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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,783 records · Page 99
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Measurement of turbulent velocity and bounds for thermal diffusivity in laser shock compressed foams by x-ray photon correlation spectroscopy

Experimental benchmarking of transport coefficients under extreme conditions is required for validation of differing theoretical models. To date, measurement of transport properties of dynamically compressed samples remains a challenge with only a limited number of studies able to quantify transport in high pressure and temperature matter. x-ray photon correlation spectroscopy utilizes coherent x-ray sources to measure time correlations of density fluctuations, thus providing measurements of length and timescale-dependent transport properties. Here, we present a first-of-a-kind experiment to conduct x-ray photon correlation spectroscopy in laser shock compression experiments. We report measurement of the turbulent velocity in the wake of a laser driven supersonic shock and place an upper bound on thermal diffusivity in a solid density plasma on nanosecond timescales.

High-energy-density plasmas↗
NASA NTRS1990

Additions and corrections to the absorption coefficients of CO2 ice - Applications to the Martian south polar cap

Reflectance spectra of carbon dioxide frosts were calculated using the optical constants provided by Warren (1986) for the wavelength region 2-6 microns. In comparing these calculated spectra to spectra of frosts observed in the laboratory and on the surface of Mars, problems in the optical constants presented by Warren (1986) became apparent. Absorption coefficients for CO2 ice have been derived using laboratory reflectance measurements and the Hapke (1981) model for calculating diffuse reflectance. This provides approximate values in regions where no data were previously available and indicates where corrections to the compilation by Warren (1986) are required. Using these coefficients to calculate the reflectance of CO2 ice at varying grain sizes indicates that a typical Mariner polar cap spectrum is dominated by absorptions due to CO2 frost or ice at grain sizes that are quite large, probably of the order of millimeters to centimeters. There are indications of contamination of water frost or dust, but confirmation will require more precise absorption coefficients for solid CO2 than can be obtained from the method used here.

Calvin, Wendy M.↗
DOE OSTI2025

Optimizing energy yield of monolithic perovskite/silicon tandem solar cells in real-world Conditions: The impact of luminescent coupling

Efficient light management is key to maximizing power conversion efficiency (PCE) in monolithic perovskite/silicon tandem solar cells. Achieving peak efficiency requires closely matched current generation in all junctions, especially in integrated configurations. However, real-world conditions vary significantly due to factors such as sunlight spectrum, diffuse-to-direct sunlight ratio, angular distribution of light, subcell temperature coefficients, and ground reflection. This study introduces a comprehensive optical and device simulation to optimize perovskite/silicon tandem cells, considering experimental luminescent coupling (LC) efficiency and its dependence on working conditions, alongside variations in radiative recombination, effect of temperature on absorptivity spectra, and cloud cover. Our results show potential energy yield improvements of up to 1.4 % with LC, based on current perovskite radiative recombination records, and up to 4 % with direct bandgap materials. Although radiative recombination's dependence on excitation intensity reduces output power and requires thicker absorbers, LC compensates for these losses. LC also lowers the optimized bandgap for the perovskite top cell from 1.72 eV to 1.64–1.68 eV, or even lower in regions with redshifted irradiance. Additionally, optimization revealed that thinner silicon bottom cells require a higher perovskite top cell bandgap, impacting the balance between fabrication cost and cell stability.

14 SOLAR ENERGY↗
DOE OSTI2022

Bayesian estimation of the $S$ factor and thermonuclear reaction rate for 16 O(p, γ) 17 F

The 16 O(p, γ) 17 F reaction is the slowest hydrogen-burning process in the CNO mass region. Its thermonuclear rate sensitively impacts predictions of oxygen isotopic ratios in a number of astrophysical sites, including AGB stars. The reaction has been measured several times at low bombarding energies using a variety of techniques. The most recent evaluated experimental rates have a reported uncertainty of about 7.5% below 1 GK. However, the previous rate estimate represents a best guess only and was not based on rigorous statistical methods. We apply a Bayesian model to fit all reliable 16 O(p, γ) 17 F cross section data, and take into account independent contributions of statistical and systematic uncertainties. The nuclear reaction model employed is a single-particle potential model involving a Woods-Saxon potential for generating the radial bound state wave function. The model has three physical parameters, the radius and diffuseness of the Woods-Saxon potential, and the asymptotic normalization coefficients (ANCs) of the final bound state in 17 F. Here, we find that performing the Bayesian S -factor fit using ANCs as scaling parameters has a distinct advantage over adopting spectroscopic factors instead. Based on these results, we present the first statistically rigorous estimation of experimental 16 O(p, γ) 17 F reaction rates, with uncertainties (±4.2%) of about half the previously reported values.

