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At least 1,765 records · Page 98

Towards chemical equilibrium in thermochemical water splitting. Part 1: Thermal reduction

The efficiency of many processes strongly depends on their thermodynamic reversibility, i.e., proximity to equilibrium throughout the process. In thermochemical cycles for water and/or carbon dioxide splitting, thermochemical air separation, and thermochemical energy storage, operating near equilibrium means that the oxygen chemical potential of the solid and gas phases must not differ significantly. Herein we show that approaching this ideal is possible in thermal reduction only if the reaction step occurs at a specific, reaction coordinate- and material-dependent temperature. The resulting thermal reduction temperature profile also depends on the ratio of gas and solid flows.

08 HYDROGEN↗

Guest Editorial: Advanced Data-Analytics for Power System Operation, Control, and Enhanced Situational Awareness

Along with the smart grid development, modern power systems are entering a ‘data-intensive’ era. A vast volume of data from power grids is being collected through advanced sensing and communication technologies, such as smart metering data, phasor measurement data, as well as meteorological data (e.g., wind speed and solar irradiance) related to renewable power generation. Such data contains comprehensive information about the power system covering equipment's health status, power grid's static and dynamic characteristics, renewable power generation, customers’ electricity usage pattern, etc. Therefore, advanced data-analytics techniques are needed to convert such data to knowledge for practical applications. In line with the trend of widespread data-driven applications in power systems, this Special Issue aims to present state-of-the-art research works on advanced data-analytics for power system's operation, control, and situational awareness. There are in total twenty-six papers accepted for publication in this Special Issue through careful peer reviews and revisions. Under the overarching theme of data-driven applications in power systems, the selected papers are broadly categorised into five topics. The summary of every topic is given below. You are, however, strongly encouraged to read the full paper if interested.

Xu, Yan↗

Ab initio theory of free-carrier absorption in semiconductors

The absorption of light by free carriers in semiconductors results in optical loss for all photon wavelengths. Since free-carrier absorption competes with optical transitions across the band gap, it also reduces the efficiency of optoelectronic devices such as solar cells because it does not generate electron-hole pairs. In this work, we develop a first-principles theory of free-carrier absorption taking into account both single-particle excitations and the collective Drude term, and we demonstrate its application to the case of doped Si. Here, we determine the free-carrier absorption coefficient as a function of carrier concentration and we obtain excellent agreement with experimental data. We identify the dominant processes that contribute to free-carrier absorption at various photon wavelengths, and analyze the results to evaluate the impact of this loss mechanism on the efficiency of Si-based optoelectronic devices.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Projected sensitivities of the LUX-ZEPLIN experiment to new physics via low-energy electron recoils

LUX-ZEPLIN is a dark matter detector expected to obtain world-leading sensitivity to weakly-interacting massive particles interacting via nuclear recoils with a ∼7-tonne xenon target mass. This paper presents sensitivity projections to several low-energy signals of the complementary electron recoil signal type: 1) an effective neutrino magnetic moment, and 2) an effective neutrino millicharge, both for 𝑝⁢𝑝-chain solar neutrinos, 3) an axion flux generated by the Sun, 4) axionlike particles forming the Galactic dark matter, 5) hidden photons, 6) mirror dark matter, and 7) leptophilic dark matter. World-leading sensitivities are expected in each case, a result of the large 5.6 t 1000 d exposure and low expected rate of electron-recoil backgrounds in the <100 keV energy regime. A consistent signal generation, background model and profile-likelihood analysis framework is used throughout.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Pricing Strategy of Electric Vehicle Aggregators Based on Locational Marginal Price to Minimize Photovoltaic (PV) Curtailment

The global climate crisis demands urgent action to mitigate global warming. Using renewable energy sources, such as solar and wind power, for electricity generation is crucial. This shift from centralized to distributed power systems, however, brings challenges, including voltage fluctuations and renewable energy curtailment. The rapid growth of the electric vehicle (EV) industry adds complexity, increasing overall electricity demand and straining the power supply during peak charging times. This paper proposes a scheduling strategy for EV aggregators to reduce renewable energy curtailment and stabilize grid operation by strategically scheduling EV charging. Using Multi -Agent Transport Simulation (MATSim), a traffic simulation tool, EV driving data in Denver, Colorado, USA, were modeled. The EV aggregator adjusts charging fees based on locational marginal prices, encouraging EVs to charge at different stations according to pricing. Simulations on an IEEE 33-bus system with distributed energy resources and EV charging stations validate the proposed algorithm, demonstrating its effectiveness in reducing curtailment by 12.55% and stabilizing grid operation.

