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Transient responses of phosphoric acid fuel cell power plant system

An analytical and computerized study of the steady state and transient response of a phosphoric acid fuel cell (PAFC) system was completed. Parametric studies and sensitivity analyses of the PAFC system's operation were accomplished. Four non-linear dynamic models of the fuel cell stack, reformer, shift converters, and heat exchangers were developed based on nonhomogeneous non-linear partial differential equations, which include the material, component, energy balance, and electrochemical kinetic features. Due to a lack of experimental data for the dynamic response of the components only the steady state results were compared with data from other sources, indicating reasonably good agreement. A steady state simulation of the entire system was developed using, nonlinear ordinary differential equations. The finite difference method and trial-and-error procedures were used to obtain a solution. Using the model, a PAFC system, that was developed under NASA Grant, NCC3-17, was improved through the optimization of the heat exchanger network. Three types of cooling configurations for cell plates were evaluated to obtain the best current density and temperature distributions. The steady state solutions were used as the initial conditions in the dynamic model. The transient response of a simplified PAFC system, which included all of the major components, subjected to a load change was obtained. Due to the length of the computation time for the transient response calculations, analysis on a real-time computer was not possible. A simulation of the real-time calculations was developed on a batch type computer. The transient response characteristics are needed for the optimization of the design and control of the whole PAFC system. All of the models, procedures and simulations were programmed in Fortran and run on IBM 370 computers at Cleveland State University and the NASA Lewis Research Center.

Lu, Cheng-Yi↗

Interplanetary magnetic field control of mantle precipitation and associated field-aligned currents

Dayside reconnection, which is particularly effective for a southward interplanetary magnetic field (IMF), allows magnetosheath particles to enter the magnetosphere where they form the plasma mantle. The motions of the reconnected flux tube produce convective flows in the ionosphere. It is known that the convection patterns in the polar cap are skewed to the dawnside for a positive IMF B(sub y) (or duskside for a negative IMF B(sub y)) in the northern polar cap. Correspondingly, one would expect to find asymmetric distributions of mantle particle precipitation, but previous results have been unclear. In this paper the correlation between B(sub y) and the distribution of mantle particle precipitation is studied for steady IMF conditions with southward IMF. Ion and electron data from the Defense Meteorological Satellite Program (DMSP) F6 and F7 satellites are used to identify the mantle region and IMP 8 is used as a solar wind monitor to characterize the IMF. We study the local time extension of mantle precipitation in the prenoon and postnoon regions. We find that, in accordance with theoretical expectations for a positive (negative) IMF B(sub y), mantle particle precipitation mainly appears in the prenoon region of the northern (southern) hemisphere. The mantle particle precipitation can extend to as early as 0600 magnetic local time (MLT) in the prenoon region but extends over a smaller local time region in the postnoon sector (we did not find mantle plasma beyond 1600 MLT in our data set although coverage is scant in this area). Magnetometer data from F7 are used to determine whether part of the region 1 current flows on open field lines. We find that at times part of the region 1 sense current extends into the region of mantle particle precipitation, and is therefore on open field lines. In other cases, region 1 currents are absent on open field lines. Most of the observed features can be readily interpreted in terms of the open magnetosphere model.

Xu, Dingan↗

F-15B/Flight Test Fixture 2: A Test Bed for Flight Research

NASA Dryden Flight Research Center has developed a second-generation flight test fixture for use as a generic test bed for aerodynamic and fluid mechanics research. The Flight Test Fixture 2 (FTF-2) is a low-aspect-ratio vertical fin-like shape that is mounted on the centerline of the F-I5B lower fuselage. The fixture is designed for flight research at Mach numbers to a maximum of 2.0. The FTF-2 is a composite structure with a modular configuration and removable components for functional flexibility. This report documents the flow environment of the fixture, such as surface pressure distributions and boundary-layer profiles, throughout a matrix of conditions within the F-15B/FTF-2 flight envelope. Environmental conditions within the fixture are presented to assist in the design and testing of future avionics and instrumentation. The intent of this document is to serve as a user's guide and assist in the development of future flight experiments that use the FTF-2 as a test bed. Additional information enclosed in the appendices has been included to assist with more detailed analyses, if required.

