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At least 1,747 records · Page 97

Field evaluation of remote wind sensing technologies: Shore-based and buoy mounted LIDAR systems

In developing a national energy strategy, the United States has a number of objectives, including increasing economic growth, improving environmental quality, and enhancing national energy security. Wind power contributes to these objectives through the deployment of clean, affordable and reliable domestic energy. To achieve U.S. wind generation objectives, the Wind and Water Power Program within the Department of Energy’s (DOE) Office of Energy Efficiency and Renewable Energy (EERE) instituted the U.S. Offshore Wind: Removing Market Barriers Program in FY 2011. Accurate and comprehensive information on offshore wind resource characteristics across a range of spatial and temporal scales is one market barrier that needs to be addressed through advanced research in remote sensing technologies. There is a pressing need for reliable offshore wind-speed measurements to assess the availability of the potential wind energy resource in terms of power production and to identify any frequently occurring spatial variability in the offshore wind resource that may impact the operational reliability and lifetime of wind turbines and their components and to provide a verification program to validate the “bankability” of the output of these alternative technologies for use by finance institutions for the financing of offshore wind farm construction. The application of emerging remote sensing technologies is viewed as a means to cost-effectively meet the data needs of the offshore wind industry. In particular, scanning and buoy mounted LIDAR have been proposed as a means to obtain accurate offshore wind data at multiple locations without the high cost and regulatory hurdles associated with the construction of offshore meteorological towers. However; before these remote sensing technologies can be accepted the validity of the measured data must be evaluated to ensure their accuracy. The proposed research will establish a unique coastal ocean test-bed in the Mid-Atlantic for the evaluation of LIDAR-based wind measurement systems to validate the accuracy of remotely measured wind data in marine applications. Specifically, the test-bed will be utilized to systematically evaluate the capability of emerging scanning LIDAR and buoy mounted vertically profiling LIDAR by: (1) Evaluating a fixed scanning LIDAR against land-based 50 and 60 meter high meteorological masts fitted with research quality cup-vane and/or sonic anemometers; (2) Evaluating a buoy mounted vertically profiling LIDAR fixed on land and floating in a sheltered bay against a co-located 60 meter high meteorological mast fitted with a research quality cup-vane and/or sonic anemometers and the fixed scanning LIDAR; and (3) Offshore field evaluation of both LIDAR platforms through a comparison of the fixed scanning LIDAR data and data obtained by the buoy mounted LIDAR located 10 miles offshore. The proposed research will systematically validate Light Detection and Ranging (LIDAR) based wind measurement systems and assess the temporal and spatial variability of the offshore wind resource in the Mid-Atlantic east of New Jersey. The goal of the proposed project is to address the technical and commercial challenges of the offshore wind energy industry by validating and assessing cost-effective, over ocean wind resource characterization technologies. The objective is to systematically evaluate the capability of both scanning and vertically profiling LIDARs to accurately measure 3D wind fields through comparison with fixed met masts and intercomparison among LIDAR platforms. Once validated, data collected by both buoy mounted vertically profiling LIDARs and shore-based, pulsed horizontally scanning LIDARs can be used to accurately assess offshore wind resources and to quantify the spatial and temporal variability in the offshore wind fields. One of the fundamental research questions to be addressed in phase 1 is the assessment of various measurement and data processing schemes to retrieve accurate wind vectors in the marine environment over large sampling ranges (10 to 12 km) and varying atmospheric aerosol levels. Atmospheric conditions and aerosol content within the coastal ocean region of the Mid-Atlantic seaboard of the US can vary significantly over short time periods in response to frontal passages and extratropical and tropical low pressure system passage offshore of the coast. Since aerosols provide the scattering medium for the determination of LIDAR Doppler shifts in the atmosphere the accuracy and range of LIDAR derived velocity measurements as a function of variation in aerosol content in the marine environment is a key research question to be addressed. In phase 1, it is desired to capture as much variation in atmospheric conditions and aerosol content as possible. To this end, collocated measurements of LIDAR and standard anemometer wind fields will be captured by the project PIs over all four seasons and during specific events (e.g., coastal low pressure system passage) in year 1. Additionally, since the meteorological masts are permanent structures, additional events can be captured over the three year duration of the field research project. All