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At least 1,765 records · Page 98

Catalog of Environmental Metrics for Hydropower

Evaluating the sustainability of new U.S. hydropower development will necessitate an approach that is comprehensive, transparent and consistent. The ORNL Environmental Metrics for Hydropower (EMH) project team addressed this need by conducting a literature review to extract and analyze a swath of environmental metrics related to hydropower projects. The assessed documents included peer-reviewed journal articles, U.S. Federal Energy Regulatory Commission licensing documents, and two sets of certification documents from the Low Impact Hydropower Institute and the International Hydropower Association. Review of 117 documents led to creation of a database of > 3000 current environmental metrics related to hydropower projects in 285 locations worldwide. Information recorded for each environmental metric was used to map the comprehensiveness of environmental measurement types gathered across primary categories, dam life cycle stages, spatial scales and locations. A majority of metrics were related to water quantity and water quality, a large number of metrics were related to biota and biodiversity, and relatively few metrics were related to the categories of geomorphology, land cover, connectivity and fragmentation, and infrastructure and design. Forty-five subcategories of environmental metrics emerged from our analysis, thereby suggesting an envelope of measurements that are important for understanding the environmental effects of new hydropower projects. The categories and subcategories of environmental metrics represented in each type of literature varied, however. The EMH database summarized in this Catalog will be used to inform stakeholder selection of appropriate environmental metrics for evaluating progress toward collective goals for new U.S. hydropower development.

13 HYDRO ENERGY↗

Hearst Health Prize for Excellence in Population Health

Sandia National Laboratories (SNL) Employee Health Services (EHS) is committed to promoting healthy, vibrant lives and embracing health. Since 1986, EHS has built a comprehensive, evidence-based program designed to measure and assess health risk prevalence, provide targeted and customizable services to address health risks, incentivize healthy behaviors, improve productivity, enhance quality of life, and lower healthcare costs for participants via collaboration between on-site and community-based providers. This unique partnership provides a broad scope of services that may not be available to employees solely through their health benefit plan, and allows a supportive, convenient approach that has proven enhanced health outcomes. EHS impacts over 12,000 SNL employees in Albuquerque, New Mexico. Corporate wellness is as important as ever as health issues and healthcare costs continue to rise. We use the 8-15-80 model as the foundation for our health program strategy: prevent or improve 8 modifiable behaviors and risks that contribute to 15 chronic health conditions that account for 80% of healthcare spending on chronic illnesses worldwide. We utilize patient-centered, cost-effective, community-connected care by providing free onsite services including the NCQA-recognized/AAAHC-accredited medical clinic, health management, preventive health, behavioral health, physical therapy, medical case management, acute care, emergency medical services, and more. These programs and services are an employer-paid benefit open to all SNL employees. The organization combines best practices, accredited programs, and top health care providers to bring employees the most comprehensive approach to health care.

99 GENERAL AND MISCELLANEOUS↗

Closure Plan for the Idaho National Laboratory Site's Materials and Fuels Complex Industrial Waste Ditch

The Materials and Fuels Complex industrial waste system currently consists of the Industrial Waste Pond and Industrial Waste Ditch, associated piping, lift station, and flow meter. The Industrial Waste Pond and Industrial Waste Ditch, are land application sites permitted under Idaho Department of Environmental Quality Reuse Permit I-160-02, Modification 1. The Reuse Permit allows for 17 million gallons of industrial wastewater to be discharged to the land application sites. For Reuse Permit year 2017, approximately 7.569 million gallons were discharged to the land application sites, of which 1.649 million gallons were discharged to the Industrial Waste Ditch. A project (MFC West Campus Utility Corridor project) is proposed to begin in the summer of 2018. The project will install a new utility corridor along the west and north sides of the Materials and Fuels Complex. As part of the design, it is proposed to reroute the wastewater currently discharged to the Industrial Waste Ditch into an underground pipe that would connect into the existing Industrial Waste Pipeline. The Industrial Waste Ditch pipe would enter the existing Industrial Waste Pipeline upstream of the existing flow meter and sampling location. This would allow for the combined wastewater streams to be monitored for flow and sampled for parameters required by the Reuse Permit. In accordance with the Reuse Permit, this closure plan is being submitted to the Idaho Department of Environmental Quality for review and approval. Once the closure plan is approved, the Reuse Permit will be modified to remove the Industrial Waste Ditch from the permit. The closure plan includes: • Brief background of the Materials and Fuels Complex. • Reuse Permit history. • Site characteristics. • Description of the Industrial Wastewater System. • History of discharges to the Industrial Waste Ditch. • Summary of the Comprehensive Environmental Response, Compensation, and Liability Act characterization, evaluation, and remediation of the Industrial Waste Ditch. • Contaminant concentrations in the effluent discharged to the Industrial Waste Ditch. • Contaminant concentrations in cross gradient, downgradient, and background monitoring wells. Based on the Comprehensive Environmental Response, Compensation, and Liability Act characterization and remediation of the Industrial Waste Ditch, low volumes and contaminant concentrations in the effluent subsequently discharged to the Industrial Waste Ditch, and contaminant concentrations at or near background levels in the monitoring wells, it is recommended that the Industrial Waste Ditch should be closed without further characterization.

