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At least 1,729 records · Page 96

Fire and Explosion Safe Technology of Storage and Regasification of Liquefied Petroleum Gas

The technology of storage and regasification of liquefied petroleum gas that implies storage in an isothermal tank and overheating the gas with subsequent supply of the vapor phase to the consumer is offered. The necessary storage and regasification temperatures are achieved by means of utilizing a vapor-compression refrigeration unit in the technological process. The technology allows to improve energy efficiency of the processes, reduce fire-and-explosion hazard, minimize LPG losses, exclude conditions formation of a combustible environment, regulate the storage temperature of LPG of various composition and efficiency of the regasification process, and ensure the composition of volatilized LPG remains constant during regasification.

02 PETROLEUM↗

The effect of African growth on future global energy, emissions, and regional development

In 2005 less than 15% of the world’s population lived in Africa, by the end of the 21st century more than one-fifth of the world’s population could live there. By dint of sheer numbers, Africa is a place to be reckoned with. But from a global perspective, Africa is not a major emitter of greenhouse gases or consumer of fossil energy today. However, Africa’s share of global emissions at the end of the century depends critically on assumptions about its growth in economic activity. This paper explores the implications of alternative assumptions about future rates of economic growth in Africa. It finds that assumptions about the rate of economic growth have profound implications for global economic activity, energy use, and greenhouse gas emissions. African emissions vary from 5% to 20% of global emissions, and emissions in Sub-Saharan Africa range from 2% to 10% of world emissions, depending on the model and scenario. In addition, affluence levels till the middle of the century remain low, as a result the population remains dependent on traditional bioenergy for the bulk of its residential energy needs. Although the share of electricity in final energy, electric capacity and electricity use per capita all rise with income, they do not reach levels commensurate with those in developed countries today. Hence, dedicated policies may be needed in order to address energy poverty and access issues in the region.

Calvin, Katherine V.↗

Bioenergy in Energy Transformation and Climate Management

Unlike fossil fuels, biomass is a renewable resource that can sequester carbon during growth, be converted to energy, and then re-grown. Biomass is also a flexible fuel that can service many end-uses. This paper explores the importance of bioenergy to potential future energy transformation and climate change management. Using a model comparison of fifteen models, we characterize and analyze future dependence on, and the value of, bioenergy in achieving potential long-run climate objectives—reducing radiative forcing to 3.7 and 2.8 W/m2 in 2100 (approximately 550 and 450 ppm carbon dioxide equivalent atmospheric concentrations). Model scenarios project, by 2050, bioenergy growth of 2 to 10% per annum reaching 5 to 35 percent of global primary energy, and by 2100, bioenergy becoming 15 to 50 percent of global primary energy. Non-OECD regions are projected to be the dominant suppliers of biomass, as well as consumers, with up to 35 percent of regional electricity from biopower by 2050, and up to 70 percent of regional liquid fuels from biofuels by 2050. Bioenergy is found to be valuable to many models with significant implications for mitigation costs and world consumption. The availability of bioenergy, in particular biomass with carbon dioxide capture and storage (BECCS), notably affects the cost-effective global emissions trajectory for climate management by accommodating prolonged near-term use of fossil fuels. We also find that models cost-effectively trade-off land carbon and nitrous oxide emissions for the long-run climate change management benefits of bioenergy. Overall, further evaluation of the viability of global large-scale bioenergy is merited.

Rose, Steven K.↗

Building a sustained climate assessment process

The leaders and authors of the Third US National Climate Assessment (NCA3) developed new modes of engaging academia, the private sector, government agencies and civil society to support their needs for usable, rigorous, and timely information and better connect science and decision-making. A strategic vision for assessment activities into the future was built during the NCA3 process, including recommendations on how to establish a sustained assessment process that would integrate evolving scientific understanding into decision making to manage the risks of climate change over time. This vision includes a collaborative assessment process that involves partnerships across a diverse and widely distributed set of non-governmental and governmental entities. The new approach to assessments would produce timely, scientifically sound climate information products and processes, rather than focusing on the production of single quadrennial synthesis reports. If properly implemented, a sustained assessment would be more efficient and cost-effective, avoiding the painful and time-consuming process of beginning the assessment process anew every 4 years. This ongoing assessment would also encourage scientific and social innovations and explore new insights and opportunities, building the capacity to advance the development and delivery of climate information to meet societal requirements and benefit from scientific opportunities.