research instruments are owned by Fishermen’s Energy and made available to the PIs though a lease agreement as part of the DOE grant. Energy Fishermen’s Energy will be responsible for the operation and maintenance of the scanning LIDAR and met mast anemometers. On a daily basis, environmental data and systems performance indicators will be transmitted from each measurement station to the Fishermen’s project team consisting of both in-house personnel and equipment manufacturer engineers. Data sets include compiled LIDAR files as well as data sets from ancillary sensors. Diagnostic parameters to be monitored include standard deviations of measured values, battery levels and charging systems output, and the operational status. Once data have been confirmed as complete and reliable, files will be transferred to the Garrad Hassan (a subcontractor to Fishermen’s Energy) for incorporation in to the validation database, which is accessible to other scientific team members. Data collection times and durations will be determined by the PI and Co-PIs in consultation with instrument engineers to ensure the capture of data representative of the expected range of mid-Atlantic atmospheric conditions (e.g., temperature, moisture, coastal low pressure systems, tropical systems, rain, snow, fog). The collection and processing of the data is a function of site specific measurement requirements (Kelley et.al. 2007; Hannon et.al. 2008). To determine the optimal profiles of wind speed and direction from the LIDAR radial velocities as a function of azimuth angle, rigorous estimates of the bias and random error of each radial velocity estimate are required. Lockheed Martin Coherent Technologies, Inc., under contract with Fishermen’s Energy, will provide analyses of raw and processed data using various scan patterns to determine optimal performance settings for the pulsed scanning LIDAR. Once optimized, appropriate processing and analyses techniques will be evaluated by Garrad Hassan for use in validating the accuracy of the LIDAR wind field measurements against the standard anemometer measurements from the meteorological masts. The most attractive capability of the scanning LIDAR is the ability to provide high spatial resolution observations in a three-dimensional volume which provides superior statistical accuracy due to the large number of samples obtained. Each radial scan provides measurements in 100 range gates over a distance of 10 to 12 km at an update rate of 5 to 10 Hz and rotation of 2.5° per second. Each rotation at a fixed azimuth requires 2.4 minutes. Depending on the number of azimuths desired a complete scan can take up to 10 minutes or longer to complete. Once collected the radial velocities are processed to produce vector wind velocity estimates based on a set of data distributed in angle and range around points of interest, typically a standard grid within the radial wind map. To calculate wind vectors over a limited spatial area of interest for the comparison of data with other measurement platforms a localized least-squares approach has been applied by Hannon et.al. (2008) and a Variation Assimilation (VAR) processing technique has been applied by Chan and al Assimilation (VAR) processing technique has been applied by Chan and Shao (2006). Additionally, Kelley et.al. (2007) applied a “stare” technique that fixed a scanning LIDAR in both azimuth and elevation angles to measure over collocated sampling volumes of the LIDAR and a 3D sonic anemometer mounted to a fixed mast. Although the stare technique is limited to wind directions aligned with the sampling radial of the LIDAR, it does provide a direct comparison of sampling volumes. Each of the processing techniques described above (and possibly others) will be evaluated to determine the validity of the LIDAR derived wind fields in the marine environment. Numerical methods such as linear regression and comparison of probability density functions of wind fields measured by each instrument platform will be used to assess the processing techniques. Linear regression has the advantage of directly evaluating corresponding pairs of wind data measured by each instrument and can lend insight into deviations and bias between instruments as a function of wind speed. Assessment of the coherency between the probability density function of the wind measured by each instrument provides insight into processes that may not be accurately resolved by each instrument at specific frequencies. Once processed and assessed the most appropriate technique will be utilized to provide valid wind measurements from the pulsed scanning LIDAR. A detailed analysis of the measurement data from the LIDAR and the three meteorological towers and comparison of the coastal wind characteristics from the different systems will be performed by the CO_PI at NREL. This analysis will evaluate how the WT LIDAR performance and measurement of the wind characteristics vary with distance from the LIDAR and by atmospheric conditions; using the tower measurements at different distances (4.8, 9.6, and 19 km) from the LIDAR as a reference. The comparative analysis will include, to the extent possible, evaluation of parameters such as wind speed and direction distributions, wind shear, turbulence intensity and their variations by atmospheric conditions, month or season, and time of day.

