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All sourcesNASA NTRSDOE OSTI
NASA NTRS2019

Satellite Salinity Observing System: Recent Discoveries and the Way Forward

Advances in L-band microwave satellite radiometry in the past decade, pioneered by ESA's SMOS and NASA's Aquarius and SMAP missions, have demonstrated an unprecedented capability to observe global sea surface salinity (SSS) from space. Measurements from these missions are the only means to probe the very-near surface salinity (top cm), providing a unique monitoring capability for the interfacial exchanges of water between the atmosphere and the upper-ocean, and delivering a wealth of information on various salinity processes in the ocean, linkages with the climate and water cycle, including land-sea connections, and providing constraints for ocean prediction models. The satellite SSS data are complimentary to the existing in situ systems such as Argo that provide accurate depiction of large-scale salinity variability in the open ocean but under-sample mesoscale variability, coastal oceans and marginal seas, and energetic regions such as boundary currents and fronts. In particular, salinity remote sensing has proven valuable to systematically monitor the open oceans as well as coastal regions up to approximately 40 km from the coasts. This is critical to addressing societally relevant topics, such as land-sea linkages, coastal-open ocean exchanges, research in the carbon cycle, near-surface mixing, and air-sea exchange of gas and mass. In this paper, we provide a community perspective on the major achievements of satellite SSS for the aforementioned topics, the unique capability of satellite salinity observing system and its complementarity with other platforms, uncertainty characteristics of satellite SSS, and measurement versus sampling errors in relation to in situ salinity measurements. We also discuss the need for technological innovations to improve the accuracy, resolution, and coverage of satellite SSS, and the way forward to both continue and enhance salinity remote sensing as part of the integrated Earth Observing System in order to address societal needs.

Vinogradova, Nadya↗
NASA NTRS1998

The Remote Sensing of Mineral Aerosols and Their Impact on Phytoplankton Productivity using Sea WiFS

The main objective of this proposal was to use SeaWiFs data to study the relationship between aerosols found in aeollan dust and photosynthesis of phytoplankton in open ocean surface waters. This project was a collaborative effort between myself and Dr. Neil Tindale at Texas A&M University and followed on our earlier funded proposal which had been designed as a proof-of-concept study to determine if ocean color sensors such as the Coastal Zone Color Scanner (CZCS) could be used to detect and map large-scale mineral aerosol plumes. Despite the large spatial and temporal gaps inherent in the CZCS data coverage, our results from this initial study indicated that an ocean color sensor could indeed be used to detect aerosols. These encouraging results led us to propose in this proposal the use of SeaWiFS data to study mineral aerosol transport and its impact on phytoplankton production. This proposal orignally intended to make use of SeaWiFS images, but as the launch delay of SeaWiFS dragged on, we had to make do with other satellite data sets. Thus, the focus of this proposal became the CSCS image archive instead. I detail my results and accomplishments with this data set.

Stegmann, Petra M.↗
NASA NTRS2016

Prediction of Weather Impacts on Airport Arrival Meter Fix Capacity

This paper introduces a data driven model for predicting airport arrival capacity with a look-ahead time 2-8 hour forecast. The model is suitable for air traffic flow management by explicitly investigating the impact of convective weather on airport arrival meter fix throughput. Estimation of the arrival airport capacity under arrival meter fix flow constraints due to severe weather is an important part of Air Traffic Management (ATM). Airport arrival capacity can be reduced if one or more airport arrival meter fixes are partially or completely blocked by convective weather. When the predicted airport arrival demands exceed the predicted available airport's arrival capacity for a sustained period, Ground Delay Program (GDP) operations will be triggered by ATM system. Serious imbalances between demand and capacity occur most frequently when the airport capacity is severely degraded due to either bad airport terminal surface weather or inclement convective weather around airport arrival fixes. A model that predicts the weather-impacted airport arrival meter fix throughput may help ATM personnel to plan GDP operations more efficiently. This paper identifies the characteristics of air traffic flow across arrival meter fixes at Newark Liberty International Airport (EWR). The proposed approach, based on machine-learning methods, is developed to predict the weather impacted EWR arrival Meter Fix (MF) throughput. Sector forecast coverage is used to envision the weather impact on airport arrival MF flow, and the validation is accomplished by using Convective Weather Avoidance Model (CWAM) 0.5 to 2-hour and Collaborative Convective Forecast Product (CCFP) 4 to 8-hour look-ahead forecast data for the period of April-September in 2014. Furthermore, the regression tree ensemble learning of random forests approach for translating a sector forecast coverage model to an EWR arrival meter fix throughput model is examined. The results suggest that ATM decision makers in charge of MF flow control and GDP planning may benefit from adopting the airport arrival meter capacity prediction models to estimate the inclement weather impacts.

