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At least 1,747 records · Page 97
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Highly Catalytically Active High-spin Single-atom Iron Catalyst Supported by Catechol-containing Microporous 2D Polymer

Traditionally, Fe-SACs are prepared through energy-intense processes, which often lead to the loss of precision in structural features from the starting substrates and impeding rational design. In this work, we have described the synthesis of a unique catechol-containing porous polymer with designed features in the substrates maintained, affording atomically dispersed iron catalyst (Fe-SAC) through treatment of ferrous chloride (FeCl 2 ). An aberration-corrected scanning transmission electron microscope (AC-STEM) and synchrotron X-ray absorption spectroscopy (XAS) were employed to shed light on the local coordination geometry of the atomically dispersed iron catalyst. The resulting Fe-SAC exhibits excellent catalytic performance in reduction of nitroaromatics with highest molar K app among all Fe based catalysts.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2012

High-force NdFeB-based magnetic tweezers device optimized for microrheology experiments

We present the design, calibration, and testing of a magnetic tweezers device that employs two pairs of permanent neodymium iron boron magnets surrounded by low-carbon steel focusing tips to apply large forces to soft materials for microrheology experiments. Our design enables the application of forces in the range of 1-1800 pN to {approx}4.5 {mu}m paramagnetic beads using magnet-bead separations in the range of 0.3-20 mm. This allows the use of standard coverslips and sample geometries. A high speed camera, custom LED-based illumination scheme, and mechanically stabilized measurement platform are employed to enable the measurement of materials with viscoelastic moduli as high as {approx}1 kPa.

36 MATERIALS SCIENCE↗
DOE OSTI2020

The role of iron in magnetic damping of Mg(Al,Fe) 2 O 4 spinel ferrite thin films

© 2020 Author(s). We have investigated magnesium aluminum ferrite thin films with a range of iron concentrations and identified the optimal iron content to obtain high crystalline quality thin films with the low magnetic damping required for spin current-based applications. Epitaxial MgAl 2-x FexO4 films with 0.8 < x < 2.0 were grown by pulsed laser deposition on single crystal MgAl2O4 substrates and were characterized structurally and magnetically. We find that the x = 1.5 composition minimizes the room-temperature magnetic damping with a typical Gilbert damping parameter of α eff = 1.8 × 10-3. This minimized damping is governed by a competition between the more robust magnetic ordering with increased iron content, x, and the more defective structure due to larger film-substrate lattice mismatch with increased iron content. The temperature-dependent magnetization curves indicate that Tc is suppressed below room temperature for iron content x ≤ 1.2 and eventually suppressed entirely for x = 0.8. X-ray magnetic circular dichroism results indicate that for all x the magnetic moment is dominated by Fe 3 + cations distributed in a 60:40 ratio on the octahedral and tetrahedral sites, with minimal contribution from Fe 2 + cations. Films with x = 1.4-1.6 exhibit very strong ferromagnetic resonance and low Gilbert damping with α eff = (1.8-6) × 10-3, making them ideal candidates for microwave and spintronic applications.

36 MATERIALS SCIENCE↗
DOE OSTI2024

A magnetic‐directed micro‐particle with near‐ IR light triggered guest‐release property

Abstract In this study, guest carriers, composed of magnetic‐directed hydrogel particles with near‐infrared (NIR)‐light‐triggered guest‐release properties, are prepared via the one‐pot method. The gel particles contain photostable NIR‐responsive polypyrrole nanoparticles with temperature‐sensitive poly(N‐isopropyl acrylamide), the combination of which can induce the accelerated release of encapsulated drugs by 337% upon 5 minutes of NIR light irradiation based on the release profile of NRMG‐1 at 10–15 min. Additionally, with magnetic iron oxide particles crosslinking the polyvinyl alcohol frames, these gel particles can form a physical barrier that decreases the release rate by 20% under an external magnetic field over 24 h. The magnetic iron oxide particles also enable the gel particles to reach their target destination without extra drug losses.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2014

