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At least 1,729 records · Page 96

NASA’s MODIS/VIIRS Global Water Reservoir Product Suite from Moderate Resolution Remote Sensing Data

Global reservoir information can not only benefit local water management but can also improve our understanding of the hydrological cycle. This information includes water area, elevation, and storage; evaporation rate and volume values; and other characteristics. However, operational wall-to-wall reservoir storage and evaporation monitoring information is lacking on a global scale. Here we introduce NASA’s new MODIS/VIIRS Global Water Reservoir product suite based on moderate resolution remote sensing data—the Moderate Resolution Imaging Spectroradiometer (MODIS), and the Visible Infrared Imaging Radiometer Suite (VIIRS). This product consists of 8-day (MxD28C2 and VNP28C2) and monthly (MxD28C3 and VNP28C3) measurements for 164 large reservoirs (MxD stands for the product from both Terra (MOD) or Aqua (MYD) satellites). The 8-day product provides area, elevation, and storage values, which were generated by first extracting water areas from surface reflectance data and then applying the area estimations to the pre-established Area–Elevation (A–E) relationships. These values were then further aggregated to monthly, with the evaporation rate and volume information added. The evaporation rate and volume values were calculated after the Lake Temperature and Evaporation Model (LTEM) using MODIS/VIIRS land surface temperature product and meteorological data from the Global Land Data Assimilation System (GLDAS). Validation results show that the 250 m area classifications from MODIS agree well with the high-resolution classifications from Landsat (R^(2) = 0.99). Validation of elevation and storage products for twelve Indian reservoirs show good agreement in terms of R^(2) values (0.71–0.96 for elevation, and 0.79–0.96 for storage) and normalized root-mean-square error (NRMSE) values (5.08–19.34% for elevation, and 6.39–18.77% for storage). The evaporation rate results for two reservoirs (Lake Nasser and Lake Mead) agree well with in situ measurements (R^(2) values of 0.61 and 0.66, and NRMSE values of 16.25% and 21.76%). Furthermore, preliminary results from the VIIRS reservoir product have shown good consistency with the MODIS based product, confirming the continuity of this 20-year product suite. This new global water reservoir product suite can provide valuable information with regard to water-sources-related studies, applications, management, and hydrological modeling and change analysis such as drought monitoring.

Yao Li↗

Effects of Unmanned Aircraft Voice Communication Delay on En Route Air Traffic Management Operations

The present study investigated the effects of remotely piloted unmanned aircraft (UA) voice communication delay on air traffic management operations with different background sector traffic-volume levels. Three one-way UA voice delay lengths of 400, 900, and 2,000 milliseconds (ms) were tested, representing the currently estimated transmission delays for terrestrial, satellite communication (SATCOM), and long SATCOM Command and Control Link System, respectively. All delay values exceeded 390 ms, the FAA’s current requirement for the maximum communication latency in the National Airspace System. Eight retired en route air traffic controllers (ATCs) and eight remote pilots (RPs) participated in a human-inthe-loop simulation study, where a simulated UA flight transitioned through an Oakland en route low-altitude sector to a local non-towered airport. The results showed that, when the 2,000-ms voice delay was present, radio transmission step-ons and detect-and-avoid (DAA) alert level elevations increased. In addition, ATC workload, ATC acceptability for the UA, and RP acceptability for the DAA were negatively affected only when the UA had a 2,000-ms voice delay under the high traffic-volume condition, but not in the other conditions.

remotely piloted unmanned aircraft, voice delay, s↗

SU-E-T-208: Incidence Cancer Risk From the Radiation Treatment for Acoustic Neuroma Patient

