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DOE OSTI2025

Ionization-driven competitive (recovery) process in pre-damaged KTaO 3 : A brief review

The nuclear (S n ) and electronic (S e ) energy dissipation processes have been considered to be independent and largely uncorrelated, influencing our understanding of ion–solid interaction and damage processes in the last decades. Recently, however, it has become more generally accepted that S n and S e are coupled as they interact both in time and space. To decouple these processes, separating these effects in experiments using sequential dual-beam irradiations have become accepted as the logical path to advance the understanding of complex interactions between S e and pre-existing defects that may be created from displacement events. This experimental approach has been recently applied to studies of KTaO 3 to reveal new insights into this critical research topic. Here, we offer a forward-looking and comprehensive perspective on the fundamental coupling between Se and pre-existing defects in KTaO 3 . The origins behind the competitive two-stage phase transition process leading to damage healing are revealed and discussed. Furthermore, the evidence resulting from synergistic effects is also included for comparison. Additionally, our findings are rationalized using both Se and the ion velocity as key parameters. We highlight how the inelastic thermal spike (i-TS) calculations provide insights into the nature of this coupled process and further confirm that the ion velocity effect governs annealing kinetics. This work emphasizes that through the introduction of a small amount of local disorder in materials, MeV ion irradiation (i.e., not extreme S e ) may also be one additional option in subsequent material modification and functionalization.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

DOE OSTI2020

Gasoline Engine and Fuels Offering Reduced Fuel Consumption and Emissions: Vehicle Modeling Final Report

The Gasoline Engine and Fuels Offering Reduced Fuel Consumption and Emissions (GEFORCE) project was proposed in response to the U.S. Department of Energy’s Funding Opportunity Announcement 0991 by a team made up of the members of the Coordinating Research Council (CRC) and the research staff at Oak Ridge National Laboratory (ORNL.) The project focused on investigating the potential benefits that might be attained through synergistic use of specific engine technology together with fuels formulated to represent potential directions that high-octane fuels of the future might progress. A stated objective in the DOE FOA was to demonstrate a 25% reduction in petroleum consumption through optimization of the engine technologies together with a suitable fuel. An advanced engine was constructed and used with a matrix of research fuels to investigate potential avenues for efficiency improvement. The engine incorporated technologies expected to become mainstream for boosted engines in the next 10 to 20 years. These included increased compression ratio, a two-stage turbocharger, and cooled external exhaust gas recirculation (EGR). The fuel matrix was designed to investigate impacts from research octane number (RON), volumetric ethanol content, and the final boiling point of the fuel. The engine calibration was optimized for each fuel individually and data collected to enable vehicle system modelling that projected energy consumption, fuel economy, tailpipe CO₂ emissions, and impact on petroleum consumption for an industry-average mid-size sedan. The engine calibration and data collection were carried out at IAV in Michigan and is the subject of a separate report. IAV provided the engine data to Oak Ridge National Laboratory to support the vehicle modelling portion of the project. The vehicle modelling results show the following trends: Ethanol content does have a consistently strong influence on the fuel economy results for all cycles and all fuels. Among the fuels of a nominal RON level, increasing ethanol content consistently lowers fuel economy, with the 30% ethanol fuels always providing the lowest fuel economy for a given RON level. However, in some cases the energy consumption improvement allows the 30% ethanol fuels to match the fuel economy of the ethanol-free fuel P. These observations underscore the importance of both engine efficiency and fuel volumetric energy content on vehicle fuel economy.; There was no consistent trend in the projected energy consumption results for differences in fuel T90 for all fuels and cycles. Fuel economy projections did show a consistent trend, with the higher T90 fuel providing slightly greater fuel economy when compared to the low T90 fuel of the same ethanol content. The observed trends were consistent with differences in the heating value of the fuels.; The 102-RON fuels provided reduced energy consumption and greater fuel economy for the advanced engine on all drive cycles. The engine compression ratio of 11.5 was higher than would typically be used in a turbocharged engine when 92-RON fuel use is expected. Hence, the engine experiences more efficiency degradation from knock avoidance when using the 92-RON fuels. This degradation causes the fuel economy results for the 92-RON fuels to be lower than those for the 102-RON fuels.; Fuels E and F (92-RON, 30% ethanol) are projected to achieve 10% or greater reduction in petroleum consumption, with fuels K (102-RON, 30% ethanol) and O (97 RON, 30% ethanol) achieving greater than a 20% reduction. Fuel L (102-RON, 30% ethanol) achieves greater than 25% reduction, meeting the petroleum reduction target of the project. All of the fuels that achieve 10% or greater reduction in petroleum consumption are 30% ethanol blends.; Increasing final boiling point increased fuel economy at fixed ethanol content when the 102-RON fuels were used. This trend is a result of differences in the volumetric energy content of the fuels and the projected energy consumption values for the fuels. In the case of the 102-RON fuels, increasing final boiling point also resulted in an increase in the energy content of the fuel. There was not a consistent trend between the energy content and final boiling point for the 92-RON fuels at fixed ethanol content.