Wang, Yao X.↗
DOE OSTI2022

Symmetry-resolved CO desorption and oxidation dynamics on O/Ru(0001) probed at the C K-edge by ultrafast X-ray spectroscopy

In this work, we report on carbon monoxide desorption and oxidation induced by 400 nm femtosecond laser excitation on the O/Ru(0001) surface probed by time-resolved X-ray absorption spectroscopy (TR-XAS) at the carbon K-edge. The experiments were performed under constant background pressures of CO (6x10 -8 Torr) and O 2 (3x10 -8 Torr). Under these conditions, we detect two transient CO species with narrow 2π* peaks, suggesting little 2π* interaction with the surface. Based on polarization measurements, we find that these two species have opposing orientations: (1) CO favoring a more perpendicular orientation and (2) CO favoring a more parallel orientation with respect to the surface. We also directly detect gas-phase CO 2 using a mass spectrometer and observe weak signatures of bent adsorbed CO 2 at slightly higher X-ray energies than the 2π* region. These results are compared to previously reported TR-XAS results at the O K-edge where the CO background pressure was three times lower (2x10 -8 Torr) while maintaining the same O 2 pressure. At the lower CO pressure, in the CO 2π* region, we observed adsorbed CO and a distribution of OC-O bond lengths close to the CO oxidation transition state, with little indication of gas-like CO. The shift towards 'gas-like' CO species may be explained by the higher CO exposure, which blocks O adsorption, decreasing O coverage and increasing CO coverage. These effects decrease the CO desorption barrier through dipole-dipole interaction, while simultaneously increasing the CO oxidation barrier.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Stress- and Time-Dependent Formation of Self-Lubricating In Situ Carbon (SLIC) Films on Catalytically-Active Noble Alloys

Abstract Low shear strength (30 MPa) organic films were grown in situ on Pt 0.9 Au 0.1 surfaces via cyclic sliding contact in dry N 2 with trace concentrations of ambient hydrocarbons. We present a systematic investigation of the stress- and time-dependent film formation. Steady-state friction coefficients were found to be as low as µ ~ 0.015 and inversely proportional to contact pressure, revealing non-Amontonian behavior. Above a Hertzian contact pressure of ~500 MPa, shear strength dropped, indicating an activated process. Raman spectroscopy identified non-uniformity in areal coverage and relative order with contact pressure. Regions of steady-state low-friction behavior exhibited spectra similar to DLC coatings. Atomic force microscopy was used to study the formation and growth of films at the nanoscale. Stress- and time-dependent measurements suggested a sublinear increase of film volume with time, and a transition from growth to wear at a Hertzian contact pressure of ~1.2 GPa.

Jones, Morgan R.↗
DOE OSTI2022

Transition of Large-Scale Environmental Conditions and Characteristics of Four Rainfall Types Observed by S-PolKa During the MJO-1 Active Phase of DYNAMO/CINDY/AMIE

Analyses of National Center for Atmospheric Research (NCAR) S-PolKa dual-polarization radar data and ERA5 reanalysis fields indicate gradual changes in convection characteristics and large-scale environmental conditions during a central Indian Ocean Madden-Julian Oscillation (MJO) event observed by the DYNAMO/CINDY/AMIE field campaigns in late October 2011 (MJO-1). Examination of four rainfall types (isolated convective cores, convective, mixed, and stratiform) reveals a transition of convection characteristics (i.e., areal coverage and depth) between distinct 5-day environmental periods at the beginning and end of this ~2-week MJO active phase. A shift toward less frequent rainfall covering less of the radar domain for all four rainfall types occurs when large-scale lower-tropospheric dry air advects into the region with the westerly wind burst (WWB). Drier and warmer lower-free-tropospheric conditions associated with the WWB contribute to increased large-scale surface-based convective inhibition (CIN), surface-based convective available potential energy (CAPE), and cloud base heights. A thermodynamic budget analysis indicates reduced surface heat fluxes contribute to the increased surface-based CAPE. Greater CAPE at the end of MJO-1 coincides with deeper 50-dBZ convective echoes, while decreased 10-dBZ depth for all rainfall types corresponds in time with WWB-related dry-air advection. Increased (decreased) reflectivity values in the lower-level vertical reflectivity distribution of convective (stratiform) precipitation indicate increased (decreased) convective (stratiform) intensities when the WWB is present. The opposite depth changes for convective echoes and opposite shifts in convective and stratiform precipitation intensities underscore how the WWB can have differing impacts at different reflectivity thresholds and stages of the deep convection lifecycle.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1972