Purpose: The present study aimed to compare the incidence risk of a secondary cancer from therapeutic doses in patients receiving intensitymodulated radiotherapy (IMRT), volumetric modulated arc therapy (VMAT), and stereotactic radiosurgery (SRS). Methods: Four acoustic neuroma patients were treated with IMRT, VMAT, or SRS. Their incidnece excess relative risk (ERR), excess absolute risk (EAR), and lifetime attributable risk (LAR) were estimated using the corresponding therapeutic doses measured at various organs by radio-photoluminescence glass dosimeters (RPLGD) placed inside a humanoid phantom. Results: When a prescription dose was delivered in the planning target volume of the 4 patients, the average organ equivalent doses (OED) at the thyroid, lung, normal liver, colon, bladder, prostate (or ovary), and rectum were measured. The OED decreased as the distance from the primary beam increased. The thyroid received the highest OED compared to other organs. A LAR were estimated that more than 0.03% of AN patients would get radiation-induced cancer. Conclusion: The tyroid was highest radiation-induced cancer risk after radiation treatment for AN. We found that LAR can be increased by the transmitted dose from the primary beam. No modality-specific difference in radiation-induced cancer risk was observed in our study.

60 APPLIED LIFE SCIENCES↗

Noninvasive assessment of left atrial maximum dP/dt by a combination of transmitral and pulmonary venous flow

OBJECTIVES: The study assessed whether hemodynamic parameters of left atrial (LA) systolic function could be estimated noninvasively using Doppler echocardiography. BACKGROUND: Left atrial systolic function is an important aspect of cardiac function. Doppler echocardiography can measure changes in LA volume, but has not been shown to relate to hemodynamic parameters such as the maximal value of the first derivative of the pressure (LA dP/dt(max)). METHODS: Eighteen patients in sinus rhythm were studied immediately before and after open heart surgery using simultaneous LA pressure measurements and intraoperative transesophageal echocardiography. Left atrial pressure was measured with a micromanometer catheter, and LA dP/dt(max) during atrial contraction was obtained. Transmitral and pulmonary venous flow were recorded by pulsed Doppler echocardiography. Peak velocity, and mean acceleration and deceleration, and the time-velocity integral of each flow during atrial contraction was measured. The initial eight patients served as the study group to derive a multilinear regression equation to estimate LA dP/dt(max) from Doppler parameters, and the latter 10 patients served as the test group to validate the equation. A previously validated numeric model was used to confirm these results. RESULTS: In the study group, LA dP/dt(max) showed a linear relation with LA pressure before atrial contraction (r = 0.80, p < 0.005), confirming the presence of the Frank-Starling mechanism in the LA. Among transmitral flow parameters, mean acceleration showed the strongest correlation with LA dP/dt(max) (r = 0.78, p < 0.001). Among pulmonary venous flow parameters, no single parameter was sufficient to estimate LA dP/dt(max) with an r2 > 0.30. By stepwise and multiple linear regression analysis, LA dP/dt(max) was best described as follows: LA dP/dt(max) = 0.1 M-AC +/- 1.8 P-V - 4.1; r = 0.88, p < 0.0001, where M-AC is the mean acceleration of transmitral flow and P-V is the peak velocity of pulmonary venous flow during atrial contraction. This equation was tested in the latter 10 patients of the test group. Predicted and measured LA dP/dt(max) correlated well (r = 0.90, p < 0.0001). Numerical simulation verified that this relationship held across a wide range of atrial elastance, ventricular relaxation and systolic function, with LA dP/dt(max) predicted by the above equation with r = 0.94. CONCLUSIONS: A combination of transmitral and pulmonary venous flow parameters can provide a hemodynamic assessment of LA systolic function.

NASA Discipline Cardiopulmonary↗

Multibaseline TanDEM-X Mangrove Height Estimation: The Selection of the Vertical Wavenumber

