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At least 1,711 records · Page 95

Hypersonic vehicle model and control law development using H(infinity) and micron synthesis

The control system design for a Single Stage To Orbit (SSTO) air breathing vehicle will be central to a successful mission because a precise ascent trajectory will preserve narrow payload margins. The air breathing propulsion system requires the vehicle to fly roughly halfway around the Earth through atmospheric turbulence. The turbulence, the high sensitivity of the propulsion system to inlet flow conditions, the relatively large uncertainty of the parameters characterizing the vehicle, and continuous acceleration make the problem especially challenging. Adequate stability margins must be provided without sacrificing payload mass since payload margins are critical. Therefore, a multivariable control theory capable of explicitly including both uncertainty and performance is needed. The H(infinity) controller in general provides good robustness but can result in conservative solutions for practical problems involving structured uncertainty. Structured singular value mu framework for analysis and synthesis is potentially much less conservative and hence more appropriate for problems with tight margins. An SSTO control system requires: highly accurate tracking of velocity and altitude commands while limiting angle-of-attack oscillations, minimized control power usage, and a stabilized vehicle when atmospheric turbulence and system uncertainty are present. The controller designs using H(infinity) and mu-synthesis procedures were compared. An integrated flight/propulsion dynamic mathematical model of a conical accelerator vehicle was linearized as the vehicle accelerated through Mach 8. Vehicle acceleration through the selected flight condition gives rise to parametric variation that was modeled as a structured uncertainty. The mu-analysis approach was used in the frequency domain to conduct controller analysis and was confirmed by time history plots. Results demonstrate the inherent advantages of the mu framework for this class of problems.

Gregory, Irene M.↗

Extraterrestrial solar energy and its possible variations

Values of the solar constant and solar spectrum have been adopted as design standards for NASA space vehicles and as engineering standards by IES/ASTM. High resolution spectral data for the UV and visible range, normalized to these standards have been derived. Applications of these results for weather analysis, air pollution, ozone production, and atmospheric energy exchange are reviewed. Indications of possible variations in solar energy, total and spectral, and their influence on the earth-atmosphere system are examined. Programs for future studies of these variations from satellites and high-altitude aircraft are discussed.

Thekaekara, M. P.↗

Grid orthogonality effects on predicted turbine midspan heat transfer and performance

The effect of five different C type grid geometries on the predicted heat transfer and aerodynamic performance of a turbine stator is examined. Predictions were obtained using two flow analysis codes. One was a finite difference analysis, and the other was a finite volume analysis. Differences among the grids in terms of heat transfer and overall performance were small. The most significant difference among the five grids occurred in the prediction of pitchwise variation in total pressure. There was consistency between results obtained with each of the flow analysis codes when the same grid was used. A grid generating procedure in which the viscous grid is embedded within an inviscid type grid resulted in the best overall performance.

Boyle, R. J.↗

Experimental Study of Combined Forced and Free Laminar Convection in a Vertical Tube

An apparatus was built to verify an analysis of combined forced and free convection in a vertical tube with uniform wall heat flux and to determine the limits of the analysis. The test section was electrically heated by resistance heating of the tube wall and was instrumented with thermocouples in such a way that detailed thermal entrance heat-transfer coefficients could be obtained for both upflow and downflow and any asymmetry in wall temperature could be detected. The experiments showed that fully developed heat-transfer results, predicted by a previous analysis, were confirmed over the range of Rayleigh numbers investigated. The concept of "locally fully developed" heat transfer was established. This concept involves the assumption that the fully developed heat-transfer analysis can be applied locally even though the Rayleigh number is varying along the tube because of physical-property variations with temperature. Thermal entrance region data were obtained for pure forced convection and for combined forced and free convection. The analysis of laminar pure forced convection in the thermal entrance region conducted by Siegel, Sparrow, and Hallman was experimentally confirmed. A transition to an eddy motion, indicated by a fluctuation in wall temperature was found in many of the upflow runs. A stability correlation was found. The fully developed Nusselt numbers in downflow were below those for pure forced convection but fell about 10 percent above the analytical curve. Quite large circumferential variations in wall temperature were observed in downflow as compaired with those encountered in upflow, and the fully developed Nussalt numbers reported are based on average wall temperatures determined by averaging the readings of two diametrically opposite wall thermocouples at each axial position. With larger heating rates in downflow the wall temperature distributions strongly suggested a cell flow near the bottom. At still larger heating rates the wall temperatures varied in a periodic way.

