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At least 1,747 records · Page 97

Constituent properties, process, and formulation effects contributing to functional characteristics in pharmaceutical and explosive composites [Slides]

Crystal properties and defects contribute substantially to basic properties. Dip-coated films display a number of properties which are expected to be present in wet agglomeration / real formulation. Nanoindentation provides more detailed information about static dislocations and a useful simulation of real deformation processes during formulation of pressed composites. Continuum measurements are limited in what can be mechanistically determined, but we are on the verge of breakthroughs in dynamic in situ experiments!

36 MATERIALS SCIENCE↗

EDS V26 Containment Vessel Explosive Qualification Test Report

The objective of the test was to qualify the vessel for its intended use by subjecting it to a 1.25 times overtest. The criteria for success are that the measured strains do not exceed the calculated strains from the vessel analysis, there is no significant additional plastic strain on subsequent tests at the rated design load (shakedown), and there is no significant damage to the vessel and attached hardware that affect form, fit, or function. Testing of the V25 Vessel in 2011 established a precedent for testing V26 [2]. As with V25, two tests were performed to satisfy this objective. The first test used 9 pounds of Composition C-4 (11.25 lbs. TNT-equivalent), which is 125 percent of the design basis load. The second test used 7.2 pounds of Composition C-4 (9 lbs. TNT-equivalent) which is 100 percent of the design basis load. The first test provided the required overtest while the second test served to demonstrate shakedown and the absence of additional plastic deformation. Unlike the V25 vessel, which was mounted in a shipping cradle during testing, the V26 vessel was mounted on the EDS P2U3 trailer prior to testing. Visual inspections of the EDS vessel, surroundings, and diagnostics were completed before and after each test event. This visual inspection included analyzing the seals, fittings, and interior surfaces of the EDS vessel and documenting any abnormalities or damages. Photographs were used to visually document vessel conditions and findings before and after each test event.

36 MATERIALS SCIENCE↗

Ranchero Armature Test LA-43-CT-2: PBXN-110 Explosive with no smoothing layer. Lower Slobovia, 6/13/13

This test, documented as LA-43-CT-2, was performed to verify calculations which indicate that the smoothing layer employed for Ranchero Armatures is not required when the slapper point spacing is 18 mm (“On the efficacy of an acrylic layer in the Ranchero armature,” Bob Watt, published in “Ranchero Status Report” LA-14463). [Naming this test –CT-2 acknowledges the previous test performed during 1/11 as the initial test in the series, and we will refer to that test as LA-43-CT-1 in the future.] In addition, higher velocity is achieved when the volume occupied by the smoother is replaced by HE. Two framing cameras were used on the shot, and a 20 point PDV array was fielded to ascertain armature performance in specific conditions. The conclusions are that the armature is smooth enough, and the terminal velocity is increased from ~3.1 mm/μs to ~3.3 mm/μs. The armature tested had casting voids in the HE that were observed in pre-test inspections, and were expected to cause ruptures. (See Appendix 3 of the Ranchero Status Report.) Such “blowouts” were observed in all three locations identified in pre-shot inspection. In addition, ruptures occurred in locations having no pre-shot indication of a problem. These unpredicted blowouts have a difference in appearance from those typically seen. Further visual examination of the inspection radiographs do not reveal the cause, and that is a serious concern for future efforts with such castings. A path forward will include attempting to digitize the inspection x-rays for the charge tested, to see if the cause of the “new” ruptures can be found via computer enhancement. In addition, there are two additional armatures from the same casting lot, and these might also be tested to see if there is some problem with the HE or the armature material in this batch. For now, this plan is on hold, pending the outcome of tests and cost estimates related to using PBX-9501 in place of the PBXN-110. Casting issues would be eliminated in such configurations.

42 ENGINEERING↗

Explosive Products EOS: Adjustment for detonation speed and energy release

Propagating detonation waves exhibit a curvature effect in which the detonation speed decreases with increasing front curvature. The curvature effect is due to the width of the wave profile. Numerically, the wave profile depends on resolution. With coarse resolution, the wave width is too large and results in a curvature effect that is too large. Consequently, the detonation speed decreases as the cell size is increased. We propose a modification to the products equation of state (EOS) to compensate for the effect of numerical resolution; i.e., to increase the CJ pressure in order that a simulation propagates a detonation wave with a speed that is on average correct. The EOS modification also adjusts the release isentrope to correct the energy release.

97 MATHEMATICS AND COMPUTING↗

High Explosive Compatibility: Aging and Compatibility of LX-21

The tasks performed in FY14 to support our overall goals include: 1) Select a mature formulation for future aging and compatibility experiments 2) Perform gross compatibility testing for a number of LX-21/material combinations using three different evaluation techniques (DSC, TGA, and CRT) 3) Evaluate moisture sorption and diffusion characteristics of LX-21 4) Get the infrastructure and procedures in place to begin long -term accelerated aging experiments with LX-21.

36 MATERIALS SCIENCE↗

Data Analysis for Explosive Firesets [Poster]

I analyzed the data from various detonators at different initial voltages to find the RLC values (resistance, inductance, capacitance) of the fireset. The data I was given contained a current and voltage for each time value taken on nanosecond intervals. From this, I was able to make plots of several variables to try and find which if any of variables correlated with a burst or a go. These results will allow us to fully understand what is required to achieve a burst in the bridgewire so that we can know what is safe or what will never cause detonation. We may also be able to predict the outcome of using the same fireset with different detonators or with different sizes or materials of bridgewire.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Environmental Baseline Survey for Proposed Land Use Permit Modification for Expansion of the Dynamic Explosive Test Site (DETS) 9940 Main Complex Parking Lot.

The approach was to perform a document search, supplemented by a visual site inspection, to identify potential environmental contamination associated with the property. Factors evaluated included hazardous substances; petroleum products and derivatives; environmental restoration sites; areas of concern; storage tanks; oil/water separators; grease traps; wash racks; waste tanks; pesticides; military munitions/ordnance; medical or bio-hazardous waste; radioactive waste; solid/municipal waste; indoor air quality; groundwater; wastewater treatment, collection, and disposal/discharge; drinking water quality; utilities; asbestos; polychlorinated biphenyls (PCBs); radon; lead-based paint; cultural resources; floodplains; and natural/biological resources.

54 ENVIRONMENTAL SCIENCES↗

Research Performance Progress Report: Diverging Supernova Explosion Experiments on NIF

The aim of this project was to design a series of blast-wave driven Rayleigh-Taylor (RT) experiments on the National Ignition Facility (NIF). The experiments of this kind are relevant to mixing in core-collapse supernovae (ccSNe) and have the potential to address previously unanswered questions in high-energy density physics (HEDP) and astrophysics. The unmatched laser power of the NIF laser offers a unique chance to observe and study “new physics” like the mass extensions observed in HEDP RT experiments performed on the Omega laser [1], which might be linked to self-generated magnetic fields [2] and so far could not be reproduced by numerical simulations. Moreover, NIF is currently the only facility that offers the possibility to execute a diverging RT experiment, which would allow to observe processes such as inter-shell penetration via turbulent mixing and shock-proximity effects (distortion of the shock by RT spikes).

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Modeling radionuclide migration from underground nuclear explosions

The travel time of radionuclide gases to the ground surface in fracture rock depends on many complex factors. Numerical simulators are the most complete repositories of knowledge of the complex processes governing radionuclide gas migration to the ground surface allowing us to verify conceptualizations of physical processes against observations and forecast radionuclide gas travel times to the ground surface and isotopic ratios

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