33 ADVANCED PROPULSION SYSTEMS↗

DOE OSTI2025

Support for the 32 nd Annual Meeting of the Inter-American Photochemical Society

This award offset the registration and travel costs for researchers from U.S. institutions to attend the 32 nd Inter-American Photochemical Society meeting held on Jan 2-5, 2025, in Miramar Beach, Florida. The Inter-American Photochemical Society (I-APS) is a non-profit organization dedicated to promoting and disseminating knowledge and encouraging the development of fundamental and allied photochemistry throughout the Americas. The I-APS annual meeting is a particularly important tool for fulfilling this goal as it provides a welcoming venue to highlight research progress in theoretical, experimental, and applied aspects of photochemistry and molecular photophysics by researchers in all stages of their careers. The participation of graduate students and postdocs at this conference is particularly important as it aids in training the next generation of scientists in photochemistry. This award provided travel awards to three Assistant Professors and fourteen graduate and two undergraduate students to attend the I-APS Meeting in 2025. A majority of the science presented/discussed at the I-APS meeting is in direct alignment with the mission of the DOE and the Solar Photochemistry program, including studying fundamental phenomena, encompassing light absorption, photoinduced energy/electron transfer, charge separation, and charge and energy transport across mesoscale dimensions, as well as their application in generating electricity and chemical bonds using light.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS2003

An Assessment of CFD Effectiveness for Vortex Flow Simulation to Meet Preliminary Design Needs

The low-speed flight and transonic maneuvering characteristics of combat air vehicles designed for efficient supersonic flight are significantly affected by the presence of free vortices. At moderate-to-high angles of attack, the flow invariably separates from the leading edges of the swept slender wings, as well as from the forebodies of the air vehicles, and rolls up to form free vortices. The design of military vehicles is heavily driven by the need to simultaneously improve performance and affordability.1 In order to meet this need, increasing emphasis is being placed on using Modeling & Simulation environments employing the Integrated Product & Process Development (IPPD) concept. The primary focus is on expeditiously providing design teams with high-fidelity data needed to make more informed decisions in the preliminary design stage. Extensive aerodynamic data are needed to support combat air vehicle design. Force and moment data are used to evaluate performance and handling qualities; surface pressures provide inputs for structural design; and flow-field data facilitate system integration. Continuing advances in computational fluid dynamics (CFD) provide an attractive means of generating the desired data in a manner that is responsive to the needs of the preliminary design efforts. The responsiveness is readily characterized as timely delivery of quality data at low cost.

Raj, P.↗

NASA NTRS1998

Oxygen and evolutionary patterns in the sea: onshore/offshore trends and recent recruitment of deep-sea faunas

Over the last 15 years a striking pattern of diversification has been documented in the fossil record of benthic marine invertebrates. Higher taxa (orders) tend to originate onshore, diversify offshore, and retreat into deep-water environments. Previous studies attribute this macroevolutionary pattern to a variety of causes, foremost among them the role of nearshore disturbance in providing opportunities for the evolution of novel forms accorded ordinal rank. Our analysis of the post-Paleozoic record of ordinal first appearances indicates that the onshore preference of ordinal origination occurred only in the Mesozoic prior to the Turonian stage of the Cretaceous, a period characterized by relatively frequent anoxic/dysoxic bottom conditions in deeper marine environments. Later, in the Cretaceous and Cenozoic, ordinal origination of benthic organisms did not occur exclusively, or even preferentially, in onshore environments. This change in environmental pattern of ordinal origination roughly correlates with Late Cretaceous: (i) decline in anoxia/dysoxia in offshore benthic environments; (ii) extinction of faunas associated with dysoxic conditions; (iii) increase in bioturbation with the expansion of deep burrowing forms into offshore environments; and (iv) offshore expansion of bryozoan diversity. We also advance a separate argument that the Cenomanian/Turonian and latest Paleocene global events eliminated much of the deep-water benthos. This requires a more recent origin of modern vent and deep-sea faunas, from shallower water refugia, than the Paleozoic or early Mesozoic origin of these faunas suggested by other workers.

