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TbRh is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Tb is bonded in a body-centered cubic geometry to eight equivalent Rh atoms. All Tb–Rh bond lengths are 2.98 Å. Rh is bonded in a body-centered cubic geometry to eight equivalent Tb atoms.
TiRh is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Ti is bonded in a body-centered cubic geometry to eight equivalent Rh atoms. All Ti–Rh bond lengths are 2.70 Å. Rh is bonded in a body-centered cubic geometry to eight equivalent Ti atoms.
TmRh is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Tm is bonded in a body-centered cubic geometry to eight equivalent Rh atoms. All Tm–Rh bond lengths are 2.93 Å. Rh is bonded in a body-centered cubic geometry to eight equivalent Tm atoms.
MgRh is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Mg is bonded in a body-centered cubic geometry to eight equivalent Rh atoms. All Mg–Rh bond lengths are 2.71 Å. Rh is bonded in a body-centered cubic geometry to eight equivalent Mg atoms.
RhHg2 crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. Rh is bonded in a body-centered cubic geometry to eight equivalent Hg atoms. All Rh–Hg bond lengths are 2.79 Å. Hg is bonded in a 4-coordinate geometry to four equivalent Rh atoms.
K(RhP)2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. K is bonded in a body-centered cubic geometry to eight equivalent P atoms. All K–P bond lengths are 3.45 Å. Rh is bonded to four equivalent P atoms to form a mixture of corner and edge-sharing RhP4 tetrahedra. All Rh–P bond lengths are 2.35 Å. P is bonded in a 8-coordinate geometry to four equivalent K and four equivalent Rh atoms.
RhV is Tetraauricupride structured and crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. V is bonded to eight equivalent Rh atoms to form a mixture of distorted corner, edge, and face-sharing VRh8 cuboctahedra. All V–Rh bond lengths are 2.67 Å. Rh is bonded to eight equivalent V atoms to form a mixture of distorted corner, edge, and face-sharing RhV8 cuboctahedra.
TbRh2B2C crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Tb3+ is bonded in a square co-planar geometry to four equivalent C4- atoms. All Tb–C bond lengths are 2.70 Å. Rh+3.50+ is bonded to four equivalent B3- atoms to form a mixture of corner and edge-sharing RhB4 tetrahedra. All Rh–B bond lengths are 2.19 Å. B3- is bonded in a distorted single-bond geometry to four equivalent Rh+3.50+ and one C4- atom. The B–C bond length is 1.50 Å. C4- is bonded in a distorted linear geometry to four equivalent Tb3+ and two equivalent B3- atoms.
YRh2B2C crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Y3+ is bonded in a square co-planar geometry to four equivalent C4- atoms. All Y–C bond lengths are 2.69 Å. Rh+3.50+ is bonded to four equivalent B3- atoms to form a mixture of edge and corner-sharing RhB4 tetrahedra. All Rh–B bond lengths are 2.19 Å. B3- is bonded in a distorted single-bond geometry to four equivalent Rh+3.50+ and one C4- atom. The B–C bond length is 1.50 Å. C4- is bonded in a distorted linear geometry to four equivalent Y3+ and two equivalent B3- atoms.
HoRhIn5 crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. Ho is bonded to twelve In atoms to form HoIn12 cuboctahedra that share corners with four equivalent HoIn12 cuboctahedra, faces with four equivalent HoIn12 cuboctahedra, and faces with four equivalent InHo4In8 cuboctahedra. There are eight shorter (3.25 Å) and four longer (3.29 Å) Ho–In bond lengths. Rh is bonded in a body-centered cubic geometry to eight equivalent In atoms. All Rh–In bond lengths are 2.77 Å. There are two inequivalent In sites. In the first In site, In is bonded to four equivalent Ho and eight equivalent In atoms to form distorted InHo4In8 cuboctahedra that share corners with four equivalent InHo4In8 cuboctahedra, faces with four equivalent HoIn12 cuboctahedra, and faces with four equivalent InHo4In8 cuboctahedra. All In–In bond lengths are 3.25 Å. In the second In site, In is bonded in a 4-coordinate geometry to two equivalent Ho, two equivalent Rh, and two equivalent In atoms.
