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DOE OSTI2025

Thermomechanical Modeling and Analysis of a High-Temperature Light Trapping Planar Cavity Receiver

Solar energy harnessed through concentrating solar power (CSP) systems offers a promising path to sustainable energy production, with the efficiency and longevity of these systems relying on key components like solar receivers. This study analyzes the thermomechanical behavior of an innovative enclosed light-trapping solar receiver optimized for particle heating applications. The receiver utilizes sheet metal alloys to form enclosed cavities that reflect and trap incoming solar flux, as well as enclosed channels that contain fluidized particle beds absorbing solar heat. Finite element analysis (FEA) is applied to predict the receiver's thermomechanical performance under extreme solar flux conditions. Temperature distributions from a thermal model simulating a multi-panel assembly at steady state are input into the FEA thermomechanical model for stress analysis. A key aspect of the analysis focuses on evaluating creep-fatigue damage, with a design target of achieving a 30- year service life. Various stress relief techniques are also proposed to extend the receiver's service life. The results highlight the significant impact of the particle-to-wall heat transfer coefficients (HTCs), ranging from 800 W/m2*K to 1400 W/m2*K. The 800 W/m2*K case shows a maximum von Mises stress of 164 MPa, while the 1400 W/m2*K case reduces it to 150 MPa. The creep life increases from 4,000 hrs in the 800 W/m2*K case to over 100,000 hrs in the 1400 W/m2*K case with Inconel 740H used, indicating that higher HTCs reduce stress and extend lifespan. This research advances the design of high-efficiency, low-stress solar receivers for particle-based thermal energy storage in CSP and industrial heating applications.

concentrating solar power↗

DOE OSTI2025

Optimal Complementarity Analysis of Potential Floating Solar Co-Located With Existing Hydropower Assets Across the Contiguous United States

The U.S. is expected to double its rate of renewable capacity from 2024 to 2030. However, the stochastic nature of renewable energy poses challenges to the operation and reliability of our power grid. The combined generation from renewable energy sources, with dispatchable sources (such as hydropower) operating as a hybrid energy plant, could mitigate this variability. In this paper, the complementarity analysis of selected U.S. reservoirs with existing hydropower assets (EHAs) and potential floating photovoltaics (FPVs) is conducted for the continuous U.S. (CONUS). The optimal FPV capacity for each site is determined by minimizing the variability of the combined output, while adhering to the FPV potential. Our results indicate that over 50% of the analyzed reservoirs achieve a stability coefficient exceeding 0.5, leading to a less-variable output after optimization. Finally, we analyze the complementary hydro-FPV hybrid reservoirs by considering both the Pearson correlation coefficient and the stability coefficient on daily, monthly, and yearly scales. Summaries are included of locations of theoretical FPVs co-located with hydropower plants that exhibit high complementarity based on the selected metrics.

13 - HYDRO ENERGY↗

DOE OSTI2022

Setup and verification of a SCALE/KENO platform for generic FHR benchmark calculations

The work presented in this article is preliminary to downstream analysis of a generic fluoride salt-cooled high-temperature reactor (gFHR) core performed by the University of Tennessee in collaboration with Kairos Power (KP). A Monte Carlo transport model of the publicly available gFHR equilibrium core is developed in SCALE/KENO with multigroup energy treatment. Several output quantities of interest are used to verify the simulations against a benchmark model developed by KP using the continuous energy Monte Carlo code Serpent 2. Good agreement is seen in flux and fission rate profiles with a maximum relative difference of 1.4% and 2.8% respectively. Furthermore, an effective multiplication factor bias of 44 pcm was observed between the two simulations. The fuel temperature reactivity coefficient calculated with SCALE is within uncertainty to the reference model. This verification acts as a publicly reproducible benchmark for the gFHR in SCALE/KENO. A simplified depletion model is also presented where a single fuel pebble is depleted to discharge burnup through the equilibrium core while the equilibrium core is assumed to be invariant. This method produces results that intercept the equilibrium core concentrations in every case, however, an interesting artifact of this particular depletion model is uncovered. The phenomenon is shown to be a fundamental feature of the differential rate equations and inspires questions about how this system behaves when the time evolution of the equilibrium core is considered. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

