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At least 1,711 records · Page 95

Rate processes in gas phase

Reaction-rate theory and experiment are given a critical review from the engineers' point of view. Rates of heavy-particle, collision-induced reaction in gas phase are formulated in terms of the cross sections and activation energies for reaction. The effect of cross section function shape and of excited state contributions to reaction both cause the slope of Arrhenius plots to differ from the true activation energy, except at low temperature. The master equations for chemically reacting gases are introduced, and dissociation and ionization reactions are shown to proceed primarily from excited states about kT from the dissociation or ionization limit. Collision-induced vibration, vibration-rotation, and pure rotation transitions are treated, including three-dimensional effects and conservation of energy, which have usually been ignored. The quantum theory of transitions at potential surface crossing is derived, and results are found to be in fair agreement with experiment in spite of some questionable approximations involved.

Hansen, C. F.↗

The interpretation of data from the Viking Mars Atmospheric Water Detectors (MAWD): Some points for discussion

Properly interpreted, water vapor column abundance measurements can provide important insights into many of the processes that govern the diurnal, seasonal, and climatic cycles of atmospheric water on Mars. The uncertain distribution of water vapor complicates this analysis. It is argued that if a significant fraction of the total atmospheric vapor content is concentrated within the lowermost scale height, then the hemispheric asymmetry in zonally averaged topography/air mass might itself explain the observed gradient in the annual and zonally averaged vapor abundance.

Clifford, Stephen M.↗

CBr4 vapor growth morphologies near the polymorphic transition point. I - Single crystals. II - Crystals with large-angle grain boundaries

High-resolution microscopy and image processing were used to investigate morphological changes in CBr4 single crystals during growth from the vapor at various levels of supersaturation and at temperatures below the compound's polymorphic phase transition. It was found that, as the temperature increased at fixed supersaturations, the corners of the crystals became rounded as a result of thermal roughening; the rounding temperatures were different for crystallographically different corners. A study of CBr4 crystals with large-angle grain boundaries or twin boundaries (extended macrodefects), conducted at the temperature of polymorphic phase transition showed that the phase transition temperature, T(tr) and crystal surface morphology of these crystals depended on the presence or absence of extended macrodefects. Unlike the case of a perfect single crystal, where the T(tr) was about 46.75 C, the phase transition in crystals with extended macrodefects occurred significantly below 46.75.

Xiao, Rong-Fu↗

Contribution of Infiltration Process Uncertainty on the Simulation of Terrestrial Water and Energy Budgets

The infiltration step is the major forking point of precipitation partition in land surface models, which plays a more significant role than canopy interception for simulating water and energy budgets.In this study, we found significant differences in water and energy-related outputs amount JULES, Noah, Noah-MP, and VIC. The differences are directly or indirectly related to the infiltration components in the models. Those differences add uncertainties to the applications of land surface models. Thorough evaluations are needed to determine the reliability of infiltration schemes used in these models.

Wang, Shugong↗

Application of a hybrid computer to sweep frequency data processing

A hybrid computer program is presented which can process as many as 10 channels of sweep frequency data simultaneously. The program needs only the sine sweep signal used to drive the system, and its correponding quadrature component, to process the data. It can handle a maximum frequency range of 0.5 to 500 hertz. Magnitude and phase are calculated at logarithmically spaced points covering the frequency range of interest. When the sweep is completed, these results are stored in digital form. Thus, a tabular listing and/or a plot of any processed data channel or the transfer function relating any two of them is immediately available.

