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At least 1,765 records · Page 98

Filled Elastomers: Mechanistic and Physics-Driven Modeling and Applications as Smart Materials

Elastomers are made of chain-like molecules to form networks that can sustain large deformation. Rubbers are thermosetting elastomers that are obtained from irreversible curing reactions. Curing reactions create permanent bonds between the molecular chains. On the other hand, thermoplastic elastomers do not need curing reactions. Incorporation of appropriated filler particles, as has been practiced for decades, can significantly enhance mechanical properties of elastomers. However, there are fundamental questions about polymer matrix composites (PMCs) that still elude complete understanding. This is because the macroscopic properties of PMCs depend not only on the overall volume fraction (ϕ) of the filler particles, but also on their spatial distribution (i.e., primary, secondary, and tertiary structure). This work aims at reviewing how the mechanical properties of PMCs are related to the microstructure of filler particles and to the interaction between filler particles and polymer matrices. Overall, soft rubbery matrices dictate the elasticity/hyperelasticity of the PMCs while the reinforcement involves polymer–particle interactions that can significantly influence the mechanical properties of the polymer matrix interface. For ϕ values higher than a threshold, percolation of the filler particles can lead to significant reinforcement. While viscoelastic behavior may be attributed to the soft rubbery component, inelastic behaviors like the Mullins and Payne effects are highly correlated to the microstructures of the polymer matrix and the filler particles, as well as that of the polymer–particle interface. Additionally, the incorporation of specific filler particles within intelligently designed polymer systems has been shown to yield a variety of functional and responsive materials, commonly termed smart materials. We review three types of smart PMCs, i.e., magnetoelastic (M-), shape-memory (SM-), and self-healing (SH-) PMCs, and discuss the constitutive models for these smart materials.

36 MATERIALS SCIENCE↗

Heliostat Sizing Methodology for Solar Heat for Industrial Processes

This study presents a method to obtain a heliostat size that minimizes the levelized cost of a heliostat-based concentrating solar thermal system for industrial process heat (IPH) applications at operating temperatures from 565 to 1550 degrees Celsius. The method extends prior work by embedding a routine for system design that obtains near-optimal subsystem sizes, increasing the fidelity of drive cost functions, and adding an optical performance model. An illustrative business case is developed for Daggett, California, targeting specified annual thermal energy outputs of 50 to 400 GWhth. Optical performance is modeled using verified estimates from the literature. A surrogate heliostat cost model, derived from commercial heliostat designs and scaled for production volume, installation, and operations and maintenance costs, is used to develop cost functions. Results show that heliostat size strongly affects the levelized cost of heat (LCOH), producing a characteristic U-shaped trend with a robust near-optimal window of 8 - 12 m2; the heliostat size producing the lowest project cost in our study grows slightly as the project size increases, and is reduced as the operating temperature increases. The findings in this study are consistent with the general trend of smaller heliostats under deployment at existing projects for high-temperature industrial process heat and reflect the significant reduction in power electronics and other per-heliostat costs. The methodology we propose is general and can be tailored to revised cost curves as the technology continues to evolve.

14 SOLAR ENERGY↗

A linear shift-invariant image preprocessing technique for multispectral scanner systems

A linear shift-invariant image preprocessing technique is examined which requires no specific knowledge of any parameter of the original image and which is sufficiently general to allow the effective radius of the composite imaging system to be arbitrarily shaped and reduced, subject primarily to the noise power constraint. In addition, the size of the point-spread function of the preprocessing filter can be arbitrarily controlled, thus minimizing truncation errors.

Mcgillem, C. D.↗

Pressure perturbation in EHD contacts due to an ellipsoidal asperity

The pressure fluctuations around an ellipsoidal asperity tip at the inlet region of an elastohydrodynamic contact is determined by solving a perturbed Reynolds equation assuming that the asperity shape is unaffected by the perturbed pressure. Results are presented as the amplitude of the perturbed pressure as a function of ellipticity ratio, maximum Hertzian pressure, nominal EHD film thickness, asperity size, asperity height, and pressure viscosity coefficient. For the case of simple sliding between a smooth surface and a stationary asperity, a comparison is also made between the results for large ellipticity ratios and the pressure fluctuations obtained by using a previous line contact EHD analysis for a two-dimensional asperity ridge. The agreement is found to be close for moderate Hertzian pressure and relatively thick EHD film thickness.