NASA NTRS1986

Pulsed mononode dye laser developed for a geophysical application

Following the extension of the lidar technique in the study of the atmosphere, the necessity of having a high power pulsed laser beam with a narrowed bandwidth and the possibility of selecting a particular wavelength within a certain spectral region arises. With the collaboration of others, a laser cavity using the multiwave Fizeau wedge (MWFW) was developed. Using the classical method of beam amplification with the aid of different stages, a new pulsed dye laser device was designed. The originality resides in the use of reflecting properties of the MFWF. Locally a plan wave coming with a particular angular incidence is reflected with a greater than unity coefficient; this is the consequence of the wedge angle which doubles the participation of every ray in the interferometric process. This dye laser operation and advantages are discussed. The feasibility of different geophysical applications envisageable with this laser is discussed.

Jegou, J. P.↗

DOE OSTI2022

Multi-Physics Investigation of a Natural Circulation Molten Salt Micro-Reactor that Utilizes an Experimental In-Pile Device to Improve Core Physics and System Thermal-Hydraulic Performance.

INL employee PhD Dissertation - The Molten Salt Reactor (MSR) concept is a rapidly evolving Generation IV design that has recently attracted favorable attention due to the potential for reducing waste generation, realizing passive safety features, and seizing on the opportunity for cost effective economics. This thesis investigates the performance benefit of a new device invented by the doctoral candidate. The device is referred to as a Wrapped Helix around an Inclined Plane or WHIP. The WHIP is protected under a provisional patent filed with the USA Patent Office on 28 September 2021 under application number 63/261,776, BEA docket number BA-1254. The WHIP device can be located in-core or near-core to promoted enhanced thermal-hydraulics and neutronics performance. While the WHIP can be employed in a variety of solid or liquid fuel designs, this thesis investigates the device’s benefit in the application of a natural-circulation, micro-molten salt nuclear battery concept (MsNB). This thesis will specifically investigate the temperature coefficient of the MsNB fuel (FLiNaK) using novel temperature sensitivity techniques unique to Serpent particle transport code, evaluate the WHIP’s thermal-hydraulic and neutronic performance effects using both established (STAR-CCM+) and novel (Python code developed to estimate the circulation effective delayed neutron fraction, ßef f ) analytical and numerical methods, evaluate the neutron noise behavior of the MsNB and how the WHIP may alter the character of the MsNB’s transfer function, and how the WHIP affects the autonomous, load-following performance under transient power conditions using Python code developed by the candidate. The sum body of this work, in part, has been published in three journal articles as the timing of the provisional patent process has allowed. Results show that creative utilization of WHIP engineering design and function reduces reactor system volume, fuel loading, control/stability in the buoyant regime

buoyant flow↗

DOE OSTI2024

Flow and Heat Transfer Experimental Study for 3D-Printed Solar Receiving Tubes With Helical Fins at Internal Surface

3D-printing technology was applied to fabricate novel solar thermal collection tubes that have internal heat transfer enhancement fins and external surfaces with high solar absorptivity and low emissivity due to the ability to use different materials in one tube. Helical fins were selected to introduce circumferential flow and thus minimize the circumferential temperature difference of the tube that receives sunlight on one side. The structures of the helical fins were previously optimized from computational fluid dynamics (CFD) analysis with the objective of low entropy production rate by looking for high heat transfer coefficient and relatively lower pressure loss. High-temperature alloy, Inconel-718, was used to 3D print the tubes, which can resist corrosion for the potential application of molten chloride salts as heat transfer fluid. Experimental tests were carried out using water as the heat transfer fluid with the high heat flux provided by a tubular furnace heater. The tested Reynolds number ranges from 3.9 × 10 3 to 6.1 × 10 4 . Heat transfer coefficients of up to 2.8 times that of the smooth tube could be obtained with the expense of increased pressure loss compared to that of the smooth tube. The total system entropy generation can be significantly reduced due to the benefit of heat transfer enhancement that is greater than the expenses of the increased pressure loss. The experimental results of the 3D-printed heat transfer tubes confirmed the CFD-based results of fin optimization. Furthermore, the novel heat transfer tube is recommended for application in concentrating solar power systems.

