Reactive CO2 capture: A path forward for process integration in carbon management
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Final Technical Presentation
A dissertation by Chidera O Iloejesi submitted to the Graduate Faculty of Auburn University In partial fulfillment of the requirements for the Degree of Doctor of Philosophy
Abstract Coastal wetland communities provide valuable ecosystem services such as erosion prevention, soil accretion, and essential habitat for coastal wildlife, but are some of the most vulnerable to the threats of climate change. This work investigates the combined effects of two climate stressors, elevated temperature (ambient, + 1.7 °C, + 3.4 °C, and 5.1 °C) and elevated CO 2 ( e CO 2 ), on leaf physiological traits of dominant salt marsh plant species. The research took place at the Salt Marsh Accretion Response to Temperature eXperiment (SMARTX) at the Smithsonian Environmental Research Center, which includes two plant communities: a C 3 sedge community and a C 4 grass community. Here we present data collected over five years on rates of stomatal conductance (g s ), quantum efficiency of PSII photochemistry ( F v / F m ), and rates of electron transport (ETR max ). We found that both warming and e CO 2 caused declines in all traits, but the warming effects were greater for the C 3 sedge. This species showed a strong negative stomatal response to warming in 2017 and 2018 (28% and 17% reduction, respectively in + 5.1 °C). However, in later years the negative response to warming was dampened to < 7%, indicating that S. americanus was able to partially acclimate to the warming over time. In 2022, we found that sedges growing in the combined + 5.1 °C e CO 2 plots exhibited more significant declines in g s , F v /F m , and ETR max than in either treatment individually. These results are important for predicting future trends in growth of wetland species, which serve as a large carbon sink that may help mitigate the effects of climate change.
Abstract Compared with a pulverized coal power plant, the integrated gasification combined cycle (IGCC) has several advantages, including, among others better environmental performance and low CO 2 capture cost. Hot/warm CO 2 removal from syngas has also been a subject of research due to its potentially higher thermal efficiency. In this study, we proposed a generic adsorption based hot/warm CO 2 removal process for IGCC power plants. Through analyses of the proposed generic process we have demonstrated that higher temperature of the hot/warm CO 2 removal process will results in larger heat of adsorption, which in turns may increase energy consumption of the process. Under most of the operating temperature range, hot/warm CO 2 removal process will lead to more electricity loss compared to the baseline Selexol process. However, if the adsorption step takes place at a temperature close to or higher than the highest steam temperature in steam cycle, our analysis indicates that the process may lead to minimal electricity loss. The study also provided some other insights into the pathways for hot/warm CO 2 removal process to improve its energy performance through process and sorbent designs. Graphical Abstract
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