Chow, L. S. H.↗

A high Reynolds number numerical solution of the Navier-Stokes equations in stream function-vorticity form

Problems encoutered in investigations of high Reynolds number, incompressible flow are reviewed. A numerical solution computer program was modified to solve the stream function-vorticity form of the Navier-Stokes equations. Using a body fitted coordinate system with a U-shaped outer boundary, a simulation of incompressible flow at a Reynolds number of one million and a body angle of attack of zero was achieved.

Bearden, J. H.↗

Determination of strains in optical windows of a high-pressure chamber by holographic interferometry and finite element analysis

Holographic interferometry and finite element analysis have been applied to determine the strain in a large optical window installed in a high-pressure chamber. Two different shapes of windows were chosen, and the outside and inside surface strains of the windows were followed as a function of internal pressure by taking double exposed holograms at 69-bar intervals up to 483 bars. The results were compared with the values calculated by a standard finite element code with an assumption of no displacement at the load-bearing edge. The agreement between two results was found to be good for both cases.

Soga, N.↗

Interpretation of spatial and temporal variations of hydrogen quadrupole absorptions in the Jovian atmosphere observed during the 1972 apparition

Results are reported for a systematic investigation of temporal and spatial variations of hydrogen quadrupole lines formed in the Jovian atmosphere, which was performed by measuring the strengths of the S(1) lines of H2 (3,0) and (4,0) quadrupole bands at several points on the Jovian disk during the 1972 apparition. The observations support the hypothesis that the strength of the (3,0) S(1) line varies significantly with time, suggest the possibility of short-term temporal variation in the strength of the (4,0) line, and indicate that the H2 line strengths vary remarkably little from limb to limb in the equatorial region. A Galatry line-shape profile is calculated, and a radiative-transfer analysis is carried out using the Henyey-Greenstein phase function for single particle scattering. It is shown that the observations are consistent with a multilayer atmospheric model having an optically thin upper cloud deck separated by a stratum of nonscattering gas from an optically thick lower cloud.

Hunt, G. E.↗

The evolution of the spaceflight tracking and data network

The evolution of the Minitrack Network, the first worldwide satellite tracking capability (1957-1962), into the Satellite Tracking and Data Acquisition Network (1960-1966) is described. Attention is also given to the Mercury Network, which became operational in 1961, was the foundation for the Manned Space Flight Network, and supported the Gemini and Apollo missions. The development of the NASA Communications Network, which began to take shape in the early 1960s, is described. An account is also given of the way in which all these functions began playing together (1965) and were consolidated in the early 1970s as the Space Tracking and Data Network.

Hocking, W. M.↗

Order reduction for models of space structures using modal cost analysis

Modal cost analysis furnishes a promising methodology for developing dynamical models of space structures for use in control systems analysis. Economy and accuracy can be attained by only retaining vibration modes that contribute significantly to an appropriately defined cost function. Expressions for modal costs (especially simple for 'lightly damped' structures) are derived for attitude control, vibration suppression, and shape control. These techniques are illustrated through application to a high-order finite element model of a large platform-type structure.

Skelton, R. E.↗

Structural sensitivity analysis: Methods, applications, and needs

Some innovative techniques applicable to sensitivity analysis of discretized structural systems are reviewed. These techniques include a finite-difference step-size selection algorithm, a method for derivatives of iterative solutions, a Green's function technique for derivatives of transient response, a simultaneous calculation of temperatures and their derivatives, derivatives with respect to shape, and derivatives of optimum designs with respect to problem parameters. Computerized implementations of sensitivity analysis and applications of sensitivity derivatives are also discussed. Finally, some of the critical needs in the structural sensitivity area are indicated along with Langley plans for dealing with some of these needs.

Adelman, H. M.↗

Numerical and experimental study of curved and planar frequency selective surfaces with arbitrary illumination

A frequency selective surface (FSS) composed of apertures in a metallic sheet is known as the inductive FSS. The infinite inductive FSS theory is derived and the aperture fields are solved by a spectral domain formulation with method of moments solution. Both full domain and subsectional basis functions are studied. A locally planar technique (LPT) is used to determine the forward scattered field from a generally shaped inductive FSS with arbitrary illumination.