Non-NASA Center↗

NASA NTRS2011

Network Flow Simulation of Fluid Transients in Rocket Propulsion Systems

Fluid transients, also known as water hammer, can have a significant impact on the design and operation of both spacecraft and launch vehicle propulsion systems. These transients often occur at system activation and shutdown. The pressure rise due to sudden opening and closing of valves of propulsion feed lines can cause serious damage during activation and shutdown of propulsion systems. During activation (valve opening) and shutdown (valve closing), pressure surges must be predicted accurately to ensure structural integrity of the propulsion system fluid network. In the current work, a network flow simulation software (Generalized Fluid System Simulation Program) based on Finite Volume Method has been used to predict the pressure surges in the feed line due to both valve closing and valve opening using two separate geometrical configurations. The valve opening pressure surge results are compared with experimental data available in the literature and the numerical results compared very well within reasonable accuracy (< 5%) for a wide range of inlet-to-initial pressure ratios. A Fast Fourier Transform is preformed on the pressure oscillations to predict the various modal frequencies of the pressure wave. The shutdown problem, i.e. valve closing problem, the simulation results are compared with the results of Method of Characteristics. Most rocket engines experience a longitudinal acceleration, known as "pogo" during the later stage of engine burn. In the shutdown example problem, an accumulator has been used in the feed system to demonstrate the "pogo" mitigation effects in the feed system of propellant. The simulation results using GFSSP compared very well with the results of Method of Characteristics.

Bandyopadhyay, Alak↗

DOE OSTI2019

Surface structures of hybrid aligned liquid crystal network coatings containing reverse tilt domain

Controlled shape changes of polymerized liquid crystalline coatings is often achieved via prepatterning the molecular orientation of liquid crystal (LC) monomers at the stage of preparation. In this work, using the so-called hybrid alignment of the LC, we produce surface structures of positive Gaussian curvature of coatings without complex techniques such as photoalignment. A mixture of LC monomers coated onto a glass plate with planar alignment of the director is exposed to air, which promotes vertical alignment. The competing planar and homeotropic boundary conditions result in a) thickness dependent director and b) spontaneous formation of spindle-like regions, limited by disclination loops, that are called the reverse tilt domains (RTDs). Here, the disclination separates different director configurations inside and outside the RTD. The RTDs produce relatively big protrusions (100 – 600 nm) of the LC network coating. Actuation of the coating by heat increases the amplitude of RTD protrusions.

42 ENGINEERING↗

DOE OSTI2021

Analysis of the microphysical properties of snowfall using scanning polarimetric and vertically pointing multi-frequency Doppler radars

Radar dual-wavelength ratio (DWR) measurements from the Stony Brook Radar Observatory Ka-band scanning polarimetric radar (KASPR, 35 GHz), a W-band profiling radar (94 GHz), and a next-generation K-band (24 GHz) micro rain radar (MRRPro) were exploited for ice particle identification using triple-frequency approaches. The results indicated that two of the radar frequencies (K and Ka band) are not sufficiently separated; thus, the triple-frequency radar approaches had limited success. On the other hand, a joint analysis of DWR, mean Doppler velocity (MDV), and polarimetric radar variables indicated potential in identifying ice particle types and distinguishing among different ice growth processes and even in revealing additional microphysical details. We investigated all DWR pairs in conjunction with MDV from the KASPR profiling measurements and differential reflectivity (Z DR ) and specific differential phase (K DP ) from the KASPR quasi-vertical profiles. The DWR-versus-MDV diagrams coupled with the polarimetric observables exhibited distinct separations of particle populations attributed to different rime degrees and particle growth processes. In fallstreaks, the 35–94 GHz DWR pair increased with the magnitude of MDV corresponding to the scattering calculations for aggregates with lower degrees of riming. The DWR values further increased at lower altitudes while Z DR slightly decreased, indicating further aggregation. Particle populations with higher rime degrees had a similar increase in DWR but a 1–1.5 m s –1 larger magnitude of MDV and rapid decreases in K DP and Z DR . The analysis also depicted the early stage of riming where Z DR increased with the MDV magnitude collocated with small increases in DWR. This approach will improve quantitative estimations of snow amount and microphysical quantities such as rime mass fraction. The study suggests that triple-frequency measurements are not always necessary for in-depth ice microphysical studies and that dual-frequency polarimetric and Doppler measurements can successfully be used to gain insights into ice hydrometeor microphysics.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS1999