Hallman, Theodore M.↗

Time-cumulated visible and infrared radiance histograms used as descriptors of surface and cloud variations

The spatial and temporal stability of the distributions of satellite-measured visible and infrared radiances, caused by variations in clouds and surfaces, are investigated using bidimensional and monodimensional histograms and time-composite images. Similar analysis of the histograms of the original and time-composite images provides separation of the contributions of the space and time variations to the total variations. The variability of both the surfaces and clouds is found to be larger at scales much larger than the minimum resolved by satellite imagery. This study shows that the shapes of these histograms are distinctive characteristics of the different climate regimes and that particular attributes of these histograms can be related to several general, though not universal, properties of clouds and surface variations at regional and synoptic scales. There are also significant exceptions to these relationships in particular climate regimes. The characteristics of these radiance histograms provide a stable well defined descriptor of the cloud and surface properties.

Seze, Genevieve↗

Structure and Dynamics of Polysulfide Clusters in a Nonaqueous Solvent Mixture of 1,3-Dioxolane and 1,2-Dimethoxyethane

Molecular clustering and associated dynamic processes of lithium polysulfide species were unraveled using classical molecular dynamics and ab initio metadynamics calculations. The spectroscopic signatures of polysulfide clusters were analyzed using a multimodal analysis including experimental and computational nuclear magnetic resonance (NMR) and X-ray absorption spectroscopies. Lithium polysulfide solutes (Li 2 S 4 , Li 2 S 6 , and Li 2 S 8 ) and their mixtures in a 1,3-dioxolane and 1,2-dimethoxyethane (DOL/DME) solvent undergo aggregation driven by intramolecular lithium–sulfur (Li–S) interactions, leading to distributions of cluster sizes, which could critically influence the functioning of lithium–sulfur batteries. Representative polysulfide clusters with systematic increases in molecular size were extracted from the classical molecular dynamics trajectories for subsequent structural and spectroscopic property calculations using density functional theory analysis. Structural analysis of these clusters reveals progressively decreasing solvent involvement in Li+ coordination varying from Li 2 S 4 to Li 2 S 8 , with more pronounced variation and changes in DME compared with those in DOL. These observations are reflected in the analysis of the experimental and theoretical 7 Li and 17 O NMR chemical shifts and pulsed field gradient-NMR diffusion measurements. A comparison of experimental and theoretical S K-edge X-ray absorption near edge spectra shows that relatively large lithium sulfide chain clusters are likely to occur in the DOL/DME-solvated lithium sulfide systems. Ab initio metadynamics simulations and NMR analysis indicate that Li + solvated by only the solvent can occur through Li + dissociation from sulfide chains. However, the occurrence of “sulfide-free” Li + is a minor mechanism compared with the dynamic aggregation and shuttling processes of polysulfide solvates in DOL/DME-based electrolytes of Li–S batteries. Overall, atomistic insights gained about clustering and lithium exchange dynamics will be critical for the predictive understanding of the polysulfide shuttling and nucleation process that dictates the Li–S battery performance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

In‐mold rheology and automated process control for injection molding of recycled polypropylene

Abstract Manufacturing plastic parts with secondary feedstocks has risen to the forefront of importance in recent years. However, the variation in molecular weight and rheology of secondary feedstock can lead to inconsistent part quality. This work evaluates the effectiveness of a novel closed‐loop adaptive process control system that adjusts nozzle pressure in response to in‐mold pressure data. Five different recycled polypropylene blends, with a broad distribution of flow properties, were evaluated to determine the effectiveness of the control system at reducing processing variation. The experimental results show that the process control strategy reduced the variation within the mold, as seen by in‐mold pressure curves and calculated in‐mold viscosity values. Additionally, the parameters that control the automated process adjustments were investigated, showing the importance of optimization. The analysis of the correlation between in‐mold rheology and mechanical properties showed a slight variation in the mechanical properties and parts weight with a coefficient of variation of under 5%. Overall, the results demonstrate the ability of pressure‐controlled molding and automated viscosity adjustment to reduce the variability when molding a secondary feedstock. Highlights Pressure‐controlled injection molding of recycled polypropylene. Automated closed‐loop adaptive process control methodology. Methodology resulted in a reduction in pressure variation during molding. Changes in mechanical properties and in‐mold viscosity were investigated. Results show the potential of pressure‐controlled molding at reducing variation.

