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At least 1,765 records · Page 98

Flight contaminant trace analyser. Phase 1: Chromatographic input system

The development of a chromatographic column capable of resolving compounds associated with spacecraft atmospheres is presented. Consideration is given to sampling techniques, column parameters and operation, and column interface with a mass spectrometer. A capillary column coated with a mixture of polyalkylene glycols is found to provide the best selectivity for resolving multicomponent mixtures found in spacecraft atmospheres. Temperature programming and isothermal operation of the column are evaluated and it is found that temperature programming has a shorter analysis time for a given carrier gas flow rate and overall superior resolution. It is observed that hydrogen provides a 15% savings in analysis time over helium. Following the optimization of column operational parameters, a mixed phase Ucon capillary is prepared for evaluation during the column test period in which the test sample is automatically analyzed. Analysis of the multicomponent test mixture is completed within 45 minutes provided temperature programming is used. All but two of the test compounds are well resolved.

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Studies on possible propagation of microbial contamination in planetary atmospheres

Maintained aerosols were studied to demonstrate the metabolism and propagation of microbes in clouds which could occur in the course of a probe of a planetary atmosphere. Bacteriophage was used as a tool to test whether the mechanisms for DNA production remain intact and functional within the airborne bacterial cell. In one test method, bacteria were mixed with coliphage in an atomizer to allow attachment before aerosolization; in another, two suspensions were atomized saperately into a common air stream prior to aerosolization. Results show that biochemical and physiological mechanisms to allow aerobic microbes to propagate in the airborne state do exist.

Dimmick, R. L.↗

Optical effect of the contamination of infrared windows by the outgassing of materials in outer space

The products and kinetics of outgassing from S13G paint were studied by using infrared absorption measurements of the material outgassed (using an evaporation cell and vacuum chamber). Two separate long-term experimental depositions from heated samples of the S13G paint were made. Before each experiment, the vacuum chamber and sample holder were carefully cleaned and outgassed to ensure that subsequent deposits on the colled-window were due only to the products evaporated from the sample. Results of experiments are listed and discussed.

Silberman, E.↗

Our contaminated atmosphere: The danger of climate change, phases 1 and 2

The effects of increased concentrations of atmospheric particulate matter on average surface temperature and on the components of the earth's radiation budget are studied. An atmospheric model which couples particulate loading to surface temperature and to changes in the earth's radiation budget was used. A determination of the feasibility of using satellites to monitor the effect of increased atmospheric particulate concentrations is performed. It was found that: (1) a change in man-made particulate loading of a factor of 4 is sufficient to initiate an ice age; (2) variations in the global and hemispheric weighted averages of surface temperature, reflected radiant fluz and emitted radiant flux are nonlinear functions of particulate loading; and (3) a black satellite sphere meets the requirement of night time measurement sensitivity, but not the required day time sensitivity. A nonblack, spherical radiometer whose external optical properties are sensitive to either the reflected radiant fluz or the emitted radiant flux meets the observational sensitivity requirements.

Cimorelli, A. J.↗

Transport of trace contaminants through porous media

Research accomplishments in the following areas are discussed: (1) the calibration of the gas chromatograph for acetaldehyde and ethanol; (2) the development of data reduction and analysis methods; (3) the generation and analysis of experimental data for the transport of 100 ppm acetaldehyde through a cylindrical bed packed with activated carbon granules; (4) the generation and analysis of experimental data for the transport of 100 ppm ethanol through a cylindrical bed packed with activated carbon granules; and (5) a comparison of the volume adsorption capacity of activated carbon for 100 ppm concentrations of acetaldehyde, ethanol, and acetone. Activities in progress and planned activities are reviewed.

Madey, R.↗

Shock tube study of ionization rates of NaCl-contaminated argon

Electron density, electron temperature, and concentration of excited sodium atoms are measured in the weakly ionized regime behind a shock wave in impure argon in a shock tube using microwave techniques and spectrally resolved radiometry. Evidence is presented to show that an apparent increase in the rate of ionization is due to electron detachment of negative chlorine ions produced from sodium chloride vapor contained as an impurity. To be consistent with this chemical model, rate coefficients are found in the temperature range between 5500 and 8600 K for the dissociation of NaCl into an ion pair, dissociation of NaCl into a neutral pair, and electron detachment of a negative chlorine ion. Electron temperature is lower than heavy-particle temperature by roughly 1000 K. The electron-argon impact-ionization rate coefficient is a weak function of electron temperature in contradiction to expectation.

Schneider, K.-P.↗

Influence of probe contamination on recombination of atomic hydrogen

Atomic hydrogen concentration profiles were measured through a screen-stabilized one-dimensional propane/oxygen front using a specially modified electron spin resonance (ESR) spectrometer. The ESR line occurring at 3075.5 G at 9261.2 MHz was monitored in the presence and absence of various halogenated hydrocarbons. A significant cumulative decrease in peak intensity occurred with addition of any halogenated compound. Further results suggest that the effect is due to inhibitor action on the transport tube walls followed by changes in atomic hydrogen interaction with the walls, and that hydrogen decay is nonlinear in the halogenated tube.

