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At least 1,747 records · Page 97

The difference between laboratory and in-situ pixel-averaged emissivity: The effects on temperature-emissivity separation

Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) is a Japanese future imaging sensor which has five channels in thermal infrared (TIR) region. To extract spectral emissivity information from ASTER and/or TIMS data, various temperature-emissivity (T-E) separation methods have been developed to date. Most of them require assumptions on surface emissivity, in which emissivity measured in a laboratory is often used instead of in-situ pixel-averaged emissivity. But if these two emissivities are different, accuracies of separated emissivity and surface temperature are reduced. In this study, the difference between laboratory and in-situ pixel-averaged emissivity and its effect on T-E separation are discussed. TIMS data of an area containing both rocks and vegetation were also processed to retrieve emissivity spectra using two T-E separation methods.

Matsunaga, Tsuneo↗

Vertical effective stress and temperature as controls of quartz cementation in sandstones: Evidence from North Sea Fulmar and Gulf of Mexico Wilcox sandstones

Here we present quantitative petrographic data, high spatial resolution oxygen isotope analyses of quartz cement, basin modelling and a kinetic model for quartz precipitation for two Paleocene-Eocene Wilcox Group sandstones from Texas and two Jurassic Fulmar Formation sandstones from the Central North Sea. At each location, one sandstone has been buried to ca. 145 °C and one to ca. 185 °C. A key difference between the Wilcox and Fulmar burial histories is that the Wilcox sandstones are currently at higher vertical effective stresses and, from basin modelling studies, have been subjected to generally higher vertical effective stresses through their burial history. The amounts of quartz cement in the Wilcox sandstones are between 12 and 18%, and between 2 and 6% in the Fulmar sandstones. High-spatial-resolution oxygen isotope data obtained from the quartz cements suggest temperature ranges for quartz precipitation from 60 to 80 °C to values approaching maximum burial temperature. Factors such as grain coatings or the timing of petroleum emplacement cannot explain the differences in the amounts of quartz cement. Petrographic data show that most of the silica for quartz cement can be derived from intergranular pressure dissolution. Although the sample set is small, we interpret the results to suggest that the differences in quartz cementation in Fulmar and Wilcox sandstones can be explained better by differences in their vertical effective stress history than their temperature history; in this case, the supply of silica rather than the precipitation of quartz becomes an important control on the rate and extent of cementation.

58 GEOSCIENCES↗

Effects of processing temperature on the corrosion and tribocorrosion resistance of perhydropolysilazane-derived coatings on AISI 304 steel

Ensuring a highly corrosion and erosion resistant surface is critical to the reliability and structural integrity of steel canisters for long-term nuclear waste storage in corrosive environments. In this work, perhydropolysilazane (PHPS)-derived coating has been successfully applied to enhance the pitting and tribocorrosion resistance of 304 stainless steels in 0.6 M NaCl solution. Two types of coatings were synthesized on the stainless steel substrate by crosslinking PHPS at room temperature or 600 °C, resulting in different mechanical and corrosion performance. Further, Raman spectra revealed that Si-O bonds were generated in the coating crosslinked at room temperature after corrosion, while absent in that pyrolyzed at 600 °C. In tribocorrosion tests, both coatings were protective to the steel substrate, with the protective effect being more pronounced in the 600 °C pyrolyzed coating. Overall, the PHPS-derived coating synthesized at 600 °C exhibited better protection for steel in wear and corrosion coexisting environments than those synthesized at room temperature.

36 MATERIALS SCIENCE↗

Analysis of the effects on life of leading-edge holes in an airfoil subjected to arbitrary spanwise and chordwise temperature distributions

The effects of temperature gradients, cooling-hole rim and bulk metal temperatures, and mechanical stress were investigated by using a finite-element structural analysis of a symmetrical airfoil with and without leading-edge holes. The results indicate that leading-edge film cooling is beneficial when large chordwise temperature gradients exist and if the cooling-hole rim temperatures are above the bulk metal temperature. The effects of film cooling at other locations on the airfoil were not considered, and the relative merits of convection or film cooling at the leading edge, in terms of allowable turbine inlet temperature or coolant flow requirements, were not evaluated.

