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At least 1,747 records · Page 97
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

A heat flux sensor leveraging the transverse Seebeck effect in elemental antimony

Certain configurations of anisotropic single crystal materials can generate a thermoelectric voltage orthogonal to an induced temperature gradient. This phenomenon is known as the Transverse Seebeck Effect (TSE) and can be leveraged to fabricate simple and robust heat flux sensors. Only a small number of materials have been considered as TSE-based transducers and, among these, few have been developed into sensors with ruggedization against chemical and mechanical degradation. Here, we report on the fabrication and characterization of a rugged TSE-based heat flux sensor using prismatic antimony single crystals. The heat flux sensor was tested under static and dynamic heating scenarios. The sensor has a linear responsivity of 16.8 µV/(W/cm2) to heat fluxes spanning more than two orders of magnitude and a time constant of 4.4 s. The sensor’s response to localized heating, probed with a laser scanning technique, validated that the transduction mechanism is primarily the TSE by ruling out a sizable contribution from the conventional Seebeck effect. Finite element analysis corroborated that components used in the sensor package are the primary determinants of the time constant and the decrement of the responsivity from its theoretical maximum. Design principles that may be applied to elicit a faster transient response or higher responsivity are proposed. Furthermore, the results establish single crystal antimony as a promising transducer material for heat flux measurement systems and demonstrate potential effects of ruggedization on sensor performance.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Characterization of blast waves induced by femtosecond laser irradiation in solid targets

Blast waves have been produced in solid target by irradiation with short-pulse high-intensity lasers. The mechanism of production relies on energy deposition from the hot electrons produced by laser–matter interaction, producing a steep temperature gradient inside the target. Hot electrons also produce preheating of the material ahead of the blast wave and expansion of the target rear side, which results in a complex blast wave propagation dynamic. Several diagnostics have been used to characterize the hot electron source, the induced preheating and the velocity of the blast wave. Results are compared to numerical simulations. These show how blast wave pressure is initially very large (more than 100 Mbar), but it decreases very rapidly during propagation.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2021

Thermoosmotic Transport in Nanochannels Grafted with pH-responsive Polyelectrolyte Brushes Modelled Using Augmented Strong Stretching Theory

In this paper, we develop a theory to establish that the thermoosmotic (TOS) effects, induced by the application of an axial temperature gradient, leads to a massive enhancement in liquid transport in nanochannels grafted with charged polyelectrolyte (PE) brushes. Here, we quantify the TOS transport by quantifying the induced electric field and the induced TOS flow field. The different components of the electric field, namely the ionic component, the thermal component, and the osmotic component, as well as the contributions of different ions to these components, are quantified. Furthermore, we express the TOS velocity as a combination of chemiosmotic (COS), thermal, and electroosmotic (EOS) components. The COS and the thermal components augment each other and the overall strength and direction of the TOS flow are dictated by the direction and the relative strength of the EOS component. Most importantly, we compare the cases of brush-grafted nanochannels with those of the brush-free nanochannels of identical surface charge densities: the TOS transport is massively augmented in the brush-grafted nanochannels attributed to the combination of the localization of the EDL (and hence any body force that depends on the EDL charge density) away from the nanochannel wall (i.e., the location of the maximum drag force) and the presence of a possible molecular slip (experienced by the liquid) along the brush surface.

42 ENGINEERING↗
DOE OSTI2021

Investigation of species-mass diffusion in binary-species boundary layers at high pressure using direct numerical simulations