Analysis and comparison of wall cooling schemes for advanced gas turbine applications

The relative performance of (1) counterflow film cooling, (2) parallel-flow film cooling, (3) convection cooling, (4) adiabatic film cooling, (5) transpiration cooling, and (6) full-coverage film cooling was investigated for heat loading conditions expected in future gas turbine engines. Assumed in the analysis were hot-gas conditions of 2200 K (3500 F) recovery temperature, 5 to 40 atmospheres total pressure, and 0.6 gas Mach number and a cooling air supply temperature of 811 K (1000 F). The first three cooling methods involve film cooling from slots. Counterflow and parallel flow describe the direction of convection cooling air along the inside surface of the wall relative to the main gas flow direction. The importance of utilizing the heat sink available in the coolant for convection cooling prior to film injection is illustrated.

Colladay, R. S.↗
NASA NTRS1980

Irregularities in the X-ray background

The X-ray background is a unique tool in having its origin in the redshift range of about unity, and in the availability of all sky coverage. The paper reviews the measurements of isotropy and compares them to what is known about the origin of the X-ray background in terms of discrete sources, a galactic component, and a possible 'truly diffuse' metagalactic emission. Only the 2-10 keV X-ray range is considered in detail. Four irregularities in the distribution of the 2-10 keV X-ray background are identified, three of them being in the angular distribution of surface brightness. Recent results from the Einstein X-ray Observatory have revealed the fourth irregularity, namely, that the extragalactic sources evolve strongly so that half the background arises from beyond a redshift of unity.

Schwartz, D. A.↗
NASA NTRS1987

Wind tunnel test results of heavy rain effects on airfoil performance

The effects of simulated heavy rain on the aerodynamic characteristics of a NACA 64-210 airfoil section equipped with high-lift devices were investigated in the NASA Langley 14- by 22-Foot Subsonic Tunnel. The experiment was part of an on-going NASA program to determine the effect of heavy rain on airplane performance, and was directed at providing insight into scaling laws for subscale model testing of rain effects. The model used in the investigation had a chord of 2.5 feet, a span of 8.0 feet, and was mounted on the tunnel centerline between two large endplates. A water spray distribution system was located 10 chord lengths upstream of the model. The sensitivity of test results to partial-span coverage of the model in the simulated rain environment as compared to full-span coverage was also investigated. The lift and drag data obtained for the high-lift configuration show excellent repeatability of results compared to the previous data. Results obtained for various spray concentrations and tunnel speeds showed significant losses in maximum lift capability, a decrease in the angle of attack for maximum lift, and an increase in drag as the stimulated rain rate was increased. The test results also indicated that the data were not strongly affected by surface tension effects for the high-lift configuration.

Bezos, G. M.↗
NASA NTRS1995

Extreme ultraviolet light curves of UZ Fornacis: Evidence for accretion stream absorption and vertical extent of the accretion spot

We report on two pointed observations of UZ For carried out by the imaging photometers aboard the Extreme Ultraviolet Explorer (EUVE), one as part of the EUVE Right Angle Program and one as an off-axis source during a guest observation. Both observations lasted approximately 3 days and covered a total of 72 orbits of the UZ For binary providing multiple coverage of all the orbital phases of UZ For. The resulting high signal-to-noise phase-folded light curve strongly constrains the emission and absorption geometry of UZ For. We have detected a narrow absorption dip that we attribute to the accretion stream at the location of the stagnation region many white dwarf radii away from the accretion spot and have also detected a broad dip caused by absorption much closer to the white dwarf surface. Both absorption effects are variable in time and phase. Based on the timescales of M-star eclipse ingress and egress, the angular spot size is constrained to be less than 5 deg; thus the ratio of spot area to white dwarf surface area is less than or equal to 0.0005. To explain the light curve phase duration given this small angular spot size, the extreme-ultraviolet (EUV) accretion spot must be raised vertically by approximately 5% of the white dwarf radius.