Individual alpha elements, C, N, and Ba in early-type galaxies

Spectral data on early-type galaxies are analyzed for chemical abundance with an emphasis on obtaining detailed abundances for the elements O and Si in addition to C, N, Na, Mg, Ca, Fe, and Ba. The abundance trends with velocity dispersion fit preconceptions based upon previous Mg conclusions, namely, that larger galaxies have a higher alpha element to iron peak ratio indicative of a higher ratio of Type II to Type Ia supernova products. The heaviest alpha elements, Ca and Ti, do not participate in this trend, although this fact does not necessarily alter the basic picture given the uncertainties in nucleosynthetic yields. Elements that likely have significant contributions from intermediate-mass stars, namely, C, N, and Ba, also gain ground relative to Fe in massive galaxies at a modest level, with the Ba conclusion uncertain from our data alone. After the velocity dispersion trend is subtracted, [M/H], [N/Fe], [Na/Fe], [Mg/Fe], and [Ca/Fe] probably have cosmic scatter, and no quantity can be shown to not have cosmic scatter.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Luxury iron uptake and storage in pennate diatoms from the equatorial Pacific Ocean

Abstract Iron is a key micronutrient for ocean phytoplankton, and the availability of iron controls primary production and community composition in large regions of the ocean. Pennate diatoms, a phytoplankton group that responds to iron additions in low-iron areas, can have highly variable iron contents, and some groups such as Pseudo-nitzschia, are known to use ferritin to store iron for later use. We quantified and mapped the intracellular accumulation of iron by a natural population of Pseudo-nitzschia from the Fe-limited equatorial Pacific Ocean. A total of 48 h after iron addition, nearly half of the accumulated iron was localized in storage bodies adjacent to chloroplasts believed to represent ferritin. Over the subsequent 48 h, stored iron was distributed to the rest of the cell through subsequent growth and division, partially supporting the iron contents of the daughter cells. This study provides the first quantitative view into the cellular trafficking of iron in a globally relevant phytoplankton group and demonstrates the unique capabilities of synchrotron-based element imaging approaches.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2025

Compositing and Characterization of SE Quadrant Waste Exemplars

This report outlines the experimental investigation and characterization of transport properties in Hanford SE quadrant High-Level Waste (HLW). The goal of the study was to establish baseline behaviors of bulk composite rheology and settling characteristics to facilitate waste treatment process design for the Waste Treatment and Immobilization Plant (WTP) and avoid waste conditions and properties favorable to bubble cascade gas release events. The study focused on two major objectives: 1) identifying, obtaining, and preparing relevant Hanford tank waste samples for evaluation and 2) quantifying the “as-received” rheology and transport properties of the samples. Twenty-three centrifuged core segments originating from tanks AN-101, AN-106, and AW-105 were selected based on compositional relevance to SE quadrant PUREX cladding waste. These materials were composited into five waste composites enriched with target analytes: aluminum (Al), iron (Fe), phosphate (PO 4 ), uranium (U), and zirconium (Zr). Physical property and transport testing examined particle size distributions, bulk densities, settling behaviors, rheological properties, shear strengths, and just-suspended mixing speeds (NJS). Testing revealed two distinct composite classifications based on rheological characteristics: non-Newtonian composites (Fe and PO 4 ) and Newtonian composites (Al, U, and Zr). The Fe and PO 4 composites exhibited slow settling rates and reduced mobilization proclivity, attributable to strong particle-particle interactions and the formation of yield structures within non-Newtonian slurries. In contrast, the Al, U, and Zr composites displayed rapid settling and dense compaction behaviors, indicative of minimal structuring and interactions. Shear strengths for all composites were generally low relative to prior studies of SE quadrant waste, with only the U composite showing elevated strength approaching values reported in previous literature. Repeat shear strength measurements revealed contributions from dense granular material in the U composite and stronger cohesive properties in the Al composite. Settling data highlighted hindered settling behavior, with rates falling more than one order of magnitude below estimates based on Stokes’ law and rate decreasing as composite UDS content increased. NJS testing demonstrated different mobilization behaviors between cohesive and granular composites. The Fe composite required the highest mixing rate for resuspension, while the Al composite was the easiest to resuspend. Comparison of measured NJS against predictions made using the Zwietering correlation suggests non-Newtonian behavior alters resuspension mechanics, rendering non-Newtonian systems more stable against resuspension lift forces relative to their granular counterparts.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2021

