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Near-infrared observations of sio maser-emitting asymptotic giant branch (AGB) stars

Near-infrared (NIR) monitoring observations of asymptotic giant branch stars exciting bright SiO masers have been made with the 1 m telescope of Kagoshima University. In order to investigate the properties of these stars and their envelopes, we combined our NIR photometric data with mid- and far-infrared flux data obtained by the IRAS satellite, SiO maser flux data provided by the Nobeyama Radio Observatory, visual magnitude data provided by the AAVSO, and the reported data on the expansion velocities of the circumstellar envelopes. The absolute magnitudes at the K-band and the distances are estimated using the period–luminosity relation of Mira variables determined by Feast et al. Then, mass-loss rates and isotropic luminosities of an SiO maser are estimated. The mass-loss rates range from approximately 10{sup −8} M{sub ⊙} yr{sup −1} to over 10{sup −5} M{sub ⊙} yr{sup −1}. We found that the NIR pulsation amplitudes are correlated with the pulsation periods and the observed wavelengths. We also found correlations of the isotropic luminosities of SiO masers with the mass-loss rates and absolute magnitudes at the K-band. These results will help us to understand the pumping mechanism of SiO masers. We measured, for the first time, the periods and/or NIR magnitudes of TX Cam, BW Cam, IRAS 06297+4045, IRAS 18387–0423, and RT Cep.

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THE CHEMICAL COMPOSITIONS OF VERY METAL-POOR STARS HD 122563 AND HD 140283: A VIEW FROM THE INFRARED

From high resolution (R ≃ 45,000), high signal-to-noise ratio (S/N > 400) spectra gathered with the Immersion Grating Infrared Spectrograph (IGRINS) in the H and K photometric bands, we have derived elemental abundances of two bright, well-known metal-poor halo stars: the red giant HD 122563 and the subgiant HD 140283. Since these stars have metallicities approaching [Fe/H] = −3, their absorption features are generally very weak. Neutral-species lines of Mg, Si, S and Ca are detectable, as well as those of the light odd-Z elements Na and Al. The derived IR-based abundances agree with those obtained from optical-wavelength spectra. For Mg and Si the abundances from the infrared transitions are improvements to those derived from shorter wavelength data. Many useful OH and CO lines can be detected in the IGRINS HD 122563 spectrum, from which derived O and C abundances are consistent to those obtained from the traditional [O i] and CH features. IGRINS high resolutions H- and K-band spectroscopy offers promising ways to determine more reliable abundances for additional metal-poor stars whose optical features are either not detectable, or too weak, or are based on lines with analytical difficulties.

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Search for hyperluminous infrared dust-obscured galaxies selected with WISE and SDSS

We aim to search for hyperluminous infrared (IR) galaxies (HyLIRGs) with IR luminosity L{sub IR} > 10{sup 13} L{sub ☉} by applying the selection method of dust-obscured galaxies (DOGs). They are spatially rare but could correspond to a maximum phase of cosmic star formation (SF) and/or active galactic nucleus (AGN) activity; hence, they are a crucial population for understanding the SF and mass assembly history of galaxies. Combining the optical and IR catalogs obtained from the Sloan Digital Sky Survey (SDSS) and Wide-field Infrared Survey Explorer (WISE), we performed the extensive HyLIRGs survey; we selected 5311 IR-bright DOGs with i − [22] > 7.0 and flux at 22 μm > 3.8 mJy in 14,555 deg{sup 2}, where i and [22] are i-band and 22 μm AB magnitudes, respectively. Among them, 67 DOGs have reliable spectroscopic redshifts that enable us to estimate their total IR luminosity based on the spectral energy distribution fitting. Consequently, we successfully discovered 24 HyLIRGs among the 67 spectroscopically confirmed DOGs. We found that (i) i − [22] color of IR-bright DOGs correlates with the total IR luminosity and (ii) the surface number density of HyLIRGs is >0.17 deg{sup −2}. A large fraction (∼73%) of IR-bright DOGs with i − [22] > 7.5 show L{sub IR} > 10{sup 13} L{sub ☉}, and the DOG criterion we adopted could be independently effective against the “W1W2-dropout method,” based on four WISE bands, for searching hyperluminous IR populations of galaxies.