RhP3O9 crystallizes in the monoclinic Cc space group. The structure is three-dimensional. there are three inequivalent Rh3+ sites. In the first Rh3+ site, Rh3+ is bonded to six O2- atoms to form RhO6 octahedra that share corners with six PO4 tetrahedra. There are a spread of Rh–O bond distances ranging from 2.02–2.05 Å. In the second Rh3+ site, Rh3+ is bonded to six O2- atoms to form RhO6 octahedra that share corners with six PO4 tetrahedra. There are a spread of Rh–O bond distances ranging from 2.02–2.06 Å. In the third Rh3+ site, Rh3+ is bonded to six O2- atoms to form RhO6 octahedra that share corners with six PO4 tetrahedra. There are a spread of Rh–O bond distances ranging from 2.03–2.06 Å. There are nine inequivalent P5+ sites. In the first P5+ site, P5+ is bonded to four O2- atoms to form PO4 tetrahedra that share corners with two RhO6 octahedra and corners with two PO4 tetrahedra. The corner-sharing octahedra tilt angles range from 37–49°. There are a spread of P–O bond distances ranging from 1.50–1.62 Å. In the second P5+ site, P5+ is bonded to four O2- atoms to form PO4 tetrahedra that share corners with two equivalent RhO6 octahedra and corners with two PO4 tetrahedra. The corner-sharing octahedra tilt angles range from 47–49°. There is two shorter (1.51 Å) and two longer (1.60 Å) P–O bond length. In the third P5+ site, P5+ is bonded to four O2- atoms to form PO4 tetrahedra that share corners with two RhO6 octahedra and corners with two PO4 tetrahedra. The corner-sharing octahedra tilt angles range from 42–46°. There are a spread of P–O bond distances ranging from 1.50–1.60 Å. In the fourth P5+ site, P5+ is bonded to four O2- atoms to form PO4 tetrahedra that share corners with two RhO6 octahedra and corners with two PO4 tetrahedra. The corner-sharing octahedra tilt angles range from 38–44°. There are a spread of P–O bond distances ranging from 1.50–1.60 Å. In the fifth P5+ site, P5+ is bonded to four O2- atoms to form PO4 tetrahedra that share corners with two RhO6 octahedra and corners with two PO4 tetrahedra. The corner-sharing octahedra tilt angles range from 41–44°. There are a spread of P–O bond distances ranging from 1.50–1.60 Å. In the sixth P5+ site, P5+ is bonded to four O2- atoms to form PO4 tetrahedra that share corners with two RhO6 octahedra and corners with two PO4 tetrahedra. The corner-sharing octahedra tilt angles range from 32–45°. There are a spread of P–O bond distances ranging from 1.50–1.60 Å. In the seventh P5+ site, P5+ is bonded to four O2- atoms to form PO4 tetrahedra that share corners with two equivalent RhO6 octahedra and corners with two PO4 tetrahedra. The corner-sharing octahedra tilt angles range from 37–42°. There are a spread of P–O bond distances ranging from 1.50–1.61 Å. In the eighth P5+ site, P5+ is bonded to four O2- atoms to form PO4 tetrahedra that share corners with two RhO6 octahedra and corners with two PO4 tetrahedra. The corner-sharing octahedra tilt angles range from 46–50°. There are a spread of P–O bond distances ranging from 1.51–1.61 Å. In the ninth P5+ site, P5+ is bonded to four O2- atoms to form PO4 tetrahedra that share corners with two equivalent RhO6 octahedra and corners with two PO4 tetrahedra. The corner-sharing octahedra tilt angles range from 39–41°. There are a spread of P–O bond distances ranging from 1.50–1.61 Å. There are twenty-seven inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one Rh3+ and one P5+ atom. In the second O2- site, O2- is bonded in a 2-coordinate geometry to one Rh3+ and one P5+ atom. In the third O2- site, O2- is bonded in a 2-coordinate geometry to one Rh3+ and one P5+ atom. In the fourth O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one Rh3+ and one P5+ atom. In the fifth O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one Rh3+ and one P5+ atom. In the sixth O2- site, O2- is bonded in a bent 150 degrees geometry to two P5+ atoms. In the seventh O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one Rh3+ and one P5+ atom. In the eighth O2- site, O2- is bonded in a bent 150 degrees geometry to two P5+ atoms. In the ninth O2- site, O2- is bonded in a bent 150 degrees geometry to two P5+ atoms. In the tenth O2- site, O2- is bonded in a bent 150 degrees geometry to two P5+ atoms. In the eleventh O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one Rh3+ and one P5+ atom. In the twelfth O2- site, O2- is bonded in a bent 150 degrees geometry to two P5+ atoms. In the thirteenth O2- site, O2- is bonded in a bent 150 degrees geometry to two P5+ atoms. In the fourteenth O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one Rh3+ and one P5+ atom. In the fifteenth O2- site, O2- is bonded in a bent 150 degrees geometry to two P5+ atoms. In the sixteenth O2- site, O2- is bonded in a bent 150 degrees geometry to two P5+ atoms. In the seventeenth O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one Rh3+ and one P5+ atom. In the eighteenth O2- site, O2- is bonded in a bent 150 degrees geometry to one Rh3+ and one P5+ atom. In the nineteenth O2- site, O2- is bonded in a 2-coordinate geometry to one Rh3+ and one P5+ atom. In the twentieth O2- site, O2- is bonded in a bent 150 degrees geometry to two P5+ atoms. In the twenty-first O2- site, O2- is bonded in a 2-coordinate geometry to one Rh3+ and one P5+ atom. In the twenty-second O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one Rh3+ and one P5+ atom. In the twenty-third O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one Rh3+ and one P5+ atom. In the twenty-fourth O2- site, O2- is bonded in a 2-coordinate geometry to one Rh3+ and one P5+ atom. In the twenty-fifth O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one Rh3+ and one P5+ atom. In the twenty-sixth O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one Rh3+ and one P5+ atom. In the twenty-seventh O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one Rh3+ and one P5+ atom.