Influence of Tall Fescue Epichloë Endophytes on Rhizosphere Soil Microbiome

Tall fescue (Lolium arundinaceum (Schreb.) S.J. Darbyshire) often forms a symbiotic relationship with fungal endophytes (Epichloë coenophiala), which provides increased plant performance and greater tolerance to environmental stress compared to endophyte-free tall fescue. Whether this enhanced performance of tall fescue exclusively results from the grass–fungus symbiosis, or this symbiosis additionally results in the recruitment of soil microbes in the rhizosphere that in turn promote plant growth, remain a question. We investigated the soil bacterial and fungal community composition in iron-rich soil in the southeastern USA, and possible community shifts in soil microbial populations based on endophyte infection in tall fescue by analyzing the 16s rRNA gene and ITS specific region. Our data revealed that plant-available phosphorus (P) was significantly (p < 0.05) influenced by endophyte infection in tall fescue. While the prominent soil bacterial phyla were similar, a clear fungal community shift was observed between endophyte-infected (E+) and endophyte-free (E−) tall fescue soil at the phylum level. Moreover, compared to E− soil, E+ soil showed a greater fungal diversity at the genus level. Our results, thus, indicate a possible three-way interaction between tall fescue, fungal endophyte, and soil fungal communities resulting in improved tall fescue performance.

Mahmud, Kishan↗
NASA NTRS1971

Use of radiation in preparative chemistry

A summary and updating of previous work on the use of radiation chemistry for the preparation of pure materials are presented. Work was chiefly concerned with the reduction of metal salts in solution to the free metal using 2 MeV electrons. Metals deposited from aqueous solution are copper, silver, zinc, cadmium, thallium, tin, lead, antimony, iron, nickel, cobalt, and palladium. Dry organic solvents were evaluated for the deposition of metals based on a study involving deposition of antimony from soltions of antimony (III) chloride. The use of organic liquids for the preparation of anhydrous metal halides is also presented. Reaction mechanisms for both organic liquids and aqueous system are discussed.

Philipp, W. H.↗
NASA NTRS1972

Frequency of light-flashes induced by Cerenkov radiation from heavy cosmic-ray nuclei

The expected frequency was calculated for light flashes induced in the dark-adapted eye by Cerenkov radiation from the flux of heavy nuclei that exists in space beyond the geomagnetic field. The expected frequency of light flashes depends on the threshold number of photons that must be absorbed in a rod cluster. The results of the calculation are presented as a curve of the mean frequency of light flashes versus the threshold number of absorbed photons. The results are not sensitive to variations in the path length from 5 to 15 grams per square centimeter of water-equivalent before the nucleus reaches the retina. Calculations were based on the fluxes and energy spectra of galactic cosmic ray nuclei of helium to iron, measured at a time of minimum solar modulation. The expected light flash frequencies induced by Cerenkov radiation are consistent with the frequencies reported by the astronauts on Apollo missions 11 through 14.

Madey, R.↗
NASA NTRS1972

Viscosity of the earth's core

Estimates of the coefficient of kinematical viscosity nu of the earth's liquid metallic core that are given in the geophysical literature range from approximately 0.001 sq cm/s, the viscosity of molten iron at ordinary pressures, to approximately less than 10 to the 8th power sq cm/s, based on the observation that compressional waves traverse the core without suffering serious attenuation. Bumps on the core-mantle boundary with typical horizontal dimensions up to a few thousand km and vertical dimensions h of a few km would produce the topographic coupling between the core and mantle that is evidently implied by the observed decade variations in the length of the day (unless the coupling is due to the presence of rapidly fluctuating magnetic fields in the core).