Aeroacoustic Resonance with Convergent-Divergent Nozzles

Convergent-divergent nozzles, when run at off-design conditions, often undergo flow resonance accompanied by the emission of a tone. Apart from screech occurring at higher operating pressures, resonance is also common at lower Mach numbers near transonic as well as subsonic conditions. With data from six nozzles of different size and design Mach number, the present paper documents the characteristics of the latter phenomenon that is morphologically quite different from conventional screech. The resonance is due to a feedback loop internal to the nozzle and is apparently driven by unsteady laminar boundary layer separation near the throat of the nozzle. Appropriate boundary layer tripping prior to the throat is found to eliminate or alter most of the tones. The Helmholtz number of the resonance, based on the throat-to-exit length, is found to attain a value of approximately 0.15 at M(sub j)=1 for all nozzles. However, its variation with M(sub j) may be different and depend on the nozzle geometry. With nozzles having larger throat-to-exit angle of divergence, the frequency is found to increase, in some cases having stage jumps to lower frequencies, with increasing operating pressure. With nozzles having smaller angle of divergence, the frequency variation exhibits an increase followed by a decrease involving one prominent stage occurring around transonic (M(sub j)= 1) condition. While the mechanisms remain far from completely clear, a model involving downstream propagating aerodynamic disturbance together with acoustic feedback explains the overall frequency characteristics for most cases.

Zaman, K. B. M. Q.↗

DOE OSTI2025

New K-feldspar Pb isotope results for Mesozoic arc crust in the Pacific Northwest, U.S.A. and Canada: comparison with the Mojave-Salinia province of southern California and Implications for Baja-BC

Measurements of lead isotopic compositions in detrital K-feldspar have been increasingly used as a tool to assess sediment provenance. We compiled a database of previously published Pb isotope data from 700 bedrock K-feldspar samples and 1,423 age-corrected bedrock whole rock samples from western North American igneous and metamorphic bodies. Additionally, we report 66 new K-feldspar Pb isotope data for plutons throughout the Pacific Northwest region of the United States and British Columbia. Results show that the Pb isotope values of plutonic K-feldspar depend on the isotopically juvenile or evolved nature of underlying crust. Samples obtained from the mid Cretaceous – mid Eocene Coast Plutonic Complex, North Cascades, and Intermontane superterrane that occur west of the initial 87 Sr/ 86 Sr (Sri) = 0.706 isopleth exhibit a highly restricted 207 Pb/ 206 Pb and 208 Pb/ 206 Pb values centred upon 0.83 and 2.03, respectively. Conversely, rocks overlying older continental crust further east such as the Middle Jurassic – Late Cretaceous Omineca crystalline belt, Idaho batholith, and Boulder Batholith exhibit far greater variation of Pb isotope values that parallel the 100 Ma isochron calculated from a two-stage Pb evolution model. We demonstrate that Pb isotopic results from the Idaho and Boulder Batholith region can be used to define distinctive subregions for Pb isotopic provenance analysis, and compare these signatures to the Mojave-Salinian batholith of southern California and western Arizona, as these two areas have previously been proposed as source regions for extraregional sediment that was deposited within the Nanaimo Basin during the Campanian – Maastrichtian. Future Pb isotopic analysis of detrital K-feldspar from the Nanaimo Basin of southwestern British Columbia may effectively distinguish between potential extraregional sources separated by thousands of kilometres.

Coast Plutonic Complex↗

DOE OSTI2017

FY17 end of year MARMOT materials model development update

This document summarizes the lower length scale progress made in FY17 in developing materials models for fuel performance modeling of oxide fuels and their implementation in the MARMOT code. The progress covers the development of a phase field recrystallization model for high-burnup structure formation in oxide fuels, a phase field model for studying stage-3 fission gas release in UO 2 , a phase-field model for irradiation-enhanced densification in UO 2 , a quantitative model for hydride morphology in Zirconium based cladding, and the calculation of hydrogen diffusivity under stress in various Zirconium based alloys as cladding candidates. Further development in the MARMOT code has been carried out as well to improve the multi-phase, multi-component phase field model, the representation of interfacial energy in the Kim-Kim-Suzuki model, and the description of interfacial stress. For most of the above, separated reports have been generated with detailed description. Here a brief summary is provided, with references pointing to the detailed reports to guide interested readers.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

