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At least 1,729 records · Page 96
All sourcesNASA NTRSDOE OSTI
DOE OSTI2014

Anticancer Properties of Novel Rhenium Pentylcarbanato Compounds against MDA-MB-468(HTB-132) Triple Node Negative Human Breast Cancer Cell Lines

To study the efficacy of novel rhenium compounds to treat triple node negative breast cancer. Six (6) novel rhenium pentycarbanato compounds (PC1-6) were synthesized and triple node negative breast cancer cell lines HTB-132 and Balb/c mouse kidney cell lines were treated with each of them for 48 hours. The results were analyzed by a common trypan blue cell death assay system and statistically analyzed. Place and Duration: The compounds were synthesized, analyzed and evaluated at the Department of Chemistryof Morgan State University, Baltimore, Maryland and the Pharmaceutical Sciences Department of Elizabeth City State University campus of the University of North Carolina system. The novel rhenium compounds were synthesized from one-pot reactions of Re2(CO)10 with the corresponding α-diimine ligands in 1-pentanol.The compounds were characterized spectroscopically. The cell lines were cultured by standard cell culture procedure and treated with each of the six compounds in DMSO for 48 hours with a negative control and a DMSO vehicular control along with a cisplatin positive control.The cytotoxicity was evaluated by standard trypan blue assay and the results were statistically analyzed. The trypan blueassay reveals that these compounds have significant cytotoxicity against MDA-MB-468 (HTB-132) triple node negative breast cancer cell lines and are less nephrotoxic than cisplatin. The novel rhenium compounds PC 1-6 can potentially find applications in the treatment of highly malignant triple node negative breast cancer.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2025

Medium Voltage Testbed for Comparing Advanced Power Line Sensors vs. Transformers with Electrical Grid Events

Electrical utilities have relied upon potential transformers (PTs) and current transformers (CTs) for very accurate metering and to provide reliable signals for protective relays. These devices measure phase voltages and currents and are commissioned by electrical engineers. PTs/CTs can detect and react to various electrical anomalies that could adversely affect electrical grid operations. Less expensive alternative sensing technologies offer the possibility of wider deployment, particularly in grids that employ distributed energy resources. In this work, the performance of an advanced medium-voltage sensor is compared with that of a reference PT and a CT and experimentally evaluated for different power grid scenarios on an advanced outdoor power line sensor testbed at the U.S. Department of Energy’s Oak Ridge National Laboratory. The sensor is based on a capacitive divider for voltage monitoring and a Rogowski coil with an integrator for current monitoring. This study simulated a power grid model based on a utility circuit at the Riverside EPB of Chattanooga. The simulation circuit was created with MATLAB/Simulink software and was integrated into an RT-LAB project to run with the OP4510 real-time simulator at the OPLST. During the tests, the real-time simulations were run for 40 s, and the signal to record the test event with the power meter was set at 30 s for the event-trigger circuit. The advanced outdoor power line sensor testbed has a real-time simulator that is used to generate transient scenarios (e.g., electrical faults, capacitor bank operation, and service restoration), while the analog signals are recorded by the same high-resolution power meter. The behaviors of analog signals, harmonic components, total harmonic distortion, and crest factors are assessed for this power line sensor and compared with those of the reference PT/CT because of the absence of testing standards for advanced outdoor power line sensors. The results showed that this OPLS technology responded identically to the PT and CT under all conditions.

Piesciorovsky, Emilio [ORNL]↗
NASA NTRS1968

Vacuum-jacketed transfer line installation technique

Rolling-type spacers in the form of steel balls retained in appropriate sleeves affixed at intervals to the exterior of the transfer line facilitate the installation of a vacuum-jacketed line. They act as standoffs to position the transfer line concentrically within the vacuum jacket line.

Bowers, W. M.↗
NASA NTRS1971

A study of LC-39 cryogenic systems. Part 1: A study of the vacuum insulated transfer lines at Kennedy Space Center. Part 2: Cooldown pressure surges

The vacuum liquid hydrogen and liquid oxygen transfer lines at Kennedy Space Center were studied to evaluate the feasibility of using a condensing gas such as CO2 inside the vacuum spaces to achieve a condensing-vacuum. The study indicates that at ambient temperature, a maximum vacuum hyphen space pressure of 4000 microns is acceptable for the LH2 transfer lines. In addition, the cooldown procedures for the 14-inch cross-country liquid oxygen line was studied using a simplified mathematical model. Preliminary cooldown times are presented for various heat leak rates to the line and for two vent configurations.