99 GENERAL AND MISCELLANEOUS↗

Aluminum Clad Spent Nuclear Fuel Task 3: Sealed and Vented Systems Episodic Breathing and Gas Generation Modeling Plan

This document presents the test plan for Task 3 of the Aluminum Clad Spent Nuclear Fuel Long Term Dry Storage Technical Issues Action Plan, which covers modeling and predictions of the generations of corrosive gases within both sealed and vented, subject to episodic breathing, storage systems. This includes aluminum clad spent nuclear fuel (ASNF) that is currently or may in the future be held in dry storage for an extended period. The overall objectives of the Task 3 modeling plan are to: 1. Comprehensively model the combined effects of episodic breathing in vented storage systems/canisters using INL INTEC CPP-603 facility as an example. Both bulk gas phase radiolysis reactions and aluminum cladding surface gas generation reactions will be included into a 3-dimensional computational fluid dynamics (CFD) model to model and predict long-term evolutions of the temperature and concentrations of corrosive gases within unsealed canisters subjected to episodic breathing. 2. Comprehensively model sealed and inert canister storage system using DOE standard canister as an example. 3. Closely integrate with Task 1 and Task 2 for identification of main gas-generation reactions and kinetics and provide simulation results back to Task 1 and 2 to further refine experimental designs. This test plan lays out the technical activities that will be performed to achieve the test objectives described above. Simulations will be performed using the Idaho National Laboratory super computer Falcon.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Automation of Data Collection Methods for Online Monitoring of Nuclear Power Plants

Maintenance activities in the United States nuclear power industry are mainly centered on preventive and corrective maintenance. Predictive maintenance, which is a variable time basis maintenance strategy that is dependent on the condition of the equipment, is less utilized but potentially more effective. In the current maintenance practices, the nuclear power plants rely on manual processes to supply information to a human decision making process. The plants have several processes that generate information that is not typically used beyond the intended target for collecting that information. This information is a source of data that is manually collected by labor intensive tasks. The data is therefore expensive to collect, yet limited in use. The industry has realized the opportunity present in reducing the labor intensive tasks by automating them and increasing the uses of the data collected by either developing advanced predictive maintenance methods using data-driven decision making that could span from trending to machine learning and artificial intelligence. This shift in maintenance strategy may result in high cost saving impact. In addition to reducing labor requirements and frequency of maintenance activities, this shift in strategy will reduce the materials portion of the operations and maintenance cost as well. The aim of this specific effort is to focus on the automation of data collection process. It is part of a series of planned efforts to target multiple elements of migrating the current preventive maintenance approach in nuclear power plants to a data-driven approach. These elements include data collection, management, analysis, visualization, in addition to value analysis and change enabling. The other five elements of migration were not considered because they are planned to be explicitly studied in multiple parallel efforts. Challenges including regulations requirements or limitations are planned in a future effort that focuses on change enabling. The risk and benefit/cost of the approach shift is planned in another effort targeted towards value. The storage, communication, computational power, data architecture, and protection are part of the information infrastructure and are planned in dedicated data management effort. The best means to present the data for assisted human decision making is planned in a data visualization effort. The data interpretation and patterns recognition for machine decision making is planned through multiple efforts in data analytics over the following years. This work identified seventeen data sources collection methods in nuclear power plants that could be automated for an integrated data platform that enables comprehensive and informed decision making. For each of the identified seventeen data sources, the base, modern, and state of the art states were described. The current state of data collection used by most utilities was identified as the "base state". The current achievable state was identified as the "modern state", a state that has either been achieved by at least some US utilities or in other industries. The future state that requires research and development to reach was identified as the "state of the art" state. The described states used an out-of-the-box thinking approach. This effort found that there is a hug potential for task automation and data fidelity improvements by evolving the current industry data collection methods. The majority of the processes analyzed were found to be manual and labor intensive and fell in the base state. As a result, the modern state often targeted reducing the manual logging efforts by using electronic and semi-intelligent means or complementing the work with sensors and mobile or fixed technologies that can reduce the demand of labor activities. The state of the art state involved applications advanced methods of data correlation, data mining, and machine learning along with increasing the spatial distribution and fidelity of data, coupling multiple data sources, and enabling the use of sophisticated mobile devices and machine comprehension methods.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Assessing the Wind Energy Potential in Bangladesh: Enabling Wind Energy Development with Data Products

