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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,729 records · Page 96
All sourcesNASA NTRSDOE OSTI
NASA NTRS2021

Lunar Asset Messaging and On Orbit Navigation

NASA has titled its 2020 thrust for the Moon, Artemis. The increased focus on the Moon as a destination for future human and robotic expeditions necessitates general purpose navigational and communications infrastructure reducing their complexity to help establish a sustained presence. A framework through which Lunar missions can relay communications and localize their positions shifts the burden from the individual mission and enables resource allocation tailored to mission-specific goals. During the summer of 2020, student interns under the Innovation to Flight (i2F) program at the National Aeronautics and Space Administration’s (NASA) Jet Propulsion Laboratory (JPL) in collaboration with the University of Colorado Boulder designed, built, and tested a prototype framework capable of providing surface assets with communication and positioning services. The team utilized the existing i2F CubeSat bus in addition to developing several CubeSat engineering development units (EDUs), a ground vehicle, and a ground station to simulate a scenario in which a lunar surface mission is supported by these services. A primary goal of the summer was to develop a method for localizing the ground vehicle through trilateration. Distances are inferred from the round-trip time of flight (ToF) of radio signals between an asset and several elements. Signals were sent and received using LimeSDR software defined radios on-board both the ground vehicle and the EDUs; ToF and trilateration were calculated on a Qualcomm Snapdragon development board located within the LA MOON payload data system. The ModalAI chipset on the Qualcomm was instrumental in executing visual based position estimation. Communications was facilitated through a bent-pipe approach addressing the NASA requirement to provide solutions for in communication denied locations. The ground vehicle relayed information to other surface assets in addition to its ground station through the supporting constellation. This project demonstrates the feasibility of a lunar CubeSat constellation for the support of surface assets and explores packaging and operations of the components critical to trilateration and bent-pipe communication into a standard CubeSat form factor. When implemented, this framework will open a door for new surface missions designed with lower power requirements and increased operational access.

Huang, Calvin↗
NASA NTRS2001

Thermal Analysis for Orbiter and ISS Plume Impingement on International Space Station

The NASA Reaction Control System (RCS) Plume Model (RPM) is an exhaust plume flow field and impingement heating code that has been updated and applied to components of the International Space Station (ISS). The objective of this study was to use this code to determine if plume environments from either Orbiter PRCS jets or ISS reboost and Attitude Control System (ACS) jets cause thermal issues on ISS component surfaces. This impingement analysis becomes increasingly important as the ISS is being assembled with its first permanent crew scheduled to arrive by the end of fall 2000. By early summer 2001 , the ISS will have a number of major components installed such as the Unity (Node 1), Destiny (Lab Module), Zarya (Functional Cargo Block), and Zvezda (Service Module) along with the P6 solar arrays and radiators and the Z-1 truss. Plume heating to these components has been analyzed with the RPM code as well as additional components for missions beyond Flight 6A such as the Propulsion Module (PM), Mobile Servicing System, Space Station Remote Manipulator System, Node 2, and the Cupola. For the past several years NASA/JSC has been developing the methodology to predict plume heating on ISS components. The RPM code is a modified source flow code with capabilities for scarfed nozzles and intersecting plumes that was developed for the 44 Orbiter RCS jets. This code has been validated by comparison with Shuttle Plume Impingement Flight Experiment (SPIFEX) heat flux and pressure data and with CFD and Method of Characteristics solutions. Previous analyses of plume heating predictions to the ISS using RPM have been reported, but did not consider thermal analysis for the components nor jet-firing histories as the Orbiter approaches the ISS docking ports. The RPM code has since been modified to analyze surface temperatures with a lumped mass approach and also uses jet-firing histories to produce pulsed heating rates. In addition, RPM was modified to include plume heating from ISS jets to ISS components where the jet coordinates are specified, together with the engine cant angle. These latter studies have been focused on the PM with plumes from its reboost and ACS jets impinging on various ISS components and also focused on the Japanese H2 Transfer Vehicle (HTV) with the plumes from its reboost engines impinging on the Cupola window. This paper will present plume heating and surface temperature results on a number of ISS components with and without jet-firing histories, evaluate post-flight data, and describe any potential thermal issues