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Infrared observations of the quintuplet proper members using SOFIA/FORCAST and GEMINI/TReCS

Since their discovery, the Quintuplet proper members (QPMs) have been somewhat mysterious in nature. Originally dubbed the “cocoon stars” due to their cool featureless spectra, high-resolution near-infrared imaging observations have shown that at least two of the objects exhibit “pinwheel” nebulae consistent with binary systems with a carbon-rich Wolf–Rayet star and O/B companion. In this paper, we present 19.7, 25.2, 31.5, and 37.1 μm observations of the QPMs (with an angular resolution of 3.2″–3.8″) taken with the Faint Object Infrared Camera for the SOFIA Telescope (FORCAST) in conjunction with high-resolution (∼0.1″–0.2″) images at 8.8 and 11.7 μm from the Thermal-Region Camera Spectrograph (TReCS). DUSTY models of the thermal dust emission of two of the four detected QPMs, Q2 and Q3, are fitted by radial density profiles that are consistent with constant mass-loss rates (ρ{sub d}∝r{sup −2}). For the two remaining sources, Q1 and Q9, extended structures (∼1″) are detected around these objects in high-resolution imaging data. Based on the fitted dust masses, Q9 has an unusually large dust reservoir (M{sub d}=1.3{sub −0.4}{sup +0.8}×10{sup −3}M{sub ⊙}) compared to typical dusty Wolf–Rayet stars, which suggests that it may have recently undergone an episode of enhanced mass loss.

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THE MID-INFRARED EVOLUTION OF THE FU ORIONIS DISK

We present new SOFIA-FORCAST observations obtained in 2016 February of the archetypal outbursting low-mass young stellar object FU Orionis, and we compare the continuum, solid-state, and gas properties with mid-infrared data obtained at the same wavelengths in 2004 with Spitzer -IRS. In this study, we conduct the first mid-infrared spectroscopic comparison of an FUor over a long time period. Over a 12-year period, UBVR monitoring indicates that FU Orionis has continued its steady decrease in overall brightness by ∼14%. We find that this decrease in luminosity occurs only at wavelengths ≲20 μ m. In particular, the continuum shortward of the silicate emission complex at 10 μ m exhibits a ∼12% (∼3 σ ) drop in flux density but no apparent change in slope; both the Spitzer and SOFIA spectra are consistent with a 7200 K blackbody. Additionally, the detection of water absorption is consistent with the Spitzer spectrum. The silicate emission feature at 10 μ m continues to be consistent with unprocessed grains, unchanged over 12 years. We conclude that either the accretion rate in FU Orionis has decreased by ∼12–14% over this time baseline or the inner disk has cooled, but the accretion disk remains in a superheated state outside the innermost region.

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MID-INFRARED SPECTROSCOPIC OBSERVATIONS OF THE DUST-FORMING CLASSICAL NOVA V2676 OPH

The dust-forming nova V2676 Oph is unique in that it was the first nova to provide evidence of C{sub 2} and CN molecules during its near-maximum phase and evidence of CO molecules during its early decline phase. Observations of this nova have revealed the slow evolution of its lightcurves and have also shown low isotopic ratios of carbon ({sup 12}C/{sup 13}C) and nitrogen ({sup 14}N/{sup 15}N) in its envelope. These behaviors indicate that the white dwarf (WD) star hosting V2676 Oph is a CO-rich WD rather than an ONe-rich WD (typically larger in mass than the former). We performed mid-infrared spectroscopic and photometric observations of V2676 Oph in 2013 and 2014 (respectively 452 and 782 days after its discovery). No significant [Ne ii] emission at 12.8 μ m was detected at either epoch. These provided evidence for a CO-rich WD star hosting V2676 Oph. Both carbon-rich and oxygen-rich grains were detected in addition to an unidentified infrared feature at 11.4 μ m originating from polycyclic aromatic hydrocarbon molecules or hydrogenated amorphous carbon grains in the envelope of V2676 Oph.

