Ultrahigh GaN:SiO 2 etch selectivity by in situ surface modification of SiO 2 in a Cl 2 -Ar plasma
Not Available
70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
SEARCH · Engineering Papers
Results for “MODIFICATIONS”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Beyond electrostatic modification: design and discovery of functional oxide phases via ionic-electronic doping
A new research field of functional materials and device physics is emerging that combines ionic transport with charge carrier modulation to realize emergent physical properties and discovery of metastable phases. The paradigm for enabling function extends far beyond carrier accumulation or depletion in band semiconductors or simply moving ions through an insulating electrolyte. Rather, by careful selection of electronically or structurally fragile materials, one can collapse or open band gaps via extreme ionic dopant concentration, or reconfigure their entire crystal structure to create new phases. Electron-electron and electron-lattice interactions can be coupled or controlled independently in such systems via electric fields without thermal constraints by use of ionic dopants. The unifying theme across these studies is to introduce ions and electrons via electric fields through interfaces with electrochemistry playing a dominant role. In this review, we briefly summarize this nascent field of iontronics and discuss principal results to date with examples from binary and complex oxides as well as selected 2D materials systems. Here, we conclude the review by highlighting gaps in fundamental scientific understanding and prospects for the use of such novel devices in future electronic, photonic and energy technologies.
36 MATERIALS SCIENCE↗
MODIFICATION OF THE MOOG SPECTRAL SYNTHESIS CODES TO ACCOUNT FOR ZEEMAN BROADENING OF SPECTRAL LINES
In an attempt to widen access to the study of magnetic fields in stellar astronomy, I present MOOGStokes, a version of the MOOG one-dimensional local thermodynamic equilibrium radiative transfer code, overhauled to incorporate a Stokes vector treatment of polarized radiation through a magnetic medium. MOOGStokes is a suite of three complementary programs, which together can synthesize the disk-averaged emergent spectrum of a star with a magnetic field. The first element (a pre-processing script called CounterPoint) calculates for a given magnetic field strength, wavelength shifts, and polarizations for the components of Zeeman-sensitive lines. The second element (a MOOG driver called SynStokes derived from the existing MOOG driver Synth) uses the list of Zeeman-shifted absorption lines together with the existing machinery of MOOG to synthesize the emergent spectrum at numerous locations across the stellar disk, accounting for stellar and magnetic field geometry. The third and final element (a post-processing script called DiskoBall) calculates the disk-averaged spectrum by weighting the individual emergent spectra by limb darkening and projected area, and applying the effects of Doppler broadening. All together, the MOOGStokes package allows users to synthesize emergent spectra of stars with magnetic fields in a familiar computational framework. MOOGStokes produces disk-averaged spectra for all Stokes vectors ( I, Q, U, V ), normalized by the continuum. MOOGStokes agrees well with the predictions of INVERS10 a polarized radiative transfer code with a long history of use in the study of stellar magnetic fields. In the non-magnetic limit, MOOGStokes also agrees with the predictions of the scalar version of MOOG.
79 ASTRONOMY AND ASTROPHYSICS↗
Controlled mechnaical modification of manganite surface with nanoscale resolution
In this study, we investigated the surfaces of magnetoresistive manganites, La 1-x Ca x MnO 3 and La 2-2x Sr 1+2x Mn 2 O 7 , using a combination of ultrahigh vacuum conductive, electrostatic and magnetic force microscopy methods. Scanning as-grown film with a metal tip, even with zero applied bias, was found to modify the surface electronic properties such that in subsequent scans, the conductivity is reduced below the noise level of conductive probe microscopy. Scanned areas also reveal a reduced contact potential difference relative to the pristine surface by ~0.3 eV. Finally, we propose that contact-pressure of the tip modifies the electrochemical potential of oxygen vacancies via the Vegard effect, causing vacancy motion and concomitant changes of the electronic properties.
36 MATERIALS SCIENCE↗
Near-surface modification of defective KTaO 3 by ionizing ion irradiation
The synergistic effect of nuclear (S n ) and electronic (S e ) energy loss observed in some ABO 3 perovskites has attracted considerable attention due to the real possibility to modify various near-surface properties, such as the electronic and optical properties, by patterning ion tracks in the defective near-surface regions. In this study, we show that low-energy ion-induced disordering in conjunction with ionizing ion irradiation (18 MeV Si, 21 MeV Ni and 91.6 MeV Xe) is a promising approach for tailoring ion tracks in the near-surface of defective KTaO 3 . Experimental characterization and computer simulations reveal that the size of these latent ion tracks increases with S e and level of pre-existing damage. These results further reveal that the threshold S e value (S e th ) for track creation increases with decreasing pre-damage level. The values of S e th increase from 5.02 keV nm -1 , for a pre-existing fractional disorder of 0.53 in KTaO 3 , to 10.81 keV nm -1 for pristine KTaO 3 . Above these thresholds, amorphous latent tracks are produced due local melting and rapid quenching. Below a disorder fraction of 0.08 and S e ≤ 6.68 keV nm -1 , the synergistic effect is not active, and damage accumulation is suppressed due to a competing ionization-induced damage annealing process. These results indicate that, depending on S e and the amount of pre-existing damage, highly ionizing ions can either enhance or suppress damage accumulation in KTaO 3 , thus providing a pathway to tailoring defects states. Comprehending the conflicting roles of highly ionizing ions in defective ABO 3 oxides is vital for understanding and predictive modeling of ion-solid interactions in complex oxides, as well as for achieving control over ion track size in the near-surface of defective KTaO 3 .
