Fault Identification in Crystalline Silicon PV Modules by Complementary Analysis of the Light and Dark Current-Voltage Characteristics
Explore the source record for details and available documents.
14 SOLAR ENERGY↗
SEARCH · Engineering Papers
Results for “INTERCONNECTIONS”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Back-contacted bottom cells with three terminals: Maximizing power extraction from current-mismatched tandem cells
Multi-junction cells can significantly improve the energy yield of photovoltaic systems over a single-junction cell. The internal interconnection scheme of the subcells is an important aspect in determining the resulting levelized cost of electricity. For a dual-junction cell, two approaches are commonly discussed: series-connected tandem cells with two terminals or independently working subcells in a four-terminal (4T) tandem device. In this paper, we explore the working principle and the operation modes of a third, rarely discussed option: a three-terminal (3T) tandem cell using a back-contacted bottom cell with 3Ts. We use current-voltage measurements of illuminated 3T interdigitated back contact cells and confirm that the front and rear base contacts are at similar quasi-Fermi level positions, which enables the bottom cell to either efficiently collect surplus carriers, in the case of a current-limiting or carrier injecting top cell, or inject majority carriers, in the case of a current-limiting bottom cell. As a result, no current matching is needed. The power output of an idealized 3T bottom cell without resistive effects is independent of the current density applied from the top cell. These characteristics of the 3T bottom cells enable a 3T tandem to operate as efficiently as a 4T tandem, while being compatible with monolithic design and not requiring intermediate grids. We propose a simple equivalent circuit model including additional resistive effects, which describes a real 3T bottom cell and achieves excellent agreement to the experiment. We deduce design guidelines for a 3T bottom cell in different operation regimes.
14 SOLAR ENERGY↗
Evaluation of bifacial module technologies with combined–accelerated stress testing
In view of the increasing interest and market share of bifacial cells and modules, suitable substrates such as glass and transparent backsheets along with ethylene vinyl acetate (EVA) and polyolefin elastomer (POE) encapsulants were examined in combined-accelerated stress testing (C-AST) to evaluate and compare degradation modes. Testing with both monofacial and bifacial cells, we found glass-glass modules with monofacial cells led to greater grid finger breakage than those with polymeric backsheets. Furthermore, this is attributed to previous X-ray topography and modeling work showing higher stress in cells and interconnections in glass-glass modules than glass-backsheet modules. Consistent with the objectives of C-AST, which stresses modules at levels corresponding to the limits seen in the natural environment, we observed the UV-fluorescence signatures of modules tested in C-AST (considering the degradation associated with developing chromophores, moisture penetration and photobleaching effects) to be like those in fielded modules, more so than other chamber stress testing implemented for comparison. We found light-induced degradation (LID) in module types with regenerated (inactive) cells with C-AST, suggesting the possibility of LID destabilization in some field conditions. We could also distinguish potential-induced degradation (PID) on the back of the bifacial passivated emitter and rear cells (PERC) in C-AST. Confirming with ex-situ tests, we found polarization-type PID most prevalent in glass-glass modules with EVA as would be anticipated considering the greater leakage current through such module encapsulation. Unlike PID tests performed in the dark, which can lead to false positive PID test results, field-representative illumination is experienced by the modules on the front and back side while –1200 V system voltage is applied in C-AST, supporting the conclusion that this module type with glass-glass construction would be susceptible to PID in the field.
14 SOLAR ENERGY↗
Quantifying optical loss of high-voltage degradation modes in photovoltaic modules using spectral analysis
The direct current bias for photovoltaic (PV) modules interconnected in series-strings may include both high voltage negative (“HV-”) and positive (“HV+”) polarity with respect to the electrical ground. Multiple degradation modes, resulting in quantifiable optical loss, were found to occur during HV-/HV+ sequential stress, including corrosion of the external glass surface, encapsulant delamination (at its interfaces with the glass and the PV cell), internal haze formation (resulting from a chemical interaction between the glass and the encapsulant), corrosion and migration of the gridlines, and corrosion of the silicon nitride (Si x N y ) antireflective coating on the cell. The effects of these separate modes were examined using monolithic (e.g., glass or PV cell) and laminated-coupon (glass/encapsulant/glass or glass/encapsulant/cell/encapsulant/backsheet) specimens. Characterizations during and after unbiased accelerated testing at 85°C/85% relative humidity included spectrophotometry, optical microscopy, electron microscopy, and ellipsometry. For some module components (i.e., the glass and the Si x N y coating), the optical performance was determined through iterative analysis of empirical measurements. Concentrating on just their spectral effect, a novel model was then developed to estimate the transfer of light to the PV cell and the return of light from the PV module with simultaneous degradation mechanisms, which was compared with a mini-module previously subjected to HV-/HV+ stress. Here the model suggests that one third of the current loss observed for the mini-module can be attributed to the optical degradation of the packaging materials. The dominant degradation modes include encapsulant delamination and corrosion of the Si x N y coating. Recommendations are given so that the optical model may be improved relative to accelerated testing and validated relative to field aging.
