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At least 1,783 records · Page 99

Electromagnetic scattering by coated convex surfaces and wedges simulated by approximate boundary conditions

Asymptotic/high-frequency solutions are developed for analyzing the non-specular scattering mechanisms associated with coated convex surfaces and edges simulated by approximate boundary conditions. In particular, the standard impedance boundary conditions (SIBC's) and the second order generalized impedance boundary conditions (GIBC's) are employed for a characterization of the edge diffraction, creeping wave, and surface diffracted wave contributions. To study the creeping wave and surface diffracted wave mechanisms, rigorous UTD (uniform geometrical theory of diffraction) diffraction coefficients are developed for a convex coated cylinder simulated with SIBC's and GIBC's. The ray solutions obtained remain valid in the transition region and reduce uniformly to those in the deep lit and shadow regions. A uniform asymptotic solution is also presented for observations in the close vicinity of the cylinder. The diffraction coefficient for a convex cylinder are obtained via a generalization of the corresponding ones of the circular cylinder. To validate the asymptotic/high-frequency solution, integral equations are derived for both E and H-polarization and solved numerically using the method of moments. Results are presented for a single and three layered coated convex cylinder. Some insights are also provided on the accuracy of the employed GIBC's versus SIBC's for application to curved surfaces. To characterize the scattering by impedance wedges illuminated at skew incidence, diffraction coefficients are derived from an approximate solution of the governing functional difference equations. This solution exactly recovers the known ones for an impedance half plane or an arbitrary wedge at normal incidence, and to validate it for other wedge angles, a moment method code was used. Finally, to test the usefulness of the approximate skew incidence impedance wedge diffraction coefficient for three dimensional structures, equivalent currents are derived in the context of the physical theory of diffraction (PTD) for a finite length impedance wedge of arbitrary internal angles. These are incorporated in a standard general purpose PTD code and results are presented for a number of different impedance structures.

Syed, H. H.↗

Emerging polyheterocyclic films, coatings and resins - Thermoplastic polyquinolines

The processing and performance characteristics of a soluble, thermoplastic polyquinoline suggest its utility in a variety of high performance applications. The polymer is characterized by excellent thermal and oxidative stability, very low moisture absorption, good mechanical properties, very low dielectric constant, and an unusually low thermal expansion coefficient. This polymer, designated PQ-100 (TM), can be cast into strong, transparent, free standing films from common solvents. Coatings of variable thickness can be spin-coated on to silicon and other surfaces. After processing into films, PQ-100 (TM) can be rendered insoluble in a wide range of solvents using a proprietary process. The low CTE contributes to very low residual stress when the polymer is spin-coated onto silicon wafers. PQ-100 (TM) is currently under evaluation for use as an interlayer dielectric substrate in high-density interconnect applications, including multichip modules. Many of the characteristics of the polymer also suggest its utility as a high-performance film and as a matrix resin for specialty composite applications.

Hendricks, Neil H.↗

Optical coating technology for the EUV

Advances in optical coating and materials technology are one of the key motivators for the development of missions such as the Far Ultraviolet Spectroscopic Explorer recently selected by NASA for an Explorer class mission in the mid 1990's. The performance of a range of candidate coatings are reviewed for normal-incidence and glancing-incidence applications, and attention is given to strengths and problem areas for their use in space. The importance of recent developments in multilayer films, chemical-vapor deposited SiC (CVD-SiC) mirrors, and SiC films are discussed in the context of EUV instrumentation design. For example, the choice of optical coatings is a design driver for the selection of the average glancing angle for the FUSE telescope, and impacts efficiency, short-wavelength cut-off, and physical size.

Osantowski, J. F.↗

Effective area of the AXAF X-ray telescope - Dependence upon dielectric constants of coating materials

This study examines the dependence of the effective area of the AXAF X-ray telescope upon the complex dielectric constants of possible mirror coatings, over the energy range 0.1-10 keV. At energies near and above the astrophysically important iron-line complex near 6.7 keV, the effective area is very sensitive to the coating density on the three innermost of the telescope's six mirror pairs. Thus, it is desirable to achieve as high a density as feasible. The telescope's spectral response exhibits sharp features at absorption edges of the coating materials. In view of the exceptional energy resolution of the AXAF spectrometers and uncertainties in reflectivities (especially near absorption edges), the AXAF goal of 1-percent accuracy requires both the precise X-ray calibration of the telescope and improved modeling of the telescope and calibration sources. Presented here in the form of plots, the results are also available (on floppy disks) in tabular form.