We generated a large-scale mangrove forest height map using multiple TanDEM-X (TDX) interferometric synthetic aperture radar (InSAR) acquisitions with various spatial baselines in order to improve the height estimation accuracy across a wide range of forest heights. The forest height inversion using InSAR data is strongly dependent upon the vertical wavenumber (i.e., perpendicular baseline). First, we investigated the role of the vertical wavenumber in forest height inversion from InSAR data using the sensitivity of the interferometric (volume) coherence to forest height. We used corrected but lower resolution and accuracy Shuttle Radar Topography Mission (SRTM) mangrove height maps as a priori information over Akanda and Pongara National Parks in Gabon to estimate lower and upper boundaries of the vertical wavenumber over test sites from the measured coherence-to-height sensitivity. Only TDX acquisitions within the boundaries of the vertical wavenumber were selected and combined for multibaseline mangrove height inversion. Mangrove forest height was obtained with multibaseline TDX acquisitions and was validated against the reference height derived from field measurement data providing improvements in multibaseline inversion over existing height estimates (i.e., SRTM height) and single-baseline inversions (multibaseline inversion: r(exp 2) = 0.98, root mean square error (RMSE) of 2.73 m; SRTM height: r(exp 2) = 0.86, RMSE = 7.21 m; single-baseline inversions: r(exp 2) = 0.08-0.97, RMSE = 3.86-11.10 m). As a result, to accurately estimate forest heights over a wide range (3-60 m), multibaseline InSAR acquisitions (at least three different baselines) are needed to exclude biases associated with the vertical wavenumber in forest height inversion.

vertical wavenumber.↗

Advanced NASA Earth Science Mission Concept for Vegetation 3D Structure, Biomass and Disturbance

Carbon in forest canopies represents about 85% of the total carbon in the Earth's aboveground biomass (Olson et al., 1983). A major source of uncertainty in global carbon budgets derives from large errors in the current estimates of these carbon stocks (IPCC, 2001). The magnitudes and distributions of terrestrial carbon storage along with changes in sources and sinks for atmospheric C02 due to land use change remain the most significant uncertainties in Earth's carbon budget. These uncertainties severely limit accurate terrestrial carbon accounting; our ability to evaluate terrestrial carbon management schemes; and the veracity of atmospheric C02 projections in response to further fossil fuel combustion and other human activities. Measurements of vegetation three-dimensional (3D) structural characteristics over the Earth's land surface are needed to estimate biomass and carbon stocks and to quantify biomass recovery following disturbance. These measurements include vegetation height, the vertical profile of canopy elements (i.e., leaves, stems, branches), andlor the volume scattering of canopy elements. They are critical for reducing uncertainties in the global carbon budget. Disturbance by natural phenomena, such as fire or wind, as well as by human activities, such as forest harvest, and subsequent recovery, complicate the quantification of carbon storage and release. The resulting spatial and temporal heterogeneity of terrestrial biomass and carbon in vegetation make it very difficult to estimate terrestrial carbon stocks and quantify their dynamics. Vegetation height profiles and disturbance recovery patterns are also required to assess ecosystem health and characterize habitat. The three-dimensional structure of vegetation provides habitats for many species and is a control on biodiversity. Canopy height and structure influence habitat use and specialization, two fundamental processes that modify species richness and abundance across ecosystems. Accurate and consistent 3D measurements of forest structure at the landscape scale are needed for assessing impacts to animal habitats and biodiversity following disturbance.

Ranson, K. Jon↗

Ab initio studies on structural and thermodynamic properties of magnetic Fe

The present work systematically investigates the total energy, phonon spectra, and thermodynamic properties of different polymorphs of pure Fe, i.e., FCC, BCC, and HCP, with the ab initio approach, considering various magnetic configurations. In general, the calculated energy vs. volume curves and phonon spectra agree well with previous calculations and the experimental data. In addition, their thermodynamic properties are estimated by the quasiharmonic approximation (QHA). Specifically, a superposition approach based on the latest Zentropy theory was utilized to predict magnetic transition temperatures and thermodynamic properties of pure Fe. With the ensemble of the partition function considering the multiplicity of each magnetic microstate, the current work successfully reproduced the Curie/Néel temperature and the Schottky anomaly of heat capacity in FCC, BCC, and HCP Fe purely based on the ab initio input, which exhibits good agreement with the experimental data and CALPHAD modeling.

