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At least 1,729 records · Page 96

Simplifying the Advanced Test Reactor LOWE Element Test Series

The Advanced Test Reactor (ATR) is one of six remaining high performance research reactors in the United States scheduled to be converted from 93% high-enriched uranium (HEU) fuel to 19.75% low-enriched uranium (LEU) fuel as part of the Department of Energy (DOE), National Nuclear Security Administration (NNSA), Office of Material Management and Minimization (MMM) reactor conversion efforts(1). The specific LEU fuel element design for the ATR is called the Low Enriched (LOWE) element. A series of fuel qualification tests are scheduled to occur over the next decade before the ATR is fully converted. In addition to several experiments of demonstration plates, a series of Element Tests (ETs) are planned for conversion, in which full sized LOWE elements are placed in ATR driver positions. The purpose of these ETs was generally to sequentially increase the amount of LEU and core power to full power, therefore creating a representative safety profile in which LEU could operate for the duration of the ATR lifetime. The planned element tests were (2): ET-1: one LOWE element at low power for once cycle ET-2: ~8 LOWE elements at low/medium power for multiple cycles, and ET-3: >8 LOWE elements for a full lobe of elements at high power for multiple cycles. Given recent improvements in modeling fidelity, scheduling considerations, and an opportunity to combine later ETs, the LEU conversion program successfully defined the operational requirements for the “ET-ATR” test, which combines the needed information collected from ET-2 and ET-3 into a single test.

42 ENGINEERING↗

Requirements of constitutive models for two nickel-base superalloys

The constitutive behavior of two nickel-base superalloys, Rene '80 and Inconel 718, utilized in gas turbine blade and disk components, respectively, is presented. In turbine blade applications, the high homologous temperatures result in strain-rate effects dominating behavior. In turbine disks, the temperatures are cooler so that mean stress effects become important. The impact of these two variables on the overall crack initiation lifetime and analysis methodology is discussed.

Laflen, J. H.↗

Comprehensive Battery Safety Risk Evaluation: Aged Cells versus Fresh Cells Upon Mechanical Abusive Loadings

Abstract Despite their wide applications, lithium‐ion batteries (LIBs) have been struggling with their safety risks arising from different lifetime stages. Here, the NCMA pouch cell is taken as an example, and the safety of both fresh and aged cells from three milestone stages, that is, internal short circuit (ISC) triggering risk, ISC mode, and the subsequent thermal runaway (TR) consequence is investigated. By combining mechanical abusive testing and physics‐based models on commercialized cells with various states‐of‐health (SOH) and states‐of‐charge, it is discovered that the ISC triggering delays with the decay of SOH and soft ISC mode will be triggered more frequently, which is mainly due to the mechanical behaviors of the current collectors. The temperature rises and peak temperature during the subsequent TR also become milder for aged cells due to the reduced capacity and deterministic soft ISC process. Results here provide a mechanistic explanation of the safety risk comparison between the fresh and aged cells, offering cornerstone guidance to the evaluation and design of next‐generation safer LIBs.

25 ENERGY STORAGE↗

Low-temperature T -linear resistivity due to umklapp scattering from a critical mode

In this study, we consider the transport properties of a model of fermions scattered by a critical bosonic mode. The mode is overdamped and scattering is mainly in the forward direction. Such a mode appears at the quantum critical point for an electronic nematic phase transition and in gauge theories for a U(1) spin liquid. It leads to a short fermion lifetime, violating Landau's criterion for a Fermi liquid. In spite of this, transport can be described by a Boltzmann equation. We include momentum relaxation by umklapp scattering, supplemented by weak impurity scattering. We find that above a very low temperature which scales with Δ q 3 , where Δ q is the minimum umklapp scattering vector, the resistivity is linear in T with a coefficient which is independent of the amount of disorder. This picture holds until the temperature dependent part of the resistivity exceeds that due to impurity scattering. We compare the relaxation time approximation with an exact numerical solution of the Boltzmann equation. Surprisingly we find that, unlike the resistivity, the Hall coefficient strongly deviates from the relaxation time approximation and shows a strong reduction with increasing temperature. We comment on possible comparisons with experiments on high T c cuprates.