Hide, R.↗
NASA NTRS1989

Analysis and test of insulated components for rotary engine

The direct-injection stratified-charge (DISC) rotary engine, while attractive for aviation applications due to its light weight, multifuel capability, and potentially low fuel consumption, has until now required a bulky and heavy liquid-cooling system. NASA-Lewis has undertaken the development of a cooling system-obviating, thermodynamically superior adiabatic rotary engine employing state-of-the-art thermal barrier coatings to thermally insulate engine components. The thermal barrier coating material for the cast aluminum, stainless steel, and ductile cast iron components was plasma-sprayed zirconia. DISC engine tests indicate effective thermal barrier-based heat loss reduction, but call for superior coefficient-of-thermal-expansion matching of materials and better tribological properties in the coatings used.

Badgley, Patrick R.↗
NASA NTRS1991

Tidal disruption of inviscid protoplanets

Roche showed that equilibrium is impossible for a small fluid body synchronously orbiting a primary within a critical radius now termed the Roche limit. Tidal disruption of orbitally unbound bodies is a potentially important process for planetary formation through collisional accumulation, because the area of the Roche limit is considerably larger then the physical cross section of a protoplanet. Several previous studies were made of dynamical tidal disruption and different models of disruption were proposed. Because of the limitation of these analytical models, we have used a smoothed particle hydrodynamics (SPH) code to model the tidal disruption process. The code is basically the same as the one used to model giant impacts; we simply choose impact parameters large enough to avoid collisions. The primary and secondary both have iron cores and silicate mantles, and are initially isothermal at a molten temperature. The conclusions based on the analytical and numerical models are summarized.

Boss, Alan P.↗
NASA NTRS1994

Resolving the Cygnus X-3 iron K line

An Advanced Satellite for Cosmology and Astrophysics (ASCA) observation of Cygnus X-3 on 1993 June 11, in its X-ray high intensity state, has for the first time resolved the broad iron K line emission into three components: a He-like line at 6.67 +/- 0.01 keV, a H-like line at 6.96 +/- 0.02 keV, and a neutral line at 6.37 +/- 0.03 keV. The line intensities of the 6.67 keV and 6.96 keV lines are modulated with the 4.8 hr orbital period and are maximum when the continuum intensity is minimum. There is a sharp minimum of the line intensity on the rising phase of the continuum intensity. An iron absorption edge is observed at 7.19 +/- 0.02 keV. The optical depth of the absorption edge varies from 0.3 to 0.5 and is in anti-phase with the overall X-ray continuum modulation. The observed complexity of the iron K line region is greater than that had been assumed in previous spectral modeling based on observations with lower resolution detectors.

Kitamoto, Shunji↗
NASA NTRS2015

Mineralogy of the Pahrump Hills Region, Gale Crater, Mars

The Pahrump Hills region of Gale crater is a approximately 12 millimeter thick section of sedimentary rocks in the Murray formation, interpreted as the basal geological unit of Mount Sharp. The Mars Science Laboratory, Curiosity, arrived at the Pahrump Hills in September, 2014, and performed a detailed six-month investigation of the sedimentary structures, geochemistry, and mineralogy of the area. During the campaign, Curiosity drilled and delivered three rock samples to its internal instruments, including the CheMin XRD/XRF. The three targets, Confidence Hills, Mojave 2, and Telegraph Peak, contain variable amounts of plagioclase, pyroxene, iron oxides, jarosite, phyllosilicates, and X-ray amorphous material. Hematite was predicted at the base of Mount Sharp from orbital visible/near-IR spectroscopy, and CheMin confirmed this detection. The presence of jarosite throughout Pahrump Hills suggests the sediments experienced acid-sulfate alteration, either in-situ or within the source region of the sediments. This acidic leaching environment is in stark contrast to the environment preserved within the Sheepbed mudstone on the plains of Gale crater. The minerals within Sheepbed, including Fe-saponite, indicate these sediments were deposited in a shallow lake with circumneutral pH that may have been habitable.