36 MATERIALS SCIENCE↗

F-18-FDG-PET Confined Radiotherapy of Locally Advanced NSCLC With Concomitant Chemotherapy: Results of the PET-PLAN Pilot Trial

Purpose: The integration of fluoro-deoxy-D-glucose positron emission tomography (FDG-PET) in the process of radiotherapy (RT) planning of locally advanced non-small-cell lung cancer (NSCLC) may improve diagnostic accuracy and minimize interobserver variability compared with target volume definition solely based on computed tomography. Furthermore, irradiating only FDG-PET-positive findings and omitting elective nodal regions may allow dose escalation by treating smaller volumes. The aim of this prospective pilot trial was to evaluate the therapeutic safety of FDG-PET-based RT treatment planning with an autocontour-derived delineation of the primary tumor. Methods and Materials: Eligible patients had Stages II-III inoperable NSCLC, and simultaneous, platinum-based radiochemotherapy was indicated. FDG-PET and computed tomography acquisitions in RT treatment planning position were coregistered. The clinical target volume (CTV) included the FDG-PET-defined primary tumor, which was autodelineated with a source-to-background algorithm, plus FDG-PET-positive lymph node stations. Limited by dose restrictions for normal tissues, prescribed total doses were in the range of 66.6 to 73.8 Gy. The primary endpoint was the rate of out-of-field isolated nodal recurrences (INR). Results: As per intent to treat, 32 patients received radiochemotherapy. In 15 of these patients, dose escalation above 66.6 Gy was achieved. No Grade 4 toxicities occurred. After a median follow-up time of 27.2 months, the estimated median survival time was 19.3 months. During the observation period, one INR was observed in 23 evaluable patients. Conclusions: FDG-PET-confined target volume definition in radiochemotherapy of NSCLC, based on a contrast-oriented source-to-background algorithm, was associated with a low risk of INR. It might provide improved tumor control because of dose escalation.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

Comparison of permeability predictions on cemented sandstones with physics-based and machine learning approaches

Permeability prediction has been an important problem since the time of Darcy. Most approaches to solve this problem have used either idealized physical models or empirical relations. In recent years, machine learning (ML) has led to more accurate and robust, but less interpretable empirical models. Using 211 core samples collected from 12 wells in the Garn Sandstone from the North Sea, this study compared idealized physical models based on the Carman-Kozeny equation to interpretable ML models. We found that ML models trained on estimates of physical properties are more accurate than physical models. The results show evidence of a threshold of about 10% volume fraction, above which pore-filling cement strongly affects permeability.

03 NATURAL GAS↗

Investigation of nonlinear mechanical behavior of two superfine-grained graphites with DIC assisted disc splitting test

Using standardized uniaxial tensile test specimens is not practical due to the limited volumes in irradiation capsules, molten salt degradation facilities, or oxidation apparatus. The ASTM International Standard Test Method for Tensile Strength Estimate by Disc Compression of Manufactured Graphite (ASTM D8289) was developed to provide a convenient way for estimating tensile strength. Unlike the traditional uniaxial tensile test in ASTM C749 (International Standard Test Method for Tensile Stress–Strain of Carbon and Graphite), which uses dog-bone shaped specimens larger than 12.95 mm × 120.65 mm, the ASTM D8289 standard uses smaller discs with diameters of 6–12.7 mm. A digital image correlation (DIC) system, which uses a full-field noncontact surface displacement measurement technique, was applied along with the ASTM D8289 disc splitting test on IG-110 samples and compared with previous measurements from Mersen 2114 samples. Results confirmed that the DIC technique can measure the surface displacement/strain on these small (Ø6 mm × 3 mm) graphite specimens with good repeatability. However, Mersen 2114 and IG-110 samples exhibited strain discrepancies when DIC measurements were compared with analytical and finite element simulation values. The loading history and strain results also indicated different mechanical behaviors between Mersen 2114 and IG-110, particularly the nonlinear behavior of the IG-110 samples. Good agreement was observed by comparing the splitting tensile strengths of two superfine-grained grades with results from other work. The specimen size effect is discussed when comparing the splitting tensile strength with corresponding uniaxial tensile strength of these two graphite grades.