USAID Bangladesh and the U.S. Department of Energy’s National Renewable Energy Laboratory partnered with the Government of Bangladesh to develop a national wind resource assessment. The assessment used sophisticated resource modeling that was validated by a ground measurement campaign. Results from the project included a long-term, correlated wind data set; validated high-resolution wind resource maps; and publicly available data accessible through the RE Data Explorer (https://www.re-explorer.org/). The Renewable Energy (RE) Data Explorer allows users to access and download the Bangladesh wind resource assessment data and related geographic information system (GIS) data sets and perform customized technical potential analyses. Figure ES-1 is an example wind resource map for Bangladesh that can be created with the RE Data Explorer. This project improved upon existing global data sets by using best-in-class modeling techniques and analysis. Global models are good first steps in predicting wind resources in various parts of the world, but they do not generate the accuracy needed to reduce project risk and stimulate renewable investment. This project improved the quality of modeled wind resource data for Bangladesh. In addition to the modeling effort, the project team used a multi-year, local data-collection campaign to validate the model and further improve the accuracy of the data sets. The measurement campaign consisted of nine meteorological sites representing all geographical regions of the country. Seven meteorological towers and one remote-sensing, sonic detection and ranging unit (deployed at two sites) collected the data. Site-selection criteria focused on geographic diversity and proximity to existing transmission lines. Figure ES-1 shows measurement locations. The measurement campaign spanned June 2014 through December 2017. The results of the Bangladesh wind resource assessment will help Bangladesh overcome significant energy challenges. Its energy sector suffers from power shortages, increasing demand, decreasing domestic natural gas reserves, and inadequate transmission infrastructure. As part of a comprehensive plan to overcome these challenges, Bangladesh has committed that 10% of the total generation capacity will be renewable energy by 2021 (Power Division 2016). High-quality renewable energy resource data and other GIS data, such as those developed in this assessment, are important if Bangladesh wishes to reach its 10% renewable energy capacity target. These data support informed decision making, ranging from policy and investment decisions to reliable power sector planning. Specifically, the Bangladesh wind resource assessment will help reduce technical risk and encourage private-sector interest in the nascent wind market in Bangladesh. In addition, the Government of Bangladesh may use the results of the wind resource assessment to develop well-designed policies that could encourage investment in wind energy. This report provides a comprehensive description of the Bangladesh wind resource assessment, including details on the modeling approach and methods, instrumentation, data quality-control techniques, and resulting data sets.

17 WIND ENERGY↗

Beamline CSX (23-ID, EPU 49): 25 mA Commissioning Radiation Survey Report

A comprehensive radiological survey of the Beamline CSX (23-ID-1) was conducted on March 27, 2015 in accordance with the Beamline CSX (23-ID, EPU 49) Radiation Survey Plan [1]. The purpose of the survey is to verify the shielding integrity of the 23-ID beamline First Optics Enclosure (FOE) and downstream beam pipe. At the time of this comprehensive survey, 23-ID-2 beamline was still undergoing technical commissioning and therefore Section II “23 ID-2 FOE, exclusion zone and downstream pipe” could not be completed. During the surveys the stored beam current varied between 21.43 mA and 23.51 mA, the 23-ID straight section vacuum was around 0.44 ntorr, and front-end slits were open near their hard stop limits.

36 MATERIALS SCIENCE↗

Comparative Assessment of Experimental Testing of Instrument with an Embedded Digital Device Using Model-Based and Conventional Methods