Kaufman, A.↗

Comparing the Effectiveness of Low Temperature Bake in EP and BCP Cavities

Electropolishing (EP) and buffered chemical polishing (BCP) are conventional surface preparation techniques for superconducting radiofrequency (SRF) cavities. Both EP and BCP treated SRF cavities display high field Q-slope (HFQS) which degrades performance at high gradients. While high gradient performance in EP cavities can be improved by introducing oxygen via a low temperature bake (LTB) of 120^{°}C by 48 hours, LTB does not consistently remove HFQS in BCP cavities. There is no consensus as to why LTB is not effective on BCP prepared cavities. We examine quench in EP, BCP, EP+LTB, and BCP+LTB treated 1.3 GHz single-cell Nb cavities by studying the heating behavior with field using a temperature mapping system. Cavity performance is correlated to characterizations of surface impurity profile obtained via time of flight secondary ion mass spectrometry studies. We observe a difference in near surface hydrogen concentration following BCP compared to EP that may suggest that the causes of quench in EP and BCP cavities are different.

43 PARTICLE ACCELERATORS↗

Effects of high temperature and e-beam irradiation on the stability of refractory thin films

Refractory thin films of Al2O3, ZrO2, MgO, ThO2, and BN have been investigated in situ in an UHV transmission electron microscope. The electron transparent refractory films were prepared by electron-beam evaporation, anodization, RF sputtering, and thinning of bulk crystal materials. The study concentrates on monitoring the thermal and mechanical stability of the films, phase and structural changes, and electron irradiation effects as a function of film-preparation conditions. With increasing temperatures, five different crystallographic phases were observed for both anodized and electron-beam-evaporated alumina films. Zirconia films exhibited two phase transitions upon heating to 1200 C and electron-irradiation-induced crystallization of ZrO2 even at room temperature. MgO, ThO2, and BN films did not undergo any noticeable phase transformation but ruptured due to sintering below 1200 C.

Lee, E. H.↗

Room-temperature terahertz anomalous Hall effect in Weyl antiferromagnet Mn 3 Sn thin films

Antiferromagnetic spin motion at terahertz (THz) frequencies attracts growing interests for fast spintronics, however, their smaller responses to external field inhibit device application. Recently the noncollinear antiferromagnet Mn 3 Sn, a Weyl semimetal candidate, was reported to show large anomalous Hall effect (AHE) at room temperature comparable to ferromagnets. Dynamical aspect of such large responses is an important issue to be clarified for future THz data processing. Here the THz anomalous Hall conductivity in Mn 3 Sn thin films is investigated by polarization-resolved spectroscopy. Large anomalous Hall conductivity Re σxyð Þ ω 20 Ω1cm1 at THz frequencies is clearly observed as polarization rotation. A peculiar temperature dependence corresponding to the breaking/recovery of symmetry in the spin texture is also discussed. Observation of the THz AHE at room temperature demonstrates the ultrafast readout for the antiferromagnetic spintronics using Mn3Sn, and will also open new avenue for studying nonequilibrium dynamics in Weyl antiferromagnets.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Effect of Initial Mixture Temperature on Flame Speed of Methane-Air, Propane-Air, and Ethylene-Air Mixtures

Flame speeds based on the outer edge of the shadow cast by the laminar Bunsen cone were determined as functions of composition for methane-air mixtures at initial mixture temperatures ranging from -132 degrees to 342 degrees c and for propane-air and ethylene-air mixtures at initial mixture temperatures ranging from -73 degrees to 344 degrees c. The data showed that maximum flame speed increased with temperature at an increasing rate. The percentage change in flame speed with change in initial temperature for the three fuels followed the decreasing order, methane, propane, and ethylene. Empirical equations were determined for maximum flame speed as a function of initial temperature over the temperature range covered for each fuel. The observed effect of temperature on flame speed for each of the fuels was reasonably well predicted by either the thermal theory as presented by Semenov or the square-root law of Tanford and Pease.

Dugger, Gordon L↗

Pressure Effects on the Temperature Sensitivity of Fiber Bragg Gratings

A 3-dimensional physical model was developed to relate the wavelength shifts resulting from temperature changes of fiber Bragg gratings (FBGs) to the thermal expansion coefficients, Young s moduli of optical fibers, and thicknesses of coating polymers. Using this model the Bragg wavelength shifts were calculated and compared with the measured wavelength shifts of FBGs with various coating thickness for a finite temperature range. There was a discrepancy between the calculated and measured wavelength shifts. This was attributed to the refractive index change of the fiber core by the thermally induced radial pressure. To further investigate the pressure effects, a small diametric load was applied to a FBG and Bragg wavelength shifts were measured over a temperature range of 4.2 to 300K.