Lin, Lianshan [ORNL] (ORCID:0000000203399219)↗

Compositional Control on Shale Pore Structure Characteristics across a Maturation Gradient: Insights from the Devonian New Albany Shale and Marcellus Shale in the Eastern United States

The pore structure characteristics of shales are controlled by their mineralogical and organic matter (OM) composition. However, the contributions by different components in shales at varying thermal maturities remain poorly understood. In this study, Devonian New Albany Shale and Marcellus Shale samples spanning a thermal maturity from marginally mature (vitrinite reflectance R o 0.55%) to post-mature (R o 2.41 %) were selected to study the control of composition on the pore structure properties of shales at different stages of thermal maturation. Scanning electron microscope (SEM) imaging was used to examine pore types in shales, and low-pressure N 2 and CO 2 adsorption analyses were used to quantitatively characterize the mesopore and micropore characteristics of bulk shales and major components in shales. The results show that matrix-associated pores including interparticle pores between silt-sized mineral grains, phyllosilicate framework pores, and intraparticle pores within mineral grains exist in all samples but become less common with increasing maturity, which is likely caused by elevated compaction, cementation, and occlusion with bitumen. Secondary organic pores were not observed under SEM at marginal maturity but were detected in the condensate–wet gas and dry gas windows, with more organic pores in the dry gas window. At marginal maturity, OM has large amounts of mesopores and micropores as demonstrated by low-pressure N 2 and CO 2 adsorption analyses of OM isolated from shales, even though no OM-hosted pores were observed under SEM. With increasing thermal maturity, the mesopore and micropore specific surface area of OM increase and make greater contributions to the pore structure properties of bulk shales. The mesopore and micropore properties of shales are controlled by OM content and maturity as well as by clay mineral type and content, and they can be estimated from the contribution of each component at different stages of thermal maturation. In conclusion, accurate evaluation of the pore volume and SSA of shales will have important implications for assessing gas adsorption and transport in shales.

03 NATURAL GAS↗

Iridium-Doped Nanosized Zn–Al Layered Double Hydroxides as Efficient Water Oxidation Catalysts

Layered double hydroxides (LDHs) are an ideal platform to host catalytic metal centers for water oxidation (WO) owing to the high accessibility of water to the interlayer region, which makes all centers potentially reachable and activated. In this paper, we report the syntheses of three iridium-doped zinc–aluminum LDHs (Ir-LDHs) nanomaterials (1–3, with about 80 nm of planar size and a thickness of 8 nm as derived by field emission scanning electron microscopy and powder X-ray diffraction studies, respectively), carried out in the confined aqueous environment of reverse micelles, through a very simple and versatile procedure. These materials exhibit excellent catalytic performances in WO driven by NaIO 4 at neutral pH and 25 °C, with an iridium content as low as 0.5 mol % (~0.8 wt %), leading to quantitative oxygen yields (based on utilized NaIO 4 , turnover number up to ~10,000). Nanomaterials 1–3 display the highest ever reported turnover frequency values (up to 402 min –1 ) for any heterogeneous and heterogenized catalyst, comparable only to those of the most efficient molecular iridium catalysts, tested under similar reaction conditions. The boost in activity can be traced to the increased surface area and pore volume (>5 times and 1 order of magnitude, respectively, higher than those of micrometric materials of size 0.3–1 μm) estimated for the nanosized particles, which guarantee higher noble metal accessibility. X-ray absorption spectroscopy (XAS) studies suggest that 1–3 nanomaterials, as-prepared and after catalysis, contain a mixture of isolated, single octahedral Ir(III) sites, with no evidence of Ir–Ir scattering from second-nearest neighbors, excluding the presence of IrO 2 nanoparticles. The combination of the results obtained from XAS, elemental analysis, and ionic chromatography strongly suggests that iridium is embedded in the brucite-like structure of LDHs, having four hydroxyls and two chlorides as first neighbors. These results demonstrate that nanometric LDHs can be successfully exploited to engineer efficient WOCs, minimizing the amount of iridium used, consistent with the principle of the noble-metal atom economy.