Elsner, R. F.↗

SiO(X) coatings for atomic oxygen protection of polyimide Kapton in low earth orbit

Sputter-deposited SiO(X) (where X between 1.9 and 2.0) thin film coatings have been found to be durable to atomic oxygen. Such coatings will be used to protect polyimide Kapton photovoltaic array blankets from atomic oxygen attack in low earth orbit (LEO) on the Space Station Freedom (SSF). Monte Carlo modeling of atomic oxygen attack at defect sites in protected Kapton exposed in laboratory RF plasma ashers and on solar tracking photovoltaic arrays in space has been conducted to enable understanding of degradation processes relevant to the durability of the SSF solar array blanket. SiO(X) protective coating performance data from RF plasma asher tests will be presented, along with Monte Carlo modeling considerations, to enable the projection of in-space durability of the SSF solar array blankets based on ground laboratory test results.

Banks, Bruce A.↗

Plasma effects on the passive external thermal control coating of Space Station Freedom

The current baseline chromic acid anodized thermal control coating on 6061-T6 aluminum meteoroid debris (M/D) shields for SSF has been evaluated. The degradation of the solar absorptance, alpha, and the thermal emittance, epsilon, of chromic acid anodized aluminum due to dielectric breakdown in plasma was measured to predict the on-orbit lifetime of the SSF M/D shields. The lifetime of the thermal control coating was based on the surface temperatures achieved with degradation of the thermal control properties, alpha and epsilon. The temperatures of each M/D shield from first element launch (FEL) through FEL+15 years were analyzed. It is shown that the baseline thermal control coating cannot withstand the -140 V potential between the conductive structure of the SSF and the current plasma environment.

Carruth, Ralph, Jr.↗

Protective Coats For Zinc-Rich Primers

Report describes tests of topcoats for inorganic zinc-rich primers on carbon steel. Topcoats intended to provide additional protection against corrosion in acidic, salty seacoast-air/rocket-engine-exhaust environment of Space Shuttle launch site. Tests focused on polyurethane topcoats on epoxy tie coats on primers. Part of study involved comparison between "high-build" coating materials and thin-film coating materials.

Macdowell, Louis G, III↗

Test Of Protective Coatings On Carbon Steel

Report describes results of tests in which carbon-steel panels coated with one-or two-component solvent-based inorganic zinc primers and top-coated with inorganic topcoat or any of various organic topcoats, placed on outdoor racks at beach at Kennedy Space Center for 5 years. From time to time, slurry of Al(2)O(3) in 10-percent HCI solution applied to some of panels to simulate corrosive effect of effluent from solid-fuel rocket booster engines. Panels coated with inorganic topcoat performed much better than organic-topcoated panels.

Macdowell, Louis↗

Oxidation-Resistant Coating For Bipolar Lead/Acid Battery

Cathode side of bipolar substrate coated with nonoxidizable conductive layer. Coating prepared as water slurry of aqueous dispersion of polyethylene copolymer plus such conductive fillers as tin oxide, titanium, tantalum, or tungsten oxide. Applied easily to substrate of polyethylene carbon plastic. As slurry dries, conductive, oxidation-resistant coating forms on positive side of substrate.

Bolstad, James J.↗

LDEF thermal control coatings post-flight analysis

The NASA Long Duration Exposure Facility (LDEF) provided a unique flight opportunity for conducting experiments in space and return of these experiments to Earth for laboratory evaluation. The results of one of these experiments, S0010, Exposure of Spacecraft Coatings, in which selected spacecraft thermal control coatings were exposed to the low-Earth orbital (LEO) environment on LDEF are reported. The objective of the experiment is to evaluate the response of thermal control coatings to LEO exposure, which includes atomic oxygen, ultraviolet and particulate radiation, meteoroid and debris, vacuum, and temperature cycling.

Slemp, Wayne S.↗

Surface pressure field mapping using luminescent coatings

In recent experiments we demonstrated the feasibility of using the oxygen dependence of luminescent molecules for surface pressure measurement in aerodynamic testing. This technique is based on the observation that for many luminescent molecules the light emitted increases as the oxygen partial pressure, and thus the air pressure, the molecules see decreases. In practice the surface to be observed is coated with an oxygen permeable polymer containing a luminescent molecule and illuminated with ultraviolet radiation. The airflow induced surface pressure field is seen as a luminescence intensity distribution which can be measured using quantitative video techniques. Computer processing converts the video data into a map of the surface pressure field. The experiments consisted of evaluating a trial luminescent coating in measuring the static surface pressure field over a two-dimensional NACA-0012 section model airfoil for Mach numbers ranging from 0.3 and 0.66. Comparison of the luminescent coating derived pressures were made to those obtained from conventional pressure taps. The method along with the experiment and its results will be described.