Rochelle, William C.↗
NASA NTRS2012

Mars Science Laboratory Engineering Cameras

NASA's Mars Science Laboratory (MSL) Rover, which launched to Mars in 2011, is equipped with a set of 12 engineering cameras. These cameras are build-to-print copies of the Mars Exploration Rover (MER) cameras, which were sent to Mars in 2003. The engineering cameras weigh less than 300 grams each and use less than 3 W of power. Images returned from the engineering cameras are used to navigate the rover on the Martian surface, deploy the rover robotic arm, and ingest samples into the rover sample processing system. The navigation cameras (Navcams) are mounted to a pan/tilt mast and have a 45-degree square field of view (FOV) with a pixel scale of 0.82 mrad/pixel. The hazard avoidance cameras (Haz - cams) are body-mounted to the rover chassis in the front and rear of the vehicle and have a 124-degree square FOV with a pixel scale of 2.1 mrad/pixel. All of the cameras utilize a frame-transfer CCD (charge-coupled device) with a 1024x1024 imaging region and red/near IR bandpass filters centered at 650 nm. The MSL engineering cameras are grouped into two sets of six: one set of cameras is connected to rover computer A and the other set is connected to rover computer B. The MSL rover carries 8 Hazcams and 4 Navcams.

Maki, Justin N.↗
DOE OSTI2023

Long‐Range Confinement‐Driven Enrichment of Surface Oxygen‐Relevant Species Promotes C−C Electrocoupling in CO 2 Reduction

Abstract CO 2 reduction is a highly attractive route to transform CO 2 into useful feedstocks, of which C 2 products are more desired than C 1 , yet face high kinetic barriers of C−C electrocoupling. Here, the engineering of pore‐enabled local confinement reaction environments is reported for tuning the enrichment of surface‐adsorbed oxygen‐relevant species and the establishment of their pronounced benefits in promoting C−C coupling over oxide‐derived Cu‐based catalysts. A new approach of utilizing the microphase separation of a block copolymer is developed to fabricate bicontinuous mesoporous CuO nanofibers (CuO‐BPNF). The enhanced confinement from long‐range mesochannels enables the adsorption of OH ad /O ad on the Cu surface at a wide negative potential range of −0.7 – −1.3 V in CO 2 reduction, which cannot be achieved over conventional deficient and short‐range pores. Constant‐potential DFT calculations reveal that the surface‐bound oxygen species weakens *CO affinity with the Cu (111) surface and lowers the kinetic barriers for both *CO−CO dimerization and *CO hydrogenation to enable *CO−CHO coupling. Accordingly, a CO 2 ‐to‐C 2 Faradaic efficiency of 74.7% over CuO‐BPNF is shown, significantly larger than counterparts with conventional pores. This work offers a general design principle of confinement engineering to manage the adsorption of reactive species for steering reaction pathways in interfacial catalysis.

Chemistry↗
DOE OSTI2018

Mathematical Model of Transfer and Deposition of Finely Dispersed Particles in a Turbulent Flow of Emulsions and Suspensions

The problem of modeling turbulent transfer of finely dispersed particles in liquids has been considered. An approach is used where the transport of particles is represented in the form of a variety of the diffusion process with the coefficient of turbulent transfer to the wall. Differential equations of transfer are written for different cases, and a solution of the cell model is obtained for calculating the efficiency of separation in a channel. Based on the theory of turbulent transfer of particles and of the boundary layer model, an expression has been obtained for calculating the rate of turbulent deposition of finely dispersed particles. The application of this expression in determining the efficiency of physical coagulation of emulsions in different channels and on the surface of chaotic packings is shown.

42 ENGINEERING↗
DOE OSTI2024

Capillary-Enhanced Two-Phase Micro-Cooler Using Copper-Inverse-Opal Wick with Silicon Microchannel Manifold for High-Heat-Flux Cooling Application

In this work, we demonstrate a two-phase capillary-fed boiling micro-cooler that consists of a ~ 25-..mu..m-thick copper inverse opal (CIO) porous wicking structure for high-heat-flux boiling and a silicon 3D-manifold for distributed liquid delivery and vapor extraction across a 0.5 cm x 0.5 cm heated area. At low inlet water mass flow rates of 1.5 to 1.9 g(min)-1, the micro-cooler displays nearly two-phase boiling with exit vapor quality ~ 1 and a high critical heat flux (CHF) of 253 to 320 W cm-2 with low superheat of ~ 10 degrees C resulting in a thermal resistance of boiling ~ 0.025 cm2 degrees C W-1 or heat transfer coefficient of 0.4 MW m-2 degrees C-1. For higher flow rates of 5, 10, and 15 g(min)-1, the micro-cooler exhibits a hybrid single-phase and two-phase cooling regime where the contribution of the sensible heat (single-phase) cooling is linearly added to that of the two-phase cooling. For the highest flow rate of 15 g(min)-1, the CHF is increased to ~ 500 W cm-2 resulting in an overall thermal resistance of ~ 0.18 cm2 degrees C W-1. However, the two-phase heat transfer effectiveness, which estimates the utilization level of the inlet mass flow rate for two-phase boiling, is reduced to ~ 0.11. To achieve the best cooling system performances, the micro-cooler must operate entirely within the two-phase boiling regime (exit vapor quality or two-phase heat transfer effectiveness ~ 1). Ideally, the "coolant" should be delivered near its saturation temperature (~ 100 degrees C for water), which provides significant advantages for the energy-efficient operation of data centers and power electronics. We present detailed analysis with Infrared and high speed camera images at various inlet flow rates and heat fluxes to understand complex heat transfer in the micro-cooler. Furthermore, a conjugate thermofluidic simulation model, which incorporates the physics of capillary-fed boiling in a porous copper layer, agrees well with the experimental data.

