crossing. These measurements suggest that pre-­existing locked modes can affect the conducted heat load structure during the thermal quench by affecting the thermal quench MHD phase. This is consistent with previous MHD simulations which indicated that pre-­disruption locked mode structures can persist and survive to some degree through the large thermal quench MHD. Finally, this work complements previous work [Shiraki2015] which showed that n = 1 structures in mitigated disruptions can create toroidal variation in the disruption radiated power.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1981

Faraday rotation measurement method and apparatus

A method and device for measuring Faraday rotation of a received RF signal is described. A simultaneous orthogonal polarization receiver compensates for a 3 db loss due to splitting of a received signal into left circular and right circular polarization channels. The compensation is achieved by RF and modulation arraying utilizing a specific receiver array which also detects and measures Faraday rotation in the presence or absence of spin stabilization effects on a linear polarization vector. Either up-link or down-link measurement of Faraday rotation is possible. Specifically, the Faraday measurement apparatus utilized in conjunction with the specific receiver array provides a means for comparing the phase of a reference signal in the receiver array to the phase of a tracking loop signal related to the incoming signal, and comparing the phase of the reference signal to the phase of the tracking signal shifted in phase by 90 degrees. The averaged and unaveraged signals, are compared, the phase changes between the two signals being related to Faraday rotation.

Brockman, M. H.↗
NASA NTRS2013

Can the 62 Day X-ray Period of ULX M82 X-1 Be Due to a Precessing Accretion Disk?

We have analyzed all the archival RXTE/PCA monitoring observations of the ultraluminous X-ray source (ULX) M82 X-1 in order to study the properties of its previously discovered 62 day X-ray period (Kaaret & Feng 2007). Based on the high coherence of the modulation it has been argued that the observed period is the orbital period of the binary. Utilizing a much longer data set than in previous studies we find: (1) The phase-resolved X-ray (3-15 keV) energy spectra - modeled with a thermal accretion disk and a power-law corona - suggest that the accretion disk's contribution to the total flux is responsible for the overall periodic modulation while the power-law flux remains approximately constant with phase. (2) Suggestive evidence for a sudden phase shift-of approximately 0.3 in phase (20 days)-between the first and the second halves of the light curve separated by roughly 1000 days. If confirmed, the implied timescale to change the period is approx. = 10 yrs, which is exceptionally fast for an orbital phenomenon. These independent pieces of evidence are consistent with the 62 day period being due to a precessing accretion disk, similar to the so-called super-orbital periods observed in systems like Her X-1, LMC X-4, and SS433. However, the timing evidence for a change in the period needs to be confirmed with additional observations. This should be possible with further monitoring of M82 with instruments such as the X-ray telescope (XRT) on board Swift.

ULX M82↗
NASA NTRS1976

A generalization of MSK-type signaling based upon input data symbol pulse shaping

Minimum-shift-keying (MSK), which is a special case of continuous phase frequency-shift-keying (CPFSK) with frequency deviation ratio equal to 0.5, is known to be spectrally equivalent to a form of offset quadrature phase-shift-keying (OQPSK) in which the symbol pulse shape is a half-cycle sinusoid rather than the usual rectangular form. Appropriate shaping of the input data symbols allows one to generate an entire class of constant envelope, MSK-type signals, whose spectral properties are in some applications more desirable than those of MSK or OQPSK. The present study derives and presents a set of conditions on the input pulse shaping which in turn describes the class of envelope shapes allowable. The autocorrelation function and power spectral density of this class of signals are then derived, and specific examples are given to illustrate the desirable spectral properties. Such properties are important considerations in system design where interchannel and intersymbol interference degradations must be kept to a minimum.

Simon, M. K.↗
DOE OSTI2021

Phase noise limited frequency shift impulsive Raman spectroscopy

We introduce a method to enable optical amplification of a coherent Raman spectroscopy signal, which we call radio frequency (RF) Doppler Raman spectroscopy. In this article, we consider the perturbation of a probe pulse in a sample due to an excited Raman vibrational coherence as a generalized Doppler shift, which connects a time-varying optical path length (the product of the propagation length and refractive index, OPL = n ℓ) with an optical frequency shift. Amplification of a Raman signal outside of the focused interaction is enabled by converting the Doppler frequency shift experienced by a laser probe pulse into a periodic timing jitter. This transit time perturbation is detected through the phase of a RF electronic signal measured at a harmonic of the probe pulse train with a method adapted from precision metrology techniques used to measure laser pulse train timing jitter. Measurement of a timing jitter allows access to much lower noise floors than other coherent Raman techniques, and by exploiting the new capability to scale the signal of a coherent Raman spectroscopic signal, this method opens the potential to detect very weak Raman signals that are currently not observable due to limits of illumination intensity imposed by laser damage to the specimen and noise.

47 OTHER INSTRUMENTATION↗
NASA NTRS1987

Opposite direction multiple-phase clocking in adjacent CCD shift registers

Parallelled charge transfer channels have multiple-phase-clocked gate electrodes overspanning them in one of a number of arrangements conditioning the transfer of charge packets in opposing directions in adjacent charge transfer channels. Three-phase, four-phase, five-phase and six-phase clocking arrangements constructed in three layers of polysilicon embody the invention.

Elabd, Hammam↗
DOE OSTI2020

Vibrational spectroscopy of shock compressed condensed phase nitrous oxide: Frequency shifts in the ν 1 mode

Over many years, we have published vibrational spectra of molecular materials at extreme pressure and temperature obtained using shock compression and coherent Raman spectroscopy methods. For diatomic molecules, we were able to extract vibrational temperatures from the intensities of spectrally resolved vibrational hot bands. Larger molecules in the condensed phase suffer band broadening effects that obscure the vibrational hot bands as the anharmonicities are typically smaller than the widths of the bands. This inability to resolve the hot bands inhibits the extraction of vibrational temperature and the measurement of the vibrational frequency of the fundamental. Here, we use a hot band model based on gas-phase anharmonic coupling coefficients to fit coherent anti-Stokes Raman spectra of the ν 1 vibrational mode of shock compressed condensed phase N 2 O with shock pressures and temperatures estimated from literature equations of state and compare to fits from a model using a single Gaussian peak. We report the resulting vibrational frequency shifts with shock pressure.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Elastic and electronic tuning of magnetoresistance in MoTe 2

Quasi–two-dimensional transition metal dichalcogenides exhibit dramatic properties that may transform electronic and photonic devices. We report on how the anomalously large magnetoresistance (MR) observed under high magnetic field in MoTe 2 , a type II Weyl semimetal, can be reversibly controlled under tensile strain. The MR is enhanced by as much as ~30% at low temperatures and high magnetic fields when uniaxial strain is applied along the a crystallographic direction and reduced by about the same amount when strain is applied along the b direction. We show that the large in-plane electric anisotropy is coupled with the structural transition from the 1T' monoclinic to the T d orthorhombic Weyl phase. A shift of the T d -1T' phase boundary is achieved by minimal tensile strain. The sensitivity of the MR to tensile strain suggests the possibility of a nontrivial spin-orbital texture of the electron and hole pockets in the vicinity of Weyl points. Our ab initio calculations show a significant orbital mixing on the Fermi surface, which is modified by the tensile strains.

36 MATERIALS SCIENCE↗