Milner, E. J.↗

The Influence of Tropospheric Processes in Modeling the Middle Atmosphere with Gravity Waves

Our Numerical Spectral Model (NSM) extends from the ground up into the thermosphere and has a vertical grid point resolution of about 0.5 km to resolve the interactions of gravity waves (GWs) described with Hines' Doppler Spread Parameterization (DSP). This model produces in the stratosphere and mesosphere the major features of QBO, SAO, tides, and planetary waves. The purpose of this paper is to discuss results from an initial study with our 3D model that shows how certain tropospheric processes can affect the dynamics of the middle atmosphere. Under the influence of tropospheric heating, and augmented by GW interactions, two distinct but related processes can be identified. (1) A meridional circulation develops in the stratosphere, with rising motions at low latitudes that are in magnitude comparable to the downward propagation of the QBO. As Dunkerton pointed out, a larger GW source is then required to reproduce the observed QBO, which tends to move us closer to the values recommended for the DSP. This has significant consequences for our model results that describe the upper mesosphere, considering the general importance of GWs for this region and in influencing planetary waves (e.g., 2-day wave) and tides in particular. (2) Tropospheric heating produces zonal jets near the tropopause that are related to latitudinal variations in pressure and reversing temperature variations (resembling the dynamical conditions near the mesopause), which in turn is conducive to generate baroclinic instability. Modeling results show that our ability to generate the QBO critically depends on the magnitude of the temperature reversal that is a measure of this instability. Planetary waves are generated in this process, which can apparently interfere with or augment the GW interactions. As originally demonstrated by Lindzen and Holton, the eastward propagating Kelvin waves and westward propagating Rossby gravity waves (generated by tropospheric convection) can in principle provide the acceleration to influence the QBO, and we were able to confirm this with our 3D model.

Mayr, H. G.↗

SSME Main Combustion Chamber (MCC) 'Hot Oil' Dewaxing

In an attempt to comply with the changing environmental regulations, a process was developed for the replacement of perchloroethylene in the dewaxing of the Space Shuttle Main Engine (SSME) Main Combustion Chamber (MCC) and other associated hardware filled with the Rigidax(registered mark) casting compound. Rigidax(registered mark) is a hard blue-dyed, calcium carbonate filled thermoplastic casting compound (melting point 77 C) that is melted and poured into hardware cavities to prevent contamination during material removal processes, i.e. machining, grinding, drilling, and deburring. Additionally, it serves as a maskant for designated areas during electroforming processes. Laboratory testing was conducted to evaluate seven alternate fluids for the replacement of perchloroethylene in the dewaxing process. Based upon successful laboratory results, a mineral oil was selected for testing on actual hardware. The final process developed involves simultaneous immersion and flushing of the MCC channels using a distinct eight stage process. A nonvolatile hydrocarbon analysis of a solvent flush sample is performed to determine the hardware cleanliness for comparison to the previous perchloroethylene dewaxing process.

Akpati, Anthony U.↗

Testing for hydrogen embrittlement: Primary and secondary influences

An overview is presented of the hydrogen embrittlement process, both internal as well as external, to make more clear the type of parameters which must be considered in the selection of a test method and test procedure, so that the resulting data may be meaningfully applied to real engineering structures. Three primary influences on the embrittlement process are considered: (1) the original location and form of the hydrogen, (2) the transport reactions involved in the transport of hydrogen from its origin to some point where it can interact with the metal to cause embrittlement, and (3) the embrittlement interaction itself. A few secondary influences on the embrittlement process are also discussed.

Nelson, H. G.↗

Method and apparatus for spatially variable rate application of agricultural chemicals based on remotely sensed vegetation data

Remotely sensed spectral image data are used to develop a Vegetation Index file which represents spatial variations of actual crop vigor throughout a field that is under cultivation. The latter information is processed to place it in a format that can be used by farm personnel to correlate and calibrate it with actually observed crop conditions existing at control points within the field. Based on the results, farm personnel formulate a prescription request, which is forwarded via email or FTP to a central processing site, where the prescription is prepared. The latter is returned via email or FTP to on-side farm personnel, who can load it into a controller on a spray rig that directly applies inputs to the field at a spatially variable rate.

