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At least 1,765 records · Page 98
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NASA NTRS2017

Removal of Carbon Dioxide from Gas Mixtures Using Ion-Exchanged Silicoaluminophosphates

Na+-SAPO-34 sorbents were ion-exchanged with several individual metal cations for CO2 absorption at different temperatures (273-348 K) and pressures (<1 atm). In general, the overall adsorption performance of the exchanged materials increased as follows: Ce3+<Ti3+<Mg2+<Ca2+<Ag+<Na+<Sr2+. The strontium exchanged materials excelled at low-pressure ranges, exhibiting very sharp isotherms slopes at all temperatures. The Sr2+ species were responsible for the surface strong interaction and the cations were occupying exposed sites (SII') in the materials Chabazite cages. All the sorbent materials exhibited higher affinity for CO2 over the other gases tested (i.e., CH4, H2, N2 and O2) due to strong ion-quadrupole interactions. Sr2+-SAPO-34 sorbents are by far the best option for CO2 removal from CH4 mixtures, especially at low concentrations.

Hernandez-Maldonado, Arturo J↗
NASA NTRS2017

Historical Carbon Dioxide Emissions Caused by Land-Use Changes are Possibly Larger than Assumed

The terrestrial biosphere absorbs about 20% of fossil-fuel CO2 emissions. The overall magnitude of this sink is constrained by the difference between emissions, the rate of increase in atmospheric CO2 concentrations, and the ocean sink. However, the land sink is actually composed of two largely counteracting fluxes that are poorly quantified: fluxes from land-use change andCO2 uptake by terrestrial ecosystems. Dynamic global vegetation model simulations suggest that CO2 emissions from land-use change have been substantially underestimated because processes such as tree harvesting and land clearing from shifting cultivation have not been considered. As the overall terrestrial sink is constrained, a larger net flux as a result of land-use change implies that terrestrial uptake of CO2 is also larger, and that terrestrial ecosystems might have greater potential to sequester carbon in the future. Consequently, reforestation projects and efforts to avoid further deforestation could represent important mitigation pathways, with co-benefits for biodiversity. It is unclear whether a larger land carbon sink can be reconciled with our current understanding of terrestrial carbon cycling. Our possible underestimation of the historical residual terrestrial carbon sink adds further uncertainty to our capacity to predict the future of terrestrial carbon uptake and losses.

Arneth, A.↗
NASA NTRS2018

Removal of Carbon Dioxide from Gas Mixtures Using Ion-Exchanged Silicoaluminophosphates

Na.sup.+-SAPO-34 sorbents were ion-exchanged with several individual metal cations for CO.sub.2 absorption at different temperatures (273-348 K) and pressures (<1 atm). In general, the overall adsorption performance of the exchanged materials increased as follows: Ce.sup.3+<Ti.sup.3+<Mg.sup.2+<Ca.sup.2+<Ag.sup.+<Na.sup.+&- lt;Sr.sup.2+. The strontium exchanged materials excelled at low-pressure ranges, exhibiting very sharp isotherms slopes at all temperatures. The Sr.sup.2+ species were responsible for the surface strong interaction and the cations were occupying exposed sites (SII') in the materials Chabazite cages. All the sorbent materials exhibited higher affinity for CO.sub.2 over the other gases tested (i.e., CH.sub.4, H.sub.2, N.sub.2 and O.sub.2) due to strong ion-quadrupole interactions. Sr.sup.2+-SAPO-34 sorbents are by far the best option for CO.sub.2 removal from CH.sub.4 mixtures, especially at low concentrations.

Hernandez-Maldonado, Arturo J↗
NASA NTRS2018

Portable, Low-Cost, Column Carbon Dioxide and Methane Measurements for Validating Satellite Observations in Remote Locations