The use of digital equipment has not been widespread in U.S. nuclear facilities. A major contributing factor to this situation arises from regulatory concerns about common cause failures (CCFs) stemming from the use of identical software in redundant systems, questions as to how to quantify the reliability of software-based products, validity of tools that are used for software verification and validation (V&V), and the effectiveness of software QA procedures. Compounding the concerns are sporadic incidents of digital equipment malfunctions in nuclear power plants, including lockups resulting from software memory leaks, feedwater control malfunctions due to excessive traffic on Ethernet networks, software logic errors, and other problems leading to plant trips. Additionally, the limited amount of demonstrated research and a lack of industry consensus on quantitative software reliability methodologies has hindered the widespread adoption of digital I&C in the nuclear industry. In a recent Regulatory Issue Summary (RIS), the U.S. Nuclear Regulatory Commission (NRC) identified concerns about the impact of greater use of instrumentation and control (I&C) equipment with an embedded digital device (EDD) [1]. Specifically, the NRC staff states that increased use of such devices “may increase a facility’s vulnerability to a CCF” (i.e., common-cause failure). The prevailing NRC guidance regarding software CCF (SCCF) identifies two design attributes that are acceptable for eliminating CCF concerns: (1) diversity or (2) testability (specifically, 100% testability). Either solution can result in high costs and remaining licensing uncertainty (i.e., how much diversity is enough? how to ensure test coverage of every possible sequence of device states?). Consequently, many utilities and reactor designers have limited or avoided more extensive use of digital technology to minimize licensing, scheduling, and financial risk. Without development of cost effective qualification methods to satisfy regulatory requirements and address the potential for CCF vulnerability associated with EDDs, the nuclear power industry may not be able to realize the benefits of digital technology achieved by other industries. In order to address these challenges, the U.S. Department of Energy (DOE) is sponsoring this research to assess the prospect of CCF in digital I&C equipment. The purpose of the current research is to develop an effective approach employing science-based methods to resolve concerns about CCF vulnerability that serve to inhibit deployment of advanced instrumentation (e.g., sensors, actuators, microcontrollers) with EDDs in nuclear power applications. The research objectives address the challenge of establishing high levels of safety and reliability assurance needed for the qualification of EDDs (e.g., microprocessors, programmable logic devices) that are subject to software design faults, complex failure modes, and CCF vulnerability. Specific objectives are: (1) assess the regulatory context for treatment of CCF vulnerability a graded approach to their qualification, (3) develop and extend model-based testing methods to enable effective demonstration of whether devices are subject to CCF, which may arise from vulnerabilities introduced at any stage of the design lifecycle, (4) establish a cost-effective testing framework that incorporates automation and test scenario prioritization, and (5) demonstrate the qualification approach through selection and testing of candidate digital device(s). This report documents an assessment of the results from experimental testing of a representative instrument with an embedded digital device. The experiment serves as a proof-of-concept demonstration of a model-based testing (MBT) framework. The objective of MBT is to ensure that an EDD undergoes suitably comprehensive testing to establish that it is not subject to SCCF. The approach by which MBT accomplishes this objective is through development and application of an effective test suite that provides the appropriate coverage to detect the full range of postulated faults that may arise at the requirements, design, and code (implementation) level of the EDD software. The findings of the experiment involve the application of the MBT framework by Ohio State University (OSU) through testing of the selected demonstration instrument (i.e., the prototype smart pressure sensor developed by Virginia Commonwealth University, VCU). In addition, the experiment findings also involve application of a more conventional black-box testing approach that serves as a baseline against which the MBT methodology can be compared. The primary outcome documented in this report is the comparative analysis of the capabilities demonstrated for each method. The results of the analysis demonstrate clear benefits that arise from the MBT methodology. The comparison indicates greater effectiveness from the more comprehensive evidence available through MBT and enhanced efficiency achieved through automation within the MBT framework. The structure of the report addresses the approach and application of each test method as well as the comparative analysis of the experimental results. Chapter 2 gives a summary overview of the demonstration approach. Chapter 3 covers the baseline testing and Chapter 4 documents the model-based testing. Chapter 5 describes the findings of the comparative analysis and presents the conclusions that can be drawn about the effectiveness and efficiency of the MBT methodology.

47 OTHER INSTRUMENTATION↗

Developing a Macro-scale SiC-cladding Behavior Model Based on Localized Mechanical and Thermal Property Evaluation on Pre- and Post-Irradiation SiC-SiC Composites (Final Report)