33 ADVANCED PROPULSION SYSTEMS↗

A Comparison of Battery Charge Controller Technologies for Wave Energy Converters

Wave energy is a uniquely challenging field for electrical system designers. High peak and low average power potential with a constantly varying energy input is difficult to harness and control through conventional means. To power the blue economy, low-powered wave energy converters (WECs) need batteries for energy storage. Safely and effectively charging batteries from waves requires a charge controller to properly monitor and control voltage and current going to the battery. Currently, off-the-shelf charge controllers exist for other renewable generation such as wind, hydro, and solar. Two topologies were validated: a buck converter and a pulse width modulation (PWM) charge controller. Using an in-lab dry testbed, wave energy power inputs were simulated to properly validate the effectiveness of existing charge controller technologies, identifying the shortcomings and improvements needed to effectively harness wave energy.

battery storage↗

RODeO (Revenue Operation and Device Optimization Model) [SWR 20-67]

The Revenue, Operation, and Device Optimization (RODeO) model explores optimal system design and operation considering different levels of grid integration, equipment cost, operating limitations, financing, and credits and incentives. RODeO is a price-taker model formulated as a mixed-integer linear programming (MILP) model in the GAMS modeling platform. The objective is to maximizes the net revenue for a collection of equipment at a given site. The equipment includes generators (e.g., gas turbine, steam turbine, solar, wind, hydro, fuel cells, etc.), storage systems (batteries, pumped hydro, gas-fired compressed air energy storage, long-duration systems, hydrogen), and flexible loads (e.g., electric vehicles, electrolyzers, flexible building loads). The input data required by RODeO can be classified into three bins: 1) utility service data, which refers to retail utility rate information (meter cost, energy and demand charges), 2) electricity market data, which include energy and reserve prices, 3) other inputs, which refer to additional electrical demand, product output demand, technological assumptions, financial properties, and operational parameters.

Guerra Fernandez, Omar Jose↗

BSDF Data generation for daylight applications: A call for international standardization

Standardized methods for generating angle-dependent, bidirectional, solar-optical properties for complex fenestration systems do not exist, which means that energy and daylight evaluations in building performance simulations often suffer from major inaccuracies. This position paper provides an overview of state-of-the-art data-driven methods for characterizing light scattering properties of fenestration materials and blind systems (e.g. fabrics, metal slats, patterned glazing), validation via laboratory, simulation and field tests, and salient issues in support of standardization of such methods via the International Standardization Organization (ISO). The ISO standard is intended to provide the fundamental underpinnings for recently mandated daylight standards that rely on bidirectional scattering distribution function data for climate-based daylight modelling and building performance simulations.

Geisler-Moroder, D.↗

North Carolina Water Utility Builds Resilience with Distributed Energy Resources

As the frequency and duration of grid outages increase, backup power systems are becoming more important for ensuring that critical infrastructure continues to provide essential services. Most facilities rely on diesel generators, which may be ineffective during long outages owing to limited fuel supplies and high generator failure rates. Distributed energy resources such as solar, storage, and combined-heat-and-power systems, coupled with on-site biofuel production, offer an alternative source of on-site generation that can provide both cost savings and resilience (i.e., the ability to respond to catastrophic events with longer-term consequences). A mixed-integer linear program minimizes costs and maximizes resilience at a wastewater treatment plant in Wilmington, North Carolina. We find that the plant can reduce life-cycle energy costs by 3.1% through the installation of a hybrid combined-heat-and-power, photovoltaic, and storage system. When paired with existing diesel generators, this system can sustain full load for seven days while saving $664,000 over 25 years and reducing diesel fuel use by 48% compared with the diesel-only solution. This analysis informed a decision by the Cape Fear Public Utility Authority to allocate funds for the implementation of a combined-heat-and-power system at the wastewater treatment plant in fiscal year 2023. Finally, the benefits of deploying hybrid combined-heat-and-power technologies and the utilization of on-site biofuel production extend, on a national scale, to thousands of wastewater treatment facilities and other types of critical infrastructure.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Integrated Heat Pump Thermal Storage and Power Cycle for CSP (Final Technical Report)

Pumped thermal energy storage (PTES) is a storage system that stores electricity in thermal reservoirs. In this project, methods of integrating PTES with concentrating solar power (CSP) systems were investigated and their feasibility evaluated. Hybrid "solar-PTES" devices can provide both flexible renewable power generation as well as a variety of electricity storage services. Techno-economic models of PTES and solar-PTES were developed and used to assess their performance, cost, and commercial viability. Systems were optimized using multi-objective optimization techniques. The value that these storage devices provide to the grid was estimated using production cost modelling. Key advances made in this project include the development of detailed techno-economic models that improve state-of-the-art assessments of these technologies. Off-design models were developed and used in grid-analysis models. This work describes for the first time how PTES and solar-PTES behave over a range of operating points and assesses the value that these systems can provide to the electrical grid. Feedback was obtained from experts in the field, which clarified key technological and economic barriers that must be addressed to improve the feasibility of these devices.