Buizer, James L.↗

Brown tree snake ( Boiga irregularis ) population density and carcass locations following exposure to acetaminophen

Mass aerial delivery of dead mouse baits treated with acetaminophen has been evaluated as a means to reduce brown treesnake (Boiga irregularis) populations over large areas, increasing the likelihood of wide-scale eradication on Guam. Given the high density of snakes in some areas of their invasive range, eradication efforts could result in a resource pulse that may influence food web dynamics and the indirect transport of acetaminophen among trophic levels. In this study, we evaluated abundance, habitat type, and snake size (i.e., age) within two study sites on Guam, a secondary limestone forest (upland) and an abandoned coconut plantation (coastal), to determine how experimentally dosing snakes with acetaminophen is likely to influence carrion availability. We found snakes trapped in 3.24 ha plots occurred in greater abundance (population size = 72.5 snakes; SE = 8.8) and were significantly larger (978.6 mm, SE = 14.9) in the coastal than in the upland site (population size = 26.9, SE = 21.5; length = 903.0 mm, SE = 15.9). Despite these differences, carcasses of snakes that died after consuming acetaminophen-laced mice (80 mg) were recovered in consistent locations between sites, with 92% located on the ground, 4% in trees, and 4% found in rock cavities at both sites. Given that most snakes died on the ground rather than in the tree canopy, our results suggest that many poisoned snake carcasses will be accessible to a wide range of potential scavengers, possibly influencing food web dynamics and potentially contributing to indirect toxicant transfer within affected ecosystems.

59 BASIC BIOLOGICAL SCIENCES↗

Evaluating the regional risks to food availability and access from land-based climate policies in an Integrated Assessment Model

Mitigating greenhouse gas (GHG) emissions is necessary to reduce the overall negative climate change impacts on crop yields and agricultural production. However, certain mitigation measures may generate unintended consequences to food availability and food access due to both land use competition and economic burden of mitigation. Integrated assessment models (IAM) are generally used to evaluate these policies; however, currently these models may not capture the importance of income and food prices for hunger and overall economic wellbeing. Here, we implement a measure of food security that captures the nutritional and economic aspects as the total expenditures on staple foods divided by income and weighted by total caloric consumption in an IAM, the Global Change Analysis Model (GCAM4.0). We then project consumer prices and our measure of food security along the Shared Socioeconomic Pathways (SSPs). Sustained economic growth underpins increases in caloric consumption and lowering expenditures on staple foods. Strict conservation policies affect food accessibility in a larger number of developing countries, whereas the negative effects of pricing terrestrial emissions is more concentrated on the poor in Sub-Saharan Africa, by substantially replacing their cropland with forests and affecting the production of key staples.

Cui, Ryna↗

A Hybrid Semi-supervised Classification Scheme for Mining Multisource Geospatial Data

Supervised learning methods such as Maximum Likelihood (ML) are often used in land cover (thematic) classification of remote sensing imagery. ML classifier relies exclusively on spectral characteristics of thematic classes whose statistical distributions (class conditional probability densities) are often overlapping. The spectral response distributions of thematic classes are dependent on many factors including elevation, soil types, and ecological zones. A second problem with statistical classifiers is the requirement of large number of accurate training samples (10 to 30 |dimensions|), which are often costly and time consuming to acquire over large geographic regions. With the increasing availability of geospatial databases, it is possible to exploit the knowledge derived from these ancillary datasets to improve classification accuracies even when the class distributions are highly overlapping. Likewise newer semi-supervised techniques can be adopted to improve the parameter estimates of statistical model by utilizing a large number of easily available unlabeled training samples. Unfortunately there is no convenient multivariate statistical model that can be employed for mulitsource geospatial databases. In this paper we present a hybrid semi-supervised learning algorithm that effectively exploits freely available unlabeled training samples from multispectral remote sensing images and also incorporates ancillary geospatial databases. We have conducted several experiments on real datasets, and our new hybrid approach shows over 25 to 35% improvement in overall classification accuracy over conventional classification schemes.

