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At least 1,729 records · Page 96
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Super‐Hydrophilic Microporous Ni(OH) x /Ni 3 S 2 Heterostructure Electrocatalyst for Large‐Current‐Density Hydrogen Evolution

Abstract Exploiting active and stable non‐precious metal electrocatalysts for alkaline hydrogen evolution reaction (HER) at large current density plays a key role in realizing large‐scale industrial hydrogen generation. Herein, a self‐supported microporous Ni(OH) x /Ni 3 S 2 heterostructure electrocatalyst on nickel foam (Ni(OH) x /Ni 3 S 2 /NF) that possesses super‐hydrophilic property through an electrochemical process is rationally designed and fabricated. Benefiting from the super‐hydrophilic property, microporous feature, and self‐supported structure, the electrocatalyst exhibits an exceptional HER performance at large current density in 1.0 M KOH, only requiring low overpotential of 126, 193, and 238 mV to reach a current density of 100, 500, and 1000 mA cm −2 , respectively, and displaying a long‐term durability up to 1000 h, which is among the state‐of‐the‐art non‐precious metal electrocatalysts. Combining hard X‐rays absorption spectroscopy and first‐principles calculation, it also reveals that the strong electronic coupling at the interface of the heterostructure facilitates the dissociation of H 2 O molecular, accelerating the HER kinetics in alkaline electrolyte. This work sheds a light on developing advanced non‐precious metal electrocatalysts for industrial hydrogen production by means of constructing a super‐hydrophilic microporous heterostructure.

Chemistry↗
DOE OSTI2023

Electrochemical properties of Gd(III) ions in LiCl-KCl-GdCl 3 at 723–1023 K

Electrochemical behavior of Gd(III) ions in molten LiCl-KCl-GdCl 3 was investigated at 723–1023 K via cyclic voltammetry using tungsten as a working electrode, Gd-Bi (mole fraction, x Gd = 0.16) as a reference electrode, and Gd-Bi (x Gd = 0.02) as a counter electrode. A single reduction–oxidation wave was observed, confirming a single-step, 3-electron transfer Gd(III)/Gd transition. The cathodic peak potential exhibited minimal change (<13 mV) over a wide range of scan rates (0.05–0.30 V s –1 ), indicating facile charge transfer kinetics (i.e., a reversible electrode process). A nucleation overpotential associated with solid Gd deposition was observable at low temperatures (T < 823 K). The mass transport properties of Gd(III) ions were estimated using the Berzins and Delahay relation based on diffusion-limiting peak current. The diffusivity values were determined to be D Gd(III) = 0.5–2.7 × 10 –5 cm 2 s –1 at 723–1023 K with an associated activation energy of E a = 33.9 (±1.0) kJ mol –1 . Finally, the two-phase [liquid + GdBi] Gd-Bi alloy reference electrode experienced less than 0.5 mV of drift over 5 days of repeated electrochemical measurements, indicating high stability.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Power and energy capacity tradeoffs in an all-aqueous copper thermally regenerative ammonia battery

Thermally regenerative ammonia batteries (TRABs) can provide energy storage and produce electrical power from low-grade waste heat instead of electricity. The use of all-aqueous copper-based electrolytes has recently produced higher power densities than those achieved using previous TRAB approaches based on reversible metal deposition and dissolution processes, but further gains are possible in power and energy density. We investigated the limitations of power and energy density and how they are impacted by the electrolyte composition and discharge currents. By increasing the ammonia concentration from 1 to 5 M, the power density of the battery increased from 11.2 to 28.5 mW cm –2 , but the energy density decreased from 0.56 to 0.31 Wh L –1 . Increasing discharge current densities from 4 to 12.5 mA cm –2 increased the average power density during discharge from 2.4 to 5.9 mW cm –2 without appreciable losses in energy density. Increasing the copper concentration from 0.1 to 0.5 M increased both energy density to 2.15 Wh L –1 and energy efficiency to 2.2% but did not substantially impact the power density. Furthermore, these results represent the highest performance metrics achieved for a low-grade waste heat to electricity system.