capillary-enhanced boiling↗
DOE OSTI2020

Bump-and-Hole Engineering Identifies Specific Substrates of Glycosyltransferases in Living Cells

Studying posttranslational modifications classically relies on experimental strategies that oversimplify the complex biosynthetic machineries of living cells. Protein glycosylation contributes to essential biological processes, but correlating glycan structure, underlying protein, and disease-relevant biosynthetic regulation is currently elusive. Here, we engineer living cells to tag glycans with editable chemical functionalities while providing information on biosynthesis, physiological context, and glycan fine structure. We introduce a non-natural substrate biosynthetic pathway and use engineered glycosyltransferases to incorporate chemically tagged sugars into the cell surface glycome of the living cell. We apply the strategy to a particularly redundant yet disease-relevant human glycosyltransferase family, the polypeptide N-acetylgalactosaminyl transferases. This approach bestows a gain-of-chemical-functionality modification on cells, where the products of individual glycosyltransferases can be selectively characterized or manipulated to understand glycan contribution to major physiological processes.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2024

Intrinsically sodiophilic, mesoporous metal-free wetting layers based on inexpensive carbon black for sodium-metal batteries

In this article, elevated temperature molten Na batteries are seeing a resurgence of interest for low-cost electrochemical energy storage for the grid. Of the many recent innovations in this battery concept, new methods focused on intermediate temperature operation (e.g. 110–190 °C) have gained prominence as a way to enable comparable performance with less thermal energy loss and lower-cost materials of construction. However, the poor wettability of molten Na on suitable solid-electrolyte separators such as sodium Beta Alumina Solid-Electrolyte (Na-β”-Al 2 O 3 , ‘BASE’) requires continued innovation in interface engineering to promote full utilization of the solid-electrolyte surface area and minimize cell resistance. There have been many successful approaches to improve Na-wettability to-date including heat treatment in an inert atmosphere to remove adsorbed surface species, deposition of alloying metals such as Pb, Sn, or Bi, and use of carbon-based interfacial layers. However, these approaches either lack the ability to provide good wetting at very low temperatures (near the melting point of Na) or rely on non-scalable processes and/or toxic/expensive metals. To solve these issues, a new carbon-based sodiophilic treatment is demonstrated, which utilizes inexpensive components to form a meso/macroporous sodiophilic layer, is easily applied via drop-casting or spray-coating, provides excellent wetting as low as 110 °C, and is completely metal-free. It is found that the good sodium wetting can be attributed to the wider range of pore sizes in the carbon layers demonstrated in this study. Na wetting may occur as surface tension is initially broken by larger pores, followed by the intrusion of molten Na into smaller pores due to the apparent intrinsic affinity of Na-metal for carbon surfaces, in conjunction with the capillarity effect. Low cell-level area specific resistances of 20–30 and 13–15 Ω·cm 2 are demonstrated at 110 and 140 °C respectively. Finally, the utility of this metal-free wetting layer for solid-Na anodes is explored, showing that the metal-free wetting layer can reach a critical current density of 1.88 mA·cm -2 at 30 °C.

25 ENERGY STORAGE↗
DOE OSTI2020

Radiation-hard miniature optical engine with high bandwidth

Future silicon trackers will be operated in an intense radiation environment and require large volumes of data to be transmitted off detector. In addition, the optical modules must be of low mass in order to limit multiple scattering and nuclear interactions that would degrade the overall performance of the detector. Here, we present a miniature optical engine that satisfies these constraints. The optical engine consists of an ASIC driving a VCSEL (Vertical Cavity Surface Emitting Laser) array in an optical package. Two ASICs are designed to operate a 12-channel VCSEL array at 1.28 or 5.12 Gb/s per channel, which yields a total data rate of up to 60 Gb/s. The core transistors are fabricated in a 65 nm CMOS process which enhance the radiation-hardness. Each channel contains equalizer (CTLE) and clock-data recovery circuits (CDR) so that the ASIC can restore the highly distorted electrical signal after propagating through several meters of cables of small diameter. The equalizer, CDR, and VCSEL driver are configured via a digital I 2 C chip interface with triple redundant memory to mitigate single event upset (SEU) effects. The bias and modulation currents are controlled by a digital-to-analog converter (DAC). We present the design of the circuit together with the results of the simulations and preliminary measurements.

