Synthesis and VOC degradation ability of a CeO{sub 2}/WO{sub 3} thin-layer visible-light photocatalyst
Highlights: • Plasma-synthesized γ/ε-WO{sub 3} showed improvement of acetaldehyde decomposition. • Ferroelectricity of ε-WO{sub 3} slowed hole-electron recombination. • Synergistic effect between WO{sub 3} and CeO{sub 2} further enhanced photocatalytic activity. - Abstract: The plasma synthesis, characterization, and photocatalytic activity of WO{sub 3}, which consisted of a mixture of gamma WO{sub 3} and epsilon WO{sub 3} (γ/ε-WO{sub 3}), and physically mixed WO{sub 3} and CeO{sub 2} (WO{sub 3}/CeO{sub 2}) were investigated. Synergistic effects were observed in acetaldehyde photocatalysis experiments using γ/ε-WO{sub 3} or WO{sub 3}/CeO{sub 2}. The synergistic effect in the γ/ε-WO{sub 3} photocatalyst system is proposed to be the concurrent reduction of oxygen at gamma WO{sub 3} and oxidation of acetaldehyde at epsilon WO{sub 3}. It is hypothesized that acetaldehyde preferentially interacts with epsilon WO{sub 3} over gamma WO{sub 3} because of dipole–dipole interactions between them. In the case of the WO{sub 3}/CeO{sub 2} photocatalyst, the electron scavenging property of CeO{sub 2} aided charge carrier separation. As a result, WO{sub 3}/CeO{sub 2} exhibited excellent photocatalytic activity in volatile organic compound decomposition under visible light at room temperature.