Warren, John K.↗
NASA NTRS2007

Forecasting Plant Productivity and Health Using Diffuse-to-Global Irradiance Ratios Extracted from the OMI Aerosol Product

Atmospheric aerosols are a major contributor to diffuse irradiance. This Candidate Solution suggests using the OMI (Ozone Monitoring Instrument) aerosol product as input into a radiative transfer model, which would calculate the ratio of diffuse to global irradiance at the Earth s surface. This ratio can significantly influence the rate of photosynthesis in plants; increasing the ratio of diffuse to global irradiance can accelerate photosynthesis, resulting in greater plant productivity. Accurate values of this ratio could be useful in predicting crop productivity, thereby improving forecasts of regional food resources. However, disagreements exist between diffuse-to-global irradiance values measured by different satellites and ground sensors. OMI, with its unique combination of spectral bands, high resolution, and daily global coverage, may be able to provide more accurate aerosol measurements than other comparable sensors.

Knowlton, Kelly↗
NASA NTRS2022

High-Resolution Imaging of Supraglacial Hydrological Features on the Greenland Ice Sheet with NASA’s Airborne Topographic Mapper (ATM) Instrument Suite

Seasonal meltwater pools on the surface of the Greenland Ice Sheet (GrIS) during late spring and summer in lakes on the surface and transforms the ice sheet's surface into a wet environment in the ablation zone below the equilibrium line. These supraglacial lakes in topographic lows on the ice surface are connected by a dendritic pattern of meandering streams and channels that together form a hydrological system consisting of supra-, en-, and subglacial components. Here, we use lidar data from NASA's Airborne Topographic Mapper (ATM) instrument suite and high-resolution optical imagery collected as part of Operation IceBridge (OIB) in spring 2019 over the GrIS to develop methods for the study of supraglacial hydrological features. While airborne surveys have a limited temporal and spatial coverage compared to imaging spaceborne sensors, their high footprint density and high-resolution imagery reveal a level of detail that is currently not obtainable from spaceborne measurements. The accuracy and resolution of airborne measurements complement spaceborne measurements, can support calibration and validation of spaceborne methods, and provide information necessary for high-resolution process studies of the supraglacial hydrological system on the GrIS that currently cannot be achieved from spaceborne observations alone.

ATM↗
NASA NTRS2001

Theoretical Basis for the Surface Spectral Reflectance Relationships Used in the MODIS Aerosol Algorithm

The analysis of data from the MODIS instrument on the Terra platform to derive global distribution of aerosols assumes a set of relationships between the blue, rho (sub blue), the red, rho (sub red), and 2.1 micrometers, rho (sub 2.1), spectral channels. These relations have been established from a series of measurements indicating that rho (sub blue) approximately 0.5 rho (sub red) approximately 0.25 rho (sub 2.1). Here we use a model to describe the transfer of radiation through a vegetation canopy composed of randomly oriented leaves to assess the theoretical foundations for these relationships. The influence of varying fractional vegetation coverage is simulated simply as a linear combination of pure soil and pure vegetation conditions, also known as Independent Pixel Approximation (IPA). Calculations for a wide range of leaf area indices and vegetation fractions show that rho (sub blue) is consistently about 1/4 of rho (sub 2.1) as used by MODIS for the whole range of analyzed cases, except for very dark soils, such as those found in burn scars. For its part, the ratio rho (sub red)/rho (sub 2.1) varies from less than the empirically derived value of 1/2 for dense and dark vegetation (rho (sub 2.1) less than 0.1), to more than 1/2 for bright mixture of soil and vegetation. This is in agreement with measurements over uniform dense vegetation, but not with measurements over mixed dark scenes. In the later case, the discrepancy is probably mitigated by shadows due to uneven canopy and terrain on a large scale. It is concluded that the value of this ratio should ideally be made dependent on the land cover type in the operational processing of MODIS data, especially over dense forests.

