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At least 1,765 records · Page 98

Quantification of the carbon bonding state in amorphous carbon materials: A comparison between EELS and NEXAFS measurements

In this report the quantitative determination of the carbon hybridization is critical for establishing processing-structure-properties relationships for carbon-based materials, including amorphous carbon coatings. While several techniques have been employed to characterize the amount of sp 2 and sp 3 carbon in these materials, direct comparisons between analytical results are limited. Here, we compare near edge X-ray absorption fine structure (NEXAFS) spectra of a silicon- and oxygen-containing hydrogenated amorphous carbon (a-C:H:Si:O) coating acquired in synchrotron-based scanning transmission X-ray microscopy (STXM) mode with electron energy loss spectra (EELS) obtained from the same a-C:H:Si:O lamella. While the fractions of sp 2 carbon computed from STXM and EELS spectra are in close agreement, the comparison of NEXAFS spectra acquired in STXM mode with NEXAFS spectra collected in partial electron yield mode on a flat a-C:H:Si:O surface indicated that the destructive preparation of thin lamellae for STXM analyses induces variations in the structure of a-C:H:Si:O, namely the breakage of carbon-silicon and carbon-hydrogen bonds, a change in ordering of sp 2 -bonded carbon, and an increase in the sp 2 carbon fraction. These findings can help scientists in the careful interpretation of spectroscopic results obtained from the analysis of samples made of metastable materials after the destructive preparation of specimens for analytical purposes.

36 MATERIALS SCIENCE↗

Some observations of surface pressures and the near wake of a blunt trailing edge airfoil

Experiments with a truncated and untruncated airfoils of profiles NACA 640A10, were carried out in subsonic wind tunnels in a velocity range of 19m/s to 54m/s corresponding to Reynolds numbers of 200,000 to 468,000 based on the chord. Airfoil spanned the test section to achieve two dimensionality of the model. Velocity measurements, pressure measurements, and vortex shedding in the wake were measured using a hotwire and pressure transducers. The measured chordwise static pressure distribution on the smooth trailing edge airfoil along the midspan plane, agreed with the theoretical results calculated on the basis of the potential flow for that airfoil. Boundary layer profiles measured in the midspan plane, behind the maximum thickness of the airfoil show no separation of the flow. Spanwise distribution of the measured static pressure on the upper surface of the airfoil shows uniformity for both configurations with and without the boundary layer trip. This uniformity of pressure distribution and separation indicates that the flow on the airfoil was uniform and two dimensional in character.

Digumarthi, R. V.↗

Investigation at Mach Numbers of 0.20 to 3.50 of a Blended Diamond Wing and Body Combination of Sonic Design but with Low Wave-Drag Increase with Increasing Mach Number

A diamond wing and body combination was designed to have an area distribution which would result in near optimum zero-lift wave-drag coefficients at a Mach number of 1.00, and decreasing wave-drag coefficient with increasing Mach number up to near sonic leading-edge conditions for the wing. The airfoil section were computed by varying their shape along with the body radii (blending process) to match the selected area distribution and the given plan form. The exposed wing section had an average maximum thickness of about 3 percent of the local chords, and the maximum thickness of the center-line chord was 5.49 percent. The wing had an aspect ratio of 2 and a leading-edge sweep of 45 deg. Test data were obtained throughout the Mach number range from 0.20 to 3.50 at Reynolds numbers based on the mean aerodynamic chord of roughly 6,000,000 to 9,000,000. The zero-lift wave-drag coefficients of the diamond model satisfied the design objectives and were equal to the low values for the Mach number 1.00 equivalent body up to the limit of the transonic tests. From the peak drag coefficient near M = 1.00 there was a gradual decrease in wave-drag coefficient up to M = 1.20. Above sonic leading-edge conditions of the wing there was a rise in the wave-drag coefficient which was attributed in part to the body contouring as well as to the wing geometry. The diamond model had good lift characteristics, in spite of the prediction from low-aspect-ratio theory that the rear half of the diamond wing would carry little lift. The experimental lift-curve slope obtained at supersonic speeds were equal to or greater than the values predicted by linear theory. Similarly the other basic aerodynamic parameters, aerodynamic center position, and maximum lift-drag ratios were satisfactorily predicted at supersonic speeds.