Here, direct numerical simulations of single-species and binary-species temporal boundary layers at high pressure are performed with special attention to species-mass diffusion. The working fluids are nitrogen or a mixture of nitrogen and methane. Mean profiles and turbulent fluctuations of mass fraction show that their qualitative characteristics are different from those of streamwise velocity and temperature, due to the different boundary conditions. In a wall-parallel plane near the wall, the streamwise velocity and temperature have streaky patterns and the fields are similar. However, the mass fraction field at the same location is different from the streamwise velocity and temperature fields indicating that species-mass diffusion is not similar to the momentum and thermal diffusion. In contrast, at the centre and near the edge of the boundary layer, the mass fraction and temperature fields have almost the same pattern, indicating that the similarity between thermal and species-mass diffusion holds away from the wall. The lack of similarity near the wall is traced to the Soret effect that induces a temperature-gradient-dependent species-mass flux. As a result, a new phenomenon has been identified for a non-isothermal binary-species system – uphill diffusion, which in its classical isothermal definition can only occur for three or more species. A quadrant analysis for the turbulent mass flux reveals that near the wall the Soret effect enhances the negative contributions of the quadrants. Due to the enhancement of the negative contributions, small species-concentration fluid tends to be trapped near the wall.

42 ENGINEERING↗
DOE OSTI2018

Projection-operator methods for classical transport in magnetized plasmas. Part 2. Nonlinear response and the Burnett equations [Projection-operator methods for classical transport in magnetized plasmas. Part 1. Nonlinear response and the Burnett equations]

The time-independent projection-operator formalism for the derivation of Burnett equations is extended and considered in the context of multispecies and magnetized plasmas. The procedure provides specific formulas for transport coefficients in terms of two-time correlation functions involving both two and three phase-space points. It is shown how to calculate those correlation functions in the limit of weak coupling. The results are used to demonstrate, with the aid of a particular non-trivial example, that the Chapman–Enskog methodology employed by Catto & Simakov (CS) (Phys. Plasmas, vol. 11, 2004, pp. 90–102) to calculate the contributions to the parallel viscosity driven by temperature gradients is consistent with formulas previously derived from the two-time formalism by Brey (J. Chem. Phys., vol. 79, 1983, pp. 4585–4598). Here, the work serves to unify previous work on plasma kinetic theory with formalism usually applied to turbulence. Additional contributions include discussions of (i) Braginskii-order interspecies momentum exchange from the point of view of two-time correlations; and (ii) a simple stochastic model, unrelated to many-body theory, that exhibits Burnett effects. Insights from that model emphasize the role of non-Gaussian statistics in the evaluation of Burnett transport coefficients, including the effects calculated by CS that stem from the nonlinear collision operator. Together, Parts 1 and 2 of this series provide an introduction to projection-operator methods that should be broadly useful in theoretical plasma physics.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2018

Stellarator microinstabilities and turbulence at low magnetic shear

Gyrokinetic simulations of drift waves in low-magnetic-shear stellarators reveal that simulation domains comprised of multiple turns can be required to properly resolve critical mode structures important in saturation dynamics. Marginally stable eigenmodes important in saturation of ion temperature gradient modes and trapped electron modes in the Helically Symmetric Experiment (HSX) stellarator are observed to have two scales, with the envelope scale determined by the properties of the local magnetic shear and an inner scale determined by the interplay between the local shear and magnetic field-line curvature. Properly resolving these modes removes spurious growth rates that arise for extended modes in zero-magnetic-shear approximations, enabling use of a zero-magnetic-shear technique with smaller simulation domains and attendant cost savings. Analysis of subdominant modes in trapped electron mode (TEM)-driven turbulence reveals that the extended marginally stable modes play an important role in the nonlinear dynamics, and suggests that the properties induced by low magnetic shear may be exploited to provide another route for turbulence saturation.

Faber, B. J. (ORCID:000000034934400X)↗
DOE OSTI2019

A comparison of turbulent transport in a quasi-helical and a quasi-axisymmetric stellarator

Ion-temperature-gradient-driven (ITG) turbulence is compared for two quasi-symmetric (QS) stellarator configurations to determine the relationship between linear growth rates and nonlinear heat fluxes. We focus on the quasi-helically symmetric (QHS) stellarator HSX and the quasi-axisymmetric (QAS) stellarator NCSX. In normalized units, HSX exhibits higher growth rates than NCSX, while heat fluxes in gyro-Bohm units are lower in HSX. These results hold for simulations made with both adiabatic and kinetic electrons. The results show that HSX has a larger number of subdominant modes than NCSX and that eigenmodes are more spatially extended in HSX. Furthermore, we conclude that the consideration of nonlinear physics is necessary to accurately assess the heat flux due to ITG turbulence when comparing QS stellarator equilibria.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2020