25 ENERGY STORAGE↗
DOE OSTI2020

Polymeric Electron-Selective Contact for Crystalline Silicon Solar Cells with an Efficiency Exceeding 19%

Carrier-selective contacts have become a prominent path forward toward efficient crystalline silicon (c-Si) photovoltaics. Among the proposed contacting materials, organic materials may offer simplified and low-cost processing compared with typical vacuum deposition techniques. In this paper, branched polyethylenimine (b-PEI) is presented as an electron-transport layer (ETL) for c-Si solar cells. The incorporation of a b-PEI interlayer between c-Si(n) and Al leads to a low contact resistivity of 24 mΩ cm 2 . A silicon heterojunction solar cell integrated with b-PEI is demonstrated achieving a power conversion efficiency of 19.4%, which improves the benchmark efficiency of a c-Si solar cell with an organic ETL. This electron selectivity of b-PEI is attributed to its Lewis basicity, i.e., electron-donating ability, promoting favorable band bending at the c-Si surface for electron transport. Moreover, several other Lewis base polymers perform as efficient ETLs in organic/c-Si hybrid devices, indicating Lewis basicity could be a guideline for future organic ETL design.

14 SOLAR ENERGY↗
DOE OSTI2020

Improving Low-Bandgap Tin–Lead Perovskite Solar Cells via Contact Engineering and Gas Quench Processing

Low-bandgap Sn/Pb ABX 3 perovskites have reached photovoltaic power conversion efficiencies >20%, but they usually have poor stability due to the common use of acidic poly(3,4-ethylenedioxythiophene):polystyrenesulfonate (PEDOT:PSS) hole transport layers and A-site cation compositions containing methylammonium (MA). In this work, we develop a process to enable high-quality MA-free Sn/Pb perovskite films grown using a gas quenching process instead of the conventional antisolvents, which provides improved control of the film growth and eliminates wrinkling. Using this method in a device structure with poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine] (PTAA) instead of PEDOT:PSS as the hole transport layer, devices can reach efficiencies up to 20% mppt at 0.06 cm 2 and up to 17.5% mppt at 1 cm 2 active area. With these improvements, the devices are characterized for thermal stability and show 80% of the initial power output remaining after 4000 h at 85 °C.

14 SOLAR ENERGY↗
DOE OSTI2022

Low-Tortuosity Thick Electrodes with Active Materials Gradient Design for Enhanced Energy Storage

The ever-growing energy demand of modern society calls for the development of high-loading and high-energy-density batteries, and substantial research efforts are required to optimize electrode microstructures for improved energy storage. Low-tortuosity architecture proves effective in promoting charge transport kinetics in thick electrodes; however, heterogeneous electrochemical mass transport along the depth direction is inevitable, especially at high C-rates. In this work, we create an active material gradient in low-tortuosity electrodes along ion-transport direction to compensate for uneven reaction kinetics and the nonuniform lithiation/delithiation process in thick electrodes. The gradual decrease of active material concentration from the separator to the current collector reduces the integrated ion diffusion distance and accelerates the electrochemical reaction kinetics, leading to improved rate capabilities. Further, the structure advantages combining low-tortuosity pores and active material gradient offer high mass loading (60 mg cm –2 ) and enhanced performance. Comprehensive understanding of the effect of active material gradient architecture on electrode kinetics has been elucidated by electrochemical characterization and simulations, which can be useful for development of batteries with high-energy/power densities.

25 ENERGY STORAGE↗
DOE OSTI2023

In situ investigation of ion irradiation-induced amorphization of (Ge 2 Sb 2 Te 5 ) 1−x C x [0 ≤ x ≤ 0.12]

Chalcogenide thin films that undergo reversible phase changes show promise for use in next-generation nanophotonics, microelectronics, and other emerging technologies. One of the many studied compounds, Ge2Sb2Te5, has demonstrated several useful properties and performance characteristics. However, the efficacy of benchmark Ge2Sb2Te5 is restricted by amorphous phase thermal stability below ∼150 °C, limiting its potential use in high-temperature applications. In response, previous studies have added a fourth species (e.g., C) to sputter-deposited Ge2Sb2Te5, demonstrating improved thermal stability. Our current research confirms reported thermal stability enhancements and assesses the effects of carbon on crystalline phase radiation response. Through in situ transmission electron microscope irradiation studies, we examine the effect of C addition on the amorphization behavior of initially cubic and trigonal polycrystalline films irradiated using 2.8 MeV Au to various doses up to 1 × 1015 cm −2 . It was found that increased C content reduces radiation tolerance of both cubic and trigonal phases.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Laminography as a tool for imaging large-size samples with high resolution