14 SOLAR ENERGY↗

DOE OSTI2021

Calibration approach and range of observed sap flow influences transpiration estimates from thermal dissipation sensors

Calibrating thermal dissipation (TD) sap flow sensors has become increasingly important to accurately estimate whole-tree transpiration, but it is unclear how the calibration approach itself influences the resulting coefficients and estimates. Here, we compare the two most common calibration approaches, gravimetric and potometric, using TD sensors inserted into Eucalyptus benthamii tree stems. The gravimetric approach uses an excised stem segment devoid of branches and leaves and pushes water through the stem using gravity, a positive force. The potometric approach uses a severed stem containing an intact canopy placed upright in a reservoir where water is pulled through the stem via transpiration, a negative force. We hypothesized that the positive pressure associated with gravimetric calibration would overestimate conductive sapwood area relative to that estimated from potometric calibration and that coefficients from these different approaches would result in different estimates of transpiration when applied to intact trees. We also predicted that calibrations could improve transpiration estimates by targeting the range of observed sap flow rates (i.e., K values) in intact trees. Conductive sapwood area was higher under gravimetric calibrations and resulting estimates of transpiration were lower compared to potometric calibrations. Segmented calibration curves, which fit two separate curves for the relationship between sap flux density (Fd) and sap flux index (K) based on the range of sap flow rates observed in intact trees, increased transpiration estimates from both gravimetric and potometric coefficients and diminished the magnitude of difference in transpiration estimates between approaches. Researchers should be aware that calibration approach and range of observed sap flow profoundly influences transpiration estimates from TD sensors and this likely applies to calibrations of other heat-based sap flow sensors.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2023

Development of a health monitoring framework: Application to a supercritical pulverized coal-fired boiler

In this study, this work details the development of a physics-based equipment health monitoring framework for a supercritical boiler, using first-principles models to estimate the remaining useful life (RUL) of its components. The framework accounts for fatigue and creep life consumption, generating spatio-temporal variations in mechanical and thermal stress. Analysis of the stress profile throughout the boiler highlights the finishing superheater inlet steam header as a vulnerable location susceptible to damage from cycling operation. The framework also yields quantified uncertainty in the RUL projection for specific locations, accounting for uncertainties in material properties and boiler operation. Results indicate that operational uncertainties (e.g., seasonal variation and operational strategy) and material properties (e.g., rupture time coefficients, Young’s modulus, yield strength, and coefficient of thermal expansion) significantly impact the RUL of the finishing superheater inlet steam header. Additionally, case studies demonstrate the use of the health monitoring framework as a predictive tool for operational planning under uncertainty, including scenarios with and without updates on the operation of the boiler.

20 FOSSIL-FUELED POWER PLANTS↗

DOE OSTI2020

Optimization of Oxygen Electrode Combined with Soluble Catalyst to Enhance the Performance of Lithium-Oxygen Battery

Lithium-air batteries possess a high theoretical energy density among the current battery technologies, and are expected to become the driving power for electric vehicles. However, the practical application of lithium air batteries is handicapped by their poor cycle life, high over-charge potential and low energy efficiency. Numerous studies have performed to improve the kinetics of the electrochemical reaction. Making a good oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) catalyst system is under intense scrutiny. In this work, we report a rational design of air electrode, which derives from biomass and presents a three-dimensional porous carbon architecture with high specific surface and large volume expansion coefficient. Combining with a soluble catalyst, this oxygen electrode presents an ultrahigh areal specific capacity of 7.95 mAh/cm 2 and a long cycling life up to 1000 cycles with suppressed polarization (about 0.46 V). Finally, the greatly improved overall performance is due to the synergetic effect of the novel designed oxygen electrode capable of mediating the redox mediators to trigger the ORR and OER process.