36 MATERIALS SCIENCE↗

High-Accuracy Simulations to Model Pyrometallurgical Processes in a Secondary Lead Reverberatory Furnace

The US manufacturing industry produces about 1.3 million tons of refined lead each year using secondary sources consisting mainly of lead batteries. ORNL is partnering with Gopher resource, the second largest lead recycling company in the United States, and GTI, to develop a high-fidelity CFD model of a directly fired, reverberatory-style, secondary lead furnace. These High Performance Computing (HPC) simulations are aimed to use first principles modeling for combustion and melting processes of the secondary lead feed while accounting for complex interphase interactions between the gas, solid charge (lead) material, slag, and metal phases. Through validation against operating plant data, this effort will enable significant improvements in design, operational parameters, and energy efficiency, thus improving productivity and refractory lifetime of secondary lead melting furnaces. Estimated savings/reduction of, at least, 1 trillion BTU, 1 million ton/year of greenhouse gas emissions, and $\$50$ million/year to the US lead industry can be expected. ORNL resources and expertise in high-performance computing and multicomponent, multiphase flows were utilized to realize this goal while advancing the understanding of the smelting and melting processes occurring within the furnace.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

The organic surface of 5145 Pholus: Constraints set by scattering theory

No known body in the Solar System has a spectrum redder than that of object 5145 Pholus. We use Hapke scattering theory and optical constants measured in this laboratory to examine the ability of mixtures of a number of organic solids and ices to reproduce the observed spectrum and phase variation. The primary materials considered are poly-HCN, kerogen, Murchison organic extract, Titan tholin, ice tholin, and water ice. In a computer grid search of over 10 million models, we find an intraparticle mixture of 15% Titan tholin, 10% poly-HCN, and 75% water ice with 10-micrometers particles to provide an excellent fit. Replacing water ice with ammonia ice improves the fits significantly while using a pure hydrocarbon tholin, Tholin alpha, instead of Titan tholin makes only modest improvements. All acceptable fits require Titan tholin or some comparable material to provide the steep slope in the visible, and poly-HCN or some comparable material to provide strong absorption in the near-infrared. A pure Titan tholin surface with 16-micrometers particles, as well as all acceptable Pholus models, fit the present spectrophotometric data for the transplutonian object 1992 QB(sub 1). The feasibility of gas-phase chemistry to generate material like Titan tholin on such small objects is examined. An irradiated transient atmosphere arising from sublimating ices may generate at most a few centimeters of tholin over the lifetime of the Solar System, but this is insignificant compared to the expected lag deposit of primordial contaminants left behind by the sublimating ice. Irradiation of subsurface N2/CH4 or NH3/CH4 ice by cosmic rays may generate approximately 20 cm of tholin in the upper 10 m of regolith in the same time scale but the identity of this tholin to its gas-phase equivalent has not been demonstrated.

Wilson, Peter D.↗

The formation of compact groups of galaxies. I: Optical properties

The small crossing time of compact groups of galaxies (t(sub cr)H(sub 0) approximately less than 0.02) makes it hard to understand why they are observable at all. Our dissipationless N-body simulations show that within a single rich collapsing group compact groups of galaxies continually form. The mean lifetime of a particular compact configuration if approximately 1 Gyr. On this time scale, members may merge and/or other galaxies in the loose group may join the compact configuration. In other words, compact configurations are continually replaced by new systems. The frequency of this process explains the observability of compact groups. Our model produces compact configurations (compact groups (CG's) with optical properties remarkably similar to Hickson's (1982) compact groups (HCG's): (1) CG's have a frequency distribution of members similar to that of HCG's; (2) CG's are approximately equals 10 times as dense as loose groups; (3) CG's have dynamical properties remarkably similar to those of HCG's; (4) most of the galaxy members of CG's are not merger remnants. The crucial aspect of the model is the relationship between CG's and the surrounding rich loose group. Our model predicts the frequency of occurrence of CG's. A preliminary analysis of 18 rich loose groups is consistent with the model prediction. We suggest further observational tests of the model.

Diaferio, Antonaldo↗

Star Formation Rates in Cooling Flow Clusters: A UV Pilot Study with Archival XMM-Newton Optical Monitor Data

We have analyzed XMM-Newton Optical Monitor (OM) UV (180-400 nm) data for a sample of 33 galaxies. 30 are cluster member galaxies, and nine of these are central cluster galaxies (CCGs) in cooling flow clusters having mass deposition rates which span a range of 8 - 525 Solar Mass/yr. By comparing the ratio of UV to 2MASS J band fluxes, we find a significant UV excess in many, but not all, cooling flow CCGs, a finding consistent with the outcome of previous studies based on optical imaging data (McNamara & O'Connell 1989; Cardiel, Gorgas, & Aragon-Salamanca 1998; Crawford et al. 1999). This UV excess is a direct indication of the presence of young massive stars, and therefore recent star formation, in these galaxies. Using the Starburst99 spectral energy distribution (SED) model of continuous star formation over a 900 Myr period, we derive star formation rates of 0.2 - 219 solar Mass/yr for the cooling flow sample. For 2/3 of this sample it is possible to equate Chandra/XMM cooling flow mass deposition rates with UV inferred star formation rates, for a combination of starburst lifetime and IMF slope. This is a pilot study of the well populated XMM UV cluster archive and a more extensive follow up study is currently underway.