Advancing the physics basis for quasi-helically symmetric stellarators

A new optimized quasi-helically symmetric configuration is described that has the desirable properties of improved energetic particle confinement, reduced turbulent transport by three-dimensional shaping and non-resonant divertor capabilities. The configuration presented in this paper is explicitly optimized for quasi-helical symmetry, energetic particle confinement, neoclassical confinement and stability near the axis. Post optimization, the configuration was evaluated for its performance with regard to energetic particle transport, ideal magnetohydrodynamic stability at various values of plasma pressure and ion temperature gradient instability induced turbulent transport. The effects of discrete coils on various confinement figures of merit, including energetic particle confinement, are determined by generating single-filament coils for the configuration. Preliminary divertor analysis shows that coils can be created that do not interfere with expansion of the vessel volume near the regions of outgoing heat flux, thus demonstrating the possibility of operating a non-resonant divertor.

Physics↗
DOE OSTI2021

Kinetic-ballooning-mode turbulence in low-average-magnetic-shear equilibria

In this work, kinetic-ballooning-mode (KBM) turbulence is studied via gyrokinetic flux-tube simulations in three magnetic equilibria that exhibit small average magnetic shear: the Helically Symmetric eXperiment (HSX), the helical-axis Heliotron-J and a circular tokamak geometry. For HSX, the onset of KBM being the dominant instability at low wavenumber occurs at a critical value of normalized plasma pressure $\beta ^{\rm KBM}_{\rm crit}$ that is an order of magnitude smaller than the magnetohydrodynamic (MHD) ballooning limit $\beta ^{\rm MHD}_{\rm crit}$ when a strong ion temperature gradient (ITG) is present. However, $\beta ^{\rm KBM}_{\rm crit}$ increases and approaches the MHD ballooning limit as the ITG tends to zero. For these configurations, $\beta ^{\rm KBM}_{\rm crit}$ also increases as the magnitude of the average magnetic shear increases, regardless of the sign of the normalized magnetic shear. Simulations of Heliotron-J and a circular axisymmetric geometry display behaviour similar to HSX with respect to $\beta ^{\rm KBM}_{\rm crit}$ . Despite large KBM growth rates at long wavelengths in HSX, saturation of KBM turbulence with $\beta > \beta _{\rm crit}^{\rm KBM}$ is achievable in HSX and results in lower heat transport relative to the electrostatic limit by a factor of roughly five. Nonlinear simulations also show that KBM transport dominates the dynamics when KBMs are destabilized linearly, even if KBM growth rates are subdominant to ITG growth rates.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

Phase contrast imaging measurements and numerical simulations of turbulent density fluctuations in gas-fuelled ECRH discharges in Wendelstein 7-X

The fundamental nature of turbulent density fluctuations in standard Wendelstein 7-X (W7-X) stellarator discharges is investigated experimentally via phase contrast imaging (PCI) in combination with gyrokinetic simulations with the code GENE. We find that density fluctuations are ion-temperature-gradient-driven and radially localised in the outer half of the plasma. It is shown that the line-integrated PCI measurements cover the right range of wavenumbers and a favourable toroidal and poloidal location to capture some of the strongest density fluctuations in W7-X. Due to the radial localisation of fluctuations, measured wavenumber–frequency spectra exhibit a dominant phase velocity, which can be related to the E × B rotation velocity at the radial position of a well in the neoclassical radial electric field. The match is robust against variations of heating power and line-integrated density, which is partly due to the localisation of fluctuations and partly due to effects of the radial gradient in the E × B velocity profile on the wavenumber–frequency spectrum. The latter effect is studied with a newly built synthetic PCI diagnostic and global gyrokinetic simulations with GENE-3D.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