36 MATERIALS SCIENCE↗

Brain ageing in schizophrenia: evidence from 26 international cohorts via the ENIGMA Schizophrenia consortium

Schizophrenia (SZ) is associated with an increased risk of life-long cognitive impairments, age-related chronic disease, and premature mortality. We investigated evidence for advanced brain ageing in adult SZ patients, and whether this was associated with clinical characteristics in a prospective meta-analytic study conducted by the ENIGMA Schizophrenia Working Group. The study included data from 26 cohorts worldwide, with a total of 2803 SZ patients (mean age 34.2 years; range 18–72 years; 67% male) and 2598 healthy controls (mean age 33.8 years, range 18–73 years, 55% male). Brain-predicted age was individually estimated using a model trained on independent data based on 68 measures of cortical thickness and surface area, 7 subcortical volumes, lateral ventricular volumes and total intracranial volume, all derived from T1-weighted brain magnetic resonance imaging (MRI) scans. Deviations from a healthy brain ageing trajectory were assessed by the difference between brain-predicted age and chronological age (brain-predicted age difference [brain-PAD]). On average, SZ patients showed a higher brain-PAD of +3.55 years (95% CI: 2.91, 4.19; I 2 = 57.53%) compared to controls, after adjusting for age, sex and site (Cohen’s d = 0.48). Among SZ patients, brain-PAD was not associated with specific clinical characteristics (age of onset, duration of illness, symptom severity, or antipsychotic use and dose). This large-scale collaborative study suggests advanced structural brain ageing in SZ. Longitudinal studies of SZ and a range of mental and somatic health outcomes will help to further evaluate the clinical implications of increased brain-PAD and its ability to be influenced by interventions.

59 BASIC BIOLOGICAL SCIENCES↗

An inconsistency in the standard maximum likelihood estimation of bulk flows

Maximum likelihood estimation of the bulk flow from radial peculiar motions of galaxies generally assumes a constant velocity field inside the survey volume. This assumption is inconsistent with the definition of bulk flow as the average of the peculiar velocity field over the relevant volume. This follows from a straightforward mathematical relation between the bulk flow of a sphere and the velocity potential on its surface. This inconsistency also exists for ideal data with exact radial velocities and full spatial coverage. Based on the same relation, we propose a simple modification to correct for this inconsistency.

79 ASTRONOMY AND ASTROPHYSICS↗

SU-E-T-74: A Simple Model of Dose Falloff for Highly Convergent SBRT Beams

Purpose: The purpose of this study was to create a simple model of dose falloff outside the target for a SBRT system employing a highly convergent beam geometry. With an estimate of the rate of reduction in dose away from a target of a given size, dose to tissues at a given distance from the target can be estimated. Our hypothesis is that dose at a given distance away from the edge of a target can be approximated using an inverse square model. Methods: With the GammaPod™ system used for this study, thirty-six rotating Co-60 beams with circular cross section converge at an isocenter and then diverge distal to the isocenter. Dose falloff beyond the target is mainly due to reduction in beam overlap, which in turn depends on projected area of all beams and projected beam area swept out during rotation. Beams also decrease in intensity beyond the isocenter. The GammaPod™ TPS calculates dose via superposition of Monte Carlo-generated kernels, each corresponding to the convergence of beams at an isocenter within a stereotactic breast cup. Results: The factors above yield a simple inverse square-based model that has been compared with TPS predictions and measurements for a variety of targets. Good agreement is seen considering the simple nature of the model. Fitting of the treatment planning and measured dose falloff data with a power law expression yields a negative exponent close to 2, confirming the inverse square nature of dose falloff. Conclusion: It is possible to apply a simple inverse square dose falloff model for SBRT or SRS systems such as the GammaPod which employ a highly-convergent beam geometry. This can be useful in estimating the “worst case scenario” for dose to critical organs at a known distance from the edge of the target volume. Authors are employees of Xcision Medical Systems.