Krantz, Joshua↗

Prediction of grain structure after thermomechanical processing of U-10Mo alloy using sensitivity analysis and machine learning surrogate model

Abstract Hot rolling and annealing are critical intermediate steps for controlling microstructures and thickness variations when fabricating uranium alloyed with 10% molybdenum (U-10Mo), which is highly relevant to worldwide nuclear non-proliferation efforts. This work proposes a machine-learning surrogate model combined with sensitivity analysis to identify and predict U-10Mo microstructure development during thermomechanical processing. Over 200 simulations were collected using physics-based microstructure models covering a wide range of thermomechanical processing routes and initial alloy grain features. Based on the sensitivity analysis, we determined that an increase in rolling reduction percentage at each processing pass has the strongest effect in reducing the grain size. Multi-pass rolling and annealing can significantly improve recrystallization regardless of the reduction percentage. With a volume fraction below 2%, uranium carbide particles were found to have marginal effects on the average grain size and distribution. The proposed stratified stacking ensemble surrogate predicts the U-10Mo grain size with a mean square error four times smaller than a standard single deep neural network. At the same time, with a significant speedup (1000×) compared to the physics-based model, the machine learning surrogate shows good potential for U-10Mo fabrication process optimization.

36 MATERIALS SCIENCE↗

NASA System Safety Handbook: System Safety Framework and Concepts for Implementation - Volume 1

System safety assessment is defined in NPR 8715.3C, NASA General Safety Program Requirements as a disciplined, systematic approach to the analysis of risks resulting from hazards that can affect humans, the environment, and mission assets. Achievement of the highest practicable degree of system safety is one of NASA's highest priorities. Traditionally, system safety assessment at NASA and elsewhere has focused on the application of a set of safety analysis tools to identify safety risks and formulate effective controls.1 Familiar tools used for this purpose include various forms of hazard analyses, failure modes and effects analyses, and probabilistic safety assessment (commonly also referred to as probabilistic risk assessment (PRA)). In the past, it has been assumed that to show that a system is safe, it is sufficient to provide assurance that the process for identifying the hazards has been as comprehensive as possible and that each identified hazard has one or more associated controls. The NASA Aerospace Safety Advisory Panel (ASAP) has made several statements in its annual reports supporting a more holistic approach. In 2006, it recommended that "... a comprehensive risk assessment, communication and acceptance process be implemented to ensure that overall launch risk is considered in an integrated and consistent manner." In 2009, it advocated for "... a process for using a risk-informed design approach to produce a design that is optimally and sufficiently safe." As a rationale for the latter advocacy, it stated that "... the ASAP applauds switching to a performance-based approach because it emphasizes early risk identification to guide designs, thus enabling creative design approaches that might be more efficient, safer, or both." For purposes of this preface, it is worth mentioning three areas where the handbook emphasizes a more holistic type of thinking. First, the handbook takes the position that it is important to not just focus on risk on an individual basis but to consider measures of aggregate safety risk and to ensure wherever possible that there be quantitative measures for evaluating how effective the controls are in reducing these aggregate risks. The term aggregate risk, when used in this handbook, refers to the accumulation of risks from individual scenarios that lead to a shortfall in safety performance at a high level: e.g., an excessively high probability of loss of crew, loss of mission, planetary contamination, etc. Without aggregated quantitative measures such as these, it is not reasonable to expect that safety has been optimized with respect to other technical and programmatic objectives. At the same time, it is fully recognized that not all sources of risk are amenable to precise quantitative analysis and that the use of qualitative approaches and bounding estimates may be appropriate for those risk sources. Second, the handbook stresses the necessity of developing confidence that the controls derived for the purpose of achieving system safety not only handle risks that have been identified and properly characterized but also provide a general, more holistic means for protecting against unidentified or uncharacterized risks. For example, while it is not possible to be assured that all credible causes of risk have been identified, there are defenses that can provide protection against broad categories of risks and thereby increase the chances that individual causes are contained. Third, the handbook strives at all times to treat uncertainties as an integral aspect of risk and as a part of making decisions. The term "uncertainty" here does not refer to an actuarial type of data analysis, but rather to a characterization of our state of knowledge regarding results from logical and physical models that approximate reality. Uncertainty analysis finds how the output parameters of the models are related to plausible variations in the input parameters and in the modeling assumptions. The evaluation of unrtainties represents a method of probabilistic thinking wherein the analyst and decision makers recognize possible outcomes other than the outcome perceived to be "most likely." Without this type of analysis, it is not possible to determine the worth of an analysis product as a basis for making decisions related to safety and mission success. In line with these considerations the handbook does not take a hazard-analysis-centric approach to system safety. Hazard analysis remains a useful tool to facilitate brainstorming but does not substitute for a more holistic approach geared to a comprehensive identification and understanding of individual risk issues and their contributions to aggregate safety risks. The handbook strives to emphasize the importance of identifying the most critical scenarios that contribute to the risk of not meeting the agreed-upon safety objectives and requirements using all appropriate tools (including but not limited to hazard analysis). Thereafter, emphasis shifts to identifying the risk drivers that cause these scenarios to be critical and ensuring that there are controls directed toward preventing or mitigating the risk drivers. To address these and other areas, the handbook advocates a proactive, analytic-deliberative, risk-informed approach to system safety, enabling the integration of system safety activities with systems engineering and risk management processes. It emphasizes how one can systematically provide the necessary evidence to substantiate the claim that a system is safe to within an acceptable risk tolerance, and that safety has been achieved in a cost-effective manner. The methodology discussed in this handbook is part of a systems engineering process and is intended to be integral to the system safety practices being conducted by the NASA safety and mission assurance and systems engineering organizations. The handbook posits that to conclude that a system is adequately safe, it is necessary to consider a set of safety claims that derive from the safety objectives of the organization. The safety claims are developed from a hierarchy of safety objectives and are therefore hierarchical themselves. Assurance that all the claims are true within acceptable risk tolerance limits implies that all of the safety objectives have been satisfied, and therefore that the system is safe. The acceptable risk tolerance limits are provided by the authority who must make the decision whether or not to proceed to the next step in the life cycle. These tolerances are therefore referred to as the decision maker's risk tolerances. In general, the safety claims address two fundamental facets of safety: 1) whether required safety thresholds or goals have been achieved, and 2) whether the safety risk is as low as possible within reasonable impacts on cost, schedule, and performance. The latter facet includes consideration of controls that are collective in nature (i.e., apply generically to broad categories of risks) and thereby provide protection against unidentified or uncharacterized risks.