Caroglanian, Armen↗

Polymer morphologh

All polymeric materials in their final application are aggregates of many molecules. For linear macromolecules, these aggregates are highly entangled and their macroscopic properties are affected in a little-known way by the interpenetration and entanglements of the molecules. Over the years, we have done occasional investigations of single molecule single crystals and found that there are many unsolved questions about their nucleation, growth, kinetically determined shape, and ultimate path to equilibrium morphology on annealing. This initial work could be extended by a study of the applicability of microgravity methods for the production and study of the formation of single molecule particles. The production of separated molecules of sufficient size to produce phase-like behavior would involve perhaps a spray of solutions containing single molecules, followed by evaporation of the volatiles, or precipitation out of dispersion droplets. Other methods may involve Langmuir films etc., as shown in our prior work. The microgravity environment should enhance the efficiency of any of these methods by avoiding the joining of growing particles by reduction of convection and settling due to density differences. Once produced, the single molecule droplets are to be quenched into the glassy state and analyzed morphologically and thermally. Their shape alone can be used for molecular mass determination (an old problem that suffered from the need to estimate the shape of collapsed (flat) droplets on a surface). Next would be the study of changes of properties as a function of time, temperature, and molecular mass (and distribution) on fusion to macroscopic single phases.

Wunderlich, Bernhard↗

Use of FUV auroral emissions as diagnostic indicators

In an earlier study we modeled selected Far Ultraviolet (FUV) auroral emissions (O I(1356 A), N2 Lyman-Birge-Hopfield (LBH) (1464 A), and LBH (1838 A)) to examine the sensitivity of these emissions and their ratios to likely changes in the neutral atmosphere. In this paper we extend that study to examine the dependence of these same emissions and their ratios on the shape of the energy distribution of the auroral electrons. In particular, we wish to determine whether changes in energy spectra might interfere with our determination of the characteristic energy. Modeled column-integrated emissions show relatively small (less than 30%) dependences on the shape and width of the incident energy spectrum, provided the average energy and total energy flux of the energy distribution are held constant. Long-wavelength FUV emissions, which are relatively unaffected by O2 absorption losses, exhibit virtually no dependence on the shape of the incident energy distribution. Changes in ratios of FUV short- to long-wavelength emissions as a function of characteristic energy are much larger than those due to changes in energy distribution. As a result, the determination of characteristic energy using these emission ratios is relatively unambiguous. We also examine the relative intensities of the aurora and the dayglow for various conditions. The intensities of modeled FUV auroral emissions relative to the dayglow emissions are presented as a function of solar zenith angle and incident energy flux. Under certain conditions (energy flux less than or equal 1 erg/sq cm/s and solar zenith angle less than or equal 50 deg) the dayglow will be limiting factor in the detection of weak auroras.

Germany, G. A.↗

Temperature Regulator for Actively Cooled Structures

In active cooling of a structure it is beneficial to use a plurality of passages for conducting coolant to various portions of the structure. Since most structures do not undergo isotropic thermal loads it is desirable to allow for variation in coolant flow to each area of the structure. The present invention allows for variable flow by a variation of the area of a portion of each of the coolant passages. Shape memory alloys and bi-material springs are used to produce passages that change flow area as a function of temperature.

Blosser, Max↗

A C-band backscatter model for lake ice in Alaska

ERS-1 SAR imagery of lake ice growing on shallow tundra lakes in northern Alaska shows interesting radar backscatter variations. Based on the analysis of ice cores from these lakes, a multi-layer backscatter model comprised of the following elements has been developed: (1) specular air-ice; ice-water and ice-frozen soil boundaries; (2) an ice layer of variable thickness; (3) ice sub-layers with air inclusions of variable density, size and shape including spheres, prolate spheroids, and cylinders of finite length. Preliminary model results confirm that backscatter is a sensitive function of greater reflectivity than from an ice-frozen soil interface. The model has also been tested using bubble data derived from ice cores in April 1992. The modelled backscatter is compared with backscatter derived from ERS-1 SAR images obtained at the same time as the fieldwork.