25 ENERGY STORAGE↗

DOE OSTI2023

Universal behavior in fragmenting brittle, isotropic solids across material properties

A bonded particle model is used to explore how variations in the material properties of brittle, isotropic solids affect critical behavior in fragmentation. To control material properties, a model is proposed which includes breakable two- and three-body particle interactions to calibrate elastic moduli and mode I and mode II fracture toughnesses. In the quasistatic limit, fragmentation leads to a power-law distribution of grain sizes which is truncated at a maximum grain mass that grows as a nontrivial power of system size. In the high-rate limit, truncation occurs at a mass that decreases as a power of increasing rate. A scaling description is used to characterize this behavior by collapsing the mean-square grain mass across rates and system sizes. Consistent scaling persists across all material properties studied, although there are differences in the evolution of grain size distributions with strain as the initial number of grains at fracture and their subsequent rate of production depend on Poisson's ratio. Importantly, this evolving granular structure is found to induce a unique rheology where the ratio of the shear stress to pressure, an internal friction coefficient, decays approximately as the logarithm of increasing strain rate. The stress ratio also decreases at all rates with increasing strain as fragmentation progresses and depends on elastic properties of the solid.

36 MATERIALS SCIENCE↗

NASA NTRS1986

Theory of beat-resonant coupling of electrostatic modes

A general expression is derived for the beat-resonant coupling electrostatic modes in a Vlasov plasma. The result for the coupling of two modes has a simple structure: the appropriate momentum gradient of the equilibrium particle distribution is weighted by a positive coupling coefficient and averaged over the resonance surface in momentum space. The contributions of all the resonance surfaces are then summed. This basic structure had been previously exhibited only for specific homogeneous plasma models. The present theory, which unifies and greatly simplifies these individual treatments, is based on a variational formulation of the Vlasov-Poisson equations. Using Lie transforms, the variational principle is reexpressed in oscillation-center variables, and then the nonlinear wave dynamics are obtained from the independent variations of the wave phase and the wave amplitude. The power of the method is then applied to a strongly magnetized, strongly inhomogeneous, non-neutral plasma model.

Crawford, John David↗

NASA NTRS1994

Surface gravity waves at equilibrium with a steady wind

Observations of wave fields' spatial evolution and of gravity wave spectra S(sub omega) are analyzed on the basis of the data reported by several research groups as well as on a 2-year data set of wind and wave measurements by stationary National Oceanic and Atmospheric Administration buoys near the Hawaiian Islands. We seek to clarify the role of the wave energy advection (with the wave group velocity) in the overall energy balance. This advective transfer appears to be no less important than the local (breaking wave induced) dissipation as a factor of wind-wave equilibrium. The advection is found to manifest itself in the shape of wave spectra by reducing the rate at which the spectra density of the wave energy, S(sub omega approximately omega (exp -p), falls off as the frequency increases away from the spectra peak. This and other conclusions are derived by comparing the field observations with theoretical predictions of the weak turbulence theory for a spatially inhomogeneous, statistically stationary, wave field. The observations also indicate that the typical wave age xi = C(sub 0)/U in the open ocean is much greater than the limiting value 1.2 attributed to the 'fully developed sea.' Although the observed spectra can be approximated by a power law with a single 'effective' exponent, this apparent exponent, p, is found to depend on the wave age. At high xi and at frequencies below the generation range, -p tends to -3 rather than the value of -11/3 predicted by the Zakharov-Zaslavskii theory. This deviation is interpreted as pointing to a nonconservative nature of the inverse cascade, the latter including a leakage of energy to low-wavenumber modes. Dependence of the overall effective exponent on xi is shown to be responsible for variation in the coefficients b, B, c, C appearing in empirical fetch laws, such as xi = C bar-x (exp c) and e = B bar-x (exp B), where bar-x and e are the dimensionless fetch and wave energy, respectively.