Holdaway, George H.↗

Exploring the impact of ions on oxygen K-edge X-ray absorption spectroscopy in NaCl solution using the GW-Bethe-Salpeter-equation approach

X-ray absorption spectroscopy (XAS) is a powerful experimental tool to probe the local structure in materials with the core hole excitations. Here, the oxygen K-edge XAS spectra of the NaCl solution and pure water are computed by using a recently developed GW-Bethe-Salpeter equation approach, based on configurations modeled by path-integral molecular dynamics with the deep-learning technique. The neural network is trained on ab initio data obtained with strongly constrained and appropriately normed density functional theory. The observed changes in the XAS features of the NaCl solution, compared to those of pure water, are in good agreement between experimental and theoretical results. We provided detailed explanations for these spectral changes that occur when NaCl is solvated in pure water. Specifically, the presence of solvating ion pairs leads to localization of electron-hole excitons. As a result, our theoretical XAS results support the theory that the effects of the solvating ions on the H-bond network are mainly confined within the first hydration shell of ions, however beyond the shell the arrangement of water molecules remains to be comparable to that observed in pure water.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Solar Flare Ribbon Fronts. I. Constraining Flare Energy Deposition with IRIS Spectroscopy

Spectral lines formed at lower atmospheric layers show peculiar profiles at the "leading edge" of ribbons during solar flares. In particular, increased absorption of the BBSO/GST He I λ10830 line, as well as broad and centrally reversed profiles in the spectra of the Mg II and C II lines observed by the IRIS satellite, has been reported. In this work, we aim to understand the physical origin of such peculiar IRIS profiles, which seem to be common of many, if not all, flares. To achieve this, we quantify the spectral properties of the IRIS Mg II profiles at the ribbon leading edge during four large flares and perform a detailed comparison with a grid of radiative hydrodynamic models using the RADYN+FP code. We also studied their transition region (TR) counterparts, finding that these ribbon front locations are regions where TR emission and chromospheric evaporation are considerably weaker compared to other parts of the ribbons. Based on our comparison between the IRIS observations and modeling, our interpretation is that there are different heating regimes at play in the leading edge and the main bright part of the ribbons. More specifically, we suggest that bombardment of the chromosphere by more gradual and modest nonthermal electron energy fluxes can qualitatively explain the IRIS observations at the ribbon leading front, while stronger and more impulsive energy fluxes are required to drive chromospheric evaporation and more intense TR emission in the bright ribbon. Our results provide a possible physical origin for the peculiar behavior of the IRIS chromospheric lines in the ribbon leading edge and new constraints for the flare models.

Solar flares↗

A contrastive study of three graphite anodes in the piperidinium based electrolytes for lithium ion batteries

Graphical abstract: The fitting results of R{sub sei} and R{sub ct} of three graphite/Li cells. Besides three graphite/Li cells show the similar R{sub sei}, the NG198/Li cell demonstrates a higher R{sub ct} value in all test temperatures. Especially, the R{sub ct} at 333 K is even up to 355.8 Ω cm{sup 2}. Obviously, the narrow distribution of edge plane for NG198 caused this result, and then greatly restricts its cell capacity. By contrast, CMB with bigger specific surface area and more Li{sup +} insertion points shows lower resistance at room temperature, which should help to improve its capacity. - Highlights: • SEI film is closely related to graphite structures and formation temperature. • The graphite with bigger surface area and more Li{sup +} insertion points behaves better. • The graphite with narrow edge plane is uncompetitive for ionic liquid electrolyte. - Abstract: The electrochemical behaviors of natural graphite (NG198), artificial graphite (AG360) and carbon microbeads (CMB) in an ionic liquid based electrolyte are investigated by cyclic voltammetry (CV). The surface and structure of three graphite materials are characterized by scanning electron microscope (SEM) and X-ray diffraction (XRD) before and after cycling. It is found that solid electrolyte interface (SEI) is closely related to graphite structure. Benefiting from larger specific surface area and more dispersed Li{sup +} insertion points, CMB shows a better Li{sup +} insertion/de-insertion behavior than NG198 and AG360. Furthermore, electrochemical impedance spectra (EIS) prove that the SEI of different graphite electrodes has different intrinsic resistance and Li{sup +} penetrability. By comparison, CMB behaves better cell performances than AG360, while the narrow edge plane makes NG198 uncompetitive as a potential anode for the ionic liquids (ILs)-type Li-ion battery.