47 OTHER INSTRUMENTATION↗
DOE OSTI2017

Multifunctional Protocells for Enhanced Penetration in 3D Extracellular Tumoral Matrices

The high density of the extracellular matrix in solid tumors is an important obstacle to nanocarriers for reaching deep tumor regions and has severely limited the efficacy of administrated nanotherapeutics. The use of proteolytic enzymes prior to nanoparticle administration or directly attached to the nanocarrier surface has been proposed to enhance their penetration, but the low in vivo stability of these macromolecules compromises their efficacy and strongly limits their application. Herein, we have designed a multifunctional nanocarrier able to transport cytotoxic drugs to deep areas of solid tumors and once there, to be engulfed by tumoral cells causing their destruction. This system is based on mesoporous silica nanocarriers encapsulated within supported lipid bilayers (SLBs). The SLB avoids premature release of the housed drug while providing high colloidal stability and an easy to functionalize surface. The tumor penetration property is provided by attachment of engineered polymeric nanocapsules that transport and controllably unveil and release the proteolytic enzymes that in turn digest the extracellular matrix, facilitating the nanocarrier diffusion through the matrix. Additionally, targeting properties were endowed by conjugating an antibody specific to the investigated tumoral cells to enhance binding, internalization, and drug delivery. This multifunctional design improves the therapeutic efficacy of the transported drug as a consequence of its more homogeneous distribution throughout the tumoral tissue.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2019

Microbe Encapsulation for Selective Rare-Earth Recovery from Electronic Waste Leachates

Rare earth elements (REEs) are indispensable components of many green technologies and of increasing demand globally. However, refining REEs from raw materials using current technologies is energy intensive and enviromentally damaging. Here, we describe the development of a novel biosorption-based flow-through process for selective REE recovery from electronic wastes. An Escherichia coli strain previously engineered to display lanthanide-binding tags on the cell surface was encapsulated within a permeable polyethylene glycol diacrylate (PEGDA) hydrogel at high cell density using an emulsion process. This microbe bead adsorbent contained a homogenous distribution of cells whose surface functional groups remained accessible and effective for selective REE adsorption. The microbe beads were packed into fixed-bed columns, and breakthrough experiments demonstrated effective Nd extraction at a flow velocity of up to 3 m/h at pH 4–6. The microbe bead columns were stable for reuse, retaining 85% of the adsorption capacity after nine consecutive adsorption/desorption cycles. A bench-scale breakthrough curve with a NdFeB magnet leachate revealed a two-bed volume increase in breakthrough points for REEs compared to non-REE impurities and 97% REE purity of the adsorbed fraction upon breakthrough. These results demonstrate that the microbe beads are capable of repeatedly separating REEs from non-REE metals in a column system, paving the way for a biomass-based REE recovery system.

Biological and medical sciences↗
DOE OSTI2020

Synthesis of a Hybrid Nanostructure of ZnO-Decorated MoS 2 by Atomic Layer Deposition

We introduce here the synthesis of hybrid nanostructures comprised of ZnO nanocrystals (NCs) decorating nanosheets and nanowires (NWs) of MoS 2 prepared by atomic layer deposition (ALD). The concentration, size, and surface-to-volume ratio of the ZnO NCs can be systematically engineered by controlling both the number of ZnO ALD cycles and the properties of the MoS 2 substrates, which are prepared by sulfurizing ALD MoO 3 . Analysis of the chemical composition combined with electron microscopy and synchrotron X-ray techniques as a function of the number of ZnO ALD cycles, together with the results of quantum chemical calculations, help elucidate the ZnO growth mechanism and its dependence on the properties of the MoS 2 substrate. The defect density and grain size of MoS 2 nanosheets are controlled by the sulfurization temperature of ALD MoO 3 , and the ZnO NCs in turn nucleate selectively at defect sites on MoS 2 surface and enlarge with increasing ALD cycle numbers. At higher ALD cycle numbers, the coalescence of ZnO NCs contributes to an increase in areal coverage and NC size. Furthermore, the geometry of the hybrid structures can be tuned by changing the dimensionality of the MoS 2 , by employing vertical NWs of MoS 2 as the substrate for ALD ZnO NCs, which in turn leads to improvement of the relevant surface-to-volume ratio. Such materials are expected to find use in newly expanded applications, especially those such as sensors or photo-devices based on a p-n heterojunction which relies on coupling transition metal dichalcogenides (TMDCs) with NCs.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Super-resolution imaging of non-fluorescent reactions via competition