Dezfuli, Homayoon↗

On the Variability of the Solar Integral Radiation Constituents

The results of spectral analysis of series of observations of the equatorial and polar diameters, as well as of series of satellite observations of the S sub O variations during 1975 to 1987 presented in papers by Laclare (1987), Delache (1988) and Delache et al. (1988) confirm with confidence the presence of an 11-year modulation in the Sun's radiation and diameter, and consequently, in the effective temperature of the photosphere. The same conclusion has been drawn with regard to the 1000th and 320th daily periodicities. In combination with the results of other research, several obvious conclusions can be drawn from the data presented. The 76-year variation in the period from 1967 to 1987 is not revealed in the data of observations; the data of the middle series will doubtless be made more precise after the facsimile from the initial information is obtained. The basic and comparable contributions to the radius variability yield the 11- and 22-year variations. The presence can easily be seen of harmonics with periods of 2 and 4 years; the 4-year period is revealed up to 1979 only, and the 2-year one, after 1980 only. This is possibly due to the combined contribution of the 11- and 22-year variations (to be more precise, 10.8 and 21.2 years) forming a certain mean 16-year periodicity. In this case, the 4- and 2-year variations can be regarded as the 4th and 8th harmonics of such a mean variation. Measurements of the horizontal diameter made at Greenwich Observatory have not lost their significance for the analysis of phenomena on the Sun, since they contain data having precision characteristics conforming to the level of the latest ground-based diameter measurements.