We present a low-cost (~$10K per instrument), portable solution to ground-based validation of satellite observations for difficult to reach locations with precisions of 1 ppm XCO2 and 10 ppb XCH4 for hourly data products. While Total Carbon Column Observing Network (TCCON) is the gold-standard for ground validation, there are locations where a ground column validation data point would be useful but conditions are not conducive to a permanent station. Examples include wetlands, thawing permafrost, the tropics, the Amazon, sub-Saharan Africa, as well as locations without a power grid or with geopolitical conflict. In addition, the low-cost and portability mean a geographical region can be studied in depth with multiple instruments. This passive, sun-pointing instrument is a miniaturized, laser heterodyne radiometer (mini-LHR) that has been under development by our team since 2009. It can be operated either in tandem with AERONET (a global network of 500 instruments that measure aerosol optical depth), or as a stand-alone instrument with a low-cost (~$3K), light-weight sun tracker. One of the main benefits of the mini-LHR is that it can quickly reach remote locations and provide a validation measurement even if there is limited or no infrastructure at the site. The instrument weighs ~10 lbs, fits into a backpack, and is powered by two folding solar panels and a battery pack. In clear conditions, the instrument can be set-up in under an hour. Portability means that mini-LHRs can be easily moved for side-by-side comparisons with other mini-LHRs and with TCCON which simplifies assessing instrument bias as well as accuracy. Like TCCON, the mini-LHR points directly at the sun with a narrow field-of-view and is its insensitivity to cloud and aerosol scattering that is common to nadir-pointing passive satellite approaches. Here we present a collection of sample data sets to demonstrate performance from locations that vary in climate, altitude, solar zenith angle, hours of sun per day, etc., as well as data from side-by-side TCCON comparisons. Retrievals of CO2 and CH4 were completed using the NASA/Goddard's Planetary Spectrum Generator (PSG) that incorporates meteorological inputs from Modern-Era Retrospective analysis for Research and Applications, Version 2 (MERRA-2) data set.

Wilson, Emily W.↗
NASA NTRS2019

A Suite of High-Resolution Atmospheric Carbon Dioxide Simulations in Support of the OCO-3 Snapshot Area Mapping (SAM) Mode Observation: PSU-WRF, CSU-OLAM and NASA GEOS

Cities and power plants are responsible more than 70% of GHG emissions. The emissions from the subnational localized sources need to be accurately quantified and properly managed in order to achieve the Paris Climate Agreement goals. The accurate estimation of these emission is also crucial for assessing the capacity of natural sinks to uptake the carbon released into the atmosphere that ultimately defines our emission allowance for the 1.5 or 2.0 degree temperature goals. New data collected by the Orbiting Carbon Observatory 3 (OCO-3) Snapshot Area Mapping (SAM) observations should provide a tremendous new opportunity for us to study CO2 emissions from targeted large localized sources, such as cities, power plants and beyond. Since 2018 (prior to the OCO-3 launch), we have studied the observational strategies for the SAM mode observation in order to collect the useful data for estimating CO2 emissions from target sources. To maximize the benefit of the SAM mode observation data for quantifying CO2 emission, it is important to define how to observe the localized sources depending on the local environmental and emission specificities. We employ a suite of state-of-the-art CO2 modeling systems, such as PSU's WRF-CO2, CSU's OLAM and NASA's GEOS models. All of these CO2 modeling systems are prescribedwith the high-resolution fuel CO2 emission estimates from the ODIAC data product to achieve realistic urban CO2 variations. We focus on cities with established ground-based observation networks, such as Los Angeles, Indianapolis, and Paris. We have examined the urban emission signal detectability in response to the influence of local background conditions that can observed by the SAM and biospheric contributions that will be a new challenge for urban emission inverse estimation. Based on the results of our simulation experiments, we plan to propose city-specific observation strategies. Upon the availability of the OCO-3 data, we will attempt to estimate city emissions using inverse models. We also developed synthetic OCO-3 data using NASA's GEOS5 model, which should be useful to assess the utility of the OCO-3 data in combination with data collected by carbon satellites in other orbits, such as NASA's OCO-2 and Japanese GOSAT-1/2. The synthetic data also provide an opportunity to study the errors due to clouds and aerosols, which have been not fully studied in the past.

Oda, Tomohiro↗
NASA NTRSDate not supplied

Feasibility Study of a Carbon Dioxide Breathing, Solid-Fueled Ramjet for Martian Descent and Landing of Human Class Payloads

This study analyzes the cross-range capabilities of solid-fueled ramjets in a Martian atmosphere for applications in entry, descent, and landing. Trajectories and engine operability are characterized using Mach and dynamic pressure operational points. It is predicted that use of atmosphere-breathing propulsion will enable access to additional surface latitudes without the need for orbital plane changes. Development of an integrated design environment facilitates preliminary ramjet design and analysis, and enables sensitivity studies to identify high impact areas of technology development. In addition, additive manufacturing supports prototyping, rapid ground testing, and allows for utilization of complex geometries.

Shi Broadwell↗