Rampe, E. B.↗
NASA NTRSDate not supplied

Regional variability of dust single scattering albedo due to mineral composition

Nearly all Earth System Models (ESMs) assume globally homogeneous dust aerosols, neglecting regional variations of the imaginary refractive index (IRI) due to varying mineral composition. This has led to a range of single scattering albedo (SSA) and direct radiative forcing (DRF) estimates, as models assign global properties using dust measurements from different regions. We use model and observational data to assess to what extent regionally varying mineral composition affects visible-band SSA and short-wave DRF of dust. We run global simulations with NASA GISS ModelE2.1, using optical properties for minerals based on laboratory-derived empirical relationships between dust IRI at visible wavelengths and the mineral content of iron oxides. When allowing mineral variations instead of homogeneous dust, we find regional differences in dust SSA up to ~0.06 and consequent variations in DRF up to ~6 and ~5 W/m2, at surface and top-of-atmosphere respectively. We compare model SSA with AERONET inversion data (Version 3.0, Level 2), filtered by aerosol size and optical properties to identify pure dust scenes. To investigate possible contamination by biomass burning aerosols, we use the dataset of Schuster et al. (2016, doi:10.5194/acp-16-1565-2016), who separately calculated the contribution of iron oxides and carbonaceous species to AERONET extinction and absorption optical depths. Our results show that: (1) the range of observed SSA (even without carbonaceous species) is larger than that resulting from homogeneous dust; (2) residual amounts of fine mode black and brown carbon may affect AERONET SSA even in seasons with limited biomass burning; (3) model SSA from our mineral scheme exceeds the AERONET range, possibly due also to an uncertain treatment of goethite. In summary, homogeneous dust cannot explain the variability of observed SSA, so regionally varying optical properties based on mineral content are necessary. Higher accuracy in soil mineralogy maps is needed to better reproduce SSA variations at regional scales. Also, distinct soil maps for hematite and goethite are required, given the high sensitivity of model SSA to their extreme optical properties.

V. Obiso↗
DOE OSTI2016

Identification of human ferritin, heavy polypeptide 1 (FTH1) and yeast RGI1 (YER067W) as pro-survival sequences that counteract the effects of Bax and copper in Saccharomyces cerevisiae

Ferritin is a sub-family of iron binding proteins that form multi-subunit nanotype iron storage structures and prevent oxidative stress induced apoptosis. Here we describe the identification and characterization of human ferritin, heavy polypeptide 1 (FTH1) as a suppressor of the pro-apoptotic murine Bax sequence in yeast. In addition we demonstrate that FTH1 is a general pro-survival sequence since it also prevents the cell death inducing effects of copper when heterologously expressed in yeast. Although ferritins are phylogenetically widely distributed and are present in most species of Bacteria, Archaea and Eukarya, ferritin is conspicuously absent in most fungal species including Saccharomyces cerevisiae. An in silico analysis of the yeast proteome lead to the identification of the 161 residue RGI1 (YER067W) encoded protein as a candidate for being a yeast ferritin. In addition to sharing 20% sequence identity with the 183 residue FTH1, RGI1 also has similar pro-survival properties as ferritin when overexpressed in yeast. Analysis of recombinant protein by SDS-PAGE and by electron microscopy revealed the expected formation of higher-order structures for FTH1 that was not observed with Rgi1p. Further analysis revealed that cells overexpressing RGI1 do not show increased resistance to iron toxicity and do not have enhanced capacity to store iron. In contrast, cells lacking RGI1 were found to be hypersensitive to the toxic effects of iron. Overall, our results suggest that Rgi1p is a novel pro-survival protein whose function is not related to ferritin but nevertheless it may have a role in regulating yeast sensitivity to iron stress. - Highlights: • Human ferritin, heavy polypeptide 1 (FTH1) was identified as a suppressor of the pro-apoptotic Bax in yeast. • Based on its similarity to ferritin we examined Rgi1p/YER067W for potential ferritin like functions. • Like human H-ferritin, RGI1 confers increased resistance to apoptotic inducing stresses in yeast. • Rgi1p is a pro-survival protein that is not a ferritin but that may play a role in iron metabolism of yeast.

60 APPLIED LIFE SCIENCES↗