Despite the increased brilliance of the new generation synchrotron sources, there is still a challenge with high-resolution scanning of very thick and absorbing samples, such as a whole mouse brain stained with heavy elements, and, extending further, brains of primates. Samples are typically cut into smaller parts, to ensure a sufficient X-ray transmission, and scanned separately. Compared with the standard tomography setup where the sample would be cut into many pillars, the laminographic geometry operates with slab-shaped sections significantly reducing the number of sample parts to be prepared, the cutting damage and data stitching problems. In this work, a laminography pipeline for imaging large samples (>1 cm) at micrometre resolution is presented. The implementation includes a low-cost instrument setup installed at the 2-BM micro-CT beamline of the Advanced Photon Source. Additionally, sample mounting, scanning techniques, data stitching procedures, a fast reconstruction algorithm with low computational complexity, and accelerated reconstruction on multi-GPU systems for processing large-scale datasets are presented. The applicability of the whole laminography pipeline was demonstrated by imaging four sequential slabs throughout an entire mouse brain sample stained with osmium, in total generating approximately 12 TB of raw data for reconstruction.

47 OTHER INSTRUMENTATION↗
DOE OSTI2022

Ozone depletion in the Arctic and Antarctic stratosphere induced by wildfire smoke

Abstract. A record-breaking stratospheric ozone loss was observed over the Arctic and Antarctica in 2020. Strong ozone depletion occurred over Antarctica in 2021 as well. The ozone holes developed in smoke-polluted air. In this article, the impact of Siberian and Australian wildfire smoke (dominated by organic aerosol) on the extraordinarily strong ozone reduction is discussed. The study is based on aerosol lidar observations in the North Pole region (October 2019–May 2020) and over Punta Arenas in southern Chile at 53.2∘ S (January 2020–November 2021) as well as on respective NDACC (Network for the Detection of Atmospheric Composition Change) ozone profile observations in the Arctic (Ny-Ålesund) and Antarctica (Neumayer and South Pole stations) in 2020 and 2021. We present a conceptual approach on how the smoke may have influenced the formation of polar stratospheric clouds (PSCs), which are of key importance in the ozone-depleting processes. The main results are as follows: (a) the direct impact of wildfire smoke below the PSC height range (at 10–12 km) on ozone reduction seems to be similar to well-known volcanic sulfate aerosol effects. At heights of 10–12 km, smoke particle surface area (SA) concentrations of 5–7 µm2 cm−3 (Antarctica, spring 2021) and 6–10 µm2 cm−3 (Arctic, spring 2020) were correlated with an ozone reduction in terms of ozone partial pressure of 0.4–1.2 mPa (about 30 % further ozone reduction over Antarctica) and of 2–3.5 mPa (Arctic, 20 %–30 % reduction with respect to the long-term springtime mean). (b) Within the PSC height range, we found indications that smoke was able to slightly increase the PSC particle number and surface area concentration. In particular, a smoke-related additional ozone loss of 1–2 mPa (10 %–20 % contribution to the total ozone loss over Antarctica) was observed in the 14–23 km PSC height range in September–October 2020 and 2021. Smoke particle number concentrations ranged from 10 to 100 cm−3 and were about a factor of 10 (in 2020) and 5 (in 2021) above the stratospheric aerosol background level. Satellite observations indicated an additional mean column ozone loss (deviation from the long-term mean) of 26–30 Dobson units (9 %–10 %, September 2020, 2021) and 52–57 Dobson units (17 %–20 %, October 2020, 2021) in the smoke-polluted latitudinal Antarctic belt from 70–80∘ S.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1975

A real-time optical data processing device

The design, operation, and structure of the hybrid field effect light valve, a real-time input device for application to coherent optical data processing (CODP), is described. The device consists of a sandwich of thin films that electrically control the optical birefringence of a thin (2 micrometer) liquid crystal layer. It has high resolution (greater than 100 1/mm), contrast ratio (greater than 100:1), speed (10 sec on, 15 sec off) and input sensitivity (about 0.3 ergs/sq cm) in addition to cost and size advantages. Performance data for a laboratory model are presented.

Jacobson, A.↗
NASA NTRS1981

Three-axis electron-beam test facility

An electron beam test facility, which consists of a precision multidimensional manipulator built into an ultra-high-vacuum bell jar, was designed, fabricated, and operated at Lewis Research Center. The position within the bell jar of a Faraday cup which samples current in the electron beam under test, is controlled by the manipulator. Three orthogonal axes of motion are controlled by stepping motors driven by digital indexers, and the positions are displayed on electronic totalizers. In the transverse directions, the limits of travel are approximately + or - 2.5 cm from the center with a precision of 2.54 micron (0.0001 in.); in the axial direction, approximately 15.0 cm of travel are permitted with an accuracy of 12.7 micron (0.0005 in.). In addition, two manually operated motions are provided, the pitch and yaw of the Faraday cup with respect to the electron beam can be adjusted to within a few degrees. The current is sensed by pulse transformers and the data are processed by a dual channel box car averager with a digital output. The beam tester can be operated manually or it can be programmed for automated operation. In the automated mode, the beam tester is controlled by a microcomputer (installed at the test site) which communicates with a minicomputer at the central computing facility. The data are recorded and later processed by computer to obtain the desired graphical presentations.