36 MATERIALS SCIENCE↗
Pressure-induced structural modifications of rare-earth hafnate pyrochlore
Abstract not provided
Turner, Katlyn M.↗
Tuning of the electronic and vibrational properties of epitaxial MoS 2 through He-ion beam modification
Abstract Atomically thin transition metal dichalcogenides (TMDs), like MoS 2 with high carrier mobilities and tunable electron dispersions, are unique active material candidates for next generation opto-electronic devices. Previous studies on ion irradiation show great potential applications when applied to two-dimensional (2D) materials, yet have been limited to micron size exfoliated flakes or smaller. To demonstrate the scalability of this method for industrial applications, we report the application of relatively low power (50 keV) 4 He + ion irradiation towards tuning the optoelectronic properties of an epitaxially grown continuous film of MoS 2 at the wafer scale, and demonstrate that precise manipulation of atomistic defects can be achieved in TMD films using ion implanters. The effect of 4 He + ion fluence on the PL and Raman signatures of the irradiated film provides new insights into the type and concentration of defects formed in the MoS 2 lattice, which are quantified through ion beam analysis. PL and Raman spectroscopy indicate that point defects are generated without causing disruption to the underlying lattice structure of the 2D films and hence, this technique can prove to be an effective way to achieve defect-mediated control over the opto-electronic properties of MoS 2 and other 2D materials.
77 NANOSCIENCE AND NANOTECHNOLOGY↗
Maximal freedom at minimum cost: linear large-scale structure in general modifications of gravity
We present a turnkey solution, ready for implementation in numerical codes, for the study of linear structure formation in general scalar-tensor models involving a single universally coupled scalar field. We show that the totality of cosmological information on the gravitational sector can be compressed — without any redundancy — into five independent and arbitrary functions of time only and one constant. These describe physical properties of the universe: the observable background expansion history, fractional matter density today, and four functions of time describing the properties of the dark energy. We show that two of those dark-energy property functions control the existence of anisotropic stress, the other two — dark-energy clustering, both of which are can be scale-dependent. All these properties can in principle be measured, but no information on the underlying theory of acceleration beyond this can be obtained. We present a translation between popular models of late-time acceleration (e.g. perfect fluids, f(R), kinetic gravity braiding, galileons), as well as the effective field theory framework, and our formulation. In this way, implementing this formulation numerically would give a single tool which could consistently test the majority of models of late-time acceleration heretofore proposed.
79 ASTRONOMY AND ASTROPHYSICS↗
ELM frequency enhancement and discharge modification through lithium granule injection into EAST H-modes
The injection of impurity granules into fusion research discharges can serve as a catalyst for ELM events. For sufficiently low ELM frequencies, and granule sizes above a threshold, this can result in full control of the ELM cycle, referred to as ELM pacing. For this research, we extend the investigation to conditions where the natural ELM frequency is too high for ELM pacing to be realized. Utilizing multiple sizes of lithium granules and classifying their effects by granule size, we demonstrate that ELM mitigation through frequency multiplication can be used at ELM triggering rates that nominally make ELM pacing unrealizable. We find that above a size threshold, injected granules promptly trigger ELMs and commensurately enhance the ELM frequency. Below this threshold size, injection of an individual granule does not always lead to the prompt triggering of an ELM; however, collective ablation in the edge pedestal region does enhance the ELM frequency. Furthermore, Li granules too small to individually trigger ELMs were injected into EAST H-mode discharges at frequencies up to 2.3 kHz; collectively the granules were observed to enhance the natural ELM frequency up to 620 Hz, resulting in a ~2.4 × multiplication of the natural ELM frequency and a 50% decrease of the ELM size.