36 MATERIALS SCIENCE↗

Dry electrodes with a printed cellulose–graphene ink for low-profile strain sensors in electromyography

Dihydrolevoglucosenone, commonly known as Cyrene, is a renewable and fully biodegradable cellulose-waste derived, environmentally friendly solvent, presenting a non-toxic alternative to N-methyl-2-pyrrolidone (NMP). Currently, solution-based processing of graphene and other similar van der Waals solids favor toxic solvents such as NMP, limiting their use for biosensing. However, with the use of Cyrene, bio-compatible printable devices are possible, and studies have already demonstrated its use in temperature and other biosensing methods through screen-printing. Screen-printing unfortunately often requires masks that constrain the minimum acquirable feature size to be above hundreds of centimeters and wastes material, adding to process complexity and cost. Conversely, inkjet-printing is an attractive alternative for the maskless patterning of hierarchically assembled structures, with micron length scales attainable. Graphene's high conductivity positions it ideally for long-wear sensors such as dry electrodes or respiration monitors. Here, we demonstrate the potential of Cyrene-based graphene inks through few-layer inkjet printing on flexible substrates for the first time, to produce non-toxic conductors toward a strain-mediated mechanism for biosensing, used to detect bodily motion for wearable electronics. The challenges overcome in this study include engineering ink chemistry and printing parameters such that Cyrene's relatively high viscosity compared to typical inkjet solvents, still allows for droplet ejection in a conventional material printer, yielding well-resolved clean line-edges in contrast to other solvents that exhibit diffuse line-edges possibly from stray droplets and ink-splashing. Temperature-dependent transport measurements on the inkjet-printed Cyrene-based graphene films showed the conductivity to be largely temperature-invariant but at lower temperatures below 100 K, conductivity decreased, likely as a result of increased inter-membrane separation arising from thermal contraction. Additionally, temperature-dependent Raman spectroscopy showed the red-shift in the G-band, 2D-band and D-band peaks, as temperature increased. As a result, by validating flexion motion detection of the proximal interphalangeal joint demonstrated in this study, our work is the first of its kind to successfully additively manufacture inkjet-printed Cyrene-based graphene strain sensors on flexible substrates for bio-sensing and wearables.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

WE-EF-303-03: A New Aperture-Based Imaging System for Prompt-Gamma Range Verification of Proton Beam Therapy

Purpose: To develop and characterize a novel aperture-based imaging system for high-energy gamma-rays. This collimated system will provide 2-dimensional imaging capability for verification of proton beam range and Bragg peak dose via prompt-gamma detection. Methods: A multi-knife-edge slit collimator has been designed, constructed, and characterized via simulations and experimental measurements. The 20×20×7.5 cm{sup 3} tungsten collimator and accompanying LSO scintillation detector were simulated using the TOPAS Geant4 -based Monte Carlo package. Iterative reconstruction methods were combined with point response functions to characterize the imaging performance of the system. The response of the system has begun to be characterized experimentally as well, using 2.6 MeV gamma-rays from Th-228. Results: Both simulation and experimental results indicate that this collimated system provides 2-D imaging capability in the energy range of interest for prompt-gamma dose verification. In the current configuration, with collimator to source distance of 13 cm, image reconstruction of point sources resulted in spatial resolution (FWHM) of approximately 4 mm in both x-and y-directions in the imaging plane. The accuracy of positioning the point sources is less than 1 mm. Conclusion: This work has characterized, via simulation and measurements, a novel multi-knife-edge slit collimator in front of a more conventional position-sensitive LSO scintillator detector. The multi-slit pattern is designed to increase detection efficiency and provide spatial information in 2-dimensions -- an improvement over a single-slit collimator design. The thickness and density of the collimator will allow this detection system to perform well in an environment with high gamma flux, while ultimately providing peak determination accuracy on the order of 1 mm. This material is based upon work supported by the Department of Energy National Nuclear Security Administration under Award Number: DE-NA0000979 through the Nuclear Science and Security Consortium.

60 APPLIED LIFE SCIENCES↗

An exact and efficient first passage time algorithm for reaction–diffusion processes on a 2D-lattice

We present an exact and efficient algorithm for reaction–diffusion–nucleation processes on a 2D-lattice. The algorithm makes use of first passage time (FPT) to replace the computationally intensive simulation of diffusion hops in KMC by larger jumps when particles are far away from step-edges or other particles. Our approach computes exact probability distributions of jump times and target locations in a closed-form formula, based on the eigenvectors and eigenvalues of the corresponding 1D transition matrix, maintaining atomic-scale resolution of resulting shapes of deposit islands. We have applied our method to three different test cases of electrodeposition: pure diffusional aggregation for large ranges of diffusivity rates and for simulation domain sizes of up to 4096×4096 sites, the effect of diffusivity on island shapes and sizes in combination with a KMC edge diffusion, and the calculation of an exclusion zone in front of a step-edge, confirming statistical equivalence to standard KMC simulations. The algorithm achieves significant speedup compared to standard KMC for cases where particles diffuse over long distances before nucleating with other particles or being captured by larger islands.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Exploration of magnetic perturbation effects on advanced divertor configurations in NSTX-U

