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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,747 records · Page 97
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Complementary dispersive mirror pair produced in one coating run based on desired non-uniformity

We report a novel one-coating-run method for producing an octave-spanning complementary dispersive mirror (DM) pair. The anti-phase group delay dispersion (GDD) oscillations are realized by two mirrors of the DM pair due to the certain thickness difference. Both mirrors are deposited within a single coating run enabled by the non-uniformity of the ion beam sputtering coating plant, which is obtained by tuning the distance between the source target and coating substrates. Since the DM pair is produced in a single deposition run, the GDD performance is more robust against deposition errors than that of the conventional complementary DM pair, in which two separated coating runs are necessary. Moreover, the new DM pair is compatible for both laser polarizations under the same angle of incidence, which could effectively reduce the difficulties of alignment for their implementation in laser systems than the double angle DM pair. The new DM pair is successfully applied to compress pulses from a Ti: Sapphire laser system down to 4.26 fs in pulse duration.

47 OTHER INSTRUMENTATION↗
DOE OSTI2023

Evaluating E. coli genome‐scale metabolic model accuracy with high‐throughput mutant fitness data

Abstract The Escherichia coli genome‐scale metabolic model (GEM) is an exemplar systems biology model for the simulation of cellular metabolism. Experimental validation of model predictions is essential to pinpoint uncertainty and ensure continued development of accurate models. Here, we quantified the accuracy of four subsequent E. coli GEMs using published mutant fitness data across thousands of genes and 25 different carbon sources. This evaluation demonstrated the utility of the area under a precision–recall curve relative to alternative accuracy metrics. An analysis of errors in the latest (iML1515) model identified several vitamins/cofactors that are likely available to mutants despite being absent from the experimental growth medium and highlighted isoenzyme gene‐protein‐reaction mapping as a key source of inaccurate predictions. A machine learning approach further identified metabolic fluxes through hydrogen ion exchange and specific central metabolism branch points as important determinants of model accuracy. This work outlines improved practices for the assessment of GEM accuracy with high‐throughput mutant fitness data and highlights promising areas for future model refinement in E. coli and beyond.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2021

Half-Metal Spin Filter for Highly Polarized Emission from GaAs Photocathodes

GaAs-based photocathodes are one of the major sources of spin-polarized electrons and are crucial for the upcoming Electron-Ion collider experiments which includes study of proton spin and spin parity violation in the standard model. The theoretical polarization limit in unstrained GaAs photocathodes is 50 % but only 35 % is routinely achieved in experiments. Spin selective filtering allows to boost the spin polarization beyond the 50 % theoretical limit. In this work, first-principle electronic calculations using standard Density Functional Theory are performed to predict possible Heusler alloy half-metal candidates to be used as spin-filter. Simulations are also performed to investigate the half-metallicity as function of the magnetic spin direction. Several devices are experimentally fabricated using dedicated Molecular Beam Epitaxy growth system. We implemented Quantum Efficiency and Polarization testing of these half-metal/GaAs heterostructures using a dedicated Mott polarimeter system. Photoemission can also be seen on magnetically switching the spin-filter direction accompanied by a change in sign of the asymmetry which is a qualitative proof of the spin-filtering effect.

Poddar, S.↗
DOE OSTI2023

Poly(oxymethylene) Ethers as a High Cetane, Low Sooting Biofuel Blendstock for Use in Medium to Heavy Duty Mixing Controlled Compression Ignition Engines