17 WIND ENERGY↗

An alpha-synuclein MRM assay with diagnostic potential for Parkinson's disease and monitoring disease progression

Aim: The alpha-synuclein (α-syn) level in human cerebrospinal fluid (CSF), as measured by immunoassays, is promising as a Parkinson’s disease (PD) biomarker. However, the levels of total α-syn are inconsistent among studies with large cohorts and different measurement platforms. Total α-syn level also does not correlate with disease severity or progression. Here, we developed a highly sensitive Multiple Reaction Monitoring (MRM) method to measure absolute CSF α-syn peptide concentrations without prior enrichment or fractionation, aiming to discover new candidate biomarkers. Results: Six peptides covering 73% of protein sequence were reliably identified, and two were consistently quantified in cross-sectional and longitudinal cohorts. Absolute concentration of α-syn in human CSF was determined to be 2.1ng/mL. A unique α-syn peptide, TVEGAGSIAAATGFVK (81-96), displayed excellent correlation with previous immunoassay results in two independent PD cohorts (p < 0.001), correlated with disease severity, and its changes significantly tracked the disease progression longitudinally. Conclusions: An MRM assay to quantify human CSF α-syn was developed and optimized. Sixty clinical samples from cross-sectional and longitudinal PD cohorts were analyzed with this approach. Although further larger-scale validation is needed, the results suggest that α-syn peptide could serve as a promising biomarker in PD diagnosis and progression.

60 APPLIED LIFE SCIENCES↗

Sensor cost-effectiveness analysis for data-driven fault detection and diagnostics in commercial buildings

Data-driven building fault detection and diagnostics (FDD) is heavily dependent on sensors. However, common sensors from Building Automation Systems are not optimized to maximize accuracy in FDD. Installing additional sensors that provide more detailed building system information is key to maximizing the performance of FDD solutions. Here in this paper, we present a sensor cost analysis workflow to quantify the economic implications of installing new sensors for FDD using the concept of sensor threshold marginal cost (STMC). STMC does not represent actual sensor cost. Rather, it represents a target cost based on the economic benefit that would be realized through improved FDD performance and one or more specified economic criteria. We calculate STMCs for multiple possible fault types and use fault prevalence information to aggregate STMCs into a single dollar value to determine the cost-effectiveness of a potential sensor investment. We conducted a case study using Oak Ridge National Laboratory's Flexible Research Platform (FRP) test facility as a reference. The case study demonstrates the feasibility of the analysis and highlights the key cost considerations in sensor selection for FDD. The results also indicate that identifying and installing the few key sensor(s) is critical to cost-effectively improve FDD performance.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

BCL: A Cross-Platform Distributed Data Structures Library

One-sided communication is a useful paradigm for irregular parallel applications, but most one-sided programming environments, including MPI's one-sided interface and PGAS programming languages, lack application-level libraries to support these applications. We present the Berkeley Container Library, a set of generic, cross-platform, high-performance data structures for irregular applications, including queues, hash tables, Bloom filters and more. BCL is written in C++ using an internal DSL called the BCL Core that provides one-sided communication primitives such as remote get and remote put operations. The BCL Core has backends for MPI, OpenSHMEM, GASNet-EX, and UPC++, allowing BCL data structures to be used natively in programs written using any of these programming environments. Along with our internal DSL, we present the BCL ObjectContainer abstraction, which allows BCL data structures to transparently serialize complex data types while maintaining efficiency for primitive types. We also introduce the set of BCL data structures and evaluate their performance across a number of high-performance computing systems, demonstrating that BCL programs are competitive with hand-optimized code, even while hiding many of the underlying details of message aggregation, serialization, and synchronization.