NASA NTRS2009

Improving Regional Forecast by Assimilating Atmospheric InfraRed Sounder (AIRS) Profiles into WRF Model

In data sparse regions, remotely-sensed observations can be used to improve analyses and produce improved forecasts. One such source comes from the Atmospheric InfraRed Sounder (AIRS), which together with the Advanced Microwave Sounding Unit (AMSU), represents one of the most advanced space-based atmospheric sounding systems. The purpose of this paper is to describe a procedure to optimally assimilate high resolution AIRS profile data into a regional configuration of the Advanced Research WRF (ARW) version 2.2 using WRF-Var. The paper focuses on development of background error covariances for the regional domain and background type, and an optimal methodology for ingesting AIRS temperature and moisture profiles as separate overland and overwater retrievals with different error characteristics. The AIRS thermodynamic profiles are derived from the version 5.0 Earth Observing System (EOS) science team retrieval algorithm and contain information about the quality of each temperature layer. The quality indicators were used to select the highest quality temperature and moisture data for each profile location and pressure level. The analyses were then used to conduct a month-long series of regional forecasts over the continental U.S. The long-term impacts of AIRS profiles on forecast were assessed against verifying NAM analyses and stage IV precipitation data.

Chou, Shih-Hung↗

NASA NTRS2014

The TSO Logic and G2 Software Product

This internship assignment for spring 2014 was at John F. Kennedy Space Center (KSC), in NASAs Engineering and Technology (NE) group in support of the Control and Data Systems Division (NE-C) within the Systems Hardware Engineering Branch. (NEC-4) The primary focus was in system integration and benchmarking utilizing two separate computer software products. The first half of this 2014 internship is spent in assisting NE-C4s Electronics and Embedded Systems Engineer, Kelvin Ruiz and fellow intern Scott Ditto with the evaluation of a newly piece of software, called G2. Its developed by the Gensym Corporation and introduced to the group as a tool used in monitoring launch environments. All fellow interns and employees of the G2 group have been working together in order to better understand the significance of the G2 application and how KSC can benefit from its capabilities. The second stage of this Spring project is to assist with an ongoing integration of a benchmarking tool, developed by a group of engineers from a Canadian based organization known as TSO Logic. Guided by NE-C4s Computer Engineer, Allen Villorin, NASA 2014 interns put forth great effort in helping to integrate TSOs software into the Spaceport Processing Systems Development Laboratory (SPSDL) for further testing and evaluating. The TSO Logic group claims that their software is designed for, monitoring and reducing energy consumption at in-house server farms and large data centers, allows data centers to control the power state of servers, without impacting availability or performance and without changes to infrastructure and the focus of the assignment is to test this theory. TSOs Aaron Rallo Founder and CEO, and Chris Tivel CTO, both came to KSC to assist with the installation of their software in the SPSDL laboratory. TSOs software is installed onto 24 individual workstations running three different operating systems. The workstations were divided into three groups of 8 with each group having its own operating system. The first group is comprised of Ubuntus Debian -based Linux the second group is windows 7 Professional and the third group ran Red Hat Linux. The highlight of this portion of the assignment is to compose documentation expressing the overall impression of the software and its capabilities.

TSO Logic↗

NASA NTRS2024

Navigation Performance Overview of Gateway During a Lunar Lander Mission

Starting with Artemis IV, the human lander system (HLS) missions will utilize the Gateway as a staging point in a near rectilinear halo orbit (NRHO) between cislunar space and the lunar surface. The presence of a crew, Orion, and HLS will cause significant perturbations from docking and venting, while attitude requirements on Gateway can cause structural antenna blockage. The HLS mission timeline and perturbations are simulated considering antenna blockage to ground stations. Simulated DSN tracking data is generated and processed to produce a navigation state estimate for orbit maintenance maneuver (OMM) targeting. The starting epoch is varied to adjust tracking availability, and the volume of tracking data processed is reduced. Separately, the observability of perturbations in the NRHO with two-way tracking data is analyzed. The mission is simulated with imperfect knowledge of venting perturbations, and finally the estimation errors from propagating an estimated state from data cutoff (DCO) to maneuvers are investigated.