Silicon carbide is being investigated for accident tolerant fuel cladding applications due to its good neutronic performance, high temperature strength, exceptional stability under irradiation, and reduced oxidation compared to Zircaloy under accident conditions. The development and investigation of these materials is particularly important in the light of the Fukushima event and subsequent emphasis in DOE on accident tolerant fuel (ATF) concepts. In this work, we propose to develop and improve upon existing small-scale mechanical and thermal characterization methods, including micro-cantilever bend tests and fiber push-out tests, and time-domain thermo-reflectance measurements. These techniques will be applied to evaluate micro-scale properties of SiC-SiC composite constituents (matrix, fibers, interphase). The results will be coupled with meso-scale fiber and void structural information and be used as input to develop a comprehensive, finite element-based model based on constituent properties. The goal of this multi-scale model is to be used to predict anisotropic mechanical and thermal cladding behaviors. The model will be benchmarked against measurements of bulk properties and validated for radiation-damaged materials by utilizing irradiated SiC-SiC composites available from General Atomics. The characterization approach developed under this program will have particular application in the property prediction of reactor irradiated materials, as only small volumes need to be tested, minimizing associated hazards and costs. The micro-scale test methods developed here will be used along with meso-scale structural data to inform a finite element model of the full SiC-based cladding system. This model will capture fabrication and irradiation effects and importantly include for the first-time separate material data for each system component. The incorporation of these micro-scale effects will lead to a more accurate model of SiC-SiC composite behavior, enabling further advancements in the development and design of SiC-based materials for improved fuel cladding performance. The aim of this work is to develop advanced localized material characterization techniques to directly measure mechanical and thermal properties of the individual constituents of SiC-based claddings at the relevant micro-scale. SiC-SiC composites will be evaluated before and after irradiation and these results will be coupled with macro-scale properties and microstructural information in order to provide the input parameters for a comprehensive finite element model, which will be developed in this program.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Computational and Experimental Benchmarking for Transient Fuel Testing

In 2018 the Transient Reactor Test (TREAT) Facility was restarted. This now-operational facility brings back world-class transient fuel testing capabilities to the U.S. Among a number of parallel efforts prior to the TREAT Facility’s restart a Department of Energy (DoE) Integrated Research Project (IRP) was funded for the purpose of benchmarking the TREAT with several goals in mind: To produce a comprehensive evaluation of existing TREAT Facility neutronics data using the next generation reactor core neutronics codes in accordance with established guidelines per the International Handbook of Evaluated Reactor Physics Benchmark Experiments (IRPhEP). To perform a benchmark using ready-use computational fluid dynamics tools against that of a historically collected sodium loop experiment collected in the TREAT. To design, develop and test a new experimental thermal hydraulic system of a representative TREAT Facility water flow loop. And benchmark the data collected against that produced via RELAP5-3D and TRACE. To develop a comprehensive instrumentation plan for the TREAT Facility by benchmarking performing of advanced in-pile instruments in the Massachusetts Institute of Technology Research Reactor (MITR) and the TREAT. The integrated team brought together collaborating members from three universities including Oregon State University (OSU), the University of Michigan (UM), and Massachusetts Institute of Technology (MIT); three national laboratories, Idaho National Laboratory, Argonne National Laboratory (ANL), and Oak Ridge National Laboratory (ORNL); and two industry partners, TerraPower (TP) and Harris Thermal Transfer Products (HTTP). A brief summary of accomplishments resulting from this IRP includes two filed patents, more than 40 conference papers, two published benchmark reports through IRPhEP, a new representative thermal hydraulic test facility alike the in-pile PWR water flow loop for TREAT and the first advanced instruments tested within the TREAT core upon its restart. The papers presented herein were developed and provide a summary of the significant technical accomplishments which align with the four project’s objectives. The collaborators has significant support from countless parties including the operational and technical staff at TREAT to ensure that their outcomes most impactfully aligned with program needs. Lastly the collaborators would like to acknowledge the fiscal support of the DoE’s Office of Nuclear Energy under work package identification number NU-15-OR-OSU- 0701-01. This report contains selected papers from the Computational and Experimental Benchmarking for Transient Fuel Testing Integrated Research Project.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Securing Vehicle Charging Infrastructure APR

Cybersecurity is essential for interoperable power systems and transportation infrastructure in the US. As the US transitions to transportation electrification, cyber attacks on vehicle charging could impact nearly all US critical infrastructure. This is a growing area of concern as more charging stations communicate to a range of entities (grid operators, vehicles, OEM vendors, etc.), as shown in Figure I.1.1.1. The research challenges are extensive and complicated because there are many end users, stakeholders, and software and equipment vendors. Poorly implemented electric vehicle supply equipment (EVSE) cybersecurity is a major risk to electric vehicle (EV) adoption because the political, social, and financial impact of cyberattacks—or public perception of such—ripples across the industry and has lasting and devastating effects. Unfortunately, there is no comprehensive EVSE cybersecurity approach and limited best practices have been adopted by the EV/EVSE industry. For this reason, there is an incomplete industry understanding of the attack surface, interconnected assets, and unsecured interfaces. Thus, comprehensive cybersecurity recommendations founded on sound research are necessary to secure EV charging infrastructure. This project is providing the automotive industry with a strong technical basis for securing this infrastructure by developing threat models, prioritizing technology gaps, and developing effective countermeasures. Specifically, the team is creating a cybersecurity threat model and performing a technical risk assessment of EVSE assets, so that automotive, charging, and utility stakeholders can better protect customers, vehicles, and power systems in the face of new cyber threats.