Hood, Kenneth Brown↗

Method and system for spatially variable rate application of agricultural chemicals based on remotely sensed vegetation data

Remotely sensed spectral image data are used to develop a Vegetation Index file which represents spatial variations of actual crop vigor throughout a field that is under cultivation. The latter information is processed to place it in a format that can be used by farm personnel to correlate and calibrate it with actually observed crop conditions existing at control points within the field. Based on the results, farm personnel formulate a prescription request, which is forwarded via email or FTP to a central processing site, where the prescription is prepared. The latter is returned via email or FTP to on-side farm personnel, who can load it into a controller on a spray rig that directly applies inputs to the field at a spatially variable rate.

Hood, Kenneth Brown↗

Evaluation of Clouds and the Earth's Radiant Energy System (CERES) Scanner Pointing Accuracy using a Coastline Detection System

Clouds and the Earth's Radiant Energy System (CERES) is a National Aeronautics and Space Administration (NASA) investigation to examine the role of clouds in the radiative energy flow through the Earth-atmosphere system. The first CERES scanning radiometer was launched on November 27, 1997 into a 35 inclination, 350 km altitude orbit, on the Tropical Rainfall Measuring Mission (TRMM) spacecraft. The CERES instrument consists of a three channel scanning broadband radiometer. The spectral bands measure shortwave (0.3 - 5 microns), window (8 - 12 microns), and total (0.3 - 100 microns) radiation reflected or emitted from the Earth-atmosphere system. Each Earth viewing measurement is geolocated to the Earth fixed coordinate system using satellite ephemeris, Earth rotation and geoid, and instrument pointing data. The interactive CERES coastline detection system is used to assess the accuracy of the CERES geolocation process. By analyzing radiative flux gradients at the boundaries of ocean and land masses, the accuracy of the scanner measurement locations may be derived for the CERES/TRMM instrument/satellite system. The resulting CERES measurement location errors are within 10% of the nadir footprint size. Precise pointing knowledge of the Visible and Infrared Scanner (VIRS) is required for convolution of cloud properties onto the CERES footprint; initial VIRS coastline results are included.

Currey, Chris↗

BEYONDPLANCK VI. Noise characterization and modeling

We present a Bayesian method for estimating instrumental noise parameters and propagating noise uncertainties within the global BeyondPlanck Gibbs sampling framework, and apply this to Planck Low Frequency Instrument (LFI) time-ordered data. Following previous literature, we initially adopt a 1/ f model for the noise power spectral density (PSD), but find the need for an additional lognormal component in the noise model for the 30 and 44 GHz bands. We implement an optimal Wiener-filter (or constrained realization) gap-filling procedure to account for masked data. We then use this procedure to both estimate the gapless correlated noise in the time-domain, n corr , and to sample the noise PSD parameters, ξ n = {σ 0 , f knee , α, A p }. In contrast to previous Planck analyses, we assume piecewise stationary noise only within each pointing period (PID), not throughout the full mission, but we adopt the LFI Data Processing Center (DPC) results as priors on α and f knee . On average, we find best-fit correlated noise parameters that are mostly consistent with previous results, with a few notable exceptions. However, a detailed inspection of the time-dependent results reveals many important findings. First and foremost, we find strong evidence for statistically significant temporal variations in all noise PSD parameters, many of which are directly correlated with satellite housekeeping data. Second, while the simple 1/ f model appears to be an excellent fit for the LFI 70 GHz channel, there is evidence for additional correlated noise not described by a 1/ f model in the 30 and 44 GHz channels, including within the primary science frequency range of 0.1–1 Hz. In general, most 30 and 44 GHz channels exhibit deviations from 1/ f at the 2–3σ level in each one hour pointing period, motivating the addition of the lognormal noise component for these bands. For some periods of time, we also find evidence of strong common mode noise fluctuations across the entire focal plane. Overall, we conclude that a simple 1/ f profile is not adequate to fully characterize the Planck LFI noise, even when fitted hour-by-hour, and a more general model is required. These findings have important implications for large-scale CMB polarization reconstruction with the Planck LFI data, and the current work is a first attempt at understanding and mitigating these issues.