Dayton, J. A., Jr.↗
NASA NTRS1988

Goldstone solar system radar

Planning, direction, experimental design, and coordination of data-acquisition and engineering activities in support of all Goldstone planetary radar astronomy were performed. This work demands familiarity with the various components of a planetary radar telescope (transmitter, receiver, antenna, computer hardware and software) as well as knowledge of how the entire system must function as a cohesive unit to meet the particular scientific objectives at hand in a given observation. Support radar data-processing facilities, currently being used for virtually all Goldstone data reduction includes: a VAX 11/780 computer system, an FPS 5210 array processor, terminals, tape drives, and image-display devices, as well as a large body of data-reduction software to accommodate the variety of data-acquisition formats and strategems. Successful 113-cm radar observation of Callisto and the near-Earth asteroid 1981 Midas and Goldstone/VLA radar observations of Saturn's rings were obtained. Quick-look verification programs from data taken with phase-coded cw (i.e., ranging) waveforms, applicable to Venus, the Moon, and small bodies were completed. Definition of scientific and engineering requirements on instrument performance, radar system configuration, and personnel, for all 1988 Goldstone radar investigations was accomplished.

Jurgens, Raymond F.↗
NASA NTRS1989

Aerosol anomalies in Nimbus-7 coastal zone color scanner data obtained in Japan area

About 400 CZCS (coastal zone color scanner) scenes covering the Japan area in November 1978-May 1982 were processed to study the applicability of the Gordon-Clark atmospheric correction scheme which produces water-leaving radiances Lw at 443 nm, 520 nm, and 550 nm as well as phytoplankton pigment maps. Typical spring-fall aerosol radiance in the images was found to be 0.8-1.5 micro-W/sq cm-nm-sr, which is about 50 percent more than reported for the US eastern coastal images. The correction for about half the data resulted in negative Lw (443) values, implying overestimation of the aerosol effect for this channel. Several possible reasons for this are considered, including deviation of the aerosol optical thickness tau(a) at 443 nm from that estimated by Angstrom's exponential law, which the algorithm assumes. The analysis shows that, assuming the use of the Gordon-Clark algorithm, and for a pigment concentration of about 1 microgram/l, -40 percent to +100 percent error in satellite estimates is common. Although this does not fully explain the negative Lw (443) in the satellite data, it seems to contribute to the problem significantly, together with other error sources, including one in the sensor calibration.

Fukushima, Hajime↗
NASA NTRS1992

The formation of coronal regions in accretion disks

A mechanism for heating the hot low-density gas or winds above accretion disks, which is similar to that used to model chromospheric heating in the sun and other stars, is proposed. Sound waves propagating through an accretion disk are refracted away from the central plane by the strong density gradient. As they move into regions of lower density, the sound waves accelerate to form shocks, which heat the gas, leading to the formation of a hot low-density region. The steeper density gradients present in disks make the process more efficient than in stellar atmospheres. Results of hydrodynamical simulations show that waves with frequencies similar to the local Keplerian frequency lead to the most efficient heating. For the optically thin region modeled in the present study, the result is the formation of coronal regions with densities less than about 10 exp 10/cu cm, and the temperatures ranging from 10 exp 4 to 6 K over a few scale heights. It is argued that the hot low-density gas which results from the shock heating is responsible for the observed UV lines from cataclysmic variables, as well as the spatially coincidental lines of H and He I.