Compression ignition (CI) engines are currently the most common prime mover for medium and heavy duty vehicles; these engines contribute roughly a quarter of US greenhouse gas emissions from transportation, and even higher percentages of particulate and nitrogen oxide emissions. As a result, there have been significant efforts made to reduce these emissions, particularly through selection of low-emissions alternative fuels. Oxymethylene ethers (OMEs) are a class of molecule, typically structured R-O-(CH2O)n-R', which have been considered as a possible blendstock in CI fuels for the goal of soot reduction. Generally, past work has focused on methyl-terminated OMEs, CH3-O-(CH2O)n-CH3, which by virtue of containing no C--C bonds, produce negligible soot. These molecules show significant reductions in soot emission from engines when blended in moderate to high ratios with traditional diesels, however, they have been shown to have inferior physical properties and poor compatibility with some legacy systems. Recent theoretical work has shown that OMEs with non-methyl alkyl groups may have superior performance, albeit at the cost of increased soot formation. In this work, a variety of OMEs with terminating alkyl groups from methyl to butyl are considered for their suitability as CI fuels. The synthesis of these extended OMEs is studied, including formation of n=1 OMEs from common chemical sources, and extension of the chain length to heavier molecules, via reactions over acidic ion exchange resins. Following the synthesis, the properties of these OMEs are studied with respect to their engine applicability. It is found that heavier (propyl- and butyl-terminated) OMEs have superior properties for diesel compatibility, particularly in reactivity, volatility, and water solubility. Extended-alkyl OMEs are found to have higher soot production than methyl-terminated OMEs, but remain superior to diesel soot production on a per-unit-energy basis. A sample of a butyl-terminated OME mixture, n=2-4, is selected as the ideal OME blend for close compatibility with legacy diesel systems. This mixture is blended with certified diesel and tested for ASTM D975 compatibility, passing all required tests but lubricity; decreased heat of combustion is observed but not governed by the diesel standard. Fundamental combustion tests of various mid-weight OMEs are performed in a rapid compression machine, where it is shown that low-temperature chemistry causes a region of decreased dependence of ignition delay on temperature, consistent with methyl-terminated OME behavior. An isopropyl-terminated OME is observed to have low reactivity compared to other OMEs; this fuel is investigated via further rapid compression machine testing and CFR engine testing. It is found that this OME has strong negative-temperature-coefficient ignition behavior - a first for OMEs - and has reactivity lower than other OMEs, but insufficient for direct spark ignition engine testing.

09 BIOMASS FUELS↗
NASA NTRS1976

A.t.m. observations on the X u.v. emission from solar flares

The paper summarizes observations of selected solar flares made with a far-UV spectroheliograph (190-465 A) and a UV spectrograph (900-1900 A) aboard Skylab. The emission lines used in the present analysis are identified, and three events are described in detail: the flare of June 15, 1973, a small subflare observed on August 9, 1973, and the flare of January 21, 1974. Ultraviolet images of two other events are also presented in an attempt to sketch a general picture of a flare as seen in this spectral region. It is found that a small kernel seems to be the source of the primary energy release of a flare. The size, electron density, and ion temperature of a typical kernel are estimated, and it is noted that hot clouds of coronal gas at 20 million K surrounded the observed kernels. It is speculated that flare kernels might be very thin channels through which high-energy particles, originating in deep layers, are ejected into the corona.

Brueckner, G. E.↗
NASA NTRS1977

Limitations to growth of microorganisms on Uranus, Neptune, and Titan

Reappraisal of the probabilistic policy toward planetary contamination by terrestrial microorganisms carried aboard space probes is suggested on the grounds that assignment of numerical probabilities to qualitatively unknown phenomena, as expressed in Phillips's (1974) formulation of the probability of contamination, is inappropriate. As an alternative, it is proposed that fundamental knowledge of the interacting nature of life on earth, interrelations between terrestrial organisms, and continuing effects of these organisms on earth's atmosphere and surface should guide the formulation of a sounder scientific quarantine policy. Simple conservative atmospheric models most favorable for life on Uranus and Neptune are examined. It is concluded that terrestrial microorganisms will not grow on either planet due to limitations of liquid water, atmospheric convection to lethal depths, the absence of energy sources and nutrients, the presence of ammonia and hydrogen, insufficient concentrations of biologically necessary ions, and the lack of a surface. The likelihood of terrestrial microorganism growth on Titan is found to be vanishingly small.

Margulis, L.↗
NASA NTRS1982

Energetic O/+/ precipitation

Fluxes of energetic O(+) ions are often observed precipitating into the atmosphere and are possibly a significant energy source for the ionosphere and thermosphere. Models of these events indicate that most of the energy of such an O(+) beam is deposited as neutral heat at F region heights and a significant escape flux of O atoms results. The distribution of this heating with altitude, however, has a major effect on the type and significance of the aeronomical consequences that it can initiate. The particulars of this distribution are very sensitive to the cross sections and scattering parameters used in the modeling. A comparison of hard sphere and classical elastic parameters indicates that using the latter, more realistic formulation not only results in a more penetrating beam but reduces the escape flux by as much as a factor of 2 over the hard sphere treatment.