Glazman, Roman E.↗

NASA NTRS1980

Balancing of a power-transmission shaft with the application of axial torque

Evaluation of power transmission shafting for high-speed balancing has shown that when axial torque is applied, the imbalance response is altered. An increase in synchronous excitation always occurs if the axial torque level is altered from the value used during balancing; this was the case even when the shaft was balanced with torque applied. The twisting of the long slender shaft produces a change in the imbalance distribution sufficient to disrupt the balanced state. This paper presents a review of the analytic development of a weighted least squares approach to influence coefficient balancing and a review of experimental results. The analytic approach takes advantage of the fact that the past testing has shown that the influence coefficients are not significantly affected by the application of axial torque. The 3.60-m (12-ft) long aluminum shaft, 7.62 cm (3 in.) in diameter was run through the first flexural critical speed at torque levels ranging from zero-torque to 903.8 N-M (8000 lb-in.) in 112.9 N-M (1000 lb-in.) increments. Good comparison was achieved between predicted and experimental results.

Zorzi, E. S.↗

NASA NTRSDate not supplied

Computational Modeling of Two Mars Powered Descent Vehicle Concepts Tested in the Langley Unitary Plan Wind Tunnel

Future human Mars missions will require powered descent starting at supersonic conditions, something which has never been done before at Mars. Computational powered descent flowfield simulations have been completed at full-scale Mars conditions, but the available ground test data are not suitable for calibrating computational uncertainties for aerodynamic interference on proposed Mars descent vehicles. Testing was conducted in the NASA Langley Unitary Plan Wind Tunnel in order to investigate the aerodynamic interference of sub-scale versions of two Mars powered descent vehicle concepts at supersonic Mach numbers (2.4 and 3.5): a model based on a blunt hypersonic inflatable aerodynamic decelerator (HIAD) and the second representing a more slender rigid vehicle with body flaps (CobraMRV). This paper covers computational flowfield predictions completed at wind tunnel conditions and comparisons to the test data. On the blowing HIAD models, the time-averaged pressure inboard of the nozzles was generally well-predicted, especially if the nozzles are canted outward, when the nozzles are located further from the nose. At intermediate CobraMRV thrust coefficients, CFD pressures are more accurately predicted than they are for the HIAD models, largely due to the nozzle locations and pointing directions. Overall, the CFD pressure coefficients were predicted within 0.2 of the steady pressure measurements for all blowing models, with smaller discrepancies at higher HIAD thrust, and larger discrepancies at lower HIAD CobraMRV thrust. All HIAD models were predicted to have a gradually decreasing axial force coefficient as the total thrust increases, in agreement with available pressure sensitive paint data. On models with canted nozzles or with nozzles further from the nose, the force coefficient was slightly higher for a given thrust. On the CobraMRV model, the CFD also shows consistent results between solvers and follows trends revealed in the data; the aerodynamic force coefficient remains near the non-blowing value at a tunnel Mach number of 2.4 regardless of thrust, and increases above that level at a Mach number of 3.5, consistent with the discrete pressure data. CFD analysis at tunnel and flight conditions will continue as flight system designs concepts mature.