The control of divertor heat loads—both steady state and transient—remains a key challenge for the successful operation of ITER and FNSF. Magnetic perturbations provide a promising technique to control ELMs (Edge Localized Modes) (transients), but understanding their detailed impact is difficult due to their symmetry breaking nature. One approach for reducing steady state heat loads is so called “advanced divertors” which aim at optimizing the magnetic field configuration: the snowflake and the (super-)X-divertor. It is likely that both concepts—magnetic perturbations and advanced divertors—will have to work together, and we explore their interaction based on the NSTX-U setup. An overview of different divertor configurations under the impact of magnetic perturbations is presented, and the resulting impact on plasma edge transport is investigated with the EMC3-EIRENE code. Variations in size of the magnetic footprint of the perturbed separatrix are found, which are related to the level of flux expansion on the divertor target. Non-axisymmetric peaking of the heat flux related to the perturbed separatrix is found at the outer strike point, but only in locations where flux expansion is not too large.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Effects of wing leading-edge deflection on low-speed aerodynamic characteristics of a low-aspect-ratio highly swept arrow-wing configuration

Static force tests were conducted in the Langley V/STOL tunnel at a Reynolds number (based on the mean aerodynamic chord) of about 2.0 x 10 to the 6th power for an angle-of-attack range from about - 10 deg to 17 deg and angles of sideslip of 0 and + or - 5 deg. Limited flow visualization studies were also conducted in order to provide a qualitative assessment of leading-edge upwash characteristics.

Coe, P. L., Jr.↗

Uncovering the spin ordering in magic-angle graphene via edge state equilibration

Abstract The flat bands in magic-angle twisted bilayer graphene (MATBG) provide an especially rich arena to investigate interaction-driven ground states. While progress has been made in identifying the correlated insulators and their excitations at commensurate moiré filling factors, the spin-valley polarizations of the topological states that emerge at high magnetic field remain unknown. Here we introduce a technique based on twist-decoupled van der Waals layers that enables measurement of their electronic band structure and–by studying the backscattering between counter-propagating edge states–the determination of the relative spin polarization of their edge modes. We find that the symmetry-broken quantum Hall states that extend from the charge neutrality point in MATBG are spin unpolarized at even integer filling factors. The measurements also indicate that the correlated Chern insulator emerging from half filling of the flat valence band is spin unpolarized and suggest that its conduction band counterpart may be spin polarized.

36 MATERIALS SCIENCE↗

Development of Advanced High Lift Leading Edge Technology for Laminar Flow Wings

This paper describes the Advanced High Lift Leading Edge (AHLLE) task performed by Northrop Grumman Systems Corporation, Aerospace Systems (NGAS) for the NASA Subsonic Fixed Wing project in an effort to develop enabling high-lift technology for laminar flow wings. Based on a known laminar cruise airfoil that incorporated an NGAS-developed integrated slot design, this effort involved using Computational Fluid Dynamics (CFD) analysis and quality function deployment (QFD) analysis on several leading edge concepts, and subsequently down-selected to two blown leading-edge concepts for testing. A 7-foot-span AHLLE airfoil model was designed and fabricated at NGAS and then tested at the NGAS 7 x 10 Low Speed Wind Tunnel in Hawthorne, CA. The model configurations tested included: baseline, deflected trailing edge, blown deflected trailing edge, blown leading edge, morphed leading edge, and blown/morphed leading edge. A successful demonstration of high lift leading edge technology was achieved, and the target goals for improved lift were exceeded by 30% with a maximum section lift coefficient (Cl) of 5.2. Maximum incremental section lift coefficients ( Cl) of 3.5 and 3.1 were achieved for a blown drooped (morphed) leading edge concept and a non-drooped leading edge blowing concept, respectively. The most effective AHLLE design yielded an estimated 94% lift improvement over the conventional high lift Krueger flap configurations while providing laminar flow capability on the cruise configuration.