Kozyra, J. U.↗
NASA NTRS1983

Photochemistry of N2(+) in the daytime F region

The photochemistry of N2(+) in the daytime F region continues to be a source of concern due primarily to the uncertain roles of the metastable O+(2D) ion and possible vibrational excitation. This investigation adopts a unique subset of data from the Atmospheric Explorer C satellite that spans distinct regions near the low-latitude F peak wherein either chemical reactions or electron processes alternatively control the N2(+) abundances. Concentrations of N2(+) calculated according to current theory and including recent laboratory data for O+(2D) losses via N2 are found to exceed ionospheric observations between 220 and 400 km by a factor near 2. Relevant characteristics of the basic molecular ion concentration measurements are described, along with an analysis for select orbits conducted according to current photochemical equilibrium theory. Possible simple modifications of this theory are discussed in terms of the constraints suggested by the nature of the observations.

Breig, E. L.↗
NASA NTRS1983

Nitrogen escape from Mars

The escape rate of nitrogen from Mars is calculated to be 2.3 x 10 to the 5th per sec for low solar flux conditions and 8.9 x 10 to the 5th per sec for high solar flux conditions. The major source of energetic atoms is dissociative recombination of ground state and vibrationally excited N2(+) ions. The measured N-15/N-14 isotope ratio can be reproduced by postulating an early dense atmosphere during which little differentiation occurred.

Fox, J. L.↗
NASA NTRS1985

Energy deposition rates by charged particles

A summary of measurements of the precipitation of electrons and positive ions (in the keV-MeV range) detected aboard eight rockets launched within the Energy Budget Campaign from Northern Scandinavia is given, together with corresponding satellite data. In some cases strong temporal variations of the downgoing integral fluxes were observed. The fluxes provide the background for the calculated ion production rates and altitude profiles of the energy deposition into the atmosphere at different levels of geomagnetic disturbance and cosmic noise absorption. The derived ion production rates by eneretic particles are compared to other night-time ionisation sources.

Torkar, K. M.↗
NASA NTRS1987

A theoretical comparison of internal gravity wave propagation and dissipation in high and low temperature thermospheres Implications for orbiting spacecraft

In this paper the propagation and dissipation characteristics of a number of individual internal gravity waves are discussed and compared by using a multilayer, time-averaged model in which the waves lose energy due to viscous, thermal conduction and ion-drag dissipation. From this both the height and horizontal distance (from an assumed 'source') at which the waves achieve a maximum density amplitude may be determined. Such calculations are performed for both a very hot and a very cold thermosphere, and the subsequent differences in the wave characteristics and their relation to the control of orbiting spacecraft for each of these is discussed.

Hickey, M. P.↗
NASA NTRS1987

DE 1 observations of theta aurora plasma source regions and Birkeland current charge carriers

Detailed analyses of the DE 1 high-altitude plasma instrument electron and ion data have been performed for four passes during which theta auroras were observed. The data indicate that the theta auroras occur on what appear to be closed field lines with particle signatures and plasma parameters that are quite similar to those of the magnetospheric boundary plasma sheet. The field-aligned currents computed from particle fluxes in the energy range 18-13 keV above the theta auroras are observed to be generally downward on the dawnside of the arcs with a narrower region of larger (higher density) upward currents on the duskside of the arcs. These currents are carried predominantly by field-aligned beams of accelerated cold electrons. Of particualr interest in regions of upward field-aligned current are downward electron beams at energies less than the inferred potential drop above the spacecraft.

Menietti, J. D.↗
NASA NTRS1990

Role of hot oxygen in Venusian ionospheric ion energetics and supersonic antisunward flow

The column heating rate of the dayside Venus ionospheric ion gas resulting from transfer of energy from the hot oxygen component of the neutral atmosphere is estimated and found equal to that which, when inserted into ionospheric models at the ionopause, raises the calculated temperature to measured values. The transfer of energy is effected through resonant charge exchange between the relatively cold ionospheric O(+) ions and the hot oxygen neutrals. The hot oxygen density in the nightside hemisphere does not appear to play a significant role in the nightside ion energetics. The hot oxygen neutral gas flowing across the terminator from its dayside source to its nightside sink will exchange momentum with the antisunward flowing ionospheric gas. Although the flow rate of hot oxygen can be estimated only crudely, the estimated rate of deposition and absorption is comparable to that produced by the plasma pressure and should be included in numerical studies of the terminator ionospheric wind.

Knudsen, William C.↗
NASA NTRS1995

Generation Of 369.4-Nanometers Second Harmonic From A Diode Laser

Experimental laser system features polarization feedback scheme maintaining frequency lock. Generates light at wavelength of 369.4 nanometers by second-harmonic generation from 738.8-nanometers laser diode. System prototype of source of 369.4-nanometers radiation used to optically pump 2S1/2 ' 2P1/2 transition in 171Yb+ ions in lightweight, low-power trapped-ion frequency-standard apparatus.