33 ADVANCED PROPULSION SYSTEMS↗

International Arctic Systems for Observing the Atmosphere (IASOA) Metadata Harvest for Oliktok Point Observations Field Campaign Report

The International Arctic Systems for Observing the Atmosphere (IASOA) was initiated as an International Polar Year (IPY) project (Uttal et al. 2015, on-line release) to address key atmospheric science questions through coordinating the considerable atmospheric observing assets at 10 pan-arctic observatories (http://iasoa.org). The mission of IASOA is to advance cross-site research objectives from independent arctic atmospheric observatories through: (1) strategically developing comprehensive observational capacity; (2) facilitating data access and usability through a single gateway; and (3) mobilizing contributions to synergistic science and socially relevant services derived from IASOA assets and expertise. In April 2015 the IASOA science steering committee invited the U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) user facility’s Oliktok Point observatory to contribute to consortium activities. The IASOA steering committee identified enhanced, cross-site data sharing through an IASOA-specific data access portal as a focus for ongoing consortium activities. The design intent of the portal has been to display the data inventories of all IASOA observatories in a succinct summary (Data-at-a-Glance) and provide the most proximal access links available to those data sets. The IASOA data access portal is not intended to replace the functions of existing archives. This succinct summary of data availability supports cross-site and interdisciplinary synthesis science activities. Efforts to enhance the legacy IASOA data access portal functionality have focused on two areas: developing a comprehensive and coherent data vocabulary for IASOA data and implementing an interoperable metadata standard for all IASOA data. The technical goal of this proposal is to work with ARM data managers to operationalize the export of metadata for observational data sets for Oliktok Point from the ARM metadata database. IASOA harvests data in the commonly used International Organization for Standardization (ISO) format. ARM has successfully generated metatdata matching this format in the past to provide metadata from its North Slope of Alaska (NSA) Barrow observatory.

54 ENVIRONMENTAL SCIENCES↗

Subsequent R + O 2 Chemistry of Intermediates Formed in Low-Temperature R + O 2 Reactions: Potential Importance in Modeling Autoignition Behavior

Comprehensive chemical kinetics models used in the simulation of hydrocarbon and biofuel oxidation rely on accurate prescription of the underlying reaction mechanisms and rate parameters of associated elementary reactions. For practical transportation fuels, such models contain thousands of elementary reactions, which collectively define chain-initiation, -propagation, -branching, and -inhibition pathways. In the low-temperature regime, below approximately 1000 K where R + O 2 reactions dominate, primary oxidation intermediates including cyclic ethers, carbonyls, and conjugate alkenes are formed in abundance via unimolecular decomposition of either chemically activated or thermalized radicals, specifically organic peroxy (ROO) or hydroperoxyalkyl species (QOOH). Experimental results from multiplexed photoionization mass spectrometry (MPIMS) experiments are detailed herein for several intermediates, derived initially from R + O 2 reactions of hydrocarbons and biofuels, and show that intermediate species formed in the initial steps of oxidation undergo similar reactions to those of the parent molecule, including through QOOH-mediated pathways. Products from QOOH decomposition via chain-inhibition and chain-propagation pathways, namely conjugate alkenes, carbonyls, and cyclic ethers, are detected directly. Despite such rich chemistry involving QOOH radicals, most comprehensive chemical kinetics models neglect the complete description of primary oxidation intermediates, and rather consider a restricted number of reaction pathways. It is suggested that exclusion of the details of the oxidation of these intermediate products may affect the interpretation of combustion simulations using such models.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Dragonstone Strategy – State of Cybersecurity in the Oil & Natural Gas Sector