Bright, Michelle M.↗

Space-charge-based electrostatic plasma confinement involving relaxed plasma species

A numerical study is reported on the equilibrium properties of a surface-emitted or edge-confined non-drifting plasma. A self-consistent finite-differences evaluation of the electrostatic potential is carried out for a non-neutral plasma that follows a Boltzmann density distribution. The non-neutral plasma generates an electrostatic potential that has an extremum at the geometric center. Poisson's equation is solved for different ratios of the non-neutral plasma size to the edge Debye length. The profiles of the electrostatic potential and the plasma density are presented for different values of that ratio. A second plasma species is then introduced for two-plasma-species confinement studies, with one species confined by the space charge of the other, while each species follows a Boltzmann density distribution. An equilibrium in which a neutral region forms is found. An equilibrium is also found in which the two species have equal temperatures and charge states.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

ECRH microwave beam broadening in the edge turbulent plasma

The influence of turbulent plasma density fluctuations on angular and spatial beam width is treated analytically in the framework of WKB based eikonal method. Reasonable agreement of analytical and numerical treatment results is demonstrated within the domain of quasi-optical approximation validity. Significant broadening of microwave beams is predicted for future ECRH experiments at ITER.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

The Prediction of Noise Due to Jet Turbulence Convecting Past Flight Vehicle Trailing Edges

High intensity acoustic radiation occurs when turbulence convects past airframe trailing edges. A mathematical model is developed to predict this acoustic radiation. The model is dependent on the local flow and turbulent statistics above the trailing edge of the flight vehicle airframe. These quantities are dependent on the jet and flight vehicle Mach numbers and jet temperature. A term in the model approximates the turbulent statistics of single-stream heated jet flows and is developed based upon measurement. The developed model is valid for a wide range of jet Mach numbers, jet temperature ratios, and flight vehicle Mach numbers. The model predicts traditional trailing edge noise if the jet is not interacting with the airframe. Predictions of mean-flow quantities and the cross-spectrum of static pressure near the airframe trailing edge are compared with measurement. Finally, predictions of acoustic intensity are compared with measurement and the model is shown to accurately capture the phenomenon.

Miller, Steven A. E.↗

AN INDUCTIVE MAPPING WITH CONVOLUTIONAL REPRESENTATIONS FOR HUMAN SETTLEMENT DETECTION: PRELIMINARY RESULTS

Undoubtedly, deep convolutional learning methods continue to improve performance in image-level classification for computer vision and remote sensing applications. However, the spatio-temporal nature of remote sensing imagery offers other interesting challenges in multiscale image understanding. Emerging opportunities include seeking fine-grained and neighborhood mapping with overhead imagery. Limitations due to lack of relevant scale ground-truth often mandates that these challenges are pursued as disjoint. We test this premise and explore representation spaces from a single deep convolutional network and their visualization to argue for a unified feature extraction framework. The objective is to utilize and re-purpose trained feature extractors without the need for network retraining on three remote sensing tasks i.e. superpixel mapping, pixel-level segmentation and semantic based image visualization. By leveraging the same convolutional feature extractors and viewing them as visual information extractors that encode different image representation spaces, we demonstrate surprising potential on multiscale experiments that incorporate edge-level details up to semantic-level informationWe test this premise and explore representation spaces from a single deep convolutional network and their visualization to argue for a novel unified feature extraction framework. The objective is to utilize and re-purpose trained feature extractors without the need for network retraining on three remote sensing tasks i.e. superpixel mapping, pixel-level segmentation and semantic based image visualization. By leveraging the same convolutional feature extractors and viewing them as visual information extractors that encode different image representation spaces, we demonstrate a preliminary inductive transfer learning potential on multiscale experiments that incorporate edge-level details up to semantic-level informationWe test this premise and explore representation spaces from a single deep convolutional network and their visualization to argue for a novel unified feature extraction framework. The objective is to utilize and re-purpose trained feature extractors without the need for network retraining on three remote sensing tasks i.e. superpixel mapping, pixel-level segmentation and semantic based image visualization. By leveraging the same convolutional feature extractors and viewing them as visual information extractors that encode different image representation spaces, we demonstrate a preliminary inductive transfer learning potential on multiscale experiments that incorporate edge-level details up to semantic-level information.

Lunga, Dalton↗

Compact waveguide circular polarizer

A multi-port waveguide is provided having a rectangular waveguide that includes a Y-shape structure with first top arm having a first rectangular waveguide port, a second top arm with second rectangular waveguide port, and a base arm with a third rectangular waveguide port for supporting a TE.sub.10 mode and a TE.sub.20 mode, where the end of the third rectangular waveguide port includes rounded edges that are parallel to a z-axis of the waveguide, a circular waveguide having a circular waveguide port for supporting a left hand and a right hand circular polarization TE.sub.11 mode and is coupled to a base arm broad wall, and a matching feature disposed on the base arm broad wall opposite of the circular waveguide for terminating the third rectangular waveguide port, where the first rectangular waveguide port, the second rectangular waveguide port and the circular waveguide port are capable of supporting 4-modes of operation.

42 ENGINEERING↗