Kaufman, Yoram J.↗
DOE OSTI2020

Effects of bubbles on the electrochemical behavior of hydrogen-evolving Si microwire arrays oriented against gravity

The size-distribution, coverage, electrochemical impedance, and mass-transport properties of H 2 gas-bubble films were measured for both planar and microwire-array platinized n + -Si cathodes performing the hydrogen-evolution reaction in 0.50 M H 2 SO 4 (aq). Inverted, planar n + -Si/Ti/Pt cathodes produced large, stationary bubbles which contributed to substantial increases in ohmic potential drops. In contrast, regardless of orientation, microwire array n + -Si/Ti/Pt cathodes exhibited a smaller layer of bubbles on the surface, and the formation of bubbles did not substantially increase the steady-state overpotential for H 2 (g) production. Experiments using an electroactive tracer species indicated that even when oriented against gravity, bubbles enhanced mass transport at the electrode surface. Microconvection due to growing and coalescing bubbles dominated effects due to macroconvection of gliding bubbles on Si microwire array cathodes. Electrodes that maintained a large number of small bubbles on the surface simultaneously exhibited low concentrations of dissolved hydrogen and small ohmic potential drops, thus exhibiting the lowest steady-state overpotentials. The results indicate that microstructured electrodes can operate acceptably for unassisted solar-driven water splitting in the absence of external convection and can function regardless of the orientation of the electrode with respect to the gravitational force vector.

25 ENERGY STORAGE↗
NASA NTRS2004

The Chesapeake Lighthouse and Aircraft Measurements for Satellites (CLAMS) Experiment

NASA has developed an Earth Observing System (EOS) consisting of a series of satellites designed to study global change from space. The EOS flagship is the EOS TERRA satellite, launched in December 1999, equipped with five unique sensors to monitor and study the Earth s heat budget and many of the key controlling variables governing the Earth's climate system. CLAMS, the Chesapeake Lighthouse and Aircraft Measurements for Satellites field campaign was conducted from NASA Wallops Flight Facility and successfully executed over the middle Atlantic eastern seaboard from July 10 August 2, 2001. CLAMS is primarily a shortwave closure experiment designed to validate and improve EOS TERRA satellite data products being derived from three sensors: CERES (Clouds and Earth's Radiant Energy System), MISR (Multi-angle Imaging Spectro-Radiometer) and MODIS (MODerate Resolution Imaging Spectroradiometer). CLAMS is jointly sponsored by the CERES, MISR and MODIS instrument teams and the NASA GEWEX Global Aerosol Climatology Project (GACP). CLAMS primary objectives are to validate satellite-based retrievals of aerosol properties and vertical profiles of radiative flux, temperature and water vapor. Central to CLAMS measurement strategy is the Chesapeake Lighthouse, a stable sea platform located in the Atlantic Ocean, 13 miles east of Virginia Beach near the mouth of the Chesapeake Bay and the site of an ongoing CERES Ocean Validation Experiment (COVE). Six research aircraft were deployed to make detailed measurements of the atmosphere and ocean surface in the vicinity of COVE, over the surrounding ocean, over nearby NOAA buoys and over a few land sites. The measurements are used to validate and provide ground truth for simultaneous products being derived from TERRA data, a key step toward an improved understanding and ability to predict changes in the Earth's climate. One of the two CERES instruments on-board TERRA was programmed for Rotating Azimuth Plane Scans (RAPS) during CLAMS, increasing the CERES coverage over COVE by a factor of 10. Nine coordinated aircraft missions and numerous additional sorties were flown under a variety of atmospheric conditions and aerosol loadings. On one golden day, July 17, all six aircraft flew coordinated patterns, vertically stacked between 100 ft and 65,000 ft over the COVE site as the TERRA satellite orbited overhead. A summary of CLAMS measurement campaign and a description of the platforms and measurements is given.