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High Spatial Resolution Thermal Infrared Spectroscopy with ALES: Resolved Spectra of the Benchmark Brown Dwarf Binary HD 130948BC

We present 2.9–4.1 μm integral field spectroscopy of the L4+L4 brown dwarf binary HD 130948BC, obtained with the Arizona Lenslets for Exoplanet Spectroscopy (ALES) mode of the Large Binocular Telescope Interferometer. The HD 130948 system is a hierarchical triple system, in which the G2V primary is joined by two co-orbiting brown dwarfs. By combining the age of the system with the dynamical masses and luminosities of the substellar companions, we can test evolutionary models of cool brown dwarfs and extrasolar giant planets. Previous near-infrared studies suggest a disagreement between HD 130948BC luminosities and those derived from evolutionary models. We obtained spatially resolved, low-resolution (R ∼ 20) L-band spectra of HD 130948B and C to extend the wavelength coverage into the thermal infrared. Jointly using JHK photometry and ALES L-band spectra for HD 130948BC, we derive atmospheric parameters that are consistent with parameters derived from evolutionary models. We leverage the consistency of these atmospheric quantities to favor a younger age (0.50 ± 0.07 Gyr) of the system compared to the older age (0.79{sub −0.15}{sup +0.22} Gyr) determined with gyrochronology in order to address the luminosity discrepancy.

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Intermediate-mass Early-type Disk Galaxies in the Virgo Cluster. II. Near-Infrared Spectra and Evidence for Differences in Evolution

We discuss near-infrared (NIR) slit spectra of six early-type disk galaxies in the Virgo Cluster that were examined previously at visible/red wavelengths. Despite having similar intrinsic luminosities, colors, and morphologies, the NIR spectrophotometric properties of these galaxies indicate that they are not a homogeneous ensemble differing only in terms of luminosity-weighted age and metallicity. While the depth of the CO(2,0) band is consistent with the centers of these galaxies having solar or slightly sub-solar luminosity-weighted metallicities, galaxy-to-galaxy variations in the depth of the Na i 2.21 μm doublet are found, with Na i2.21 μm lines in three galaxies (NGC 4491, NGC 4584, and NGC 4620) that are deeper than those predicted for a solar chemical mixture and a solar-neighborhood mass function. In contrast, the Ca i2.26 μm triplet shows good galaxy-to-galaxy agreement but tends to be deeper than the model prediction. Considering the depth of the NaD lines, the deep Na i2.21 μm lines are tentatively attributed to a bottom-heavy mass function. This is counter to observed trends between mass function slope and velocity dispersion, and so the possibility of a super-solar [Na/Fe] is also discussed. Two of the three galaxies with deep Na i 2.21 μm (NGC 4584 and NGC 4620) have Sérsic exponents that are consistent with a classical bulge. As for NGC 4491, its central NIR spectrum contains prominent emission lines. The relative strengths of Brγ and H{sub 2}S(1), the presence of [Fe ii] emission, and the mid-infrared spectral-energy distribution are all consistent with intense recent star formation near the center of that galaxy. The NIR spectrum of NGC 4584 is devoid of line emission in the NIR, suggesting that star formation does not power the emission detected at visible wavelengths from that galaxy. Wavelengths that contain the Ballick–Ramsey C{sub 2} band at 1.76 μm are matched by moderately metal-poor E-MILES model spectra with an age of 2 Gyr. The radial age trends in these galaxies are in the opposite sense to those in late-type disk galaxies, and it is concluded that they have evolved in a cluster environment for at least several Gyr.

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SCExAO/CHARIS Near-infrared Integral Field Spectroscopy of the HD 15115 Debris Disk

We present new, near-infrared (1.1–2.4 μm) high-contrast imaging of the debris disk around HD 15115 with the Subaru Coronagraphic Extreme Adaptive Optics (SCExAO) system coupled with the Coronagraphic High Angular Resolution Imaging Spectrograph (CHARIS). The SCExAO/CHARIS resolves the disk down to ρ ∼ 0.″2 (r {sub proj} ∼ 10 au), a factor of ∼3–5 smaller than previous recent studies. We derive a disk position angle of PA ∼ 279.°4–280.°5 and an inclination of i ∼ 85.°3–86.2.°. While recent SPHERE/IRDIS imagery of the system could suggest a significantly misaligned two-ring disk geometry, CHARIS imagery does not reveal conclusive evidence for this hypothesis. Moreover, optimizing models of both one- and two-ring geometries using differential evolution, we find that a single ring having a Hong-like scattering phase function matches the data equally well within the CHARIS field of view (ρ ≲ 1″). The disk’s asymmetry, well evidenced at larger separations, is also recovered; the west side of the disk appears, on average, around 0.4 mag brighter across the CHARIS bandpass between 0.″25 and 1″. Comparing Space Telescope Imaging Spectrograph (STIS) 50CCD optical photometry (2000–10500 Å) with CHARIS near-infrared photometry, we find a red (STIS/50CCD−CHARIS broadband) color for both sides of the disk throughout the 0.″4–1″ region of overlap, in contrast to the blue color reported at similar wavelengths for regions exterior to ∼2″. Further, this color may suggest a smaller minimum grain size than previously estimated at larger separations. Finally, we provide constraints on planetary companions and discuss possible mechanisms for the observed inner disk flux asymmetry and color.