David M Richwine↗

The CERES S'COOL Project: Development and Operational Phases

As part of NASA's Mission to Planet Earth, the first Clouds and the Earth's Radiant Energy System (CERES) instrument will be launched on the Tropical Rainfall Measuring Mission (TRMM) spacecraft from the Tanegashima launch site in Japan in November 1997. The instrument will measure the radiation budget incoming and outgoing radiant energy - of the Earth. The major feature of interest is clouds, which play a very strong role in regulating our climate. CERES will identify clear and cloudy regions and determine cloud physical and microphysical properties using imager data from a companion instrument. Validation efforts for the remote sensing algorithms will be intensive. As one component of the validation, the S'COOL (Students' Cloud Observations On-Line) project will involve school children around the globe in making ground truth measurements at the time of a CERES overpass. They will report cloud type, height, fraction, and opacity, as well as the local surface conditions. Their observations will be collected at the NASA Langley Distributed Active Archive Center (DAAC) and made available over the Internet for educational purposes as well as for use by the CERES Science Team in validation efforts. Pilot testing of the S'COOL project began in January 1997 with two local schools in Southeastern Virginia and one remote site in Montana. National testing in April 1997 involved 8 schools (grades 3 to high school) across the United States. Global testing will be carried out in October 1997. Details of the S'COOL project, which is mainly Internet-based, are being developed in each of these phases according to feedback received from participants. In 1998, when the CERES instrument is operational, a global observer network should be in place providing useful information to the scientists and learning opportunities to the students. Broad participation in the S'COOL project is planned, both to obtain data from a wide range of geographic areas, and to involve as many students as possible in learning about clouds and atmospheric science. This paper reports on the development phase of the S'COOL project, including the reaction of the teachers and students who have been involved. It describes the operational state of the S'COOL network, and identifies opportunities for additional participants.

Chambers, Lin H.↗

Modeling the Growth Rates of Tetragonal Lysozyme Crystal Faces

The measured macroscopic growth rates of the (110) and (101) faces of tetragonal lysozyme show an unexpectedly complex dependence on the supersaturation. The growth rates decay asymptotically to zero when the supersaturation is lowered to zero and increase rapidly when the supersaturation is increased. When supersaturations are increased still further the growth rates attain a maximum before starting to decrease. However, growth of these crystals is known to proceed by the classical dislocation and 2D nucleation growth mechanisms. This anomaly can be explained if growth is assumed to occur not by monomer units but by lysozyme aggregates. Analysis of the molecular packing of these crystals revealed that they were constructed of strongly bonded 4(sub 3) helices, while weaker bonds were responsible for binding the helices to each other. It follows that during crystal growth the stronger bonds are formed before the weaker ones. Thus, the growth of these crystals could be viewed as a two step process: aggregate growth units corresponding to the 4(sub 3) helix are first formed in the bulk solution by stronger intermolecular bonds and then attached to the crystal face by weaker bonds on dislocation hillocks or 2D islands. This will lead to a distribution of aggregates in the solution with monomers and lower order aggregates being predominant at low supersaturations and higher order aggregates being predominant at high supersaturations. If the crystal grows mostly by higher order aggregates, such as tetramers and octamers, it would explain the anomalous dependence of the growth rates on the supersaturation. Besides the analysis of molecular packing, a comprehensive analysis of the measured (110) and (101) growth rates was also undertaken in this study. The distribution of aggregates in lysozyme nutrient solutions at various solution conditions were determined from reversible aggregation reactions at equilibrium. The supersaturation was defined for each aggregate species with respect to its concentration at saturation in order to apply growth rate models to this process. The measured growth rates were then compared with the predicted ones from several dislocation and 2D nucleation growth models, employing tetramer and octamer growth units in polydisperse solutions and monomer units in monodisperse solutions. For the (110) face, the calculations consistently showed that the measured growth rates followed the expected model relations with octamer growth units. For the (101) face, it is not possible to obtain a clear agreement between the predicted and measured growth rates for a single growth unit as done for the (110) face. However, the calculations do indicate that the average size of the growth unit is between a tetramer and an octamer. This suggests that tetramers, octamers and other intermediate size growth units all participate in the growth process for this face. These calculations show that it is possible to model the macroscopic protein crystal growth rates if the molecular level processes can be account for, particularly protein aggregation processes in the bulk solution. Our recent investigations of tetragonal lysozyme crystals employing high resolution atomic force microscopy scans have further confirmed the growth of these crystals by aggregate growth units corresponding to 4(sub 3) helices.