CeRh3 is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Ce is bonded to twelve equivalent Rh atoms to form a mixture of corner and face-sharing CeRh12 cuboctahedra. All Ce–Rh bond lengths are 2.88 Å. Rh is bonded in a distorted square co-planar geometry to four equivalent Ce atoms.
Nb3Rh crystallizes in the cubic Pm-3n space group. The structure is three-dimensional. Nb is bonded in a 6-coordinate geometry to two equivalent Nb and four equivalent Rh atoms. Both Nb–Nb bond lengths are 2.59 Å. All Nb–Rh bond lengths are 2.90 Å. Rh is bonded to twelve equivalent Nb atoms to form a mixture of face and edge-sharing RhNb12 cuboctahedra.
CuRh2S4 is Spinel structured and crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. Rh+3.50+ is bonded to six equivalent S2- atoms to form RhS6 octahedra that share corners with six equivalent CuS4 tetrahedra and edges with six equivalent RhS6 octahedra. All Rh–S bond lengths are 2.38 Å. Cu1+ is bonded to four equivalent S2- atoms to form CuS4 tetrahedra that share corners with twelve equivalent RhS6 octahedra. The corner-sharing octahedral tilt angles are 58°. All Cu–S bond lengths are 2.30 Å. S2- is bonded to three equivalent Rh+3.50+ and one Cu1+ atom to form a mixture of distorted edge and corner-sharing SCuRh3 trigonal pyramids.
CuRh2Se4 is Spinel structured and crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. Rh+3.50+ is bonded to six equivalent Se2- atoms to form RhSe6 octahedra that share corners with six equivalent CuSe4 tetrahedra and edges with six equivalent RhSe6 octahedra. All Rh–Se bond lengths are 2.51 Å. Cu1+ is bonded to four equivalent Se2- atoms to form CuSe4 tetrahedra that share corners with twelve equivalent RhSe6 octahedra. The corner-sharing octahedral tilt angles are 58°. All Cu–Se bond lengths are 2.42 Å. Se2- is bonded to three equivalent Rh+3.50+ and one Cu1+ atom to form a mixture of distorted edge and corner-sharing SeCuRh3 trigonal pyramids.
V3Rh crystallizes in the cubic Pm-3n space group. The structure is three-dimensional. V is bonded in a 6-coordinate geometry to two equivalent V and four equivalent Rh atoms. Both V–V bond lengths are 2.39 Å. All V–Rh bond lengths are 2.67 Å. Rh is bonded to twelve equivalent V atoms to form a mixture of edge and face-sharing RhV12 cuboctahedra.
Ti5RhSb2 crystallizes in the tetragonal I4/mcm space group. The structure is three-dimensional. there are two inequivalent Ti sites. In the first Ti site, Ti is bonded in a 6-coordinate geometry to two equivalent Rh and four equivalent Sb atoms. Both Ti–Rh bond lengths are 2.68 Å. There are two shorter (2.81 Å) and two longer (3.08 Å) Ti–Sb bond lengths. In the second Ti site, Ti is bonded in a 6-coordinate geometry to two equivalent Ti and four equivalent Sb atoms. Both Ti–Ti bond lengths are 2.62 Å. All Ti–Sb bond lengths are 2.76 Å. Rh is bonded in a 10-coordinate geometry to eight equivalent Ti atoms. Sb is bonded in a 10-coordinate geometry to ten Ti atoms.
PuRh3 is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Pu is bonded to twelve equivalent Rh atoms to form a mixture of face and corner-sharing PuRh12 cuboctahedra. All Pu–Rh bond lengths are 2.83 Å. Rh is bonded in a distorted square co-planar geometry to four equivalent Pu atoms.