Williams, Angelyn P.↗
NASA NTRS1995

Detectability of electrostatic decay products in Ulysses and Galileo observations of type 3 solar radio sources

Recent in situ Ulysses and Galileo observations of the source regions of type 3 solar radio bursts appear to show an absence of ion acoustic waves S produced by nonlinear Langmuir wave processes such as the electrostatic (ES) decay, in contradiction with earlier ISEE 3 observations and analytic theory. This letter resolves these apparent contradictions. Refined analyses of the maximum S-wave electric fields produced by ES decay and of the characteristics of the Ulysses Wave Form Analyzer (WFA) instrument show that the bursty S waves observed by the ISEE 3 should be essentially undetectable by the Ulysses WFA. It is also shown that the maximum S-wave levels predicted for the Galileo event are approximately less than the instrumental noise level, thereby confirming an earlier suggestion. Thus, no contradictions exist between the ISEE 3 and Ulysses/Galileo observation, and no evidence exists against ES decay in the published Ulysses and Galileo data. All available data are consistent with, or at worst not inconsistent with, the ES decay proceeding and being the dominant nonlinear process in type 3 bursts.

Cairns, Iver H.↗
NASA NTRS2002

Variable Specific Impulse Magnetoplasma Rocket Engine

An engine is disclosed, including a controllable output plasma generator, a controllable heater for selectably raising a temperature of the plasma connected to an outlet of the plasma generator, and a nozzle connected to an outlet of the heater, through which heated plasma is discharged to provide thrust. In one embodiment, the source of plasma is a helicon generator. In one embodiment, the heater is an ion cyclotron resonator. In one embodiment, the nozzle is a radially diverging magnetic field disposed on a discharge side of the heater so that helically travelling particles in the beater exit the heater at high axial velocity. A particular embodiment includes control circuits for selectably directing a portion of radio frequency power from an RF generator to the helicon generator and to the cyclotron resonator so that the thrust output and the specific impulse of the engine can be selectively controlled. A method of propelling a vehicle is also disclosed. The method includes generating a plasma, heating said plasma, and discharging the heated plasma through a nozzle. In one embodiment, the nozzle is a diverging magnetic field. In this embodiment, the heating is performed by applying a radio frequency electro magnetic field to the plasma at the ion cyclotron frequency in an axially polarized DC magnetic field.

Franklin R Chang-Diaz↗
NASA NTRS2003

Microbatteries for Combinatorial Studies of Conventional Lithium-Ion Batteries

Integrated arrays of microscopic solid-state batteries have been demonstrated in a continuing effort to develop microscopic sources of power and of voltage reference circuits to be incorporated into low-power integrated circuits. Perhaps even more importantly, arrays of microscopic batteries can be fabricated and tested in combinatorial experiments directed toward optimization and discovery of battery materials. The value of the combinatorial approach to optimization and discovery has been proven in the optoelectronic, pharmaceutical, and bioengineering industries. Depending on the specific application, the combinatorial approach can involve the investigation of hundreds or even thousands of different combinations; hence, it is time-consuming and expensive to attempt to implement the combinatorial approach by building and testing full-size, discrete cells and batteries. The conception of microbattery arrays makes it practical to bring the advantages of the combinatorial approach to the development of batteries.

West, William↗
NASA NTRS2022

The First Gradual Solar Energetic Particle Event With an Enhanced He-3 Abundance on Solar Orbiter

The origin of 3 He abundance enhancements in gradual solar energetic particle (SEP) events remains largely unexplained. Two mechanisms have been suggested: the reacceleration of remnant flare material by coronal mass ejection (CME)-driven shocks in interplanetary space, and concomitant activity in the corona. We explore the first gradual SEP event with enhanced 3 He abundance that was observed by Solar Orbiter. The event started on 2020 November 24 and was associated with a relatively fast halo CME. During the event, the spacecraft was at 0.9 au from the Sun. The event-averaged 3 He/ 4 He abundance ratio is 24 times higher than the coronal or solar wind value, and the timing of the 3He intensity was similar to that of other species. We inspected available imaging, radio observations, and the spacecraft magnetic connection to the CME source. The most probable cause of the enhanced 3He abundance apparently are residual 3He ions remaining from a preceding long period of 3 He-rich SEPs on 2020 November 17–23.

Solar particle emission↗