Li, Meirong↗

Raman Lidar Measurements of Aerosol Extinction and Backscattering: Derivation of Aerosol Real Refractive Index, Single-Scattering Albedo, and Humidification Factor using Raman Lidar and Aircraft Size Distribution - Report 2

Aerosol backscattering and extinction profiles measured by the NASA Goddard Space Flight Center Scanning Raman Lidar (SRL) during the remote cloud sensing (RCS) intensive operations period (IOP) at the Department of Energy Atmospheric Radiation Measurement (ARM) southern Great Plains (SGP) site during two nights in April 1994 are discussed. These profiles are shown to be consistent with the simultaneous aerosol size distribution measurements made by a PCASP (Passive Cavity Aerosol Spectrometer Probe) optical particle counter flown on the University of North Dakota Citation aircraft. We describe a technique which uses both lidar and PCASP measurements to derive the dependence of particle size on relative humidity, the aerosol real refractive index n, and estimate the effective single-scattering albedo Omega(sub 0). Values of n ranged between 1.4-1.5 (dry) and 1.37-1.47 (wet); Omega(sub 0) varied between 0.7 and 1.0. The single-scattering albedo derived from this technique is sensitive to the manner in which absorbing particles are represented in the aerosol mixture; representing the absorbing particles as an internal mixture rather than the external mixture assumed here results in generally higher values of Omega(sub 0). The lidar measurements indicate that the change in particle size with relative humidity as measured by the PCASP can be represented in the form discussed by Hattel with the exponent gamma = 0.3 + or - 0.05. The variations in aerosol optical and physical characteristics captured in the lidar and aircraft size distribution measurements are discussed in the context of the meteorological conditions observed during the experiment.

Ferrare, R. A.↗

The TRMM Precipitation Radar: Opportunities and Challenges

Although studies on the feasibility of spaceborne weather radar date back to the 1960's, it was only with the launch of the Tropical Rainfall Measuring Mission (TRMM) Satellite in November 1997 that the first weather radar was placed into low earth orbit. The long delay between the initial concept and implementation was caused not only by the demanding requirements of active sensors such as mass, power, and reliability, but because of scientific and technological challenges. For example, the demand for adequate spatial resolution arises from the need to resolve the horizontal structure of convective storm cells and to avoid surface contamination of the rain return at off-nadir angles. To achieve a horizontal resolution on the order of 4 km from low earth orbit with a modest antenna size of 2 m requires the use of a much higher frequency (Ku-band) than those typically used for ground-based weather radars (S- and C-band). Higher frequencies are subject to higher attenuation. As Hitschfeld and Bordan (1954) showed in their classic paper, attenuation correction with a single-wavelength radar is inherently unstable at high attenuations unless the drop size distribution and the radar constant are known precisely. Since these conditions are seldom met, much work over the last decade has been devoted to formulating and testing alternative methods of attenuation correction. The operational method used in the TRMM radar processing is discussed in section 3 of the paper.

Meneghini, R.↗

Magmatic Intrusions and a Hydrothermal Origin for Fluvial Valleys on Mars

Numerical models of Martian hydrothermal systems demonstrate that systems associated with magmatic intrusions greater than several hundred cubic kilometers can provide sufficient groundwater outflow to form the observed fluvial valleys, if subsurface permeability exceeds about 1.0 darcy. Groundwater outflow increases with increasing intrusion volume and subsurface permeability and is relatively insensitive to intrusion depth and subsurface porosity within the range considered here. Hydrothermally-derived fluids can melt through 1 to 2 km thick ice-rich permafrost layers in several thousand years. Hydrothermal systems thus provide a viable alternative to rainfall for providing surface water for valley formation. This mechanism can form fluvial valleys not only during the postulated early warm, wet climatic epoch, but also during more recent epochs when atmospheric conditions did not favor atmospheric cycling of water. The clustered distribution of the valley networks on a given geologic surface or terrain unit of Mars may also be more compatible with localized, hydrothermally-driven groundwater outflow than regional rainfall. Hydrothermal centers on Mars may have provided appropriate environments for the initiation of life or final oases for the long-term persistence of life.