14 SOLAR ENERGY↗

Study of Storage Requirements and Costs for Shaping Renewables and Nuclear Energy (FY23 Summary Report)

To decarbonize electricity generation primarily by using wind and solar resources, it is likely that additional low (or zero) carbon dioxide (CO 2 ) alternatives will be required for ensuring a reliable electricity supply. This study extends the work and modeling framework that we consolidated in FY 2022, by assessing the zero-CO 2 pathways of a Texas power system in which the availability of variable renewable energy (VRE), nuclear energy, and energy storage types (i.e., battery and thermal energy storage [TES]) are considered the sole resources available for expansion. Using the Risk Analysis Virtual Environment (RAVEN) and Holistic Energy Resource Optimization Network (HERON) frameworks, this study investigates the market of two nuclear energy technologies (i.e., large light-water reactors [LWRs] and LWR-type small modular reactors [SMRs]) under two plausible storage coupling scenarios (i.e., electric coupling and direct thermal coupling). We also explore optimal environments for nuclear energy deployment, and identify key performance characteristics that make nuclear energy economically viable in areas with significant intermittent energy sources. Our analysis encompasses 24 cases. We model the least-cost grid systems, highlight the potential for a coupled LWR-TES approach, and utilize SMRs to achieve deep decarbonization in an affordable, technically feasible manner. We also examine seasonal variations in balancing electricity supply and demand, and account for varying performance, costs, and grid constraints. Overall, the findings of our modeling afford valuable insights for supporting future technology investment decisions in the energy sector.

25 ENERGY STORAGE↗

Advanced Fuel Cycle Cost Basis Report: Supporting Document 5 Considerations on Learning

Learning refers here to the increased experience associated to each new build of a given type of fuel cycle facility, which results generally in design improvements, increased construction and operational efficiencies and reduced mistakes, and therefore in reduced costs. These are important considerations, for example, when modeling transitions from first-of-a-kind (FOAK) to nth-of-a-kind (NOAK) nuclear facilities and deciding the magnitude of the cost reduction (if any) to be applied to each successive build. Different assumptions on learning can significantly affect the results of the economic analyses during transitions. Other competing electricity-generation technologies, such as wind and solar power for example, have demonstrated substantial cost reductions through learning during the last few decades.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Experimental Investigations into the Corrosion of Alloy 625 Using NaCl-PuCl3 Molten Salt in a Natural Circulation Microloop

Molten salt reactors (MSRs) can potentially revolutionize the nuclear industry by providing a path to a near-zero nuclear waste fuel cycle, contributing to more sustainable energy sources. As a plethora of MSR developers in the United States work toward an aggressive commercialization timeline, many of their fueled-salts—notably, chloride-based compositions—have limited operational testing with nuclear material. Licensing and operating these reactors require an understanding of corrosion effects on reactor materials of construction under operational conditions. The TerraPower Molten Chloride Fast Reactor (MCFR) is a liquid-fueled chloride-salt fast reactor which has received notable interest from the utility sector based on its desirable economic characteristics. The reactor operates at low pressure but does not require the use of highly reactive chemicals, leading to a reduced use of concrete and steel during construction. Additionally, liquid fuel allows for inherently stable behavior and natural circulation during a loss-of-site-power scenario. MCFR can be refueled while operating which makes it compatible with variable generation sources such as wind and solar. MCFR is a breed-and-burn in-situ reactor that does not implement any chemical processing or separations in the fuel cycle. Only mechanical filtration of noble metals and off-gassing of noble gases are utilized while the actinides stay mixed with the fuel at all times. The MCFR will require technology development to reach commercialization. With a breed-and-burn in-situ reactor like MCFR, the transmutation of fertile U-238 to fissile Pu-239 allows for much greater fuel utilization.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Novel Hot Gas Components for Gas Turbine Engines Enabled by Materials and Additive Manufacturing Process Development

Additive Manufacturing (AM), also known as 3D printing, has emerged as a manufacturing method that enables new design freedom for gas turbine engine manufacturers. However, the material selection for AM processable high-temperature super alloys is currently limited. Additionally, the heat transfer performance of AM enabled micro-cooling architectures is not yet well understood. Accordingly, in support of advanced manufacturing and engine performance development, Oak Ridge National Laboratory (ORNL)and Solar Turbines (Solar) conducted a multidisciplinary project to generate both AM super alloy material properties data and micro-channel performance data for two AM super alloys. The data supported the design and analysis of an internally cooled turbine hot section AM tip shoe component. This data was used to analytically predict the reduction in operating temperature of a gas turbine tip shoe. The work concluded that the cooling flow required to cool the tip shoe can be tuned to suit the efficiency improvements desired in an industrial gas turbine.

36 MATERIALS SCIENCE↗