Brock, Benjamin↗

Low global warming potential (GWP) refrigerant supermarket refrigeration system modeling and its application

As an environmentally friendly low global warming potential (GWP) refrigerant, Carbon dioxide (CO 2 ) has continuously gained popularity and research attention as alternative refrigerant for supermarket refrigeration system. In this paper, to fulfill the increasing need of accurate Low-GWP supermarket refrigeration models for development of supervisory level control and optimization strategies, a high fidelity model is developed for CO 2 transcritical supermarket refrigeration system which includes compressor rack of low temperature (LT) compressors and medium temperature (MT) compressors, air-cooled gas cooler, evaporator, expansion valves and other auxiliary equipment. A resistance-capacity model structure is proposed to simulate the display cases. Semi-thermodynamic models are proposed to estimate reciprocating compressors volumetric efficiency and power consumption. Furthermore the zone modeling approach is used for evaporator simulation, and air-cooled gas cooler is modeled with distributed modeling method. The expansion valve simulation is based on orifice flow model. To calibrate these models, both manufacture performance data and experimental data are used. The experiments are conducted with a full instrumental CO 2 supermarket refrigeration system installed in Oak Ridge National Lab Flexible Research Platform (FRP). The simulation model can predict the system performance, including power consumption, cooling capacity, mass flow rate, temperature, and pressure, with high accuracy (within ±4%) compared to experimental data. In addition, this developed model has been used to create the system optimum high side pressure for high side expansion valve control, and to generate wide operating range simulation data for developing the batter-equivalent commercial refrigeration system model which can be used in grid interactive control development.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Real Time implementation of Artificial Intelligence compression algorithm for High-Speed Streaming Readout signals

The new generation of high-energy physics experiments plans to acquire data in streaming mode. With this approach, it is possible to access the information of the whole detector (organized in time slices) for optimal and lossless triggering of data acquisitions. With this approach, data rates, especially in large detectors, are often very high, and the network is likely to be the bottleneck for the entire Streaming Read Out system. The aim of this work is to study the implementation of a lossy compression algorithm based on Artificial Intelligence: an Autoencoder. With Machine Learning it is possible to achieve a high compression ratio and fast inference time with only a small degradation of the signals, almost negligible for the specific application. This work explores different configurations of the Autoencoder and the implementation on different hardware. Different Autoencoder configurations are explored to find the best trade-off between compression ratio and reconstruction loss, both for signals and energy spectrum. Different hardware implementations are also explored to find the best platform to achieve real-time performance for the specific application.

Rossi, Fabio (ORCID:0009000385713885)↗

Toward cities without slums: Topology and the spatial evolution of neighborhoods

The world is urbanizing quickly with nearly 4 billion people presently living in urban areas, about 1 billion of them in slums. Achieving sustainable development from rapid urbanization relies critically on creating cities without slums. We show that it is possible to diagnose systematically the central physical problem of slums—the lack of spatial accesses and related services—using a topological analysis of neighborhood maps and resolved by finding solutions to a sequence of constrained optimization problems. We set up the problem by showing that the built environment of any city can be decomposed into two types of networked spaces—accesses and places—and prove that these spaces display universal topological characteristics. We then show that while the neighborhoods of developed cities express the same common topology, urban slums fall into a different topological class. We demonstrate that it is always possible to find solutions that grow a street network in existing slums, providing universal accesses at minimal disruption and cost. We then show how elaborations of this procedure that include local preferences and reduce travel distances between places result from additional access construction. These methods are presently taking effect in neighborhoods in Cape Town (South Africa) and Mumbai (India), demonstrating their practical feasibility and emphasizing their role as a platform to enable communities and local governments to combine technical knowledge with local aspirations into contextually appropriate urban sustainable development solutions.