Gulick, Virginia C↗

Thermal Radiation Effects Analyzed in Translucent Composite and Thermal Barrier Coating

Ceramic parts and coatings are needed to withstand high temperatures in advanced aircraft engines. In hot environments, such as in the combustion chambers of these engines, infrared and visible radiation can penetrate into some ceramics and heat them internally. The internal temperatures depend on radiative effects combined with heat conduction, and on convection and radiation at the material boundaries. Since engine temperatures are high, radiant emission can be large from within translucent parts and coatings, and this must be included in the analysis. Transient and steady-state behavior are both important. During a transient, radiant penetration provides more rapid internal heating than conduction alone, and the temperature distributions are usually considerably different than for steady-state conditions; this can produce transient thermal stresses. Analytical and numerical methods are being used at the NASA Lewis Research Center to predict transient temperatures and heat flows in translucent materials. A transient analysis was done for a composite of two translucent layers. The layer refractive indices were larger than 1, producing internal reflections at the boundaries and at the internal interface. In addition, steady-state results were computed for a two-layer composite with one layer opaque. The results were used to assess the importance of internal radiation in a zirconia thermal barrier coating on a cooled metal wall. Since the radiative transfer equations are rather complex, especially when internal scattering is included, approximate methods are being investigated that might be convenient for computer design programs. An approximate two-flux method was used and verified by comparisons with solutions that used exact radiative transfer relations. The two-flux equations include scattering without increasing solution difficulty.

Siegel, Robert↗

Transient Temperature Behavior of a Sphere Heated by Microwaves

We have developed a model for microwave heating of a sphere in a rectangular resonant cavity. The model calculates transient temperature distributions within a sphere during the approach to steady state conditions or on the path to thermal runaway.

microwave heating microwave absorption↗

Comparison of Cloud Properties from CALIPSO-CloudSat and Geostationary Satellite Data

Cloud properties are being derived in near-real time from geostationary satellite imager data for a variety of weather and climate applications and research. Assessment of the uncertainties in each of the derived cloud parameters is essential for confident use of the products. Determination of cloud amount, cloud top height, and cloud layering is especially important for using these real -time products for applications such as aircraft icing condition diagnosis and numerical weather prediction model assimilation. Furthermore, the distribution of clouds as a function of altitude has become a central component of efforts to evaluate climate model cloud simulations. Validation of those parameters has been difficult except over limited areas where ground-based active sensors, such as cloud radars or lidars, have been available on a regular basis. Retrievals of cloud properties are sensitive to the surface background, time of day, and the clouds themselves. Thus, it is essential to assess the geostationary satellite retrievals over a variety of locations. The availability of cloud radar data from CloudSat and lidar data from CALIPSO make it possible to perform those assessments over each geostationary domain at 0130 and 1330 LT. In this paper, CloudSat and CALIPSO data are matched with contemporaneous Geostationary Operational Environmental Satellite (GOES), Multi-functional Transport Satellite (MTSAT), and Meteosat-8 data. Unlike comparisons with cloud products derived from A-Train imagers, this study considers comparisons of nadir active sensor data with off-nadir retrievals. These matched data are used to determine the uncertainties in cloud-top heights and cloud amounts derived from the geostationary satellite data using the Clouds and the Earth s Radiant Energy System (CERES) cloud retrieval algorithms. The CERES multi-layer cloud detection method is also evaluated to determine its accuracy and limitations in the off-nadir mode. The results will be useful for constraining the use of the passive retrieval data in models and for improving the accuracy of the retrievals.