Clark P Newman↗

DOE OSTI2021

Midfidelity Model Verification for a Point-Absorbing Wave Energy Converter with Linear Power Takeoff: Preprint

In the preliminary design stage of a wave energy converter (WEC), fast and reliable simulation tools are required. High-fidelity numerical models are usually employed to study the wave-structure interaction, yet the computational cost is demanding. Instead, mid-fidelity models provide simulations in the order of real time. In this study, Uppsala University WEC operates in a relatively mild sea state and is modeled using WEC-Sim. The model is verified based on OpenFOAM simulations. To analyze the ability of mid-fidelity model to capture the WEC dynamics, the system is investigated separately in 1, 2 and 3 DoF. The contribution of viscous phenomena is examined. Moreover, linear and weakly non-linear solutions provided by WEC-Sim are studied. The results obtained indicate that the viscous effects in heave and surge motion can be neglected but not for the pitch. The weakly non-linear WEC-Sim solution successfully agrees with the CFD, whereas the linear solution could drive to misleading results.

CFD↗

DOE OSTI2021

Midfidelity Model Verification for a Point-Absorbing Wave Energy Converter with Linear Power Take-Off

CFD↗

DOE OSTI2016

SU-F-T-499: Anatomic Features for Selection of Electronic Tissue Compensation Radiotherapy in Early-Stage Breast Cancer Patients After Breast-Conserving Surgery

Purpose: To explore the correlations between anatomic features and dose-volumetric parameters in 3DCRT and eComp whole breast irradiation and identify the feasibility of anatomic parameters to predict the planning method selection. Methods: We compared the effectiveness between conventional three-dimensional conformal radiotherapy (3DCRT) and electronic tissue compensation (eComp) for whole breast irradiation. 3DCRT and eComp planning techniques were used to generate treatment plans for 60 whole breast patients, respectively. The planning goal was to cover 95% of the planning target volume (PTV) with 95% of the prescription dose while minimizing dose to lung, heart, and skin. Statistical analyses were performed between critical organ doses and patient anatomic features, i.e., central lung distance (CLD), maximal heart distance (MHD), maximal heart length (MHL) and breast separation (BS). Results: Comparing to 3DCRT plans, on the average, eComp treatment planning process was about 7 minutes longer, but resulted in lower lung V20Gy, lower mean skin dose, with similar heart dose. The benefits were more pronounced for larger breast patients. To keep the lung V20Gy lower than 20% and mean skin dose lower than 85% of the prescription dose, eComp was the preferred method for patients with more than 2.3 cm CLD or larger than 22.5 cm BS. Conclusion: The study results may be useful in providing a handy criterion in clinical practice allowing us to easily choose between different planning techniques to satisfy the planning goal with minimal increase in complexity and cost. This study was supported by National Natural Science Foundation of China (NO. 31420103915) and Chongqing Health and Family Planning Commission Project (2015MSXM012).

60 APPLIED LIFE SCIENCES↗

DOE OSTI2021

Unraveling the Early-Stage Ordering of Krypton Solid Bubbles in Molybdenum: A Multimodal Study

Self-organization of defects such as fission gas bubbles in materials can lead to high inventory capacity for fission gas storage and help mitigate swelling caused by fission gases in nuclear fuel materials under radiation in nuclear reactors. Here, we report the physical mechanism of self-organization of krypton (Kr) gas bubbles in molybdenum (Mo) under ion implantation. The ion fluence and temperature-dependent formation of Kr solid bubble superlattice (SBS) in Mo were investigated by using both synchrotron-based small-angle X-ray scattering (SAXS) and transmission electron microscopy (TEM). Early stage self-organization of gas bubbles is observed at a fluence of 2.5 × 10 16 ions/cm 2 at temperatures of 300–400 °C. The bubble lattice constant increases with increasing implantation temperature from 300 to 400 °C. Both experiments and atomic kinetic Monte Carlo modeling indicate that the Kr solid bubbles are weakly ordered in comparison to previously studied helium (He) gas bubble superlattice (GBS) while the lattice constant are relatively smaller for Kr SBS compared to that of He GBS. The irradiation conditions suggest that spinodal decomposition, which is a form of phase separation, probably precedes gas bubble ordering in Mo. Altogether, our work sheds light on the formation mechanism of noble gas superlattice toward the development of radiation-tolerant materials which are important for the design of advanced nuclear reactors.

36 MATERIALS SCIENCE↗