Collins, L. W.↗

Monitor for optical-window contamination

System uses window itself as principal element of well-known attenuated total reflection technique frequently used for spectroscopic analysis of thin films. Monitor includes notch in monitored window, which acts as beam splitter to reflect portion of light at less than critical angle and causes total internal reflection.

Harnett, L. N.↗

Contamination monitoring of fluids

Electro-optical device, consisting of laser and photodiodes, is adaptable to processing industries, pollution control, medical technology, and food technology.

Bonnell, R. D.↗

AESC multinodal free molecular contamination transport model

The film formation effects are examined of self-induced clouds and condensed films of volatile condensible materials (VCMs) which outgas from such sources as paints, coatings, adhesives, and other nonmetallic surfaces of satellites. A semi-empirical theory for the multiple scattering of free neutral molecules from dielectric surfaces which includes the effects of condensation and evaporation is defined and a mathematical model of the process is developed. The formation rate of thin surface films is considered to be the net accumulation of two simultaneous molecular processes; emission (evaporation) and adsorption (condensation). The net formation rate is considered to be dependent upon the temperature of the surface nodes, the mass and temperatures of the gas molecules, and the total pressure of the incident molecular flux. Apparatus and procedures for measuring these parameters are presented.

Zeiner, E. A.↗

Evaluation of high pressure water blast with rotating spray bar for removing paint and rubber deposits from airport runways, and review of runway slipperiness problems created by rubber contamination

A high pressure water blast with rotating spray bar treatment for removing paint and rubber deposits from airport runways is studied. The results of the evaluation suggest that the treatment is very effective in removing above surface paint and rubber deposits to the point that pavement skid resistance is restored to trafficked but uncontaminated runway surface skid resistance levels. Aircraft operating problems created by runway slipperiness are reviewed along with an assessment of the contributions that pavement surface treatments, surface weathering, traffic polishing, and rubber deposits make in creating or alleviating runway slipperiness. The results suggest that conventional surface treatments for both portland cement and asphaltic concrete runways are extremely vulnerable to rubber deposit accretions which can produce runway slipperiness conditions for aircraft operations as or more slippery than many snow and ice-covered runway conditions. Pavement grooving surface treatments are shown to be the least vulnerable to rubber deposits accretion and traffic polishing of the surface treatments examined.

Horne, W. B.↗

Electrets and their application in contamination studies

Data are presented on the surface charge of many different types of electrets formed by several different techniques. Results are presented on the investigation of electrets as pollution control devices for their possible use in the control of a spacecraft environment.

Pillai, P., K.c.↗

Integrated Real Time Contamination Monitor (IRTCM)

Preparations for a sampling of the ozone layer on a balloon flight and design modifications to the flight sampling system are reported. Special attention was given to technical problems with the evacuated sampling flask valve and its performance at a vacuum of 10 to the 7th power Torr.

Luttges, W. E.↗

Contamination, misuse and abuse of the global oceans leading to ecosystem damage and destruction, health consequences and international conflict

Unregulated uses of the oceans may threaten the global ecological balance, alter plant and animal life and significantly impact the global climatic systems. Recent plans to locate large scale structures on the oceans and to exploit the mineral riches of the seas pose even greater risk to the ecological system. Finally, increasing use of the oceans for large scale transport greatly enhances the probability of collision, polluting spills and international conflict.

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Contamination control in hybrid microelectronic modules

Thin and thick film test specimens were utilized to study the effects of silicone and epoxy hybrid microcircuit coatings on 0.025 mm diameter aluminum and gold ultrasonic bonds, and 0.051 diameter gold pulsed-thermocompression bonds. Chip-to-substrate and substrate-to-substrate geometries were included. Because sealed packages were utilized, a test pattern design was incorporated that allowed the determination of bond failures by making resistance measurements external to the package after the various environmental tests. All wire bonds were non-destructively pull tested prior to sealing. Tests included the PIN test, temperature cycling, and high temperature storage.

Himmel, R. P.↗

Hydrazine engine plume contamination mapping

Instrumentation for the measurement of plume exhaust specie deposition rates were developed and demonstrated. The instruments, two sets of quartz crystal microbalances, were designed for low temperature operation in the back flow and variable temperature operation in the core flow regions of an exhaust plume. These quartz crystal microbalances performed nominally, and measurements of exhaust specie deposition rates for 8400 number of pulses for a 0.1-lb monopropellant thruster are reported.

Chirivella, J. E.↗

Flight contaminant trace analyser. Phase 1: Chromatographic input system

The purpose of this investigation was to develop two chromatographic columns which would enable a mass spectral identification of 40 specified compounds. The columns are for use in a toxic gas analyzer, which incorporates an automated gas chromatograph-mass spectrometer. Different types of stationary phases were investigated. The columns used were of the open tubular capillary type and were made of nickel. Limitations of initial and final temperature of operation led to final development of a column which could resolve most of the compounds required. The few unresolved components are capable of resolution and identification by the mass spectrometer. The columns (182m Ni x 0.8m 0.D x 0.5mm I.D) coated with Witconal La 23, yielded in excess of 200,000 theoretical plates and completed the analysis in less than 90 minutes using a carrier gas flow rate of 4 cc/min hydrogen.

Zlatkis, A.↗