79 ASTRONOMY AND ASTROPHYSICS↗

Proof-of-Concept Experiments on a Gallium-Based Ignitron for Pulsed Power Applications

Ignitrons are electrical switching devices that operate at switching times that are on the order of microseconds, can conduct high currents of thousands of amps, and are capable of holding off tens of thousands of volts between pulses. They consist of a liquid metal pool within an evacuated tube that serves both the cathode and the source of atoms and electrons for an arc discharge. Facing the liquid metal pool is an anode suspended above the cathode, with a smaller ignitor electrode tip located just above the surface of the cathode. The ignitron can be charged to significant voltages, with a potential difference of thousands of volts between anode and cathode. When an ignition pulse is delivered from the ignitor electrode to the cathode, a small amount of the liquid metal is vaporized and subsequently ionized, with the high voltage between the anode and cathode causing the gas to bridge the gap between the two electrodes. The electrons and ions move rapidly towards the anode and cathode, respectively, with the ions liberating still more atoms from the liquid metal cathode surface as a high-current plasma arc discharge is rapidly established. This arc continues in a self-sustaining fashion until the potential difference between the anode and cathode drops below some critical value. Ignitrons have been used in a variety of pulsed power applications, including the railroad industry, industrial chemical processing, and high-power arc welding. In addition, they might prove useful in terrestrial power grid applications, serving as high-current fault switches, quickly shunting dangerous high-current or high-voltage spikes safely to ground. The motivation for this work stemmed from the fact that high-power, high-reliability, pulsed power devices like the ignitron have been used for ground testing in-space pulsed electric thruster technologies, and the continued use of ignitrons could prove advantageous to the future development and testing of such thrusters. Previous ignitron designs have used mercury as the liquid metal cathode, owing to its presence as a liquid at room temperatures and a vapor pressure of 10 Pa (75 mtorr) at room temperature. While these are favorable properties, there are obvious environmental and personal safety concerns with the storage, handling, and use of mercury and its compounds. The purpose of the present work was to fabricate and test an ignitron that used as its cathode an alternate liquid metal that was safe to handle and store. To that end, an ignitron test article that used liquid gallium as the cathode material was developed and tested. Gallium is a metal that has a melting temperature of 29.76 C, which is slightly above room temperature, and a boiling point of over 2,300 C at atmospheric pressure. This property makes gallium the element with the largest relative difference between melting and boiling points. Gallium has a limited role in biology, and when ingested, it will be subsequently processed by the body and expelled rather than accumulating to toxic levels. The next section of this Technical Memorandum (TM) provides background information on the development of mercury-based ignitrons, which serves as the starting point for the development of the gallium-based variant. Afterwards, the experimental hardware and setup used in proof-of-concept testing of a basic gallium ignitron are presented. Experimental data, consisting of discharge voltage and current waveforms as well as high-speed imaging of the gallium arc discharge in the gallium ignitron test article, are presented to demonstrate the efficacy of the concept. Discussion of the data and suggestions on improvements for future iterations of the design are presented in the final two sections of this TM.

Ali, H. K.↗

Testing the Simple Biosphere model (SiB) using point micrometeorological and biophysical data

The suitability of the Simple Biosphere (SiB) model of Sellers et al. (1986) for calculation of the surface fluxes for use within general circulation models is assessed. The structure of the SiB model is described, and its performance is evaluated in terms of its ability to realistically and accurately simulate biophysical processes over a number of test sites, including Ruthe (Germany), South Carolina (U.S.), and Central Wales (UK), for which point biophysical and micrometeorological data were available. The model produced simulations of the energy balances of barley, wheat, maize, and Norway Spruce sites over periods ranging from 1 to 40 days. Generally, it was found that the model reproduced time series of latent, sensible, and ground-heat fluxes and surface radiative temperature comparable with the available data.