Smith, William L., Jr.↗
NASA NTRS2008

Evolution of the Lunar Network

The National Aeronautics and Space Administration (NASA) is planning to upgrade its network Infrastructure to support missions for the 21st century. The first step is to increase the data rate provided to science missions to at least the 100 megabits per second (Mbps) range. This is under way, using Ka-band 26 Gigahertz (GHz), erecting an 18-meter antenna for the Lunar Reconnaissance Orbiter (LRO), and the planned upgrade of the Deep Space Network (DSN) 34-meter network to support the James Webb Space Telescope (JWST). The next step is the support of manned missions to the Moon and beyond. Establishing an outpost with several activities such as rovers, colonization, and observatories, is better achieved by using a network configuration rather than the current method of point-to-point communication. Another challenge associated with the Moon is communication coverage with the Earth. The Moon's South Pole, targeted for human habitat and exploration, is obscured from Earth view for half of the 28-day lunar cycle and requires the use of lunar relay satellites to provide coverage when there is no direct view of the Earth. The future NASA and Constellation network architecture is described in the Space Communications Architecture Working Group (SCAWG) Report. The Space Communications and Navigation (SCAN) Constellation Integration Project (SCIP) is responsible for coordinating Constellation requirements and has assigned the responsibility for implementing these requirements to the existing NASA communication providers: DSN, Space Network (SN), Ground Network (GN) and the NASA Integrated Services Network (NISN). The SCAWG Report provides a future architecture but does not provide implementation details. The architecture calls for a Netcentric system, using hundreds of 12-meter antennas, a ground antenna array, and a relay network around the Moon. The report did not use cost as a variable in determining the feasibility of this approach. As part of the SCIP Mission Concept Review and the second iteration of the Lunar Architecture Team (LAT), the focus is on cost, as well as communication coverage using operational scenarios. This approach maximizes use of existing assets and adds capability in small increments. This paper addresses architecture decisions such as the Radio Frequency (RF) signal and network (Netcentric) decisions that need to be made and the difficulty of implementing them into the existing Space Network and DSN. It discusses the evolution of the lunar system and describes its components: Tracking and Data Relay Satellite System (TDRSS), Earth-based ground stations, Lunar Relay, and surface systems.

Gal-Edd, Jonathan↗
NASA NTRS2009

CRISM Limb Observations of Aerosols and Water Vapor

Near-infrared spectra taken in a limb-viewing geometry by the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) on-board the Mars Reconnaissance Orbiter (MRO) provide a useful tool for probing atmospheric structure. Here we describe preliminary work on the retrieval of vertical profiles of aerosols and water vapor from the CRISM limb observations. The first full set of CRISM limb observations was taken in July 2009, with subsequent limb observations planned once every two months. Each set of limb observations contains about four dozen scans across the limb giving pole-to-pole coverage for two orbits at roughly 100 and 290 W longitude. Radiative transfer modeling taking account of aerosol scattering in the limb-viewing geometry is used to model the observations. The retrievals show the height to which dust and water vapor extend and the location and height of water ice clouds. Results from the First set of CRISM limb observations (July 2009, Ls=300) show dust aerosol well-mixed to about three scale heights above the surface with thin water ice clouds above the dust near the equator and at mid-northern latitudes. Water vapor is concentrated at high southern latitudes.

Smith, Michael D.↗
DOE OSTI2024

Operando Surface-Enhanced Infrared Spectroscopy Connects Interfacial Dynamics with Reaction Kinetics During Electrochemical CO 2 Reduction on Copper

The reaction microenvironment plays a key role in dictating the selectivity of electrochemical CO 2 reduction. However, understanding the chemical nature of this microenvironment under operating conditions remains a substantial challenge. For this study, we employed attenuated total reflectance surface-enhanced infrared absorption spectroscopy (ATR-SEIRAS) in operando for simultaneous measurements of reaction kinetics and concentrations of reactants and intermediates at the reaction interface, all under controlled mass transport conditions. These operando measurements enable direct correlations between the reaction microenvironment, mass transport, and kinetics for a Cu electrocatalyst, such as higher local concentrations of CO 2 under faster mass transport corresponding to higher rates of CO 2 reduction. We observed that faster mass transport decreased the *CO coverage at less negative potentials (-0.6 V RHE ) and increased the *CO coverage at more negative potentials (-1.1 V RHE ). We developed a transport-coupled kinetic model that captures these spectroscopic observations and provides insight into the processes controlling interfacial concentrations of reactants and intermediates, aiding future efforts toward tailoring reaction microenvironments.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