14 SOLAR ENERGY↗
Performance and durability of electrically conductive tape for shingled Si heterojunction technology cells
We report electrically conductive tape (ECT) was characterized and used to assemble shingled cell strings at low temperature to achieve high reliability Pb- and Ag-free interconnections. The volume resistivity for two considered ECTs are 0.13 ± 0.06 mΩ·cm and 0.47 ± 0.20 mΩ·cm and specific contact resistances, 6.85± 2.00 mΩ·cm 2 and 6.30 ± 0.37 mΩ·cm 2 using the emerging IEC 62788-8-1 Technical Specification for assessment of electrically conductive adhesives (ECA). Durability and performance of the technology in glass–glass mini modules were evaluated with temperature cycling, damp heat testing, and combined-accelerated stress testing (CAST). Through temperature cycling (-40°C to 85°C) applying five times the mini module short-circuit current in forward bias and in the multi climate CAST protocol, there was negligible degradation of fill factor after replacing connectors at the modules' cable leads; however, CAST resulted in short circuit current loss attributed to degradation in light collection by the cells, not the ECT. The IEC 61215-2 85°C, 85% relative humidity damp heat testing showed susceptibility of the HJT cells to effects of humidity in the electroluminescence intensity around the module perimeter that degraded power performance by 4% (relative). Contrasting the IEC 61215-2 qualification testing-based damp heat testing with CAST, factors such as the optical stress of CAST may precipitate the degradation of the modules whereas the humidity levels and duration of IEC 61215-2 damp heat testing may lead to excessive levels of humidity diffused into the modules, potentially resulting in degradation that is unrepresentative of the field.
14 SOLAR ENERGY↗
Gas Transport in the Insensitive High Explosive PBX 9502
Small-scale laboratory experiments were performed to analyze gas transport mechanics in PBX 9502, an insensitive high explosive (IHE) composition. Two independent investigations are reported here. First, gas permeametry and dynamic pycnometry techniques were used to measure the molecular flow (Knudsen) coefficient and the internally interconnected void fraction of pristine and thermally damaged samples in two uniaxial pressing orientations. The permeability of PBX 9502 was found to be unmeasurably low (of the same order of magnitude as PTFE) with gas transport being diffusion-dominated. Secondly, a pressure vessel experiment was developed to measure quasi-static and dynamic gas generation as the explosive was heated to self-ignition (cookoff). The gas generation results and the permeability/diffusivity findings provide evidence that PBX 9502 remains impermeable until seconds prior to self-ignition. At ignition, internal void-pressure drives macro-scale cracking and the sample becomes uniformly incorporated in the following deconsolidating deflagration. These results are discussed within the context of previous observations of pressure-dependent cookoff behavior of PBX 9502 and provide a more complete description of thermal damage evolution in this explosive composition.
45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗
Preferred Void Orientation in Uniaxially Pressed PBX 9502
Ultra- and small-angle neutron scattering techniques were used to study the morphology of voids in directions parallel and perpendicular to the compaction plane of a uniaxially pressed cylinder of PBX 9502. Two-dimensional scattering patterns from samples cut parallel to the compaction plane had circular equal-intensity contours, implying that along this view the voids are circular or randomly oriented. Identical measurements of samples cut perpendicular to the compaction plane produced elliptical equal-intensity contours, indicating preferred orientation of voids. Analysis of the two dimensional scattering patterns confirmed that the voids are non-spherical with an average aspect ratio of 1.20, flattened so that the larger dimensions of the voids lie within the compaction plane. Model analysis of the combined ultra- and small-angle neutron scattering curves revealed that the PBX 9502 porosity is interconnected, in the form of aggregates comprised of non-spherical, primary voids. The volume dimension was found to be the same in both directions, indicating that the aggregate is randomly oriented throughout the sample, and that it is the primary voids that are preferentially oriented. Furthermore, void interfaces with the surrounding matrix were found to be rough or polydisperse, with a common roughness dimension or polydispersity in all directions.