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HAWC+ Far-infrared Observations of the Magnetic Field Geometry in M51 and NGC 891

Stratospheric Observatory for Infrared Astronomy High-resolution Airborne Wideband Camera Plus polarimetry at 154 μm is reported for the face-on galaxy M51 and the edge-on galaxy NGC 891. For M51, the polarization vectors generally follow the spiral pattern defined by the molecular gas distribution, the far-infrared (FIR) intensity contours, and other tracers of star formation. The fractional polarization is much lower in the FIR-bright central regions than in the outer regions, and we rule out loss of grain alignment and variations in magnetic field strength as causes. When compared with existing synchrotron observations, which sample different regions with different weighting, we find the net position angles are strongly correlated, the fractional polarizations are moderately correlated, but the polarized intensities are uncorrelated. We argue that the low fractional polarization in the central regions must be due to significant numbers of highly turbulent segments across the beam and along lines of sight in the beam in the central 3 kpc of M51. For NGC 891, the FIR polarization vectors within an intensity contour of 1500 MJy sr{sup −1} are oriented very close to the plane of the galaxy. The FIR polarimetry is probably sampling the magnetic field geometry in NGC 891 much deeper into the disk than is possible with NIR polarimetry and radio synchrotron measurements. In some locations in NGC 891, the FIR polarization is very low, suggesting we are preferentially viewing the magnetic field mostly along the line of sight, down the length of embedded spiral arms. There is tentative evidence for a vertical field in the polarized emission off the plane of the disk.

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High-resolution Near-infrared Spectroscopy of Diffuse Sources around MWC 1080

To reveal the origins of diffuse Hα emissions observed around the Herbig star MWC 1080, we have performed a high-resolution near-infrared (NIR) spectroscopic observation using the Immersion Grating Infrared Spectrograph. In the NIR H and K bands, we detected various emission lines (six hydrogen Brackett lines, seven H{sub 2} lines, and an [Fe ii] line) and compared their spatial locations with the optical (Hα and [S ii]) and radio ({sup 13}CO and CS) line maps. The shock-induced H{sub 2} and [Fe ii] lines indicate the presence of multiple outflows, consisting of at least three associated young stars in this region. The kinematics of H{sub 2} and [Fe ii] near the northeast (NE) cavity edge supports the idea that the NE main outflow from MWC 1080A is the blueshifted one with a low inclination angle. The H{sub 2} and [Fe ii] lines near the southeast molecular region newly reveal that additional highly blueshifted outflows originate from other young stars. The fluorescent H{sub 2} lines were found to trace photodissociation regions formed on the cylindrical surfaces of the main outflow cavity, which are expanding outward with a velocity of about 10–15 km s{sup −1}. For the Hα emission, we identify its components associated with two stellar outflows and two young stars in addition to the dominant component of MWC 1080A scattered by dust. We also report a few faint Hα features located ∼0.4 pc away in the southwest direction from MWC 1080A, which lie near the axes of the NE main outflow and one of the newly identified outflows.

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SPITZER OBSERVATIONS OF LONG-TERM INFRARED VARIABILITY AMONG YOUNG STELLAR OBJECTS IN CHAMAELEON I

Infrared variability is common among young stellar objects, with surveys finding daily to weekly fluctuations of a few tenths of a magnitude. Space-based observations can produce highly sampled infrared light curves, but are often limited to total baselines of about 1 month due to the orientation of the spacecraft. Here we present observations of the Chameleon I cluster, whose low declination makes it observable by the Spitzer Space Telescope over a 200-day period. We observe 30 young stellar objects with a daily cadence to better sample variability on timescales of months. We find that such variability is common, occurring in ∼80% of the detected cluster members. The change in [3.6]–[4.5] color over 200 days for many of the sources falls between that expected for extinction and fluctuations in disk emission. With our high cadence and long baseline we can derive power spectral density curves covering two orders of magnitude in frequency and find significant power at low frequencies, up to the boundaries of our 200-day survey. Such long timescales are difficult to explain with variations driven by the interaction between the disk and stellar magnetic field, which has a dynamical timescale of days to weeks. The most likely explanation is either structural or temperature fluctuations spread throughout the inner ∼0.5 au of the disk, suggesting that the intrinsic dust structure is highly dynamic.