Microstability of β ~ 1 tokamak equilibria

High-power-density tokamaks offer a potential solution to design cost-effective fusion devices. One way to achieve high power density is to operate at a high β value (the ratio of thermal to magnetic pressure), i.e. β~1 . However, a β~1 state may be unstable to various pressure- and current-driven instabilities or have unfavourable microstability properties. To explore these possibilities, we generate β~1 equilibria and investigate their stability. First, we demonstrate the generation of high-β equilibria with the computer code VMEC. We then analyse these equilibria to determine their stability against the infinite-n ideal-ballooning mode. We follow that by engaging in a detailed microstability study using the GS2 code, beginning with assessments of electrostatic ion-temperature-gradient and trapped election mode instabilities. We observe interesting behaviour for the high-β equilibria – stabilization of these modes through two distinct mechanisms – large negative local shear and reversal of electron precession drift. Finally, we perform electromagnetic gyrokinetic simulations and observe enhanced stability in the outer core of high-β equilibria and absence of kinetic ballooning modes in the negative-triangularity, high-β equilibria. The enhanced outer-core stability of high-β equilibria is different from their lower-β counterparts and offers an alternative, potentially favourable regime of tokamak operation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2019

Influence of the Laser Scanning Rate on the Structure of Rotating Lattice Single Crystal Lines

Localized controlled heating of glass with a continuous wave laser has introduced the possibility of engineering the lattice of recently discovered rotating lattice single (RLS) crystals and thus obtaining novel metamaterials. On this account, we report the role of the laser scanning speed on the lattice structure of a model system: Sb 2 S 3 straight RLS crystal lines created in a 16SbI 3 -84Sb 2 S 3 glass. The electron backscatter diffraction analysis shows that above a critical laser scanning speed the lattice rotates along the direction of scanning, the rate of lattice rotation is relatively insensitive to scanning speed, and the growth front is symmetric. In contrast, for laser scanning speeds below this critical value, the rate and direction of lattice rotation are strongly affected by the speed. Further, the growth front becomes asymmetric, which promotes the formation of new grains misoriented by ≤10°. These observations are reported on in terms of the relative dominance of the temperature gradient from laser scanning vis-á-vis the intrinsic preferred crystallographic direction of crystal growth. In addition to providing guidelines for fabricating the RLS crystal of the desired rate of the lattice rotation, new insight is gained for the mechanism of plumose formation in spherulitic crystals.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Anomalously Large Seebeck Coefficient of CuFeS 2 Derives from Large Asymmetry in the Energy Dependence of Carrier Relaxation Time

The Seebeck effect in a material originates from the distribution of asymmetry in the electron transport under a temperature gradient, which has contributions from the energy-dependent electronic density-of-states and carrier mobility. However, because the energy dependence of common electron scattering mechanisms is weak, the mobility-driven Seebeck coefficient has long been ignored in most thermoelectric materials, and the energy asymmetry of the density-of-states has been considered the dominant contribution. In this work, we describe a hopping transport behavior observed in CuFeS 2 , and a large carrier Hall mobility gradient of dμH/dT that creates an unusually large energy-dependent mobility contribution to the Seebeck coefficient. This work offers several ideas regarding the mobility-driven Seebeck effect and its potential utilization in the design of thermoelectric materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Prediction of the Thermal Runaway Limit and Optimal Operation of Heat Transfer-Limited, Fixed-Bed Reactor Systems

Here, we derive a new prediction for thermal runaway starting from the alpha model for fixed-bed reactor systems. This method accounts for thermal resistance internal to the reactor tube and the radial temperature gradients that result. To showcase our method, we compare its predictions to other common criteria for thermal runaway using o-xylene oxidation as the example chemistry. Even in systems where internal heat transfer is negligible, the empirical practical design criterion for thermal runaway is inaccurate. For cases where internal heat transfer is relevant, our runaway limit is more stringent than limits derived from simpler 1-D models. To augment our work, we optimize the product yield with the thermal runaway constraint using orthogonal collocation. Using the alpha model, the results illustrate that the thermal runaway limit can be accurately determined using either numerical or analytical methods.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Ethanol as a Renewable Building Block for Fuels and Chemicals

Three factors, i) the ethanol “blend wall”, which limits its market as a transportation fuel, ii) advances in production efficiency, and iii) feedstock diversification, could lead to excess ethanol at competitive prices. Those factors have already motivated a search for value-added derivatives (e.g., distillate fuels, olefins, and asymmetric amines). Siting small, low cost, flexible conversion facilities to process ethanol at or near the fermentation plant could encourage the growth of an enterprise. Decreasing the barriers to entry, matching supply and demand, and enhancing access to production incentives are enabling success factors. This review discusses the process chemistries that might be employed by such ethanol conversion facilities based on market prices. Finally, how these technologies might benefit from process intensification, and without the requirement of complex processing or large pressures or temperature gradients typically employed in conventional, large scale facilities.