Nikolsky, G. A.↗

Polar motion and earth tides from Beacon Explorer C

Seventeen months of laser tracking of the Beacon Explorer C spacecraft by a Goddard Space Flight Center laser system were analyzed. The amplitude and phase of the solid-earth and ocean-tide perturbations of the orbit and the variation in latitude of the tracking station were determined. From an analysis of the orbital inclination obtained from 6 hour data spans the tidal perturbations of the orbit were found to have a magnitude equivalent to a second degree Love number, k sub 2, of 0.245 with a phase lag of about 3.2 degrees. These numbers are in complete agreement with values obtained previously from a much shorter data span, although k sub 2, is lower than the value derived from seismic data. This discrepancy is probably due to the influence of the oceans on the satellite result. After removing the tidal perturbations the residuals in inclination were of order 0.04 arcseconds. This implies that the variation in latitude of the station was being determined during the 17 months period with an rms deviation of about 1.4 meters with respect to the smoothed Bureau International de l'Heure values.

Kolenkiewicz, D. E.↗

A Parametric Model of Shoulder Articulation for Virtual Assessment of Space Suit Fit

Shoulder injury is one of the most severe risks that have the potential to impair crewmembers' performance and health in long duration space flight. Overall, 64% of crewmembers experience shoulder pain after extra-vehicular training in a space suit, and 14% of symptomatic crewmembers require surgical repair (Williams & Johnson, 2003). Suboptimal suit fit, in particular at the shoulder region, has been identified as one of the predominant risk factors. However, traditional suit fit assessments and laser scans represent only a single person's data, and thus may not be generalized across wide variations of body shapes and poses. The aim of this work is to develop a software tool based on a statistical analysis of a large dataset of crewmember body shapes. This tool can accurately predict the skin deformation and shape variations for any body size and shoulder pose for a target population, from which the geometry can be exported and evaluated against suit models in commercial CAD software. A preliminary software tool was developed by statistically analyzing 150 body shapes matched with body dimension ranges specified in the Human-Systems Integration Requirements of NASA ("baseline model"). Further, the baseline model was incorporated with shoulder joint articulation ("articulation model"), using additional subjects scanned in a variety of shoulder poses across a pre-specified range of motion. Scan data was cleaned and aligned using body landmarks. The skin deformation patterns were dimensionally reduced and the co-variation with shoulder angles was analyzed. A software tool is currently in development and will be presented in the final proceeding. This tool would allow suit engineers to parametrically generate body shapes in strategically targeted anthropometry dimensions and shoulder poses. This would also enable virtual fit assessments, with which the contact volume and clearance between the suit and body surface can be predictively quantified at reduced time and cost.

Kim, K. Han↗

Disentangling Coexisting Structural Order Through Phase Lock-In Analysis of Atomic-Resolution STEM Data

As a real-space technique, atomic-resolution STEM imaging contains both amplitude and geometric phase information about structural order in materials, with the latter encoding important information about local variations and heterogeneities present in crystalline lattices. Such phase information can be extracted using geometric phase analysis (GPA), a method which has generally focused on spatially mapping elastic strain. Here we demonstrate an alternative phase demodulation technique and its application to reveal complex structural phenomena in correlated quantum materials. As with other methods of image phase analysis, the phase lock-in approach can be implemented to extract detailed information about structural order and disorder, including dislocations and compound defects in crystals. Extending the application of this phase analysis to Fourier components that encode periodic modulations of the crystalline lattice, such as superlattice or secondary frequency peaks, we extract the behavior of multiple distinct order parameters within the same image, yielding insights into not only the crystalline heterogeneity but also subtle emergent order parameters such as antipolar displacements. When applied to atomic-resolution images spanning large (~0.5 × 0.5 μm 2 ) fields of view, this approach enables vivid visualizations of the spatial interplay between various structural orders in novel materials.

74 ATOMIC AND MOLECULAR PHYSICS↗

Natural transformation as a tool in Acinetobacter baylyi : Streamlined engineering and mutational analysis

Natural transformation and homologous recombination in a soil bacterium, Acinetobacter baylyi ADP1, occur with exceptionally high efficiency. These genetic features can be harnessed to address a wide variety of fundamental and applied scientific topics. Recent advances in synthetic biology and laboratory evolution have led to renewed appreciation for the use of A. baylyi as a model organism. To complement several review articles that highlight new tool sets, this chapter focuses on simple protocols and examples of transformation assays that facilitate genetic analysis and engineering. Whole genome sequencing often reveals extensive genetic variation among closely related isolates that can confound the association of genotypic and phenotypic changes. In A. baylyi, such associations can be deciphered in unique ways by directly transforming cells with linear DNA fragments. The resulting allelic replacement, which occurs at high frequency, rapidly generates desired mutants via targeted chromosomal editing. Diverse screening and selection methods can be used to test hypotheses and streamline experimental strategies to reveal the significance of specific DNA sequences. Moreover, large procedural variations are well tolerated, and techniques can be readily adapted for new purposes. Furthermore, one goal of highlighting natural transformation methodology in A. baylyi is to expand the community of researchers using this versatile bacterial host.