42 ENGINEERING↗
Recombination and Resistive Losses of Transferred Foil Contacts for Silicon Heterojunction Solar Cells
Not provided.
Materials Science↗
Robust control of a family of uncertain nonminimum‐phase systems via continuous‐time and sampled‐data output feedback
Summary The problem of global robust stabilization is studied by both continuous‐time and sampled‐data output feedback for a family of nonminimum‐phase nonlinear systems with uncertainty. The uncertain nonlinear system considered in this paper has an interconnect structure consisting of a driving system and a possibly unstable zero dynamics with uncertainty, ie, the uncertain driven system. Under a linear growth condition on the uncertain zero dynamics and a Lipschitz condition on the driving system, we show that it is possible to globally robustly stabilize the family of uncertain nonminimum‐phase systems by a single continuous‐time or a sampled‐data output feedback controller. The sampled‐data output feedback controller is designed by using the emulated versions of a continuous‐time observer and a state feedback controller, ie, by holding the input/output signals constant over each sampling interval. The design of either continuous‐time or sampled‐data output compensator uses only the information of the nominal system of the uncertain controlled plant. In the case of sampled‐data control, global robust stability of the hybrid closed‐loop system with uncertainty is established by means of a feedback domination method together with the robustness of the nominal closed‐loop system if the sampling time is small enough.
Lin, Wei↗
Power grid frequency prediction using spatiotemporal modeling
Understanding power system dynamics is essential for interarea oscillation analysis and the detection of grid instabilities. The FNET/GridEye is a GPS-synchronized wide-area frequency measurement network that provides an accurate picture of the normal real-time operational condition of the power system-dynamics, giving rise to new and intricate spatiotemporal patterns of power loads. We propose to model FNET/GridEye grid frequency data from the U.S. Eastern Interconnection with a spatiotemporal statistical model. We predict the frequency data at locations without observations, a critical need during disruption events where measurement data are inaccessible. Spatial information is accounted for either as neighboring measurements in the form of covariates or with a spatiotemporal correlation model captured by a latent Gaussian field. Finally, the proposed method is useful in estimating power system dynamic response from limited phasor measurements and holds promise for predicting instability that may lead to undesirable effects such as cascading outages.
24 POWER TRANSMISSION AND DISTRIBUTION↗
Birnessite-Type MnO 2 Nanosheets with Layered Structures Under High Pressure: Elimination of Crystalline Stacking Faults and Oriented Laminar Assembly
Explore the source record for details and available documents.
catalysis (heterogeneous)↗
Deformation Rate‐Adaptive Conducting Polymers and Composites
Abstract Materials are more easily damaged during accidents that involve rapid deformation. Here, a design strategy is described for electronic materials comprised of conducting polymers that defies this orthodox property, making their extensibility and toughness dynamically adaptive to deformation rates. This counterintuitive property is achieved through a morphology of interconnected nanoscopic core–shell micelles, where the chemical interactions are stronger within the shells than the cores. As a result, the interlinked shells retain material integrity under strain, while the rate of dissociation of the cores controls the extent of micelle elongation, which is a process that adapts to deformation rates. A prototype based on polyaniline shows a 7.5‐fold increase in ultimate elongation and a 163‐fold increase in toughness when deformed at increasing rates from 2.5 to 10 000% min −1 . This concept can be generalized to other conducting polymers and highly conductive composites to create “self‐protective” soft electronic materials with enhanced durability under dynamic movement or deformation.
Hernandez, Victor↗
Holistic Microstructure Control Strategies in Photopolymerization‐Induced Phase Separation of Acrylate Systems
Open porous materials, known for their large surface area and interconnected structures, are essential in various applications, including batteries, ion exchange, catalysis, filtration, and electronic waste recycling. A critical aspect of the functionality of porous membranes is the precise control of pore size and morphology. Photopolymerization-induced phase separation (photo-PIPS) offers a convenient and versatile methods for creating porous structures. However, controlling the porous morphology remains challenging due to the complex interplay between thermodynamics, polymerization kinetics, and monomer structures, which makes it difficult to establish the relationship between processing conditions and resulting morphology in photo-PIPS. Herein, a physics-based phase-field model capable of generating and characterizing the microstructures of porous materials based on both average and localized features is developed. Using the phase-field simulations as test bed, the effects of polarity, light intensity, and curing temperature, as well as the previously unexplored roles of chain transfer agents and substrates, on the morphology of the resulting porous microstructure are investigated. Experiments are performed to verify the results predicted by the simulations. This work lays out a comprehensive guide for designing PIPS-derived porous microstructures and offers practical engineering strategies for tailoring microstructure-level topology and size of pores for application-specific needs.