Supersonic Retropropulsion↗

NASA NTRSDate not supplied

Computational Modeling of Two Mars Powered Descent Vehicle Concepts Tested in the Langley Unitary Plan Wind Tunnel

Supersonic Retropropulsion↗

DOE OSTI2021

Enhanced Air-Cooling System with Optimized Asynchronously-Cooled Thermal Energy Storage

A transformative dry-cooling system that includes two primary dry-cooling components has been developed in this project. The two main features of this new technology consist of: (a) an ultra-enhanced air-cooled condenser (ACC), with novel swirl-producing and boundary-layer disrupting enhanced surface on the air-side of the condenser that substantially increase the heat transfer coefficients, and (b) a novel daytime peak-load shifting system that reduces the ambient air inlet temperature for air cooling, consisting of a highly compact and enhanced air pre-cooler that transfers the heat load to a unique thermal energy storage (TES), and which is coupled to the ACC in (a).

20 FOSSIL-FUELED POWER PLANTS↗

DOE OSTI2026

Material‐Driven Neuronal Oscillators and Filters via Active Reactance in CC‐NDR and VC‐NDR Electro‐Thermal Memristors

The continued scaling of artificial intelligence and telecommunications hardware is increasingly constrained by the power, bandwidth, and area limitations of transistor-based circuits. Neuromorphic processor units, analog oscillators, and active inductors and capacitors rely on complex multi-transistor architectures restricting material choices and incurring energy and footprint overhead. Here, we show that active reactance in electro-thermal memristors provides an intrinsic, material driven route to neuronal oscillator dynamics and signal processing. Using a physics-based compact modeling framework, we bridge negative differential resistance (NDR) and bias-tunable reactance, which underlies spiking dynamics in electro-thermal memristors. Memristors with negative temperature coefficients of resistance (TCR) manifest current-controlled (CC-) NDR and act as active inductors, thus generating spiking above a critical circuit capacitance; whereas memristors with positive TCR manifest voltage-controlled (VC-) NDR and active capacitance, leading to spiking above a critical inductance. By creating a compact model for La 0.7 Ca 0.3 MnO 3 as a representative VC-NDR material and comparing it with LaCoO 3 manifesting CC-NDR, we explain the physical origins of their distinct current-voltage characteristics, reactive phase shifts and consequent spiking behaviors. Finally, we demonstrate tunable filtering enabled by the active reactance of electro-thermal memristors, establishing them as a compact hardware platform for neuronal oscillator functionality and integrated filtering beyond conventional CMOS.

active reactance↗

DOE OSTI2019

Semitransparent Sb 2 S 3 thin film solar cells by ultrasonic spray pyrolysis for use in solar windows

The integration of photovoltaic (PV) solar energy in zero-energy buildings requires durable and efficient solar windows composed of lightweight and semitransparent thin film solar cells. Inorganic materials with a high optical absorption coefficient, such as Sb 2 S 3 (>10 5 cm -1 at 450 nm), offer semitransparency, appreciable efficiency, and long-term durability at low cost. Oxide-free throughout the Sb 2 S 3 layer thickness, as confirmed by combined studies of energy dispersive X-ray spectroscopy and synchrotron soft X-ray emission spectroscopy, semitransparent Sb 2 S 3 thin films can be rapidly grown in air by the area-scalable ultrasonic spray pyrolysis method. Integrated into a ITO/TiO 2 /Sb 2 S 3 /P3HT/Au solar cell, a power conversion efficiency (PCE) of 5.5% at air mass 1.5 global (AM1.5G) is achieved, which is a record among spray-deposited Sb 2 S 3 solar cells. An average visible transparency (AVT) of 26% of the back-contact-less ITO/TiO 2 /Sb 2 S 3 solar cell stack in the wavelength range of 380–740 nm is attained by tuning the Sb 2 S 3 absorber thickness to 100 nm. In scale-up from mm 2 to cm 2 areas, the Sb 2 S 3 hybrid solar cells show a decrease in efficiency of only 3.2% for an 88 mm 2 Sb 2 S 3 solar cell, which retains 70% relative efficiency after one year of non-encapsulated storage. A cell with a PCE of 3.9% at 1 sun shows a PCE of 7.4% at 0.1 sun, attesting to the applicability of these solar cells for light harvesting under cloud cover.

36 MATERIALS SCIENCE↗