99 GENERAL AND MISCELLANEOUS↗

Catalytic Upgrading of Renewable Feedstock (Final Technical Report)

The goal of this DOE-funded project was to investigate the fundamental science related to the development of homogeneous (de)hydrogenation catalysts in order to enable energy-relevant transformations of bio-relevant chemical feedstocks including ethanol. The primary focus was to improve the activity of ethanol upgrading catalysts, specifically informed through mechanistic studies, in order to enable rational design optimization strategies. Following in depth mechanistic studies, targeted reaction optimization approaches included ligand redesign to improve catalyst stability, developing new carbon-carbon bond forming reactions using ethanol as a precursor, and examining photochemically-mediated reactions, ultimately to integrate within other reactor designs such as continuous flow reactors. The high modularity of the catalyst components (ligands) has enabled the preparation and analyses of multiple catalyst precursors. These studies uncovered an unexpectedly beneficial substitution pattern of the ligand structure that led to the development of new catalysts that are the best in class for upgrading ethanol to butanol with a turnover number of 155,890 and a turnover frequency of 12,690 h –1 . In addition to upgrading ethanol to butanol, cascade reaction sequences were developed to form new C-C bonds using ethanol as a bio-relevant feedstock, providing access to platform chemicals from renewable sources. As part of the reaction discovery process, new mechanistic details were uncovered that provided insights into: a) catalyst speciation, b) decomposition pathways, c) carbon monoxide releasing pathways, and d) carbon-carbon and carbon hydrogen bond breaking pathways. Most of these outcomes were previously not known; however, they provide important directions for new catalyst design strategies. Finally, use of high throughput and in situ photochemical reaction analyses enabled detailed studies into changes to the catalyst structure upon irradiation. Irradiation was found to improve hydrogen transfer catalysis, by promoting a ligand dissociation event.

09 BIOMASS FUELS↗

Comparative Analysis of HEATNETS for Geothermal Network Performance

Thermal energy networks (TENs), also known as 5th generation district energy systems, or more specifically geothermal networks when exchanging heat with geothermal boreholes, are an important technology for decarbonization. In these networks an ambient loop connects buildings and thermal sources, such as a borehole field, to exchange energy and maintain a desired loop temperature. Water-source heat pumps are used at the buildings to connect to the ambient or thermal loop to meet to the building heating and cooling loads and maintain comfort. A semi-transient, reduced-order technical model and techno-economic model, called HEATNETS, has been developed at NREL that captures the flow of energy around a TEN. In this work, a comparison of the HEATNETS technical model and a well-known coding platform used for modeling geothermal networks, TRNSYS, has been completed for a proposed geothermal network as a verification and validation process. Hourly data provided from the TRNSYS simulation included building loads, pumping power, heat pump power, temperature entering and leaving the borehole field, and mass flow rates. The hourly borehole temperatures were used to create a linear regression model utilized in HEATNETS to estimate the borehole field heat exchange. The building loads and mass flow rates were direct inputs to HEATNETS while the pumping power, heat pump power, borehole temperatures, and coefficients of performance were all simulated and calculated by HEATNETS, allowing for direct comparison of the thermal energy transfer HEATNETS considers the full process from design inputs to economic outputs and can provide modeling options for high-level initial system design and operational optimization. This study focuses on a validation of HEATNETS using results from TRNSYS. HEATNETS is not intended to replace other modeling tools, but this work demonstrates, via a comparison with an industry standard code, that HEATNETS can be a unique, high-level and rapid modeling tool for estimating the performance of a full geothermal network system.

15 GEOTHERMAL ENERGY↗

An operation verification strategy against network attack of DCS in nuclear power plant - 323

Digital Instrumentation and control (I and C) system serves as the 'senses and nervous system' of a nuclear power plant (NPP). It plays an important role in the safe and economic operation in the NPPs. Digital I and C system has a series of advantages compared with analogue ones, but the introduction of the operation system platform, the application software, and the network communication structure are causing security risk to the power plant. Different kinds of procedures have already been adopted against these risks such as the communication isolation, but the security attacks still occur from time to time in the industrial fields around the world. This paper presents two computer security methods based on the thought of software verification and validation with step-by-step operation identification. First, three scenarios of security attack are proposed according to the structure of a distributed control system (DCS). Then a method with two network bypasses and a security computer are adopted to obtain the operation commands, the actuation signal, and the operation feedback in case of the first two scenarios by identifying the consistency of the obtained data. Furthermore, the method is optimized by combining the operation procedure and the camera shot to identify the anomaly of the information flow, thus to improve the effectiveness against the computer security issues. In the end, the influence and feasibility of this method is discussed. (authors)