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THE PHYSICAL ENVIRONMENT AROUND IRAS 17599–2148: INFRARED DARK CLOUD AND BIPOLAR NEBULA

We present a multiscale and multiwavelength study to investigate the star formation process around IRAS 17599–2148, which is part of an elongated filamentary structure (EFS) (extension ∼21 pc) seen in the Herschel maps. Using the Herschel data analysis, at least six massive clumps (M {sub clump} ∼ 777–7024 M {sub ⊙}) are found in the EFS with a range of temperature and column density of ∼16–39 K and ∼(0.6–11) × 10{sup 22} cm{sup −2} (A {sub V} ∼ 7–117 mag), respectively. The EFS hosts cold gas regions (i.e., infrared dark cloud) without any radio detection and a bipolar nebula (BN) linked with the H ii region IRAS 17599–2148, tracing two distinct environments inferred through the temperature distribution and ionized emission. Based on virial analysis and higher values of self-gravitating pressure, the clumps are found unstable against gravitational collapse. We find 474 young stellar objects (YSOs) in the selected region, and ∼72% of these YSOs are found in the clusters distributed mainly toward the clumps in the EFS. These YSOs might have spontaneously formed due to processes not related to the expanding H ii region. At the edges of BN, four additional clumps are also associated with YSO clusters, which appear to be influenced by the expanding H ii region. The most massive clump in the EFS contains two compact radio sources traced in the Giant Metre-wave Radio Telescope 1.28 GHz map and a massive protostar candidate, IRS 1, prior to an ultracompact H ii phase. Using the Very Large Telescope/NACO near-infrared images, IRS 1 is resolved with a jet-like feature within a 4200 au scale.

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Clustering of infrared-bright dust-obscured galaxies revealed by the Hyper Suprime-Cam and WISE

We present measurements of the clustering properties of a sample of infrared (IR) bright dust-obscured galaxies (DOGs). Combining 125 deg{sup 2} of wide and deep optical images obtained with the Hyper Suprime-Cam on the Subaru Telescope and all-sky mid-IR images taken with Wide-Field Infrared Survey Explorer, we have discovered 4367 IR-bright DOGs with (i−[22]){sub AB}>7.0 and flux density at 22 μm>1.0 mJy. We calculate the angular autocorrelation function (ACF) for a uniform subsample of 1411 DOGs with 3.0 mJy < flux (22 μm) < 5.0 mJy and i{sub AB} < 24.0. The ACF of our DOG subsample is well-fit with a single power law, ω(θ) = (0.010 ± 0.003) θ{sup −0.9}, where θ is in degrees. The correlation amplitude of IR-bright DOGs is larger than that of IR-faint DOGs, which reflects a flux dependence of the DOG clustering, as suggested by Brodwin et al. We assume that the redshift distribution for our DOG sample is Gaussian, and consider two cases: (1) the redshift distribution is the same as IR-faint DOGs with flux at 22 μm < 1.0 mJy, mean and sigma z = 1.99 ± 0.45, and (2) z = 1.19 ± 0.30, as inferred from their photometric redshifts. The inferred correlation length of IR-bright DOGs is r{sub 0} = 12.0 ± 2.0 and 10.3 ± 1.7 h{sup −1} Mpc, respectively. IR-bright DOGs reside in massive dark matter halos with a mass of log[〈M{sub h}〉/(h{sup −1} M{sub ⊙})]=13.57{sub −0.55}{sup +0.50} and 13.65{sub −0.52}{sup +0.45} in the two cases, respectively.

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The complete infrared view of active galactic nuclei from the 70 month Swift/BAT catalog

We systematically investigate the near- to far-infrared (FIR) photometric properties of a nearly complete sample of local active galactic nuclei (AGNs) detected in the Swift/Burst Alert Telescope (BAT) all-sky ultra-hard X-ray (14–195 keV) survey. Out of 606 non-blazar AGNs in the Swift/BAT 70 month catalog at high galactic latitudes of |b|>10{sup ∘}, we obtain IR photometric data of 604 objects by cross-matching the AGN positions with catalogs from the WISE, AKARI, IRAS, and Herschel infrared observatories. We find a good correlation between the ultra-hard X-ray and mid-IR luminosities over five orders of magnitude (41<logL{sub 14--195}<46). Informed by previous measurements of the intrinsic spectral energy distribution of AGNs, we find FIR pure-AGN candidates whose FIR emission is thought to be AGN-dominated with low star-formation activity. We demonstrate that the dust covering factor decreases with the bolometric AGN luminosity, confirming the luminosity-dependent unified scheme. We also show that the completeness of the WISE color–color cut in selecting Swift/BAT AGNs increases strongly with 14–195 keV luminosity.