Wakabayashi, H.↗

Spot Radiative Ignition and Subsequent Three Dimensional Flame Spread Over Thin Cellulose Fuels

Spontaneous radiative ignition and transition to flame spread over thin cellulose fuel samples was studied aboard the USMP-3 STS-75 Space Shuttle mission, and in three test series in the 10 second Japan Microgravity Center (JAMIC). A focused beam from a tungsten/halogen lamp was used to ignite the center of the fuel sample while an external air flow was varied from 0 to 10 cm/s. Non-piloted radiative ignition of the paper was found to occur more easily in microgravity than in normal gravity. Ignition of the sample was achieved under all conditions studied (shuttle cabin air, 21%-50% O2 in JAMIC), with transition to flame spread occurring for all but the lowest oxygen and flow conditions. While radiative ignition in a quiescent atmosphere was achieved, the flame quickly extinguished in air. The ignition delay time was proportional to the gas-phase mixing time, which is estimated using the inverse flow rate. The ignition delay was a much stronger function of flow at lower oxygen concentrations. After ignition, the flame initially spread only upstream, in a fan-shaped pattern. The fan angle increased with increasing external flow and oxygen concentration from zero angle (tunneling flame spread) at the limiting 0.5 cm/s external air flow, to 90 degrees (semicircular flame spread) for external flows at and above 5 cm/s, and higher oxygen concentrations. The fan angle was shown to be directly related to the limiting air flow velocity. Despite the convective heating from the upstream flame, the downstream flame was inhibited due to the 'oxygen shadow' of the upstream flame for the air flow conditions studied. Downstream flame spread rates in air, measured after upstream flame spread was complete and extinguished, were slower than upstream flame spread rates at the same flow. The quench regime for the transition to flame spread was skewed toward the downstream, due to the augmenting role of diffusion for opposed flow flame spread, versus the canceling effect of diffusion at very low cocurrent flows.

Olson, Sandra L.↗

Parametric Studies of Square Solar Sails Using Finite Element Analysis

Parametric studies are performed on two generic square solar sail designs to identify parameters of interest. The studies are performed on systems-level models of full-scale solar sails, and include geometric nonlinearity and inertia relief, and use a Newton-Raphson scheme to apply sail pre-tensioning and solar pressure. Computational strategies and difficulties encountered during the analyses are also addressed. The purpose of this paper is not to compare the benefits of one sail design over the other. Instead, the results of the parametric studies may be used to identify general response trends, and areas of potential nonlinear structural interactions for future studies. The effects of sail size, sail membrane pre-stress, sail membrane thickness, and boom stiffness on the sail membrane and boom deformations, boom loads, and vibration frequencies are studied. Over the range of parameters studied, the maximum sail deflection and boom deformations are a nonlinear function of the sail properties. In general, the vibration frequencies and modes are closely spaced. For some vibration mode shapes, local deformation patterns that dominate the response are identified. These localized patterns are attributed to the presence of negative stresses in the sail membrane that are artifacts of the assumption of ignoring the effects of wrinkling in the modeling process, and are not believed to be physically meaningful. Over the range of parameters studied, several regions of potential nonlinear modal interaction are identified.

Sleight, David W.↗

Convection in a Very Compressible Fluid: Comparison of Simulations With Experiments

The time profile (Delta)T(t) of the temperature difference, measured across a very compressible fluid layer of supercritical He-3 after the start of a heat flow, shows a damped oscillatory behavior before steady state convection is reached. The results for (Delta)T(t) obtained from numerical simulations and from laboratory experiments are compared over a temperature range where the compressibility varies by a factor of approx. = 40. First the steady-state convective heat current j(sup conv) as a function of the Rayleigh number R(alpha) is presented, and the agreement is found to be good. Second, the shape of the time profile and two characteristic times in the transient part of (Delta)T(t) from simulations and experiments are compared, namely: 1) t(sub osc), the oscillatory period and 2) t(sub p), the time of the first peak after starting the heat flow. These times, scaled by the diffusive time tau(sub D) versus R(alpha), are presented. The agreement is good for t(sup osc)/tau(sub D), where the results collapse on a single curve showing a powerlaw behavior. The simulation hence confirms the universal scaling behavior found experimentally. However for t(sub p)/tau(sub D), where the experimental data also collapse on a single curve, the simulation results show systematic departures from such a behavior. A possible reason for some of the disagreements, both in the time profile and in t(sub p) is discussed. In the Appendix a third characteristic time, t(sub m), between the first peak and the first oscillation minimum is plotted and a comparison between the results of experiments and simulations is made.

Meyer, H.↗