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Non-Gaussian photonic state engineering with the quantum frequency processor

Non-Gaussian quantum states of light are critical resources for optical quantum information processing, but methods to generate them efficiently remain challenging to implement. Here we introduce a generic approach for non-Gaussian state production from input states populating discrete frequency bins. Based on controllable unitary operations with a quantum frequency processor, followed by photon-number-resolved detection of ancilla modes, our method combines recent developments in both frequency-based quantum information and non-Gaussian state preparation. Leveraging and refining the K-function representation of quantum states in the coherent basis, we develop a theoretical model amenable to numerical optimization and, as specific examples, design quantum frequency processor circuits for the production of Schrödinger cat states, exploring the performance tradeoffs for several combinations of ancilla modes and circuit depth. Our scheme provides a valuable framework for producing complex quantum states in frequency bins, paving the way for single-spatial-mode, fiber-optic-compatible non-Gaussian resources.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Design and Demonstration of a NH3-Fueled Two-Stroke Uniflow Engine for Greenhouse Gas Reduction

The maritime shipping industry is growing increasingly interested in both low and non-carbon-containing fuels to meet future greenhouse gas emission targets. Specifically of interest is ammonia, as it has a relatively high volumetric energy density compared to other future fuels, such as hydrogen, making it more economical to transport. The robust engine architecture of low-speed two-stroke marine engines makes them an ideal candidate for ammonia fuel, overcoming many of the issues surrounding its poor ignitability and low flame speed. If emissions and fueling system challenges can be addressed, retrofits of current low-speed two-stroke dual-fuel engines represent a viable pathway for bringing ammonia engines to market. This study explores these technical hurdles by describing the design, analysis, and experimental validation of a single cylinder research engine converted to operate on ammonia fuel. The engine is a reduced-scale uniflow two-stroke marine engine with two previous hardware configurations available – diesel and high-pressure CNG dual-fuel. A concept study was used to evaluate possible ammonia-fueled engine architectures and the associated tradeoffs and design considerations. With the chosen architecture, low-pressure dual fuel, 1D and 3D analysis tools were used to inform hardware selection and to determine hardware configurations which minimized ammonia-slip. In addition to these considerations the hardware and engine configuration were designed to provide a versatile and robust testing platform. This includes options to test both gaseous and liquid ammonia injection, as well as a wide range of performance parameters such as AFR, swirl, valve timing, SOI, and many others. Design constraints imposed by the existing engine hardware necessitated an iterative loop between design and analysis toolsets, ultimately converging on a final design for the ammonia-conversion hardware. The engine was rebuilt with the new hardware and evaluated in an engine test cell. A new control strategy developed and flashed onto a prototyping electronic control unit allowed for full control over all engine parameters. An initial calibration was developed, providing test data for validation of the engine 1D and 3D models. The impact of the design choices on engine operability and the ability to meet program targets is discussed as well as opportunities for further optimization of the ammonia-conversion hardware, informed by the validated models.

Kaul, Brian [ORNL] (ORCID:0000000184813620)↗

EVI-EnSitePy (Electric Vehicle Infrastructure – Energy Estimation and Site Optimization Tool in Python) [EVI-X Modeling Suite] [SWR-25-07]

EVI-EnSitePy is a comprehensive agent-based tool designed for the analysis and design of high-power charging sites, encompassing a wide array of site agents including Electric Vehicles (EVs), chargers, energy storage units (ESS), renewable energy resources (DER), and loads. This versatile tool offers diverse functionalities and a modular modeling approach, allowing detailed configuration of agents based on power ratings, port numbers, energy capacities, demand requirements, charger interfaces, and flexibility to customize the tool for project specific goals. By simulating agent interactions and employing various metrics, EVI-EnSitePy enables the assessment of site performance, exploration of energy management systems (EMS), and implementation of innovative EV charging policies. Utilizing EV charge schedules and arrival states, the tool performs thorough charging site simulations, with outputs consisting of agent and site-level power profiles and statistical metrics. Employing a tree graph structure, EVI-EnSitePy supports nested site structures and power distribution modeling. The tool's ability to generate charging schedules deterministically or via stochastic analysis further enhances its versatility. Through its features and capabilities, EVI-EnSitePy offers a powerful platform for informed decision-making in the realm of high-power charging site design and operation.