09 BIOMASS FUELS↗
DOE OSTI2021

Vapor-Phase Intercalation of Cesium into Black Phosphorous

Cesium vapors were charged into black phosphorous (BP) flakes at varied times and at a temperature gradient of 150 °C. The X-ray diffraction (XRD) measurements of these samples suggest a reduction in the strength of van der Waal interactions between BP layers leading to the loss of coherence of out-of-plane peaks. At the same time, the three main Raman modes of BP (A g 1 , B 2 g , and A g 2 ) steadily redshifted as exposure times were increased, with modes B 2 g and A g 2 shifting faster than A g 1 . After initial rapid downshifts of active BP phonon modes, this intercalation strategy showed its limits following prolonged exposure times. Saturation of BP flakes by Cs vapors ensued and the kinetics was fitted with an exponential decay function. Furthermore, the thermoelectric power (TEP) of cesiated BP exhibited an inversion in sign from positive to negative around 400 K, lending credence to the transformation of as-prepared BP which is a p-type semiconductor to an n-type equivalent due to Cs atom intercalation driven shifting of the Fermi level toward the conduction band of BP and the donation of electrons from Cs. Furthermore, density functional theory (DFT) calculations were used to delve deeper into understanding Cs intercalation on the structural evolution of BP.

36 MATERIALS SCIENCE↗
DOE OSTI2015

Hierarchical, ultrathin single-crystal nanowires of CdS conveniently produced in laser-induced thermal field

Hierarchical nanowires (HNWs) exhibit unique properties and have wide applications, while often suffering from imperfect structure. We report a facile strategy toward ultrathin CdS HNWs with monocrystal structure, where a continuous-wave (CW) Nd:YAG laser is employed to irradiate an oleic acid (OA) solution containing precursors and a light absorber. The high heating rate and large temperature gradient generated by the CW laser lead to the rapid formation of tiny zinc-blende CdS nanocrystals which then line up into nanowires with the help of OA molecules. Next, the nanowires experience a phase transformation from zinc-blende to wurtzite structure, and the transformation-induced stress creates terraces on their surface, which promotes the growth of side branches and eventually results in monocrystal HNWs with an ultrathin diameter of 24 nm. The one-step synthesis of HNWs is conducted in air and completes in just 40 seconds, thus being very simple and rapid. The prepared CdS HNWs display photocatalytic performance superior to their nanoparticle counterparts, thus showing promise for catalytic applications in the future.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Localized Plasmonic Heating for Single-Molecule DNA Rupture Measurements in Optical Tweezers

To date, studies on the thermodynamic and kinetic processes that underlie biological function and nanomachine actuation in biological- and biology-inspired molecular constructs have primarily focused on photothermal heating of ensemble systems, highlighting the need for probes that are localized within the molecular construct and capable of resolving single-molecule response. Here we present an experimental demonstration of wavelength-selective, localized heating at the single-molecule level using the surface plasmon resonance of a 15 nm gold nanoparticle (AuNP). Our approach is compatible with force-spectroscopy measurements and can be applied to studies of the single-molecule thermodynamic properties of DNA origami nanomachines as well as biomolecular complexes. We further demonstrate wavelength selectivity and establish the temperature dependence of the reaction coordinate for base-pair disruption in the shear-rupture geometry, demonstrating the utility and flexibility of this approach for both fundamental studies of local (nanometer-scale) temperature gradients and rapid and multiplexed nanomachine actuation.

77 NANOSCIENCE AND NANOTECHNOLOGY↗