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On the Incidence of Wise Infrared Excess Among Solar Analog, Twin, and Sibling Stars

This study presents a search for infrared (IR) excess in the 3.4, 4.6, 12, and 22 μ m bands in a sample of 216 targets, composed of solar sibling, twin, and analog stars observed by the Wide-field Infrared Survey Explorer ( WISE ) mission. In general, an IR excess suggests the existence of warm dust around a star. We detected 12 μ m and/or 22 μ m excesses at the 3 σ level of confidence in five solar analog stars, corresponding to a frequency of 4.1% of the entire sample of solar analogs analyzed, and in one out of 29 solar sibling candidates, confirming previous studies. The estimation of the dust properties shows that the sources with IR excesses possess circumstellar material with temperatures that, within the uncertainties, are similar to that of the material found in the asteroid belt in our solar system. No photospheric flux excess was identified at the W1 (3.4 μ m) and W2 (4.6 μ m) WISE bands, indicating that, in the majority of stars of the present sample, no detectable dust is generated. Interestingly, among the 60 solar twin stars analyzed in this work, no WISE photospheric flux excess was detected. However, a null-detection excess does not necessarily indicate the absence of dust around a star because different causes, including dynamic processes and instrument limitations, can mask its presence.

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Optical and Near-infrared Spectra of σ Orionis Isolated Planetary-mass Objects

We have obtained low-resolution optical (0.7–0.98 μ m) and near-infrared (1.11–1.34 μ m and 0.8–2.5 μ m) spectra of 12 isolated planetary-mass candidates ( J = 18.2–19.9 mag) of the 3 Myr σ Orionis star cluster with the aim of determining the spectroscopic properties of very young, substellar dwarfs and assembling a complete cluster mass function. We have classified our targets by visual comparison with high- and low-gravity standards and by measuring newly defined spectroscopic indices. We derived L0–L4.5 and M9–L2.5 using high- and low-gravity standards, respectively. Our targets reveal clear signposts of youth, thus corroborating their cluster membership and planetary masses (6–13 M {sub Jup}). These observations complete the σ Orionis mass function by spectroscopically confirming the planetary-mass domain to a confidence level of ∼75%. The comparison of our spectra with BT-Settl solar metallicity model atmospheres yields a temperature scale of 2350–1800 K and a low surface gravity of log g ≈ 4.0 [cm s{sup −2}], as would be expected for young planetary-mass objects. We discuss the properties of the cluster’s least-massive population as a function of spectral type. We have also obtained the first optical spectrum of S Ori 70, a T dwarf in the direction of σ Orionis. Our data provide reference optical and near-infrared spectra of very young L dwarfs and a mass function that may be used as templates for future studies of low-mass substellar objects and exoplanets. The extrapolation of the σ Orionis mass function to the solar neighborhood may indicate that isolated planetary-mass objects with temperatures of ∼200–300 K and masses in the interval 6–13 M {sub Jup} may be as numerous as very low-mass stars.

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Variations in the Infrared Spectra of Wüstite with Defects and Disorder

The presence of FeO particles in circumstellar space has been suggested based on the observation of a mysterious 21 μm emission band. However, the complete infrared spectra of FeO have not been obtained so far; hence, data of the infrared (IR) spectra of FeO need to be investigated. We prepared synthetic and commercial samples of FeO, which were obtained by crushing bulk samples, annealing iron oxalate dihydrate (FeC{sub 2}O{sub 4}⋅2H{sub 2}O), and mechanical milling of a powder mixture comprising (Fe and Fe{sub 2}O{sub 3}) particles with different milling times. We present a new study on the IR spectra of these samples, and show that these spectra changed according to defects and disorders. Furthermore, FeO particles are very sensitive to oxygen fugacity and temperature. The spectra of FeO particles were compared with the unidentified observed feature. It may be difficult for FeO particles to exist alone in the ISM and circumstellar space. This may be connected to the problem of missing iron in the ISM.

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