6 ≤ A ≤ 19↗
NASA NTRS1975

Combined environmental effects on polymers

A series of space simulation tests on FEP Teflon and other polymeric thermal control coatings was conducted using UV, electrons, protons and Lyman-alpha wavelength vacuum UV radiation. Interest was centered on simulating synchronous altitude radiation environment conditions. Physical changes in materials included loss of specularity and introduction of a high density of photographable tracking defects on a microscopic scale. An example shows the discharge of trapped electrons when dielectric strength is exceeded. This leaves a portion of the Teflon volume no longer clear, but diffusely transmitting and reflecting. Thermophysical changes included degradation of solar absorptance coefficients as much as five-fold. The situation that prevails for earth orbit contrasted with polymer performance in the solar wind. It is suggested that conductive overcoatings be developed for polymers and other flexible materials, comparable or superior to those available for fused silica SSMs.

Fogdall, L. B.↗
NASA NTRS1976

Cosmic-ray transport theory and out-of-the-ecliptic exploration

The reasons for studying cosmic-ray transport theory are summarized and the fundamentally three-dimensional nature of the process is pointed out. It is shown that observations in the solar ecliptic plane cannot unambiguously test transport theories since the solutions to the transport equations depend critically on boundary conditions and variation of parameters such as diffusion tensor out of the ecliptic. Sample calculations (Fokker-Planck coefficient) are shown which illustrate the problem. It is concluded that out-of-the-ecliptic observations are essential to further test transport theory.

Jokipii, J. R.↗
NASA NTRS1984

Transformation toughened ceramics for the heavy duty diesel engine technology program

The objective of this program is to develop an advanced high temperature oxide structural ceramic for application to the heavy duty diesel engine. The approach is to employ transformation toughening by additions of ZrO.5HfO.5O2 solid solution to the oxide ceramics, mullite (2Al2O3S2SiO2) and alumina (Al2O3). The study is planned for three phases, each 12 months in duration. This report covers Phase 1. During this period, processing techniques were developed to incorporate the ZrO.5HfO.5O2 solid solution in the matrices while retaining the necessary metastable tetragonal phase. Modulus of rupture and of elasticity, coefficient of thermal expansion, fracture toughness by indent technique and thermal diffusivity of representative specimens were measured. In Phase 2, the process will be improved to provide higher mechanical strength and to define the techniques for scale up to component size. In Phase 3, full scale component prototypes will be fabri-]cated.

Musikant, S.↗
NASA NTRS1998

[PAH Cations as Viable Carriers of DIBs]

This report is intended to fill in the blanks in NASA's file system for our lab astro study of molecular ions of astrophysical interest. In order to give NASA what it needs for its files, I attach below the text of the section from our recent proposal to continue this work, in which we describe progress to date, including a large number of publications. Our initial studies were focused on PAH cations, which appear to be viable candidates as the carriers of the DIBs, an idea that has been supported by laboratory spectroscopy of PAH cations in inert matrices. Beginning with the simplest aromatic (benzene; C6H6) and moving progressively to larger species (naphthalene, C10OH8; pyrene, C16H10; and most recently chrysene, C18H12), we have been able to derive rate coefficients for reactions with neutral spices that are abundant in the diffuse interstellar medium.

Snow, Ted↗
NASA NTRS1982

Application of Kubelka-Munk theory of diffuse reflectance to geologic problems - The role of scattering

An understanding of the reflectance spectra of scattering media is vital for the appropriate interpretation of the reflectance spectra of planetary surfaces. When the absorption coefficient (k) and the mean size of the scattering centers are small, the Kubelka-Munk (K-M) theory of diffuse reflectance is valid. Since small values of k are characteristic of a wide variety of geologically important materials over a significant range of wavelength, the K-M theory should be applicable to appropriate portions of the reflectance spectra of these media if the dimensions of the scattering centers are sufficiently small. To test the utility of the K-M theory, a comparison is conducted of a set of theoretically generated spectra with a set of independently measured experimental spectra. The similarities found in the behavior of the two sets of spectra demonstrate the applicability of the K-M theory to the understanding of physical phenomena. Aspects of wavelength-dependent scattering are investigated.