Mclachlan, B. G.↗

High reflectance coatings for space applications in the EUV

Advances in optical coating and materials technology have made possible the development of instruments with substantially improved efficiency and made possible to consider more complex optical designs in the EUV. The importance of recent developments in chemical vapor deposited silicon carbide (CVD-SiC), SiC films and multilayer coatings is discussed in the context of EUV instrumentation design. The EUV performance of these coatings as well as some strengths and problem areas for their use in space will be addressed.

Keski-Kuha, Ritva A. M.↗

Stresses in sulfuric acid anodized coatings on aluminum

Stresses in porous anodic alumina coatings have been measured for specimens stabilized in air at different temperatures and humidities. In ambient atmosphere the stress is tensile after anodic oxidation and is compressive after sealing. Exposure to dry atmosphere causes the stress to change to strongly tensile, up to 110 MPa. The stress increase is proportional to the loss of water from the coating. These changes are reversible with changes in humidity. Similar reversible effects occur upon moderate temperature changes. The biaxial modulus of the coating is about 100 GPa.

Alwitt, R. S.↗

Tribological evaluation and analysis of coating materials

A physical characterization of coating materials by analytical techniques such as XPS, AES, ellipsometry, and nuclear reaction analysis can contribute to the understanding of adhesion and friction of the coatings and can partially predict the tribological properties of the coatings. This two-part paper describes the tribological properties and physical characteristics of (1) diamondlike carbon (DLC) films and (2) silicon nitride (SiN(x)) films. Emphasis is to relate plasma deposition conditions to the film chemistry and composition and to the adhesion and friction of the films. With the DLC films, the higher the plasma deposition power, the less the hydrogen concentration and the greater the film density and the hardness. The friction behavior of DLC films deposited at higher deposition powers (200 to 300 W) is similar to that of bulk diamond. Even in a vacuum, the DLC films effectively lubricate ceramic surfaces (Si3N4) at temperatures to 500 C. With SiN(x) films, the silicon to nitrogen ratios and the amount of amorphous silicon depend on deposition frequency. The presence of rich amorphous silicon in the high-frequency plasma-deposited SiN(x) films increases their adhesion and friction above 500 C in vacuum.

Miyoshi, Kazuhisa↗

Performance and properties of atomic oxygen protective coatings for polymeric materials

Such large LEO spacecraft as the Space Station Freedom will encounter high atomic oxygen fluences which entail the use of protective coatings for their polymeric structural materials. Such coatings have demonstrated polymer mass losses due to oxidation that are much smaller than those of unprotected materials. Attention is here given to protective and/or electrically conductive coatings of SiO(x), Ge, and indium-tin oxide which have been exposed to atomic oxygen in order to ascertain mass loss, electrical conductivity, and optical property dependence on atomic oxygen exposure.

Banks, Bruce A.↗

Protective, Sacrificial Coats On Optical Surfaces

Clear, easily cleaned sacrificial coats of polytetrafluoroethylene, polyurethane, silicone, or other low-outgassing organic films help maintain optical properties of surfaces of radiators, solar panels, and other components. Contamination removed by erosion of coats. Applied by conventional spraying or other techniques. Originally coats intended to protect surfaces of radiators on spacecraft in low orbit around the Earth. On Earth, used to protect optical surfaces against damage during manufacture or protect and facilitate cleaning of optical surfaces particularly delicate or otherwise not cleaned easily.

Babel, Henry W.↗

Capacitive Measurement Of Coating Thickness On Carbon Fibers

Technique for gauging coating thickness during prepreg processing of carbon fibers developed. Technique based on measurement of capacitance of cylindrical condenser through which bundle of prepregged fibers passed axially. Empirical results indicate capacitance linearly related to thickness of polymer coat on fibers in bundle. Capacitive transducer used successfully to measure thickness of polymer coats on several test bundles of fibers under static conditions.

Eftekhari, Abe↗

Plasma-Spray Metal Coating On Foam

Molds, forms, and other substrates made of foams coated with metals by plasma spraying. Foam might be ceramic, carbon, metallic, organic, or inorganic. After coat applied by plasma spraying, foam left intact or removed by acid leaching, conventional machining, water-jet cutting, or another suitable technique. Cores or vessels made of various foam materials plasma-coated with metals according to method useful as thermally insulating containers for foods, liquids, or gases, or as mandrels for making composite-material (matrix/fiber) parts, or making thermally insulating firewalls in automobiles.

Cranston, J.↗