Jackson, Derek [National Renewable Energy Laborato↗

A Novel Platform for Algal Biomass Production Using Cellulosic Mixotrophy (CeMix) (Final Technical Report)

This novel project, branded CeMIX for cellulosic mixotrophy, targets solutions for several technological barriers limiting the deployment of algae cultivation in sunny, arid regions (specifically the southwest United States). Opening up the region for algae cultivation could increase DOE’s resource assessments and biofuel potential for the U.S. Mixotrophic metabolism in support of liquid fuel production is completely dependent on the availability of waste organic carbon in order to avoid diversion of food resources for fuel production. The use of cellulosic sugar hydrolysate (CSH) produced via the NREL process provided a standardized carbon source for study of the underlying biochemistry and metabolic adjustments to mixotrophy. Mixotrophic metabolism uses both photosynthetic CO 2 fixation and sugar oxidation to improve biomass productivity and harvest yield. The project was high-risk, high-reward in the sense that adding organic carbon to algal cultivation is an invitation for rapid-growth, heterotrophic contaminants to overtake the culture and consume mineral nutrients needed for algal growth. To help evade this outcome the project focused on acidophilic red algae that require low pH conditions with 40-48°C optimal temperature profiles that define them as low-range thermophiles. This is the only project in the BETO portfolio to utilize extreme conditions of low pH and high operating temperatures to control pathogens and competitors in mass culture. The project yielded five major outcomes. 1) Harvest densities of 5-10 g ash-free dry weight are easily achieved, providing a 10-fold reduction in water required and dewatering demand. 2) Catabolic repression of photosynthesis in G. sulphuraria is conditionally repressed by low oxygen. 3) Mixotrophic growth on cellulosic hydrolysate consumes all C6 and C5 sugars concomitant with increases in floridean starch with little change in lipid content. Protein content can be manipulated between 35 and 54 wt% by varying the C:N molar ratio from 10:1 to 20:1, respectively. 4) Mixotrophic cultures with up to 50 mM total sugar are remarkably stable at pH 2.5 and daily average reactor temperatures of 40°C. 5) Capital costs for glass tubular photobioreactors are prohibitive for liquid fuel production using a hydrothermal liquefaction processing pathway. The economic outlook for covered raceway ponds is better with a project minimum fuel selling price at $3.32 dm 3 GE -1 .

09 BIOMASS FUELS↗

ACStor: Optimizing Access Performance of Virtual Disk Images in Clouds

In virtualized data centers, virtual disk images (VDIs) serve as the containers in virtual environment, so their access performance is critical for the overall system performance. Some distributed VDI chunk storage systems have been proposed in order to alleviate the I/O bottleneck for VM management. As the system scales up to a large number of running VMs, however, the overall network traffic would become unbalanced with hot spots on some VMs inevitably, leading to I/O performance degradation when accessing the VMs. Here, we propose an adaptive and collaborative VDI storage system (ACStor) to resolve the above performance issue. In comparison with the existing research, our solution is able to dynamically balance the traffic workloads in accessing VDI chunks, based on the run-time network state. Specifically, compute nodes with lightly loaded traffic will be adaptively assigned more chunk access requests from remote VMs and vice versa, which can effectively eliminate the above problem and thus improves the I/O performance of VMs. We also implement a prototype based on our ACStor design, and evaluate it by various benchmarks on a real cluster with 32 nodes and a simulated platform with 256 nodes. Experiments show that under different network traffic patterns of data centers, our solution achieves up to 2-8 performance gain on VM booting time and VM’s I/O throughput, in comparison with the other state-of-the-art approaches.