Morris, R. V.↗
NASA NTRS1976

The ionization of a low-density intercloud medium by a single O star

The ionization structure of hydrogen in a cloud-containing low-density gas surrounding an O star is calculated, emphasizing how UV photons cause the ionization of hydrogen in regions which are totally obscured from the star by neutral clouds. Particular consideration is given to the ionization of such obscured regions by diffuse Lyman continuum radiation produced when H(+) recombines directly to the ground state. The assumed physical structure of the cloud-containing neighborhood of an O star is discussed, a method is outlined for expressing the emission and absorption properties of the neutral clouds and their shadows in terms of effective volume emissivities and absorption coefficients on a line of sight, and equations of radiative transfer are derived for diffuse and stellar radiation in a cloud-containing H II region. Reradiation of Lyman continuum photons from the ionized boundary layer of a neutral cloud or shadow is analyzed. The expected emission measure across a large cloud-containing H II region is determined and found to compare well with that obtained from observations of H-alpha emission around runaway O stars. It is shown that the hydrogen in cloud shadows may be completely ionized by diffuse radiation within approximately half the Stroemgren radius, depending on the extent of that radius, the average frequency of the Lyman continuum radiation from the star, and the average cloud size.

Elmegreen, B. G.↗
DOE OSTI2020

Enabling fast charging of lithium-ion batteries through secondary- /dual- pore network: Part I - Analytical diffusion model

Battery performance is strongly correlated with electrode microstructural properties. Enabling fast charging of lithium-ion batteries requires improved through-plane ionic diffusion that can be achieved through, among other strategies, structured electrodes with a secondary- or dual-pore network (SPN). In this work, an analytical model investigates the impact of such an SPN on ionic diffusion with a composite electrode, considering various pore-channel geometries and comparing to standard electrodes with identical gravimetric- and volumetric-specific theoretical capacities. Relevant SPN design parameters and tortuosity coefficients are identified according to three optimization objectives that aim to balance the improved overall through-plane diffusion, thanks to the coarse aligned channels, and degraded in-plane diffusion because of the porous matrix densification required to maintain gravimetric- and volumetric-specific theoretical capacities. The model indicates that a relatively low amount of SPN is required and that electrodes with high through-plane tortuosity and low in-plane tortuosity benefit most from such architecture.

25 ENERGY STORAGE↗
NASA NTRS1986

Bidirectional reflectance spectroscopy. IV - The extinction coefficient and the opposition effect

An analytical model is developed for the opposition effect (heiligenshein) in the case of light scattering from a semi-infinite, particulate medium with particles that are large relative to the wavelength. The effect is common for natural materials, and comprises a brightness surge in light diffusively reflected from a surface at near zero phase. A generalized expression is devised for the extinction coefficient of a particulate medium. Models are developed for step function and hyperbolic tangent distributions of light scattered from a stratified medium and exhibiting the opposition effect. A maximum brightness amplitude increase of 0.753 is projected for the effect. Greater values must have other causes.

Hapke, B.↗
DOE OSTI2021

Reproducibility of protein x-ray diffuse scattering and potential utility for modeling atomic displacement parameters

Protein structure and dynamics can be probed using x-ray crystallography. Whereas the Bragg peaks are only sensitive to the average unit-cell electron density, the signal between the Bragg peaks—diffuse scattering—is sensitive to spatial correlations in electron-density variations. Although diffuse scattering contains valuable information about protein dynamics, the diffuse signal is more difficult to isolate from the background compared to the Bragg signal, and the reproducibility of diffuse signal is not yet well understood. We present a systematic study of the reproducibility of diffuse scattering from isocyanide hydratase in three different protein forms. Both replicate diffuse datasets and datasets obtained from different mutants were similar in pairwise comparisons (Pearson correlation coefficient ≥0.8). The data were processed in a manner inspired by previously published methods using custom software with modular design, enabling us to perform an analysis of various data processing choices to determine how to obtain the highest quality data as assessed using unbiased measures of symmetry and reproducibility. The diffuse data were then used to characterize atomic mobility using a liquid-like motions (LLM) model. This characterization was able to discriminate between distinct anisotropic atomic displacement parameter (ADP) models arising from different anisotropic scaling choices that agreed comparably with the Bragg data. Our results emphasize the importance of data reproducibility as a model-free measure of diffuse data quality, illustrate the ability of LLM analysis of diffuse scattering to select among alternative ADP models, and offer insights into the design of successful diffuse scattering experiments.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1997

High Pressure Gas Permeation and Liquid Diffusion Studies of Coflon and Tefzel Thermoplastics

