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GdRh is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Gd is bonded in a body-centered cubic geometry to eight equivalent Rh atoms. All Gd–Rh bond lengths are 3.01 Å. Rh is bonded in a body-centered cubic geometry to eight equivalent Gd atoms.
ScRh is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Sc is bonded in a body-centered cubic geometry to eight equivalent Rh atoms. All Sc–Rh bond lengths are 2.80 Å. Rh is bonded in a body-centered cubic geometry to eight equivalent Sc atoms.
RhY is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Y is bonded in a body-centered cubic geometry to eight equivalent Rh atoms. All Y–Rh bond lengths are 2.98 Å. Rh is bonded in a body-centered cubic geometry to eight equivalent Y atoms.
FeRh is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Fe is bonded in a body-centered cubic geometry to eight equivalent Rh atoms. All Fe–Rh bond lengths are 2.61 Å. Rh is bonded in a body-centered cubic geometry to eight equivalent Fe atoms.
NbRh is Tetraauricupride structured and crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. Nb is bonded to eight equivalent Rh atoms to form a mixture of distorted face, edge, and corner-sharing NbRh8 cuboctahedra. All Nb–Rh bond lengths are 2.81 Å. Rh is bonded to eight equivalent Nb atoms to form a mixture of distorted face, edge, and corner-sharing RhNb8 cuboctahedra.
GdRh2B2C crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Gd3+ is bonded in a square co-planar geometry to four equivalent C4- atoms. All Gd–C bond lengths are 2.70 Å. Rh+3.50+ is bonded to four equivalent B3- atoms to form a mixture of edge and corner-sharing RhB4 tetrahedra. All Rh–B bond lengths are 2.20 Å. B3- is bonded in a distorted single-bond geometry to four equivalent Rh+3.50+ and one C4- atom. The B–C bond length is 1.50 Å. C4- is bonded in a distorted linear geometry to four equivalent Gd3+ and two equivalent B3- atoms.
CeRhIn5 crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. Ce is bonded to twelve In atoms to form CeIn12 cuboctahedra that share corners with four equivalent CeIn12 cuboctahedra, faces with four equivalent CeIn12 cuboctahedra, and faces with four equivalent InCe4In8 cuboctahedra. There are eight shorter (3.29 Å) and four longer (3.33 Å) Ce–In bond lengths. Rh is bonded in a body-centered cubic geometry to eight equivalent In atoms. All Rh–In bond lengths are 2.79 Å. There are two inequivalent In sites. In the first In site, In is bonded to four equivalent Ce and eight equivalent In atoms to form distorted InCe4In8 cuboctahedra that share corners with four equivalent InCe4In8 cuboctahedra, faces with four equivalent CeIn12 cuboctahedra, and faces with four equivalent InCe4In8 cuboctahedra. All In–In bond lengths are 3.29 Å. In the second In site, In is bonded in a 4-coordinate geometry to two equivalent Ce, two equivalent Rh, and two equivalent In atoms.
TbRhIn5 crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. Tb is bonded to twelve In atoms to form TbIn12 cuboctahedra that share corners with four equivalent TbIn12 cuboctahedra, faces with four equivalent TbIn12 cuboctahedra, and faces with four equivalent InTb4In8 cuboctahedra. There are eight shorter (3.26 Å) and four longer (3.30 Å) Tb–In bond lengths. Rh is bonded in a body-centered cubic geometry to eight equivalent In atoms. All Rh–In bond lengths are 2.78 Å. There are two inequivalent In sites. In the first In site, In is bonded to four equivalent Tb and eight equivalent In atoms to form distorted InTb4In8 cuboctahedra that share corners with four equivalent InTb4In8 cuboctahedra, faces with four equivalent TbIn12 cuboctahedra, and faces with four equivalent InTb4In8 cuboctahedra. All In–In bond lengths are 3.26 Å. In the second In site, In is bonded in a 4-coordinate geometry to two equivalent Tb, two equivalent Rh, and two equivalent In atoms.