54 ENVIRONMENTAL SCIENCES↗

Emergency Cooling of Nuclear Power Plant Reactors With Heat Removal By a Forced-Draft Cooling Tower

The feasibility of heat removal during emergency cooling of a reactor by a forced-draft cooling tower with accumulation of the peak heat release in a volume of precooled water is evaluated. The advantages of a cooling tower over a spray cooling pond are demonstrated: it requires less space, consumes less material, employs shorter lines in the heat removal system, and provides considerably better protection of the environment from wetting by entrained moisture.

42 ENGINEERING↗

Analysis and modeling of Nannochloropsis growth in lab, greenhouse, and raceway experiments

Efficient production of algal biofuels could reduce dependence on foreign oil by providing a domestic renewable energy source. Moreover, algae-based biofuels are attractive for their large oil yield potential despite decreased land use and natural resource (e.g., water and nutrients) requirements compared to terrestrial energy crops. Important factors controlling algal lipid productivity include temperature, nutrient availability, salinity, pH, and the light-to-biomass conversion rate. Here, computational approaches allow for inexpensive predictions of algae growth kinetics for various bioreactor sizes and geometries without the need for multiple, expensive measurement systems. Parametric studies of algal species include serial experiments that use off-line monitoring of growth and lipid levels. Such approaches are time consuming and usually incomplete, and studies on the effect of the interaction between various parameters on algal growth are currently lacking. However, these are the necessary precursors for computational models, which currently lack the data necessary to accurately simulate and predict algae growth. In this work, we conduct a lab-scale parametric study of the marine alga Nannochloropsis salina and apply the findings to our physics-based computational algae growth model. We then compare results from the model with experiments conducted in a greenhouse tank and an outdoor, open-channel raceway pond. Results show that the computational model effectively predicts algae growth in systems across varying scale and identifies the causes for reductions in algal productivities. Applying the model facilitates optimization of pond designs and improvements in strain selection.

09 BIOMASS FUELS↗

Combining Deep Learning and scatterControl for High-Throughput X-ray CT Based Non-Destructive Characterization of Large-Scale Casted Metallic Components

X-ray computed tomography (XCT) is essential for nondestructive evaluation and quality control of large-scale metal components. XCT imaging, however, faces significant challenges from metal artifacts, particularly those caused by Compton scattering, which degrade image quality and obscure critical details. Hardware-based solutions (e.g. scatterControl) offer advancements by intercepting scattered photons and reducing artifacts, but they can be time-consuming and require additional processing. Here, we propose modifying and leveraging a novel deep learning (DL) framework, Simurgh, to enhance and accelerate scatter correction in XCT. By combining scatterControl with DL-based artifact removal, we demonstrate significant reduction in scan time while producing high-quality reconstructions. Through extensive evaluation on industrial XCT data, we show that our methods reduce scan time by up to more than 10 x while preserving flaw detectability. Quantitative analysis across multiple segmentation techniques confirms that Simurgh-based reconstructions consistently outperform traditional Feldkamp-Davis-Kress, model-based iterative reconstruction, and commercial DL models in both pixel-level and task-specific evaluations, enabling scalable, high-throughput XCT workflows for characterization of large scale components in applications such as casting and metal additive manufacturing.

Complex metal parts↗

Effects of Aging and Different Mechanical Recycling Processes on the Structure and Properties of Poly(lactic acid)-clay Nanocomposites

The growing use of poly(lactic acid) (PLA) and PLA-based nanocomposites in packaging has raised the interest of studying the mechanical recycling of the wastes and the properties of the recycled materials. The main objective of this work was to study the effect of two different mechanical recycling processes on the structure and properties of a PLA-montmorillonite nanocomposite. The two recycling processes included accelerated thermal and photochemical aging steps to simulate the degradation experienced by post-consumer plastics during their service life. One of them also included a demanding washing process prior to the reprocessing. A decrease in the molecular weight of PLA was observed in the recycled materials, especially in those subjected to the washing step, which explained the small decrease in microhardness and the increased water uptake at long immersion times. Water absorption at short immersion times was similar in virgin and recycled materials and was accurately described using a Fickian model. The recycled materials showed increased thermal, optical and gas barrier properties due to the improved clay dispersion that was observed by XRD and TEM analysis. The results suggest that recycled PLA-clay nanocomposites can be used in demanding applications.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Synthesis of Recycled Poly(ethylene terephthalate)/Polyacrylonitrile/Styrene Composite Nanofibers by Electrospinning and Their Mechanical Properties Evaluation