70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
Modification of the Alfvén wave spectrum by pellet injection
Alfvén eigenmodes driven by energetic particles are routinely observed in tokamak plasmas. These modes consist of poloidal harmonics of shear Alfvén waves coupled by inhomogeneity in the magnetic field. In this work, further coupling is introduced by 3D inhomogeneities in the ion density during the assimilation of injected pellets. This additional coupling modifies the Alfvén continuum and discrete eigenmode spectrum. We find that the frequencies of Alfvén eigenmodes drop dramatically when a pellet is injected in JET. From these observations, information about the changes in the ion density caused by a pellet can be inferred. To use Alfvén eigenmodes for MHD spectroscopy of pellet injected plasmas, the 3D MHD codes Stellgap and AE3D were generalised to incorporate 3D density profiles. Additionally, a model for the expansion of the ionised pellet plasmoid along a magnetic field line was derived from the fluid equations. Thereby, the time evolution of the Alfvén eigenfrequency is reproduced. By comparing the numerical frequency drop of a toroidal Alfvén eigenmode (TAE) to experimental observations, the initial ion density of a cigar-shaped ablation region of length 4 cm is estimated to be n * =6.8×10 22 m -3 at the TAE location (r/a≈0.75). The frequency sweeping of an Alfvén eigenmode ends when the ion density homogenises poloidally. Modelling suggests that the time for poloidal homogenisation of the ion density at the TAE position is τ h =18±4 ms for inboard pellet injection, and τ h =26±2 ms for outboard pellet injection. By reproducing the frequency evolution of the elliptical Alfvén eigenmode (EAE), the initial ion density at the EAE location (r/a≈0.9) can be estimated to be n * =4.8×10 22 m -3 . Poloidal homogenisation of the ion density takes 2.7 times longer at the EAE location than at the TAE location for both inboard and outboard pellet injection.
70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
Modification of favorable average curvature effect by changing parallel sound wave behavior in tokamak plasmas
Abstract The favorable average curvature effect, also known as the GGJ effect (Glasser et al 1975 Phys. Fluids 18 875), is intrinsically associated with parallel sound wave propagation in a tokamak plasma. This work investigates how the GGJ effect is modified by changing the parallel sound wave behavior. Two physics models beyond the standard single fluid theory, i.e. an anisotropic thermal transport model and a parallel sound wave damping model, are employed to change parallel sound waves in a toroidal plasma, and the consequence on the GGJ effect is demonstrated for two important classes of problems, i.e. the resistive plasma response to the applied resonant magnetic perturbation and the stability of the tearing mode. Toroidal modeling reveals that the GGJ effect is significantly altered by both of the aforementioned physics effects. Compared to the thermal transport physics, which completely removes the GGJ effect, the sound wave damping effect only offers partial mitigation. The differences between these two models are further illustrated in terms of the radial structure of the shielding current and the eigenfunction of the tearing instability. In particular, a fundamental reason for complete suppression of the GGJ effect by the thermal transport is identified as an extra toroidal coupling of the poloidal harmonics.
Physics↗
Real-time wall conditioning and recycling modification utilizing boron and boron nitride powder injections into the Large Helical Device
Controlled particulate injections from the PPPL impurity powder dropper (IPD) into the Large Helical Device have demonstrated positive effects on the wall conditions on both an intra and inter-shot basis. Here injections over a range of densities, input powers, pulse lengths, heating schemes, injection quantities and main ion species show conclusive evidence of improvement to plasma wall conditions. Successful injections are confirmed by both spectroscopic measurements as well as real-time visible camera signals. In 7 s long plasmas the responses include a reduction in wall recycling as well as a reduction in native impurity content as observed over the course of several discharges. For plasmas longer than 40 s, improvements to the recycling rate and increased impurity control are observed in real time as a consequence of the extended particulate injections. These experiments demonstrate the extended applicability of this solid particulate conditioning technique to the control and maintenance of the plasma wall conditions. In addition they are an important initial step in the development of the real-time boronization technique as a supplement to standard conditioning scenarios.
70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
Modifications of high-p T di-hadron correlations for identified triggers
Angular correlations with high transverse momentum hadrons have become an established tool for studying properties of the medium created in ultra-relativistic heavy ion collisions. When investigated in two dimensions, relative azimuth and relative pseudorapidity, the small-angle part of such correlations is commonly attributed to QCD jets, while long-range correlations, specifically ridge observed at low- and intermediate momentum, are often described as manifestations of hydrodynamic expansion of the system, e.g. flow. Comparative analysis of both features, presented in this work for correlations with identified leading hadrons, explores the particle type dependence of the jet structures, and challenges the flow-only hypotheses behind the ridge.
72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
Modification of Wind Turbine Performance by Statistically Distinct Atmospheric Regimes
Abstract not provided
17 WIND ENERGY↗
Modification of the electronic properties of hexagonal boron-nitride in BN/graphene vertical heterostructures
Van der Waals (vdW) heterostructures consist of isolated atomic planar structures, assembled layer- by-layer into desired structures in a well-defined sequence. Graphene deposited on hexagonal boron nitride (h-BN) has been first considered as a testbed system for vdW heterostructures, and many others have been demonstrated both theoretically and experimentally, revealing many attractive properties and phenomena. However, much less emphasis has been placed on how graphene actively affects h-BN properties. Here, we perform local probe measurements on single-layer h-BN grown over graphene and highlight the manifestation of a proximity effect that significantly affects the electronic properties of h-BN due to its coupling with the underlying graphene. We find electronic states originating from the graphene layer and the Cu substrate to be injected into the wide electronic gap of the h-BN top layer. Such proximity effect is further confirmed in a study of the variation of h-BN in-gap states with interlayer couplings, elucidated using a combination of topographical/ spectroscopic measurements and first-principles density functional theory calculations. In conclusion, the findings of this work indicate the potential of mutually engineering electronic properties of the components of vdW heterostructures.
36 MATERIALS SCIENCE↗