The oil & natural gas (ONG) system touches every corner of the nation and increased communications & control capabilities have not only allowed for greater efficiency of system operation, but have also created a massive target for adversaries to launch cyber-attacks. Like any other heavy industrial process, the ONG system relies on a complex system of information technology (IT) and operational technology (OT) devices. The current state of cyber-preparedness across the ONG industry varies from organization to organization. Among the most common challenges that ONG companies face are remote locations, longlived field assets, and lacking capabilities to find and track malware on their systems. ONG companies tend to be concerned with lack of cyber-awareness from employees, risk stemming from remote access for operations & maintenance, and software vulnerabilities within third-party equipment. Various industry and government organizations are performing research and development activities to address some of these challenges, but in many cases industry stakeholders are not aware of solutions that already exist. It is clear that a need exists for a coherent, comprehensive, multi-layered strategy for assuring the security and resilience of the nation's pipeline infrastructure against cyber threats. For a variety of reasons, the general consensus from stakeholders interviewed by LLNL is that the state of cyber-security within the electric grid is currently outpacing its ONG cousin. Existing strategies for the resilience and cyber-security of the electric grid can and should be leveraged to provide immediate benefits to the ONG system. In LLNL’s view, there are two key factors currently limiting the development of necessary cyber-practices within the ONG industry: The sheer number of differing regulatory bodies and trade groups offering both standards and best-practice recommendations for ONG cyber-security makes it difficult to create a comprehensive, directed, and coherent strategy that is applicable to all players within the ONG industry. The ONG industry is unaware of potentially useful technologies that have been developed for ensuring cyber-security of other infrastructure systems, such as the electric grid. Leveraging these technologies—and the science and engineering behind them—can provide some low-hanging fruit that can greatly improve cyber-security in the ONG industry without significant investments in terms of time and money. In the months following this report, LLNL will continue to perform outreach to key oil & gas industry stakeholders in a continual effort to identify the most pressing cyber-resilience issues in the industry. This outreach will be supplemented with LLNL’s threat intelligence capabilities to begin painting a clearer picture of the overall threat landscape faced by this sector. This assessment will be threat-informed and while the strategy itself will not be classified we will leverage intelligence analysis and adversary capabilities to identify gaps in current cybersecurity practices for oil & gas pipeline systems. Recommended efforts will be compiled into a cyber-resilience roadmap for the oil & gas pipeline sector, in which LLNL will highlight priority activities to immediately improve the state of cyber-resilience in the industry.

02 PETROLEUM↗

Heat Integration Optimization and Dynamic Modeling Investigation for Advancing the Coal-Direct Chemical Looping Process

The purpose of the project is to address the optimization and startup operation of a modular coal direct chemical looping (CDCL) combustion system integrated with a steam cycle for power generation to reduce the risks involved in further scale-up of the technology. The modular reactor design of the CDCL process provides flexibility in the fabrication of the reactor and in its operating capacity (i.e. turndown ratio) at the cost of a more complex heat exchange network (HEN) design and integration. To address the technology gaps and advance the efficiency and economic feasibility of the CDCL technology, the project will perform a detailed and comprehensive analysis of the integration of a modular CDCL reactor system and a steam cycle system under both static and transient conditions via HEN process performance simulations and system dynamic modeling, respectively. The scope of work consists of 1) Experimental and computational studies of the CDCL combustor reactor 2) Comprehensive static (i.e. steady-state) system HEN design analysis in CDCL 550 MWe commercial unit for power generation and 3) Dynamic modeling of site specific design of 10MWe CDCL large pilot plant. The project team has successfully developed and validated a kinetic model for the oxidation of oxygen carriers in the combustor using the unreacted shrinking core model (UCSM). The model is capable of capturing the oxidation kinetics of fully or partially reduced oxygen carrier particles. A computational fluid dynamics (CFD) model is developed to simulate the hydrodynamics, heat transfer, and chemical reaction occurring in the CDCL combustor. The model is developed in MFIX and ANSYS Fluent. Key aspects of CDCL combustor operation, including heat transfer, oxygen carrier oxidation, and the transport of oxygen carrier particles, are simulated using this CFD model. The HEN for a commercial scale 550 MWe CDCL power plant is simulated and optimized using ASPEN Plus. Practical design considerations are incorporated based on industrial experiences. The performance and cost for the commercial CDCL plant is updated based on these analyses. A dynamic model for the 10 MWe CDCL pilot plant is developed in ProTRAX simulation software. The model is based on the pilot plant design developed in project DE-FE0027654 “10 MWe CDCL Large Pilot Plang – Pre-FEED Study” and the steam cycle data obtained from Dover Light & Power plant. The transient behaviors during pilot plant load variation are simulated using the dynamic model.