59 BASIC BIOLOGICAL SCIENCES↗

Molybdenum isotope compositions of uranium ore concentrates by double spike MC-ICP-MS

The molybdenum (Mo) isotope composition of uranium ore concentrate (UOC) has been proposed as a nuclear forensic signature due to the ubiquitous presence of Mo in the nuclear fuel cycle and to the possibility that different UOC production pathways lead to characteristic Mo isotope fractionation. Furthermore, Mo forms a volatile hexafluoride which leads to the retainment of Mo in the nuclear fuel cycle through U enrichment and reactor operation processes. As a result, it is possible that the nuclear fuel cycle generates a rich array of Mo isotope signatures. The first step in interpreting Mo isotope signatures generated during the nuclear fuel cycle is to characterize the Mo isotope composition of starting materials. In this study, a suite of UOC samples were analyzed for their Mo isotope composition in order to constrain the range of Mo isotope compositions entering the front end of the nuclear fuel cycle. Analytical protocols were developed to purify Mo from a U rich matrix prior to Mo isotope analysis by double spike MC-ICP-MS. A >3‰ variation in the 98 Mo/ 95 Mo ratio was observed in the suite of UOC samples with δ 98 Mo ranging from -1.15 to +1.96‰ relative to the NIST 3134 Mo standard reference material. The δ98Mo range observed in the UOC samples is very similar to the δ 98 Mo range observed in crustal igneous rocks and Mo-bearing minerals, suggesting that Mo isotope variability in UOC is driven by variability in the parent U ores. However, Mo isotope fractionation during UOC production is evident with one of the UOC samples being isotopically heavy relative to its parent U ore by 0.75‰, suggesting that different UOC production processes also contribute to the total Mo isotope variability observed. Overall, it is expected that the Mo isotope signatures generated during enrichment and reactor process will be clearly discernible from those generated during UOC production.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Database development and exploration of process–microstructure relationships using variational autoencoders

The paper demonstrates graphical representation of a large database containing process–microstructure relationships using an unsupervised machine learning algorithm. Correlating microstructural features to processing is an essential first step to answer the difficult problem of process sequence design. Here, a large database of 346,200 orientation distribution functions resulting from a variety of process sequences is constructed, where each sequence comprises up to four stages of tension, compression and rolling along different directions in various permutations. This open-source database is constructed for collaborative development of process design algorithms. The paper demonstrates a novel application of the large database: graphical representation of texture–process relationships. A variational autoencoder is used to reduce the entire database to a two dimensional latent space where variations in processes and properties can be visualized. Using proximity analysis in this latent space, we can quickly unearth multiple process solutions to the problem of texture or property design.

36 MATERIALS SCIENCE↗

Electronic parameters in cobalt-based perovskite-type oxides as descriptors for chemocatalytic reactions

Perovskite-type transition metal (TM) oxides are effective catalysts in oxidation and decomposition reactions. Yet, the effect of compositional variation on catalytic efficacy is not well understood. The present analysis of electronic characteristics of B-site substituted LaCoO3 derivatives via in situ X-ray absorption spectroscopy (XAS) establishes correlations of electronic parameters with reaction rates: TM t2g and eg orbital occupancy yield volcano-type or non-linear correlations with NO oxidation, CO oxidation and N2O decomposition rates. Covalent O 2p-TM 3d interaction, in ultra-high vacuum, is a linear descriptor for reaction rates in NO oxidation and CO oxidation, and for N2O decomposition rates in O2 presence. Covalency crucially determines the ability of the catalytically active sites to interact with surface species during the kinetically relevant step of the reaction. The nature of the kinetically relevant step and of surface species involved lead to the vast effect of XAS measurement conditions on the validity of correlations.

Science & Technology - Other Topics↗