Ludtke, P. R.↗
NASA NTRS1972

An investigation of satellites to the resonance lines in some hydrogen-like ions

An experimental and theoretical investigation was conducted on the origin of satellite to resonance lines of the hydrogen-like ions of boron, carbon, and nitrogen. A theta pinch was employed with a grazing incidence spectrograph to measure the wavelengths of the satellites. The spectroscopic data also provided an estimate of the satellite/resonance line intensity ratio. Wavelengths of spectral lines due to transition from doubly excited states were calculated by a Hartree-Fock computer program. Wave functions were also calculated and were used to obtain the oscillator strengths of the transitions. Experimental work confirmed that the lines investigated were not satellites but were due to highly ionized argon which was present as an impurity in the filling gas.

Jalufka, N. W.↗
NASA NTRS1972

Computer-aided CO2 laser cavity-length selection for reduced line competition

The advantages of carbon dioxide lasers for space communications systems are considered. An attempt was made to predict the signature of CO2 lasers. It was found that this requires accurate data on the laser wavelengths (accuracy on the order of 10 MHz). The results of absolute frequency measurements of CO2 lines were utilized, and a list of accurate frequencies was calculated. A computer program was written for the signature prediction. A second program was written which searches through large ranges of cavity length and prints lists of regions where a particular line is well separated from adjacent lines in the signature. Lasers designed according to this list will have an undisturbed tuning profile for one or more lines.

Schiffner, G.↗
NASA NTRS1972

The influence of line shape and band structure on temperatures in planetary atmospheres

Numerical experiments are performed to examine the effects of line shape and band structure on the radiative equilibrium temperature profile in planetary atmospheres. In order to accurately determine these effects, a method for calculating radiative terms is developed which avoids the usual approximations. It differs from the more commonly used methods in that it allows arbitrary dependence of the absorption coefficient on wave number, without requiring tedious line by line integration and without the constraints of band models. The present formulation is restricted to homogeneous atmospheres but the concept can be extended to the more general case. The numerical experiments reveal that the line shape and band structure of the absorbing gases have a large effect on temperatures in the higher layers of the atmosphere (corresponding to the stratosphere and mesosphere). The more nongrey the spectrum (that is, the higher the peaks and the deeper the troughs in the spectrum), the lower the temperature.

Arking, A.↗
NASA NTRS1972

Metal line blanketing and opacity in the ultraviolet of alpha 2 Canum Venaticorum

Ultraviolet photometry by OAO-2 was made of alpha 2 CVn covering the entire 5.5d period of this magnetic Ap variable. The light curves ranging from 1330 A to 3320 A indicate the dominant role of rare-earth line-blanketing in redistributing flux. In a broad depression of the continuum covering 2300-2600 A, scanner observations possibly identify strong lines of Eu III as major contributors to this feature. At maximum intensity of the rare-earth lines, the ultraviolet continuum shortward of 2900 A is greatly diminished while the longer wavelength regions into the visual become brighter. In addition, there is evidence that the hydrogen line opacity is variable and the photoionization edge of Si I at 1680 A is identified.

Molnar, M. R.↗
NASA NTRS1971

Dispersion studies of the 22 GHz water vapor line shape. II - Instrumental correction.

Anomalies in the resonance dispersion of the pressure-broadened water vapor line at a frequency of 22.235 GHz are resolved. The pressure-scanning differential-refraction spectrometer gives rise to a signal enhancement as the line center moves within the width of the dispersion discriminator. Resonance absorption prevents the frequency of peak transmitted power from coinciding with the resonance condition of zero phase. The results reported for the 23.6 GHz rotational line of ethylene oxide show a Lorentzian molecular line shape.

Dillon, T. A.↗
NASA NTRS1972

Comparison of experimental and theoretical pressure-broadened atomic line shapes.

Line-structure calculations of the longer wavelength resonance line of cesium pressurized by argon are compared with experimental values over a range of perturber relative densities from 0.5 to 61. The main features of the line shapes are reproduced by the general pressures method using Lennard-Jones potentials. The calculations indicate that results are very sensitive to the potential parameters employed, but are not sensitive to changes in the temperature. The data are also compared with the method that makes the quasi-static approximation and with the high-pressure limit that leads to a Gaussian line profile. The former technique yields good agreement over the range of pressures where the approximation is warranted, and the latter appears to have several disadvantages.

Atakan, A. K.↗
NASA NTRS1972

Formation of spectral lines in planetary atmospheres. I - Theory for cloudy atmospheres: Application to Venus.

The theory of the formation of spectral lines in a cloudy planetary atmosphere is studied in detail. It is shown that models based upon homogeneous, isotropically scattering atmospheres cannot be used to reproduce observed spectroscopic features of phase effect and the shape of spectral lines for weak and strong bands. The theory must, therefore, be developed using an inhomogeneous (gravitational) model of a planetary atmosphere, accurately incorporating all the physical processes of radiative transfer. Such a model of the lower Venus atmosphere, consistent with our present knowledge, is constructed. The results discussed in this article demonstrate the effects of the parameters that describe the atmospheric model on the spectroscopic features of spectral line profile and phase effect, at visible and near infrared wavelengths. This information enables us to develop a comprehensive theory of line formation in a Venus atmosphere.