96 KNOWLEDGE MANAGEMENT AND PRESERVATION↗

Mechanical Characteristics of SiC Coating Layer in TRISO Fuel Particles

Tristructural isotropic (TRISO) particles are considered as advanced fuel forms for a variety of fission platforms. While these fuel structures have been tested and deployed in reactors, the mechanical properties of these structures as a function of production parameters need to be investigated in order to ensure their reliability during service. Nanoindentation techniques, indentation crack testing, and half sphere crush testing were utilized in order to evaluate the integrity of the SiC coating layer that is meant to prevent fission product release in the coated particle fuel form. The results are complimented by scanning electron microscopy (SEM) of the grain structure that is subject to change as a function of processing parameters and can alter the mechanical properties such as hardness, elastic modulus, fracture toughness and fracture strength. Through utilization of these advanced techniques, subtle differences in mechanical properties that can be important for in-pile fuel performance can be distinguished and optimized in iteration with processing science of coated fuel particle production.

99 GENERAL AND MISCELLANEOUS↗

Temperature‐Dependent Crystallization in Two‐Step Perovskite Deposition Revealed by In Situ GIWAXS and Machine Learning‐Guided Analysis

The performance and stability of perovskite solar cells are strongly governed by the crystallization behavior of their active layer. In two-step sequential deposition, early-stage film formation plays a decisive role in determining final phase purity and device quality. Guided by a data-driven analysis of nearly 39 000 devices in the FAIR perovskite database, we identified solvent-mediated quenching and thermal processing as key variables affecting power conversion efficiency (PCE), particularly in two-step fabrication. Here, to investigate these effects in real time, we designed and implemented a custom-built, temperature-controlled spin-coating system, enabling precise thermal modulation during precursor deposition. Using this platform, we performed in situ GIWAXS measurements to study the crystallization dynamics of FA 0.5 MA 0.5 PbI 3 films over a temperature range of 30°C–90°C. Our results reveal a non-monotonic relationship between spin-coating temperature and α-phase formation, governed by the interplay between precursor interdiffusion, PbI 2 crystallinity, and δ-phase suppression. The custom thermal control enabled us to isolate and quantify these competing effects during the earliest stages of film formation, providing mechanistic insight into how spin-coating temperature governs both phase purity and kinetic pathways in two-step perovskite systems. Temperature-dependent SEM and photovoltaic device measurements further demonstrate that early-stage crystallization pathways directly translate into differences in morphology, charge-transport continuity, and device performance. These findings inform targeted strategies for optimizing deposition protocols to balance rapid nucleation, phase stability, and device performance.

Saadawy, Ahmed [King Fahd University of Petroleum ↗

Size‐Induced Ferroelectricity in Antiferroelectric Oxide Membranes

Abstract Despite extensive studies on size effects in ferroelectrics, how structures and properties evolve in antiferroelectrics with reduced dimensions still remains elusive. Given the enormous potential of utilizing antiferroelectrics for high‐energy‐density storage applications, understanding their size effects will provide key information for optimizing device performances at small scales. Here, the fundamental intrinsic size dependence of antiferroelectricity in lead‐free NaNbO 3 membranes is investigated. Via a wide range of experimental and theoretical approaches, an intriguing antiferroelectric‐to‐ferroelectric transition upon reducing membrane thickness is probed. This size effect leads to a ferroelectric single‐phase below 40 nm, as well as a mixed‐phase state with ferroelectric and antiferroelectric orders coexisting above this critical thickness. Furthermore, it is shown that the antiferroelectric and ferroelectric orders are electrically switchable. First‐principle calculations further reveal that the observed transition is driven by the structural distortion arising from the membrane surface. This work provides direct experimental evidence for intrinsic size‐driven scaling in antiferroelectrics and demonstrates enormous potential of utilizing size effects to drive emergent properties in environmentally benign lead‐free oxides with the membrane platform.

36 MATERIALS SCIENCE↗