Sellers, P. J.↗

Exposing Hidden Parts of the SE Process: MBSE Patterns and Tools for Tracking and Traceability

An interesting benefit of applying Model-Based Systems Engineering (MBSE) is that the rigor and coordination intrinsic to MBSE forces us to apply Systems Engineering to our own traditional activities, processes, and products, which results in richer, more expressive models, more powerful reasoning, and a clearer and more effective Systems Engineering (SE) process. Our MBSE frameworks and languages contain semantic richness sufficient to describe our systems at any particular point in time, often with an emphasis on the description of the system at major milestones. This is unarguably a real asset. However, when we apply MBSE in service of missions that are in development, rapidly evolving, of a larger scale, and where interpersonal communication is a critical part of the design process, we discover that our frameworks and languages are still not quite rich enough to enable us to ask the kinds of questions and get the kinds of answers we want in order to address the concerns of day to day work. This paper will discuss some patterns and tools we have developed to help address some of the not-always-explicit SE concerns that we have identified through our MBSE work. Particularly, this paper will discuss flexible yet practical methods for defining and capturing maturity, workflow, and agreement traceability within our system models, extensible ways to perform and track model audits, and ways to report and interact with this knowledge in the context of MBSE applied to support NASA’s Europa Project.

Jackson, Maddalena↗

Exposing Hidden Parts of the SE Process: MBSE Patterns and Tools for Tracking and Traceability

An interesting benefit of applying Model-Based Systems Engineering (MBSE) is that the rigor and coordination intrinsic to MBSE forces us to apply Systems Engineering to our own traditional activities, processes, and products, which results in richer, more expressive models, more powerful reasoning, and a clearer and more effective Systems Engineering (SE) process. Our MBSE frameworks and languages contain semantic richness sufficient to describe our systems at any particular point in time, often with an emphasis on the description of the system at major milestones. This is unarguably a real asset. However, when we apply MBSE in service of missions that are in development, rapidly evolving, of a larger scale, and where interpersonal communication is a critical part of the design process, we discover that our frameworks and languages are still not quite rich enough to enable us to ask the kinds of questions and get the kinds of answers we want in order to address the concerns of day to day work. This paper will discuss some patterns and tools we have developed to help address some of the not-always-explicit SE concerns that we have identified through our MBSE work. Particularly, this paper will discuss flexible yet practical methods for defining and capturing maturity, workflow, and agreement traceability within our system models, extensible ways to perform and track model audits, and ways to report and interact with this knowledge in the context of MBSE applied to support NASA’s Europa Project

Jackson, Maddalena↗

Virtual Construction of Space Habitats: Connecting Building Information Models (BIM) and SysML

Current trends in design, construction and management of complex projects make use of Building Information Models (BIM) connecting different types of data to geometrical models. This information model allow different types of analysis beyond pure graphical representations. Space habitats, regardless their size, are also complex systems that require the synchronization of many types of information and disciplines beyond mass, volume, power or other basic volumetric parameters. For this, the state-of-the-art model based systems engineering languages and processes - for instance SysML - represent a solid way to tackle this problem from a programmatic point of view. Nevertheless integrating this with a powerful geometrical architectural design tool with BIM capabilities could represent a change in the workflow and paradigm of space habitats design applicable to other aerospace complex systems. This paper shows some general findings and overall conclusions based on the ongoing research to create a design protocol and method that practically connects a systems engineering approach with a BIM architectural and engineering design as a complete Model Based Engineering approach. Therefore, one hypothetical example is created and followed during the design process. In order to make it possible this research also tackles the application of IFC categories and parameters in the aerospace field starting with the application upon the space habitats design as way to understand the information flow between disciplines and tools. By building virtual space habitats we can potentially improve in the near future the way more complex designs are developed from very little detail from concept to manufacturing.

space architecture↗