Consumption of polyethylene terephthalate (PET) products has increased dramatically in recent decades, resulting in the generation of a large amount of PET waste. For that reason, is necessary to find a new application of recycled material. In this article, we report the synthesis and characterization of recycled poly (ethylene terephthalate) (RPET) obtained from the chemical recycling of post-consumer PET bottles by glycolysis method and the formation of composites nanofibers RPET/polyacrylonitrile (PAN)/styrene (ST). The RPET synthesis was studied through infrared spectroscopy (FT-IR) and thermogravimetric analysis (TGA). The viscosity and frequency sweep of the polymeric solutions was evaluated. The composites nanofibers were elaborated by the electrospinning technique and characterized by scanning electron microscopy (SEM), FT-IR, TGA/DSC and nanoindentation. The RPET/PAN/ST composite nanofibers present an average diameter of 456 nm and higher thermal stability compared PAN fibers. The mechanical properties such as hardness and elastic modulus were 4.5 and 7.5 times PAN fibers values, respectively.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Bioactivity Potentials of Biodegradable Chitosan/Gelatin Film Forming Solutions Combined with Monoterpenoid Compounds

Novel food packaging systems including biodegradable/edible films have been introduced to the market for consumers who desire natural products for their nutrition. Biochemically active plant compounds are added to the biopolymer-based films to improve their functionality. Within the present study, chitosan (1%) and gelatin (4%) biopolymer-based film forming solutions (FFSs) combined with 1, 2, 5 and 10% (v/v) eugenol, pulegone and carvacrol, monoterpenoid compounds, were evaluated for their antimicrobial and antioxidative potential. Antioxidant activities and total phenolic contents (TPC) of the FFSs were determined by 1,1-diphenyl-2-picrylhydrazyl (DPPH) free radical scavenging activity and Folin–Ciocalteau assays, respectively. Screening the antimicrobial activity of FFSs were performed against food spoilage microorganisms including Bacillus cereus, Escherichia coli, Salmonella typhimurium, Staphylococcus aureus and Listeria monocytogenes and a fungi, Candida albicans by using agar well diffusion method. The chitosan FFS containing 10% carvacrol had greater TPC (3857.3 ± 0.07 mg gallic acid equivalent/L). The highest antioxidative capacity was observed for the chitosan FFS containing 10% eugenol as 97.92 ± 0.01%. FFSs with monoterpenoids showed promising antimicrobial activities against tested microorganisms. Based on antioxidative and antimicrobial potentials of the FFSs, it can be envisaged to use monoterpenoid incorporation to biopolymer films for food packaging applications.

60 APPLIED LIFE SCIENCES↗

Hopes Beyond PET Recycling: Environmentally Clean and Engineeringly Applicable

Disposal of plastics in the environment has become a core of anxiety in developing countries, while in the developed countries the focus has additionally been placed on design and manufacture of emerging products from plastic wastes—a somewhat vague yet promising horizon. Central to environmental concerns are poly(ethylene terephthalate) (PET) wastes, mainly from post-consumer bottles. Because of a considerable drop in molecular weight in the course of recycling, recycled PETs are not suitable for engineering uses. An efficient yet reasonably green synthesis route is employed here to convert PET wastes into polyurethane, and then carbon nanotubes (CNTs) was added at different levels to obtain nanocomposites with high mechanical properties. The effects of isocyanate (NCO)/hydroxyl (OH) molar ratio and CNTs content on the morphology, physical and mechanical properties were discussed. Chemical/physical crosslink density was calculated from initial slope of stress–strain curves, Mooney–Rivlin plots, strain-hardening modulus, rubbery-plateau storage modulus and swelling data. High tensile strength (300 MPa) and breaking elongation (160%) of polyurethane/CNTs nanocomposites born from PET wastes seemed promising. Microscopic analyses by AFM, SEM, and TEM gave useful information about distribution of CNTs in polyurethane. Lastly, structural changes were correlated to mechanical properties improvement.