RhGe crystallizes in the cubic P2_13 space group. The structure is three-dimensional. Rh is bonded in a 4-coordinate geometry to seven equivalent Ge atoms. There are a spread of Rh–Ge bond distances ranging from 2.47–2.84 Å. Ge is bonded in a 7-coordinate geometry to seven equivalent Rh atoms.
DyRhIn5 crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. Dy is bonded to twelve In atoms to form DyIn12 cuboctahedra that share corners with four equivalent DyIn12 cuboctahedra, faces with four equivalent DyIn12 cuboctahedra, and faces with four equivalent InDy4In8 cuboctahedra. There are eight shorter (3.26 Å) and four longer (3.29 Å) Dy–In bond lengths. Rh is bonded in a body-centered cubic geometry to eight equivalent In atoms. All Rh–In bond lengths are 2.77 Å. There are two inequivalent In sites. In the first In site, In is bonded to four equivalent Dy and eight equivalent In atoms to form distorted InDy4In8 cuboctahedra that share corners with four equivalent InDy4In8 cuboctahedra, faces with four equivalent DyIn12 cuboctahedra, and faces with four equivalent InDy4In8 cuboctahedra. All In–In bond lengths are 3.26 Å. In the second In site, In is bonded in a 4-coordinate geometry to two equivalent Dy, two equivalent Rh, and two equivalent In atoms.
(Mn3Rh)2N2 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional and consists of one ammonia molecule and one Mn3Rh framework. In the Mn3Rh framework, Mn is bonded in a linear geometry to two equivalent Rh atoms. Both Mn–Rh bond lengths are 2.41 Å. Rh is bonded to six equivalent Mn atoms to form corner-sharing RhMn6 octahedra. The corner-sharing octahedral tilt angles are 0°.
LaRhIn5 crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. La is bonded to twelve In atoms to form LaIn12 cuboctahedra that share corners with four equivalent LaIn12 cuboctahedra, faces with four equivalent LaIn12 cuboctahedra, and faces with four equivalent InLa4In8 cuboctahedra. All La–In bond lengths are 3.35 Å. Rh is bonded in a body-centered cubic geometry to eight equivalent In atoms. All Rh–In bond lengths are 2.80 Å. There are two inequivalent In sites. In the first In site, In is bonded to four equivalent La and eight equivalent In atoms to form distorted InLa4In8 cuboctahedra that share corners with four equivalent InLa4In8 cuboctahedra, faces with four equivalent LaIn12 cuboctahedra, and faces with four equivalent InLa4In8 cuboctahedra. All In–In bond lengths are 3.35 Å. In the second In site, In is bonded in a 2-coordinate geometry to two equivalent La, two equivalent Rh, and two equivalent In atoms.
HoRh is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Ho is bonded in a body-centered cubic geometry to eight equivalent Rh atoms. All Ho–Rh bond lengths are 2.96 Å. Rh is bonded in a body-centered cubic geometry to eight equivalent Ho atoms.
RhGe is Modderite structured and crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Rh is bonded in a 6-coordinate geometry to six equivalent Ge atoms. There are a spread of Rh–Ge bond distances ranging from 2.49–2.59 Å. Ge is bonded in a 6-coordinate geometry to six equivalent Rh atoms.
RhBi is alpha-derived structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Rh is bonded in a 12-coordinate geometry to six equivalent Bi atoms. All Rh–Bi bond lengths are 2.87 Å. Bi is bonded in a 12-coordinate geometry to six equivalent Rh atoms.
Rh2As is Fluorite structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Rh is bonded to four equivalent As atoms to form a mixture of distorted corner and edge-sharing RhAs4 tetrahedra. All Rh–As bond lengths are 2.49 Å. As is bonded in a body-centered cubic geometry to eight equivalent Rh atoms.
DyRh is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Dy is bonded in a body-centered cubic geometry to eight equivalent Rh atoms. All Dy–Rh bond lengths are 2.97 Å. Rh is bonded in a body-centered cubic geometry to eight equivalent Dy atoms.
ErRh is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Er is bonded in a body-centered cubic geometry to eight equivalent Rh atoms. All Er–Rh bond lengths are 2.94 Å. Rh is bonded in a body-centered cubic geometry to eight equivalent Er atoms.