60 APPLIED LIFE SCIENCES↗

SU-F-T-650: The Comparison of Robotic Partial Breast Stereotactic Irradiation Using MLC Vs. Iris Cone

Purpose: To evaluate the dosimetric impact on treatment planning for partial breast stereotactic irradiation using Cyberknife with MLC versus Iris Cone. Methods: Ten patients whom underwent lumpectomy for DCIS or stage I invasive non-lobular epithelial breast cancer were included in this study. All patients were previously treated on the Cyberknife using Iris cone with the prescription dose of 37.5Gy in 5 fractions covering at least 95% of PTV on our phase I SBRT 5 fraction partial breast irradiation trial. Retrospectively, treatment planning was performed and compared using the new Cyberknife M6 MLC system for each patient. Using the same contours and critical organ constraints for both MLC and Iris cone plans, the dose on target and critical organs were analyzed accordingly. Results: Dose to critical organs such as ipsilateral lung, contralateral lung, heart, skin, ipsilateral breast, and rib were analyzed, as well as conformity index and high dose spillage of the target area. In 9 of 10 patients, the MLC plans had less total ipsilateral breast volume encompassing the 50% prescription isodose (mean:22.3±8.2% MLC vs. 31.6±8.0 Iris, p=0.00014) .The MLC plans mean estimated treatment delivery time was significantly less than the Iris plans (51±3.9min vs. 56.2±9min, p=0.03) Both MLC and Iris cone plans were able to meet all dose constraints and there was no statistical difference between those dose constraints. Conclusion: Both MLC and Iris Cone can deliver conformal dose to a partial breast target and satisfy the dose constraints of critical organs. The new Cyberknife with MLC can deliver a more conformal dose in the lower dose region and spare more ipsilateral breast tissue to the 50% prescription isodose. The treatment time for partial breast SBRT plans was also reduced using MLC. Project receives research support from Accuray Inc.

60 APPLIED LIFE SCIENCES↗

Properties of Silver Nanoparticles in the Presence of Dysprosium

Various methods of binding rare-earth metal ions with nanoparticles make it possible to obtain materials with new properties. The “green” synthesis method has been used for obtaining silver nanoparticles functionalized with Dy{sup 3+} ions. The absorption and photoluminescence spectra of colloidal solutions have been measured, and the characteristics of resultant Ag nanoparticles have been analyzed using an electron microscope. The results of observations are in good agreement with the estimates obtained from the absorption spectra using the classical model. The nanoparticle shape (mainly spherical), size (d = 70 nm), and volume fraction (f = 6 × 10{sup –4}) of silver in the colloidal solutions have been determined. Functionalizing silver nanoparticles with dysprosium ions with the help of the technique developed in this study can be extended to other rare-earth elements.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

A scale-consistent method for imaging porosity and micrite in dual-porosity carbonate rocks

Unlike many other clastic rocks, relating velocity and permeability to porosity for micrite-bearing carbonate rocks has been largely unsuccessful. Recent studies have shown that additional parameters, most notably the distribution and/or proportion of micrite, can be used to parameterize the velocity and permeability behavior. However, there is currently no scale-consistent, 3D methodology for differentiating macroporosity and microporosity from the total porosity measured on bench-top laboratory equipment. Previous studies estimated microporosity and micrite content by combining total porosity measurements conducted on whole 50 mm cores with measurements of phase volumes on 1 mm digital rocks (i.e., scale-inconsistent). As a step forward from those, we imaged dual-porosity carbonate rocks using X-ray microcomputed tomography and then leveraged a recently developed, optimization-based technique, called data-constrained modeling, to map the macroporosity and microporosity distribution of our samples. We evaluate the volumetric proportions of macropores, micropores, and coarse-grained calcite as a function of micrite content — with their respective uncertainties — all measured on the same digital rock and with the same method. Finally, we determine how measurements of the volumetric phase proportions could be extended using standard effective medium models to predict reservoir physical properties. Here, the sensitivity of these models to the proportion of micrite and microporosity within the micrite is evidence that the nonuniqueness among permeability, velocity, and porosity that is commonly observed of micrite-bearing carbonate rocks can be explained by a variation of micrite content and microporosity at a similar porosity.

58 GEOSCIENCES↗