36 MATERIALS SCIENCE↗

Thermal, Rheological and Mechanical Properties of PETG/rPETG Blends

This paper presents the reuse process of post-consumer printed foils made of glycol-modified poly(ethylene terephthalate) (PETG). Fourier-transform infrared spectroscopy and a scanning electron microscope confirmed that these foils consist of PETG and PS layers. Firstly, foil pieces were immersed in the organic solution to remove all prints and after washing and drying they were extruded into regranulate rPETG pellets. Three types of PETG/rPETG blends were fabricated with the addition of 10, 20 and 30 wt% of virgin PETG. Microscopic analysis of the blends confirmed their homogeneity, as was also shown by the fact that there was only one glass transition peak in the heating curve given by differential scanning calorimetry. Moreover, in the presence of fresh PETG the degradation temperatures of rPETG improved significantly, and the viscosity of all blends was reduced as a result of shortened macromolecule chains in rPETG. Mechanical analysis of the materials showed that all blends have comparable tensile strength and a Young’s modulus that is higher than rPETG but lower than virgin PETG. Elongation at break decreases together with the content of rPETG.

36 MATERIALS SCIENCE↗

A Low-Cost Fabrication Technique for the Growth of Single-Domain GdBCO Bulk Superconductor from Raw Metal Oxides

A single-domain GdBCO bulk superconductor is usually fabricated using a mixture of pre-reacted precursor powders (including GdBa{sub 2}Cu{sub 3}O{sub 7−δ} and Gd{sub 2}BaCuO{sub 5}) by the top-seeded melt texture growth (TSMTG) process. However, the synthesis of pure-phase precursor powder by the solid-state sintering reaction can not only consume time for weeks but also prolong the fabrication process and can lead to a low-efficiency and high-cost process. In this paper, we reported the successful growth of single-domain GdBCO bulk superconductors by the top-seeded metallic oxide melt growth (TS-MOMG) process in which the raw materials of Gd{sub 2}O{sub 3}, BaO, and CuO, the three different metallic oxides, are just involved to fabricate the single-domain GdBCO bulk superconductors. After detailed investigations in the morphology, levitation force, trapped magnetic field, and critical temperature of the grown samples with different ratios, it was found that the simplified precursor-phase source can be used to fabricate the single-domain GdBCO bulk superconductors more efficiently, which can combine the crystal growth procedure and greatly economize the preparation cost and the time to the most extent.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Determining HPGe Total Detection Efficiency Using γ–γ Coincidence

Abstract Both the peak and total detection efficiencies are generally needed in order to calculate sample activity from a gamma spectroscopic measurement, except in the case of isotope specific calibration. This is particularly true when the sample is in close proximity to the detector and corrections for cascade summing effects are required to avoid significant inaccuracy in the result. These corrections use the total detection efficiency to correct for summing-in and summing-out events, and the extent of the correction depends on both the geometry and the gamma cascade for the isotope in question. Experimentally determining the total efficiency is a labor intensive endeavor requiring multiple measurements with a set of single-gamma-emitting standards. Modeling the total efficiency vs. energy may be less time consuming, but is also likely to produce less confidence in the final result. Pacific Northwest National Laboratory's Radiation Detection and Nuclear Sciences group has constructed a low background 14-crystal HPGe array for sample measurement; in all measurements, samples will be in close proximity to the germanium crystals. This close geometry and the sheer number efficiency calibrations required for the system have led us to investigate methods to simplify the efficiency calibration procedure. One method we are developing uses the Y-Y coincidence plane to isolate Compton scattering event populations, allowing experimental determination of total detection efficiency values from the measurement of a single mixed isotope standard. A description of the analysis and experimental results of this method are presented.

low background HPGe High Purity Germanium detector↗