36 MATERIALS SCIENCE↗
The water–climate nexus: Intersections across sectors
Water security and climate change are important priorities for communities and regions worldwide. The intersections between water and climate change extend across many environmental and human activities. This Primer is intended as an introduction, grounded in examples, for students and others considering the interactions between climate, water, and society. In this Primer, we summarize key intersections between water and climate across four sectors: environment; drinking water, sanitation, and hygiene; food and agriculture; and energy. We begin with an overview of the fundamental water dynamics within each of these four sectors, and then discuss how climate change is impacting water and society within and across these sectors. Emphasizing the relationships and interconnectedness between water and climate change can encourage systems thinking, which can show how activities in one sector may influence activities or outcomes in other sectors. We argue that to achieve a resilient and sustainable water future under climate change, proposed solutions must consider the water–climate nexus to ensure the interconnected roles of water across sectors are not overlooked. Toward that end, we offer an initial set of guiding questions that can be used to inform the development of more holistic climate solutions.
54 ENVIRONMENTAL SCIENCES↗
libwfa: Wavefunction analysis tools for excited and open‐shell electronic states
Abstract An open‐source software library for wavefunction analysis, libwfa, provides a comprehensive and flexible toolbox for post‐processing excited‐state calculations, featuring a hierarchy of interconnected visual and quantitative analysis methods. These tools afford compact graphical representations of various excited‐state processes, provide detailed insight into electronic structure, and are suitable for automated processing of large data sets. The analysis is based on reduced quantities, such as state and transition density matrices (DMs), and allows one to distill simple molecular orbital pictures of physical phenomena from intricate correlated wavefunctions. The implemented descriptors provide a rigorous link between many‐body wavefunctions and intuitive physical and chemical models, for example, exciton binding, double excitations, orbital relaxation, and polyradical character. A broad range of quantum‐chemical methods is interfaced with libwfa via a uniform interface layer in the form of DMs. This contribution reviews the structure of libwfa and highlights its capabilities by several representative use cases. This article is categorized under: Software > Quantum Chemistry Theoretical and Physical Chemistry > Spectroscopy
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Characterization of demand response in the commercial, industrial, and residential sectors in the United States
The goal of our study is to provide an overview of demand response (DR) technologies, including standards and end uses, in the United States and describe resource characteristics and the attributes of 14 specific DR resources in the U.S. commercial, residential, and industrial sectors. The attributes reviewed for the end uses being considered are response frequency, response time, the need for and impacts of energy pre- or recharge, the cost of enabling a resource to respond to a load-curtailment signal, and the magnitude of load curtailment in a given resource. We also describe controls and communications technologies that can enable end uses to participate in DR programs. The characterization was initially developed as a foundational work to quantify hourly availability of DR resources from the selected end uses followed by a multi-laboratory effort that quantified DR's value within the Western Interconnection.
24 POWER TRANSMISSION AND DISTRIBUTION↗
Estimating the impacts of natural gas power generation growth on solar electricity development: PJM's evolving resource mix and ramping capability
Abstract Expansion of distributed solar photovoltaic (PV) and natural gas‐fired generation capacity in the United States has put a renewed spotlight on methods and tools for power system planning and grid modernization. This article investigates the impact of increasing natural gas‐fired electricity generation assets on installed distributed solar PV systems in the Pennsylvania–New Jersey–Maryland (PJM) Interconnection in the United States over the period 2008–2018. We developed an empirical dynamic panel data model using the system‐generalized method of moments (system‐GMM) estimation approach. The model accounts for the impact of past and current technical, market and policy changes over time, forecasting errors, and business cycles by controlling for PJM jurisdictions‐level effects and year fixed effects. Using an instrumental variable to control for endogeneity, we concluded that natural gas does not crowd out renewables like solar PV in the PJM capacity market; however, we also found considerable heterogeneity. Such heterogeneity was displayed in the relationship between solar PV systems and electricity prices. More interestingly, we found no evidence suggesting any relationship between distributed solar PV development and nuclear, coal, hydro, or electricity consumption. In addition, considering policy effects of state renewable portfolio standards, net energy metering, differences in the PJM market structure, and other demand and cost‐related factors proved important in assessing their impacts on solar PV generation capacity, including energy storage as a non‐wire alternative policy technique. This article is categorized under: Photovoltaics > Economics and Policy Fossil Fuels > Climate and Environment Energy Systems Economics > Economics and Policy
29 ENERGY PLANNING, POLICY, AND ECONOMY↗