Hicks, A. K.↗

Build-To-Replace Strategy to Reduce O&M Costs of Advanced Reactors

This paper targets the goal of reducing fixed operations and maintenance (O&M) costs to $2/MWh for advanced reactor (AR) designs, an order of magnitude reduction from current nuclear fleets. Such goal will be severely constrained if the underlying assumptions of O&M approaches and practices are not questioned and reexamined, especially today when changes can be implemented effectively and efficiently. Achieving a 90% reduction in AR O&M costs requires a completely new way of thinking – a paradigm shift – not through incremental, technology-focused approaches alone. Here, we address this challenge by evaluating the impact of moving to shorter design life for major structures, systems and components (SSCs) and shorter, more predictable refurbishment cycles as modeled by the commercial airline industry. This paper provides a brief overview of this different mindset to O&M applied to ARs: the build-to-replace approach. We provide a direct example of analysis of a build-to-replace scenario by identifying and evaluating scenarios for reduced system and component lifetimes and associated replacement and refurbishment schedules to evaluate impacts on O&M costs and other lifecycle elements such as SSC reliability.

97 - MATHEMATICS AND COMPUTING↗

Numerical Modeling and Testing of an Inductively-Driven and High-Energy Pulsed Plasma Thrusters

Pulsed Plasma Thrusters (PPTs) are advanced electric space propulsion devices that are characterized by simplicity and robustness. They suffer, however, from low thrust efficiencies. This summer, two approaches to improve the thrust efficiency of PPTs will be investigated through both numerical modeling and experimental testing. The first approach, an inductively-driven PPT, uses a double-ignition circuit to fire two PPTs in succession. This effectively changes the PPTs configuration from an LRC circuit to an LR circuit. The LR circuit is expected to provide better impedance matching and improving the efficiency of the energy transfer to the plasma. An added benefit of the LR circuit is an exponential decay of the current, whereas a traditional PPT s under damped LRC circuit experiences the characteristic "ringing" of its current. The exponential decay may provide improved lifetime and sustained electromagnetic acceleration. The second approach, a high-energy PPT, is a traditional PPT with a variable size capacitor bank. This PPT will be simulated and tested at energy levels between 100 and 450 joules in order to investigate the relationship between efficiency and energy level. Arbitrary Coordinate Hydromagnetic (MACH2) code is used. The MACH2 code, designed by the Center for Plasma Theory and Computation at the Air Force Research Laboratory, has been used to gain insight into a variety of plasma problems, including electric plasma thrusters. The goals for this summer include numerical predictions of performance for both the inductively-driven PPT and high-energy PFT, experimental validation of the numerical models, and numerical optimization of the designs. These goals will be met through numerical and experimental investigation of the PPTs current waveforms, mass loss (or ablation), and impulse bit characteristics.

Parma, Brian↗

Stream Lifetimes Against Planetary Encounters

We study, both analytically and numerically, the perturbation induced by an encounter with a planet on a meteoroid stream. Our analytical tool is the extension of pik s theory of close encounters, that we apply to streams described by geocentric variables. The resulting formulae are used to compute the rate at which a stream is dispersed by planetary encounters into the sporadic background. We have verified the accuracy of the analytical model using a numerical test.