Murray, Stephen D.↗
NASA NTRS1994

Energetic-particle abundances in impulsive solar flare events

We report on the abundances of energetic particles from impulsive solar flares, including those from a survey of 228 He-3 rich events, with He-3/He-4 is greater than 0.1, observed by the International Sun Earth Explorer (ISEE) 3 spacecraft from 1978 August through 1991 April. The rate of occurrence of these events corresponds to approximately 1000 events/yr on the solar disk at solar maximum. Thus the resonant plasma processes that enhance He-3 and heavy elements are a common occurrence in impulsive solar flares. To supply the observed fluence of He-3 in large events, the acceleration must be highly efficient and the source region must be relatively deep in the atmosphere at a density of more than 10(exp 10) atoms/cu cm. He-3/He-4 may decrease in very large impulsive events because of depletion of He-3 in the source region. The event-to-event variations in He-3/He-4, H/He-4, e/p, and Fe/C are uncorrelated in our event sample. Abundances of the elements show a pattern in which, relative to coronal composition, He-4, C, N, and O have normal abundance ratios, while Ne, Mg, and Si are enhanced by a factor approximately 2.5 and Fe by a factor approximately 7. This pattern suggests that elements are accelerated from a region of the corona with an electron temperature of approximately 3-5 MK, where elements in the first group are fully ionized (Q/A = 0.5), those in the second group have two orbital electrons (Q/A approximately 0.43), and Fe has Q/A approximately 0.28. Ions with the same gyrofrequency absorb waves of that frequency and are similarly accelerated and enhanced. Further stripping may occur after acceleration as the ions begin to interact with the streaming electrons that generated the plasma waves.

Reames, D. V.↗
NASA NTRS2004

Meridional Variations of C2H2 and C2H6 in Jupiter's Atmosphere from Cassini CIRS Infrared Spectra

The abundances of hydrocarbons such as acetylene (C2H2) and ethane (C2H6) in Jupiter's atmosphere are important physical quantities, constraining our models of the chemical and dynamical processes. However, our knowledge of these quantities and their vertical and latitudinal variations has remained sparse. The flyby of the Cassini spacecraft with Jupiter at the end of 2000 provided an excellent opportunity to observe the infrared spectrum with the Composite Infrared Spectrometer (CIRS) instrument, mapping the spatial variation of emissions from 10-1400 cm-1. CIRS spectra taken at the highest resolution (0.5 cm-1) in early December 2000 have been analysed to infer atmospheric temperatures in the stratosphere at 0.5-20 mbar via the v4 of CH4, and in the troposphere at 100-400 mbar, via the hydrogen collision-induced continuum absorption at 600-800 cm. Simultaneously, we have searched for meridional abundance variations in C2H2 and C2H6 via the v5 and vg bands respectively. Tropospheric absorption and stratospheric emission are highly anti-correlated at the CIM resolution, introducing a non-uniqueness into the retrievals, which means that vertical gradient and column abundance cannot be simultaneously found without additional constraints. If we assume the profile shapes from photochemical model calculations, we show that the column abundance of C2H2 must decrease sharply towards the poles, while C2H6 is constant or slightly increasing. The relevance of these results to current photochemical and dynamical knowledge of Jupiter's atmosphere is discussed.

Nixon, C. A.↗
NASA NTRS2004

AS04-AS02-133 Electroformed-Nickel Hard-X-Ray Optic Development at NASA/MSFC

We are developing the nickel electroforming process to fabricate high-quality mirrors for the region. Two applications for these optics are a balloon-borne payload, termed HERO, and a hard-X-ray telescope module for consideration for the Constellation-X mission. In the formation on shells, of 15 arcsec angular resolution, will provide over 200 sq cm of effective collecting area unprecedented sensitivity in the 20-75 keV region. A first flight of a partial payload, feature approximately 1/4 of the total collecting area, is scheduled for the Spring of 2004. In the Co-application, two mirror shells, of diameters 150 and 230 mm, are being fabricated. This is particularly challenging as high angular resolution must be maintained with shells of only 1 mm thickness (driven by the tight weight budget for the mission). Further, the shells must be low (less than 5 A on sub-micron spatial scales) to permit efficient use of planned multilayer coatings which must release cleanly from their forming mandrels without any surface degradation.

Ramsey, Brian↗
NASA NTRS2008

Improved Thermal Design of a Compression Mold

A compression tool used to make 1-in. (2.5-cm) diameter disks of high-temperature polymers was designed to be shorter and of larger diameter than conventional tools to reduce heat loss to the surrounding air, thus making more efficient use of applied heat. This system is less sensitive to the amount and quality of insulation than previous tools, provides more repeatable processing, and improves the quality of the samples produced. These improvements come without increasing the weight of the punch portion of the tool over that of a conventional version, an important quality when handling lower-viscosity resins. In use, the base and body of the tool are assembled, and the polymer to be processed is placed into the body of the tool. The punch is inserted, and the assembled tool is placed into the press. A temperature/ pressure profile appropriate to the nature of the polymer is applied. A series of computational and experimental runs were made using a conventional tool to validate the computational model. The new tool design was then modeled, and when the performance showed a marked improvement, the new tool was manufactured. A new series of experimental runs showed that the thermal performance of the new tool agreed well with model predictions.

Kuczmarski, Maria A.↗