Hunt, G. E.↗
NASA NTRS1972

Measurement and calculation of the Stark-broadening parameters for the resonance lines of singly ionized calcium and magnesium.

The electron-impact-broadened profiles of the resonance lines of singly ionized calcium and magnesium have been measured using an electromagnetically driven shock tube and a rapid-scanning Fabry-Perot spectrometer. For an electron density of 10 to the 17th power per cu cm and a temperature of 19,000 K, we found the Lorentzian half-width of the Ca+ line to be 0.086 A plus or minus 10% and of the Mg+ line to be 0.044 A plus or minus 10%. Using the quantum-mechanical theory of Barnes and Peach and our semiclassical calculation for the calcium lines, we found that the temperature dependence of the theoretical curves is close to that measured, although both theories predict actual values which are somewhat large.

Jones, W. W.↗
NASA NTRS1972

Field line motion in the presence of finite conductivity.

The relation of plasma motion to field line motion is determined in the case where the conductivity is imperfect. The imperfect conductivity may result from collisions between plasma particles and neutrals, as in the case of the earth's ionosphere, or from the scattering of charged particles by the enhanced field fluctuations which characterize a turbulent plasma. A magnetic field is assumed which is a given, known function of space and time, and it is further assumed that all field lines intersect an ideally conducting surface and are identified by their points of intersection. It is shown that the relative displacement between drifting particles and moving field lines has significance only when compared with some other pertinent length such as the total particle drift distance. In such a comparison, when the latter quantity is much larger than the first, the particles can be followed by tracing field lines.

Birmingham, T. J.↗
NASA NTRS1973

Apollo experience report: Evolution of the attitude time line

The evolution of the attitude time line is discussed. Emphasis is placed on the operational need for and constraints on the time line and on how these factors were involved in the time line generation procedure. Examples of constraints on and applications of the complete time line are given.

Duncan, R. D.↗
NASA NTRS1973

Thermal expansion method for lining tantalum alloy tubing with tungsten

A differential-thermal expansion method was developed to line T-111 (tantalum - 8 percent tungsten - 2 percent hafnium) tubing with a tungsten diffusion barrier as part of a fuel element fabrication study for a space power nuclear reactor concept. This method uses a steel mandrel, which has a larger thermal expansion than T-111, to force the tungsten against the inside of the T-111 tube. Variables investigated include lining temperature, initial assembly gas size, and tube length. Linear integrity increased with increasing lining temperature and decreasing gap size. The method should have more general applicability where cylinders must be lined with a thin layer of a second material.

Watson, G. K.↗
NASA NTRS1972

Search for coronal line emission from the Cygnus Loop.

The flux from the edges of the Cygnus Loop in the forbidden Fe XIV coronal line at 5303 A is measured to be less than 5 nanoergs per sq cm per sterad per sec (0.017 R) in a 3 A band centered on the line. This upper limit is an order of magnitude lower than the predicted total flux in the line and implies that there must be substantial broadening of the line profile by mass motion or that the temperature is somewhat higher than the present best estimate from X-ray data.

Kurtz, D. W.↗
NASA NTRS1973

An inverse theorem about the magnetic field line velocity.

It is shown that every field line velocity is associated with a set of Euler potentials (alpha prime, beta prime) such that particles moving with this velocity observe constant values of alpha prime and beta prime. The field line and flux preservation properties of the motion follow immediately, and a short independent proof of the Helmholtz-Zorawski criterion for field line preservation is also given. Arguments are given to show that in general it is not possible to single out one 'basic' field line velocity when only the time dependent magnetic field configuration is given.

Stern, D. P.↗
NASA NTRS1973

Stark broadening of high-principal-quantum-number n-alpha lines of hydrogen.

High n-alpha lines (transitions n + 1 to n) with quantum numbers n between 50 and 250 have been observed emanating from galactic H II regions where the electron density and temperature are about 1000/cu cm and 1 eV, respectively. High n-alpha lines have not previously been seen in the laboratory where fairly homogeneous plasmas may be produced and relatively precise measurements of electron densities and temperatures can be made. The present work describes experiments where the first members of the hydrogen line series with lower states n = 10, 11, 12, and 13 have been detected in a laboratory plasma. The width of the 12-alpha line at 88.7 microns could be measured and was consistent with calculated broadening from elastic electron collisions and quasi-static ion effects.

Lasalle, T. R.↗