Valsecchi, G. B.↗

Theoretical, observational, and isotopic estimates of the lifetime of the solar nebula

There are a variety of isotopic data for meteorites which suggest that the protostellar nebula existed and was involved in making planetary materials for some 10(exp 7) yr or more. Many cosmochemists, however, advocate alternative interpretations of such data in order to comply with a perceived constraint, from theoretical considerations, that the nebula existed only for a much shorter time, usually stated as less than or = 10(exp 6) yr. In this paper, we review evidence relevant to solar nebula duration which is available through three different disciplines: theoretical modelling of star formation, isotopic data from meteorites, and astronomical observations of T Tauri stars. Theoretical models based on observations of present star-forming regions indicate that stars like the Sun form by dynamical gravitational collapse of dense cores of cold molecular clouds in the interstellar medium. The collapse to a star and disk occurs rapidly on a time scale of the order 10(exp 5) yr. Disks evolve by dissipating energy while redistributing angular momentum, but it is difficult to predict the rate of evolution, particularly for low mass (compared to the star) disks which nonetheless still contain enough material to account for the observed planetary system. There is no compelling evidence, from available theories of disk structure and evolution, that the solar nebula must have evolved rapidly and could not have persisted for more than 1 Ma. In considering chronologically relevant isotopic data for meteorites, we focus on three methodologies: absolute ages by U-Pb/Pb-Pb, and relative ages by short-lived radionuclides (especially Al-26) and by evolution of Sr-87/Sr-86. Two kinds of meteoritic materials-refractory inclusions such as CAIs and differentiated meteorites (eucrites and angrites) - appear to have experience potentially dateable nebular events. In both case, the most straightforward interpretations of the available data indicate nebular events spanning several Ma. We also consider alternative interpretations, particularly the hypothesis of radically heterogeneous distribution of Al-26, which would avoid these chronological interpretations. The principal impetus for such alternative interpretations seems to be precisely the obviation of the chronological interpretation (i.e., the presumption rather than the inference of a short (less than or = Ma) lifetime of the nebula). Astronomical observations of T Tauri stars indicate that the presence of dusty disks is a common if not universal feature, that the disks are massive enough to accomodate a planetary system such as ours, and that at least some persist for 10(exp 7) yr or more. The results are consistent with the time scales inferred from the meteorite isotopic data. They cannot be considered conclusive with regard to solar nebula time scales, however,in part because it is difficult to relate disk observations to processes that affect meteorites, and in part because the ages assigned for these stars could be wrong by a factor of several in either direction. We conclude that the balance of available evidence favors the view that the nebula existed and was active for at least several Ma. However, because the evidence is not definitive, it is important that the issue be perceived to be an open question, whose answer should be sought rather than presumed.

Podosek, Frank A.↗

Simultaneous optimization of simulated moving bed adsorption and distillation for 2,3‐butanediol recovery

Abstract A combined simulated moving bed (SMB) and distillation separation scheme is developed to recover 2,3‐butanediol (BDO) from a dilute fermentation broth. The scheme was integrated into a lignocellulosic biorefinery that produces hydrocarbon fuels from corn stover with BDO as an intermediate. BDO recovery is one of the most challenging processes in this biorefinery; and given the high associated energy duties, direct distillation is considered cost‐prohibitive. An alternative separation is SMB adsorption in nanoporous materials, which can reject 90% of the water and reduce subsequent distillation costs. Rigorous models were used to optimize the SMB and distillation simultaneously. The separation can be added to the biorefinery while keeping the projected minimum fuel selling price (MFSP) below $0.66 USD (US dollars) per liter gasoline‐equivalent ($2.50/GGE, gallon gasoline equivalent). Finally, sensitivity analyses were conducted to assess the effects of cost and lifetime of the adsorbent, titer concentration, and BDO purity.

09 BIOMASS FUELS↗

Thermal Energy Grid Storage (TEGS) Using Multi-Junction Photovoltaics (MPV) (Final Technical Report)

The project aimed to develop a thermal energy storage battery that converts electricity to heat and stores heat at ultra-high temperatures (>2000°C) in graphite blocks. The thermal battery discharge uses TPV cells that directly convert thermal energy to electrical energy without any moving parts. All components of this technology were successfully demonstrated at the laboratory scale in this project. Development of extremely low cost (< $20/kWh) grid level energy storage is a crucial necessity to reach high penetrations of renewables. The thermal battery technology developed in this project is expected to meet the cost targets that would enable full renewable penetration. The project focused on four key aspects of this technology: Converting electricity to ultra-high temperature heat: This was done through development of graphite Joule heaters. Major issues related to arcing, heater evaporation and deterioration due to long term oxidation were addressed to ensure lifetime exceeding the service lifetime of the battery. Converting ultra-high temperature heat back to electricity: This was done through development of beyond state-of-the-art TPV cells. We demonstrated energy conversion efficiency of >40% that is a world record and exceeds the average energy conversion efficiency of turbines in the USA. The findings are peer-reviewed and published in Nature, and received a wide media attention globally. Protecting the TPV cells to ensure lifetime: Deposition of volatilized material, such as sublimated material or particles, on the TPV cell could greatly reduce the efficiency and lifetime of the TPV cells by blocking their view to the heat source and causing cell overheating. In this project we developed and demonstrated an approach that reduces the deposition rate, ensuring long > 30 year life. Technoeconomic feasibility and commercialization: In collaboration with the project’s technical advisory board, we developed a technoeconomic model. The model shows that, at large scales (> 1GWh) the thermal battery technology is projected to reach a cost of energy stored below $10/kWh-e, with a cost per unit power < $0.5/W-e and a roundtrip efficiency of 50%. These results, along with the technical achievements in the project led to the creation of a startup company (i.e., Fourth Power) that is pursuing commercialization of the technology.