01 COAL, LIGNITE, AND PEAT↗

2020 Review Panel Workshop on Energy Intensity Indicators: Summary Findings and Meeting Notes

On January 28-29, 2020, the U.S. Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy (EERE), in coordination with Pacific Northwest National Laboratory (PNNL), sponsored an expert workshop focused on energy intensity indicators. The intent of the workshop was to support a comprehensive review of the EERE Energy Intensity Indicators (EII), a national system of indicators used to track changes in the energy intensity of economic sectors. One goal of the workshop was to gather input from a panel of experts who have experience and knowledge related to the EII methodological approach and key data sources used to calculate indicators for each of the end-use sectors of the economy—transportation, residential, commercial, industrial, and electricity. The current EERE EII methodology is documented in a 2017 PNNL report, A Comprehensive System of Energy Intensity Indicators for the U.S.: Methods, Data and Key Trends, which is available online. The workshop also included a presentation by Dr. Beng Ang, who discussed the Log Mean Divisia index (LMDI) approach to decomposition analysis, which was followed by a discussion concerning the methodological approaches that could be applied to future EII efforts.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Development of an In-Situ Method for Cable Condition Monitoring in Nuclear Power Plants (SBIR Phase IIB Final Report)

This is the final report of a Small Business Innovation Research (SBIR) project that Analysis and Measurement Services Corporation (AMS) has conducted for the U.S. Department of Energy (DOE) over a seven-and-a-half year period (February 2013 through April 2020 with the awards of Phase I, Phase II and Phase IIB projects). The goal of the project was to design, develop, validate, and demonstrate a technique for in-situ testing of cable insulation polymers that will identify, locate, and provide the degree of aging for cables commonly used in nuclear power plants. During the Phase I project, AMS established that the frequency domain reflectometry (FDR) technique can successfully identify and measure cable insulation degradation that can be trended with aging. In Phase II, AMS performed extensive cable aging studies to correlate FDR measurements with other laboratory condition monitoring techniques and developed aging condition categories to quantify the severity of insulation degradation. In Phase IIB, the project expanded the research to include a wider variety of cable polymers that are used in the commercial nuclear power industry. This work also involved developing acceptance criteria to objectively assess age-related cable degradation while sharing the results of this research with industry, academia, and national laboratories to advance the state of the art in cable aging management technologies. The products developed under this research project provide the nuclear industry with an effective condition monitoring tool to support safe and long-term plant operation. Throughout the project, collaborations and support were received from a variety of industry organizations and individuals including DOE National Laboratories as well as nuclear plant utilities and several other industry experts and cable manufacturers. Contributions from these organizations included the donation of new cables, naturally aged cables, and research collaboration. The validation and commercialization of the products of this project were achieved through opportunities to test and demonstrate the technologies’ capabilities on-site at nuclear power generation and research facilities as well as in the laboratory alongside industry peers and cable testing service companies. The research resulted in a technology that can be used to identify, locate, and quantify age-related degradation in several types of cable polymers. This included developing software and hardware as well as the methodology for using the FDR technique to assess age-related degradation of installed cables. The technology developed under this project can provide nuclear plant management, engineers, and technicians with an in-situ electrical test method to determine if in-service cables need to be replaced, monitored on a periodic basis, or show no evidence of significant age-related degradation that may require action. Near the end of this Phase IIB project, the FDR product was sold to a nuclear power utility in South Korea. This sale of a dedicated aging assessment tool is the beginning of a comprehensive contract with the expectation of twelve (12) units sold to that country. Additionally, the FDR technology has been sold to several industry organizations including a nuclear research institute and the Diablo Canyon nuclear power plant. This technology is also being leased by other nuclear industry service companies for incorporation into aging management programs. The cable testing technology that was developed under this project was also integrated into a comprehensive cable aging assessment service that is being offered to the nuclear industry at the request of U.S. nuclear utilities and is currently part of onsite testing services provided by AMS.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

The Scientific Justification for a U.S. Domestic High-Performance Reactor-Based Research Facility

The Basic Energy Science Advisory Committee (BESAC) was charged with forming a subcommittee to assess the scientific justification for a U.S. domestic high-performance reactor-based research facility in order to continue providing the U.S scientific community with leading neutron capabilities in support of DOE's missions in science, energy, environment, and national security. The assessment included consideration of current international plans and existing domestic facility infrastructure. The subcommittee held a series of meetings from August 19, 2019 to April 24, 2020 that included DOE senior officials, leaders of national and international neutron facilities (SNS, HFIR, NIST, ILL, FRM-II), chairs of the NAS and POPA HEU-LEU committees, and outside experts on important areas of science, technology, and industry where high flux nuclear reactor facilities make important contributions. Also included were tours of neutron facilities (SNS, HFIR, NIST, BR2 reactor, and the planned Jules Horowitz Reactor). This July 2020 (revised 10-28-2020) report describes scientific use cases, brief summaries of existing and planned neutron facilities in the US and Europe, a comprehensive review of HFIR, a comprehensive discussion of the current state of progress on HEU-LEU conversion, user information from NIST and ORNL, and three recommendations to DOE for moving forward.

36 MATERIALS SCIENCE↗