The life of fluid-carrying flexible or umbilical pipes during service at elevated temperatures and pressures depends inter alia on their resistance to attack by the fluids present and the rate at which these fluids are absorbed by the pipe lining materials. The consequences of fluid ingress into the thermoplastic lining could mean a) a reduction in its mechanical strength, to increase chances of crack formation and growth and thus a loss of integrity, b) the occurrence of permeation right through the lining material, with pressure build- up in the outer pipe wall construction (of flexible pipes) or chemical attack (from a hostile permeant) on outer layers of reinforcements. Therefore it is important within this project to have relevant permeation data for Coflon and Tefzel thermoplastics: the former is plasticised, the latter is not. A previous report (CAPP/M.2) described experimental equipment and techniques used by MERL when measuring high pressure (up to 5000 psi) gas permeation and liquid diffusion through thermoplastic samples cut from extruded bar or pipe, and provided the basic theory involved. Norsk Hydro are also performing gas permeation tests on pipe sections, at up to 100 bars (1450 psi) pressure or so, and reporting separately. Some comparisons between data from Norsk Hydro and MERL have been made herein. The tests should be considered as complementary, as the Norsk Hydro test has the obvious benefit of using complete pipe sections, whilst MERL can test at much higher pressures, up to 1000 bar if necessary. The sophisticated analytical measuring equipment of Norsk Hydro can distinguish the individual components of mixed gases and hence the various permeation-linked coefficients whereas MERL, in using pressure increase at constant volume to determine permeation rate, is limited to obtaining single gas data, or apparent (or representative) coefficients for a mixed gas as a whole. Except for the initial fluid diffusion data for Tefzel described in CAPP/M.2, the present report covers all aspects of fluid permeation and diffusion for Coflon and Tefzel, including all the pen-neation data accumulated in the project to date. Test gases have mainly been methane (CH4) and carbon dioxide (CO2). More high pressure (HP) gas permeation tests have been performed since the last issue of this report, most being concerned with changes in permeation characteristics brought about by ageing in various relevant fluids. This revision supersedes previous issues.

Morgan, G. J.↗
NASA NTRS2024

Metallurgical and Thermal Properties of 57Ni–40Ti–3Hf (wt%)

Selected properties of 57Ni-40Ti-3Hf (wt%) were measured to further develop this material for use in aerospace rolling-element bearings. The average grain size and microindentation hardness of the material at room temperature were 90 μm and 549 HV, respectively. From room temperature to 500 °C, electrical resistivity increased from 8.9×10 –7 to 11.3×10 –7 Ω⋅m, thermal expansion coefficients varied from 1.1×10 –5 to 1.2×10 –5 mm/mm⋅°C, specific heat increased from 0.44 to 0.53 W⋅sec/g⋅K, thermal diffusivity rose from approximately 0.003 to 0.005 cm 2 /sec and thermal conductivity increased from approximately 0.09 to 0.19 W/cm⋅K. The behavior of the material can be explained by well-known metallurgical theory. These results are expected to provide a basis for design and modeling of future aerospace components.

intermetallics↗
NASA NTRS2011

MODIS On-orbit Calibration Uncertainty Assessment

MODIS has 20 reflective solar bands (RSB) and 16 thermal emissive bands (TEB). Compared to its heritage sensors, MODIS was developed with very stringent calibration uncertainty requirements. As a result, MODIS was designed and built with a set of on-board calibrators (OBC), which allow key sensor performance parameters and on-orbit calibration coefficients to be monitored and updated. In terms of its calibration traceability, MODIS RSB calibration is reflectance based using an on-board solar diffuser (SD) and the TEB calibration is radiance based using an on-board blackbody (BB). In addition to on-orbit calibration coefficients derived from its OBC, calibration parameters determined from sensor pre-launch calibration and characterization are used in both the RSB and TEB calibration and retrieval algorithms. This paper provides a brief description of MODIS calibration methodologies and an in-depth analysis of its on-orbit calibration uncertainties. Also discussed in this paper are uncertainty contributions from individual components and differences due to Terra and Aqua MODIS instrument characteristics and on-orbit performance.

Chiang, Vincent↗
DOE OSTI2022

Integrability breaking in the Rule 54 cellular automaton

Cellular automata have recently attracted a lot of attention as testbeds to explore the emergence of many-body quantum chaos and hydrodynamics. We consider the Rule 54 model, one of the simplest interacting integrable models featuring two species of quasiparticles (solitons), in the presence of an integrability-breaking perturbation that allows solitons to backscatter. Here, we study the onset of thermalization and diffusive hydrodynamics in this model, compute perturbatively the diffusion constant of tracer particles, and comment on its relation to transport coefficients.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