25 ENERGY STORAGE↗

Large-area silicon sheet task

A set of computer models was used to define a growth system configuration that was then built and used to grow web with lower thermally generated stress. Aspects of research in the edge-defined film-fed growth (EFG) method of making Si ribbon are reported. A technique was developed to determine base resistivity and carrier lifetime in semicrystalline wafers. Automated growth of 150 kg of 15 cm-dia ingot material per crucible is reviewed. Scanning transmisson electron microscopy (STEM) and microprobe investigations of processed EFG ribbon are reported. The chemical composition of the large precipitates was studied. The structural arrangement and the electrical activity of distentions or close to the central twin plane in processed material were studied. The electrical and structural properties of grain boundaries in silicon are discussed. Temperature-dependence measurements of zero-bias conductance, a photoconductivity technique, and deep-level transient spectroscopy (DLTS) were developed. A grooving and staining technique, secondary ion mass spectroscopy, and EBIC measurements in scanning electron microscopy were used to study enhanced diffusion of phosphorus at grain boundaries in polycrystaline silicon. The fundamental mechanisms of abrasion and wear and the deformation of Si by a diamond in various fluid environments are described. The efficiency of solar cells made from EFG ribbon and Semix Inc. material is reported.

Morrison, A. D.↗

Space power distribution system technology. Volume 1: Reference EPS design

The multihundred kilowatt electrical power aspects of a mannable space platform in low Earth orbit is analyzed from a cost and technology viewpoint. At the projected orbital altitudes, Shuttle launch and servicing are technically and economically viable. Power generation is specified as photovoltaic consistent with projected planning. The cost models and trades are based upon a zero interest rate (the government taxes concurrently as required), constant dollars (1980), and costs derived in the first half of 1980. Space platform utilization of up to 30 years is evaluated to fully understand the impact of resupply and replacement as satellite missions are extended. Such lifetimes are potentially realizable with Shuttle servicing capability and are economically desirable.

Decker, D. K.↗

Is GX5 - 1 a millisecond pulsar?

It is proposed that the quasi-periodic behavior of the bright galactic bulge source GX5 - 1 results from fluctuations in accretion rate onto a millisecond pulsar which has been spun up by accretion to its steady-state spin rate. According to models that use spin-up by accretion to bring the neutron stars to steady-state fast short periods, galactic bulge sources are likely progenitors of millisecond pulsars. After steady state is achieved in these systems, accretion may continue without further spin-up, so that for a substantial fraction of the lifetime of a galactic bulge X-ray source, the neutron star may already be spinning rapidly at the equilibrium spin. The behavior of GX5 - 1 can be explained in terms of deviations from this equilibrium state resulting from changes in the accretion rate.

Alpar, M. A.↗

The Atmospheric Infrared Sounder (AIRS) on the Earth Observing System

AIRS, the Atmospheric Infrared Sounder on the EOS-Aqua, produces global high precision spectra from 3.7 - 15.4 micron with spectral resolving power mu/delta mu = 1200 twice each day from 708 km orbital altitude. AIRS is the first hyperspectral infrared spectrometer designed to support NOAA/NCEP's operational requirements for medium range weather forecasting during its nominal 7 year lifetime. AIRS, together with the AMSU and HSB microwave radiometers, will achieve global retrieval accuracy of better then 1K rms in the lower troposphere under clear and partly cloudy condition. Based on the excellent radiometric and spectral performance demonstrated during the pre-launch testing, the assimilation of AIRS data into the forecast model is expected to result in major forecast improvements. Launch of AIRS on the EOS AQUA is scheduled for May 2001.

Aumann, Hartmut H.↗