Wu, Meng-Chou↗

Editors’ Choice—Natural Convection Boundary Layer Thickness at Elevated Chloride Concentrations and Temperatures and the Effects on a Galvanic Couple

The natural convection boundary layer ( δ n c ) and its influence on cathodic current in a galvanic couple under varying electrolytes as a function of concentration (1 − 5.3 M NaCl) and temperature (25 °C−45 °C) were understood. Polarization scans were obtained under quiescent conditions and at defined boundary layer thicknesses using a rotating disk electrode on platinum and stainless steel 304L (SS304L); these were combined to determine δ n c . With increasing chloride concentration and temperature, δ n c decreased. Increased mass transport (Sherwood number) results in a decrease in δ n c , providing a means to predict this important boundary. Using Finite Element Modeling, the cathodic current was calculated for an aluminum alloy/SS304L galvanic couple as a function of water layer ( WL ) thickness and cathode length. Electrolyte domains were delineated, describing (i) dominance of ohmic resistance over mass transport under thin WL , (ii) the transition from thin film to bulk conditions at δ n c , and (iii) dominance of mass transport under thick WL . With increasing chloride concentration, cathodic current decreased due to decreases in mass transport. With increasing temperature, increased cathodic current was related to increases in mass transport and solution conductivity. This study has implications for sample sizing and corrosion prediction under changing environments.

25 ENERGY STORAGE↗

Influence of the preshock temperature on shock effects in quartz

Shock metamorphic features are the prime indicators for recognizing impact phenomena on Earth and other planetary bodies. Although the pressure dependence of shock features is well known, information about the influence of the preshock temperature is almost lacking. Especially in the case of large-scale impacts like Sudbury, it is expected that deep-seated crustal rocks were subjected to shock at elevated temperatures. Therefore, we continued to perform shock experiments at elevated temperatures on less than 0.5-mm thin disks of single crystal quartz cut parallel to the (1010) face. All recovered quartz samples were investigated by universal stage, spindle stage, and a newly developed density gradient technique. Errors of refractive index and density measurements are +/- 0.0005 and +/- 0.002 g/cu cm respectively. Our investigations indicate that shock metamorphic features are strongly dependent on the preshock temperature. This statement has far-reaching implications with respect to shock wave barometry that is based on data from recovery experiments at room temperature. These datasets might be applicable only to low-temperature target rocks. Moreover, this study demonstrates that shock recovery experiments are definitely required for understanding the complete pressure-temperature regime of shock metamorphism on planetary bodies.

Langenhorst, F.↗

The effect of ambient temperature and humidity on the carbon monoxide emissions of an idling gas turbine

Changes in ambient temperature and humidity affect the exhaust emissions of a gas turbine engine. The results of a test program employing a JT8D combustor are presented which quantize the effect of these changes on carbon monoxide emissions at simulated idle operating conditions. Analytical results generated by a kinetic model of the combustion process and reflecting changing ambient conditions are given. It is shown that for a complete range of possible ambient variations, significant changes do occur in the amount of carbon monoxide emitted by a gas turbine engine.

Kauffman, C. W.↗

Effect of Wall Temperature on Roughness Induced Attachment-Line Transition

An experiment on a cooled swept cylinder in a low-disturbance Mach 1.6 wind tunnel is described. The flow attachment line is disturbed by trip wires of varying size and the laminar/turbulent state of the downstream boundary layer is determined with a hot wire. The results demonstrate that although cooling the wall increases the stability of the boundary layer, it promotes roughness induced transition. Analysis of the data suggests that the attachment- line Reynolds number can account for the effect of wall cooling if the viscosity is evaluated at a particular reference temperature.

Dietz, Anthony↗

Effect of wind and temperature gradients on received acoustic energy

The effect of refraction due to wind and temperature gradients on energy received from low flying aircraft is examined. A series of helicopter and jet flyby's were recorded with a microphone array on two separate days, each with distinctly different meteorological conditions. Energy in the 100 to 200 Hertz band is shown as a function of aircraft range from the array, and compared with the output of the Fast Field Program.

Brienzo, Richard K.↗