Super-resolved fluorescence microscopy techniques have enabled substantial advances in the chemical and biological sciences. However, they can only interrogate entities that fluoresce, and most chemical or biological processes do not involve fluorescent species. Here we report a competition-enabled imaging technique with super-resolution (COMPEITS) (a COMPetition-Enabled Imaging Technique with Super-resolution) that enables quantitative super-resolution imaging of non-fluorescent processes. It is based on the incorporation of competition into a single-molecule fluorescence-detection scheme. We demonstrate COMPEITS by investigating a photoelectrocatalytic reaction; we map, with nanometre precision, a non-fluorescent surface reaction that is important for water decontamination on single photocatalyst particles. The subparticle-level quantitative information of reactant adsorption affinities unambiguously decouples size- and shape-scaling laws on specific particle facets and uncovers a surprising biphasic shape dependence, leading to catalyst design principles for optimal reactant adsorption efficacy. With its ability to provide spatially resolved information on the behaviours of unlabelled, non-fluorescent entities under operando conditions, COMPEITS could interrogate a variety of surface processes in fields ranging from heterogeneous catalysis and materials engineering to nanotechnology and energy sciences.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Rapid advances enabling high-performance inverted perovskite solar cells

Perovskite solar cells (PSCs) that have a positive–intrinsic–negative (p–i–n, or often referred to as inverted) structure are becoming increasingly attractive for commercialization owing to their rapid increase in power conversion efficiency, easily scalable fabrication, reliable operation and compatibility with various perovskite-based tandem device configurations. In this report we review key material and device considerations for making highly efficient and stable p–i–n PSCs. First, we summarize key advances in charge transport materials, which were critical to the rapid power conversion efficiency progress. Second, we discuss promising perovskite compositions and fabrication methods. We highlight various additive engineering approaches to improve the perovskite layer as well as interface engineering strategies that target either the buried or top perovskite surface layer. Third, we review progress in tandem devices, focusing on optimization of the interconnection layer. Next, we summarize the status and strategies for improving p–i–n PSC stability, especially considering the challenges of outdoor applications. We also provide prospects for future research directions and challenges.

14 SOLAR ENERGY↗
DOE OSTI2018

Monitoring solid metal structures with a nervous system embedded with ultrasonic 3D printing

Active and regular monitoring of structural components is a critical safety precaution, particularly as it concerns infrastructure, aerospace, industry, and many other applications. Solutions for effective structural health monitoring need to be able to probe surface and bulk properties using durable and low-power engineering. Towards these ends it is possible to build smarter, highly networked, and secure materials in order to enable remote real-time material sensing with a lesser-known form of 3D printing, ultrasonic consolidation (UC). This approach harnesses sound waves to weld metal layers in a low temperature process that does not damage sensors and electronics as they are embedded into a solid metal structure. This makes UC perfectly suited for designing solid metal parts with active embedded sensing components. However, the process parameters, material influences and mechanical factors that result in high-quality UC metal components are difficult to control or are loosely understood. The use of trial-and-error optimization during fabrication represents the chief hurdle between its current state of use and its potential to transform rapid prototyping and manufacturing of high-impact technologies (e.g., metal smart structures, wearable sensors, lab-on-a-chip, etc.). In this paper we will describe how embedded sensors may be used for in situ process monitoring and optimization. We will also discuss efforts towards standardizing UC welding for similar and dissimilar metal bonding and for embedding active sensors that can be used to create smart structures that will enable long-term structural health monitoring and other high impact applications.

Suter, Jonathan D.↗
DOE OSTI2018

Studying the Dependence of the Aerodynamic Characteristics of Rotating Cylinders on the Rake Angle of Air Flow

The results of experimental studies on estimating the lift force and lift coefficient of a rotating cylinder of constant cross section are presented. The data on the effect of the flow rake angle on the aerodynamic characteristics of rotating cylinders within a range of angles from 0° to 90° are analyzed. It has been established that a decrease in the lift coefficient is observed at flow rake angles above 30°, so the wind engine element shows a positive result within a range of rake angles from–30 ° ≤ α ≤ 30°. The data of these experimental studies can be used for the development of wind engines with blades designed as rotating cylinders with a smooth surface.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