Nguyen, L.↗

Improving Forecast Skill by Assimilation of Quality-controlled AIRS Temperature Retrievals under Partially Cloudy Conditions

The National Aeronautics and Space Administration (NASA) Atmospheric Infrared Sounder (AIRS) on board the Aqua satellite has been long recognized as an important contributor towards the improvement of weather forecasts. At this time only a small fraction of the total data produced by AIRS is being used by operational weather systems. In fact, in addition to effects of thinning and quality control, the only AIRS data assimilated are radiance observations of channels unaffected by clouds. Observations in mid-lower tropospheric sounding AIRS channels are assimilated primarily under completely clear-sky conditions, thus imposing a very severe limitation on the horizontal distribution of the AIRS-derived information. In this work it is shown that the ability to derive accurate temperature profiles from AIRS observations in partially cloud-contaminated areas can be utilized to further improve the impact of AIRS observations in a global model and forecasting system. The analyses produced by assimilating AIRS temperature profiles obtained under partial cloud cover result in a substantially colder representation of the northern hemisphere lower midtroposphere at higher latitudes. This temperature difference has a strong impact, through hydrostatic adjustment, in the midtropospheric geopotential heights, which causes a different representation of the polar vortex especially over northeastern Siberia and Alaska. The AIRS-induced anomaly propagates through the model's dynamics producing improved 5-day forecasts.

Reale, O.↗

The Atmospheric Dynamics of Jupiter, Saturn, and Titan

Comparative studies of Jupiter and Saturn often emphasize their similarities, but recent observations have highlighted important differences. The stratospheres of both planets exhibit an equatorial oscillation reminiscent of that in Earth's middle atmosphere. Jupiter's oscillation has a 4-5 year period, not linked to its season, and it has been modeled as an analog to the terrestrial quasi-biennial oscillation, driven by the stresses associated with vertically propagating waves. Saturn's equatorial oscillation is nearly semiannual, but wave activity may still be a driver. Jupiter's internal rotation rate is inferred from its steady modulated radio emission. Saturn's internal rotation is more enigmatic. It has been inferred from the modulation of the body's kilometric radio emission, but this period has varied by 1% over the last 25 years. Saturn's equatorial winds are also puzzling, as those inferred from cloud tracking by Cassini and more recent HST observations are weaker than those from Voyager. Whether this is attributable to a difference in altitudes of the tracked clouds in winds with vertical shear or a real temporal change in the winds is not known. Both winter and summer poles of Saturn exhibit very compact circumpolar vortices with warm cores, indicating subsidence. Titan's middle atmosphere is characterized by global cyclostrophic winds, particularly the strong circumpolar vortex in the winter hemisphere. In many ways, the spatial distribution of temperature, gaseous constituents, and condensates is reminiscent of conditions in terrestrial winter vortices, albeit with different chemistry. The meridional contrast in Titan's tropospheric temperatures is small, only a few kelvins.

Flasar, F. M.↗

An Experimental Investigation of Jet Noise from Septa Nozzles

Results of an experimental study with a large aspect ratio rectangular nozzle, divided into multiple compartments or septa, as pertinent to distributed propulsion, are presented. Noise measurements at high-subsonic conditions show that the nozzle with the septa is quieter than the corresponding baseline nozzle without the septa. At relatively lower Mach numbers a high-frequency tone is heard. This is shown to be due to Karmann vortex shedding from the trailing edge of the partitions that separate a septum from the adjacent ones. Flowfield measurements for a six septa case show that the cellular flow structure, issuing from the nozzle, goes through a curious coalescence with increasing downstream distance (x) from the nozzle. Adjacent cells pair to yield a three-cell structure by x/D =2, where D is the equivalent diameter of the baseline nozzle. By about x/D =16, both the septa case and the baseline case evolve to yield axisymmetric flowfields.

turbulence↗

The Influence of SLD Drop Size Distributions on Ice Accretion in the NASA Icing Research Tunnel

An ice shape database has been created to document ice accretions on a 21-inch chord NACA0012 model and a 72-inch chord NACA 23012 airfoil model resulting from an exposure to a Supercooled Large Drop (SLD) icing cloud with a bimodal drop size distribution. The ice shapes created were documented with photographs, laser scanned surface measurements over a section of the model span, and measurement of the ice mass over the same section of each accretion. The icing conditions used in the test matrix were based upon previously used conditions on the same models but with an alternate approach to evaluation of drop distribution effects. Ice shapes resulting from the bimodal distribution as well as from equivalent monomodal drop size distributions were obtained and compared. Results indicate that the ice shapes resulting from the monomodal and bimodal drop size distributions had similar shapes, but the bimodal distributions had greater mass and volume measurements and icing limits that extended further back on the chord of the model.

Potapczuk, Mark G.↗

Spectroscopic Behavior of Composite, Black Thermal Paint, Solar Cell, and Multi-layered Insulation Materials in a GEO Simulated Environment

Materials currently populating Earth orbital regimes can be distinguished by comparing remote observational data to that of optical material measurements obtained in the laboratory. Experimentation for this research primarily involved the acquisition of spectroscopic measurements on materials of interest to the telescopic observational community for enhanced space situational awareness. Common spacecraft materials worthy of preeminent analysis for this investigation include a carbon-carbon (c-c) matrix composite, various black thermal paints, a GPS solar cell and three different cover glass components. These materials were subjected to a simulated geosynchronous Earth orbit (GEO) space environment with the intent of observing material optical property behavior over quantitative exposure time. The aforementioned materials have been measured in their pristine and GEO simulated exposed conditions. A reflectance spectrometer and a bi-directional reflectance distribution function (BRDF) optical system have been operated to perform material characterization, optical property analysis, and to further compare such data to telescopic observational data acquired on equal materials.

Reyes, Jacqueline A.↗

Variations in radiative heating of humid biomass burning aerosols in the southeast Atlantic from airborne observations and reanalysis

The atmosphere over the southeast Atlantic Ocean (SEA) experiences consistent springtime biomass burning (BB) smoke from widespread agricultural fires on the African continent. This smoke layer is initially lofted high in a continental mixed layer (~5-6km) and is then transported westward into the free troposphere where it overlies and ultimately mixes into a stratocumulus-topped oceanic boundary layer. Coincident with this smoke is an elevated humidity signal which is present from the time a given airmass is over the continental source region. ORACLES (ObseRvations of Aerosols above CLouds and their intEractionS) was a NASA Earth Venture Suborbital mission with the goal of measuring aerosol, cloud, and atmospheric properties over this region over three deployments in September 2016, August 2017, and October 2018. Measurements included in situ profile measurements of aerosol physical and optical properties, trace gas concentrations, and cloud properties, as well as column measurements of aerosol optical depth and trace gas concentrations from an airborne sun photometer. Here we present results from each of the ORACLES deployments over the southeast Atlantic Ocean. Despite the differing locations and season of each deployment, we show that there is good agreement between the airborne ORACLES dataset and large-scale reanalyses, specifically the ECMWF ERA5 reanalyses (and, to a degree, the CAMS product) as compared to other available products. This agreement allows us to examine multi-year seasonal patterns and trends beyond the three months with available aircraft data. In both the data and reanalysis, we find distinct variations between each deployment in terms of vertical smoke distribution and correlation to atmospheric specific humidity, due to changing conditions over the BB season. We trace the origin and the history of these smoky airmasses and finally, we briefly discuss the broader radiative and dynamical implications of these results for conditions of aerosols overlying stratocumulus clouds.

K. Pistone↗

TLife-LSTM: Forecasting Future COVID-19 Progression with Topological Signatures of Atmospheric Conditions

Understanding the impact of atmospheric conditions on SARS-CoV2 is critical to model COVID-19 dynamics and sheds a light on the future spread around the world. Furthermore, geographic distri- butions of expected clinical severity of COVID-19 may be closely linked to prior history of respiratory diseases and changes in humidity, tem- perature, and air quality. In this context, we postulate that by tracking topological features of atmospheric conditions over time, we can provide a quanti?able structural distribution of atmospheric changes that are likely to be related to COVID-19 dynamics. As such, we apply the machinery of persistence homology on time series of graphs to extract topological signatures and to follow geographical changes in relative humidity and temperature. We develop an integrative machine learning framework named Topological Lifespan LSTM (TLife-LSTM) and test its predictive capabilities on forecasting the dynamics of SARS-CoV2 cases. We validate our framework using the number of con?rmed cases and hospitalization rates recorded in the states of Washington and California in the USA. Our results demonstrate the predictive potential of TLife-LSTM in forecasting the dynamics of COVID-19 and modeling its complex spatio-temporal spread dynamics.

Gel, Yulia R.↗