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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,711 records · Page 95

Assessment of the frequency and nature of erroneous x-ray photoelectron spectroscopy analyses in the scientific literature

Here, this study was undertaken to understand the extent and nature of problems in x-ray photoelectron spectroscopy (XPS) data reported in the literature. It first presents an assessment of the XPS data in three high-quality journals over a six-month period. This analysis of 409 publications showing XPS spectra provides insight into how XPS is being used, identifies the common mistakes or errors in XPS analysis, and reveals which elements are most commonly analyzed. More than 65% of the 409 papers showed fitting of XP spectra. An ad hoc group (herein identified as “the committee”) of experienced XPS analysts reviewed these spectra and found that peak fitting was a common source of significant errors. The papers were ranked based on the perceived seriousness of the errors, which ranged from minor to major. Major errors, which, in the opinion of the ad hoc committee, can render the interpretation of the data meaningless, occurred when fitting protocols ignored underlying physics and chemistry or contained major errors in the analysis. Consistent with other materials analysis data, ca. 30% of the XPS data or analysis was identified as having major errors. Out of the publications with fitted spectra, ca. 40% had major errors. The most common elements analyzed by XPS in the papers sampled and researched at an online database, include carbon, oxygen, nitrogen, sulfur, and titanium. A scrutiny of the papers showing carbon and oxygen XPS spectra revealed the classes of materials being studied and the extent of problems in these analyses. As might be expected, C 1s and O 1s analyses are most often performed on sp2-type materials and inorganic oxides, respectively. These findings have helped focus a series of XPS guides and tutorials that deal with common analysis issues. The extent of problematic data is larger than the authors had expected. Quantification of the problem, examination of some of the common problem areas, and the development of targeted guides and tutorials may provide both the motivation and resources that enable the community to improve the overall quality and reliability of XPS analysis reported in the literature.

Major, George H.↗

DOE nuclear separation technologies - 15148

Realizing that challenges are facing US actinide science, separations, and waste form research and development activities including meeting future manpower needs, the U.S Department of Energy (DOE), Office of Environmental Management (EM), Office of Nuclear Energy (NE), and National Nuclear Security Administration (NNSA) jointly co-sponsored a workshop entitled 'Separations Technologies: 'Going from Where We Are to Where We Want to Be' on nuclear separations technologies in Bethesda, Maryland (July 2011) to identify common needs and potential requirements in separations technologies and opportunities for program partnerships. Recognizing the different mission requirements of the sponsoring programs, participants were able to identify areas with common uses and related applications. The two follow-on technical workshops held during the Fall 2012 addressed both the chemical aspects and the physical aspects of nuclear separations. Each workshop consisted of technical discussions regarding future work relevant to DOE goals. The large number of subject matter experts from the national laboratories, academia, and headquarters staff developed a long list of existing and new technology developments in the areas of aqueous separations, pyrochemical processing, waste forms, fuel technology etc... Each of these workshops identified the current state of knowledge or technology, the resources needed, technology development opportunities, and the objectives to reach the desired end-state(s). A consolidated report with its eight appendices will be issued at the end of December 2014 summarizing the outcomes of these workshops. Some examples of these findings will be presented in our contribution. It is clear that, in the current environment of decreasing budgets it is illogical for NE, EM and NNSA to develop its own home-grown technology. Therefore, there is a strong case to be made for leveraging limited resources in order to accomplish all objectives while significantly reducing development costs. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Developing a Framework for Reference Cell Standards for PV Resource Applications

Quantifying and predicting electricity production from photovoltaic (PV) systems is based on measured or modeled irradiance data. These solar resource data consist of global horizontal irradiance, global tilted irradiance, direct normal irradiance, and diffuse horizontal irradiance, which are either derived from satellite observations validated against ground-based measurements or directly obtained from ground-based measurements. The ground-based measurements are made using thermopile or photodiode radiometers. For a PV plant, the efficiency of the energy production is verified by comparing measured output with the modeled production, which is computed using either modeled or measured irradiance data. Thus, plant performance assessments typically include the uncertainty of the transposition and, in some cases, decomposition of a given irradiance to convert to the appropriate plane-of-array (POA) irradiance corresponding to the orientation of the PV installation. Additionally, the various types of uncertainty in radiometric measurements or the modeled irradiance and the PV module specifications influence the model results and thereby further increase the uncertainty. An alternative method of assessing the PV system performance has been to use reference cells to measure the "PV resource." When used to calculate PV performance ratios, there are inherent systematic differences between radiometers and reference cells, such as spectral, directional, temperature, time responses, nonstability, and nonlinearity differences. Reference cells tend to mimic the performance and characteristics of a PV module more closely. In this report, a framework is proposed to develop standards that will better quantify and characterize the use of reference cells for PV resource measurements. The measurement from an appropriate reference cell in the POA correlates closely with the plant performance, reduces the number of modeling steps needed to simulate PV performance, and hence reduces the uncertainties of the comparisons. Because technologically matched reference cells and PV modules respond similarly to each wavelength of light that composes the incident solar radiation, the uncertainty associated with the changing spectral distribution of incident radiation during the day and year can be greatly reduced. This will reduce the overall uncertainty in estimated PV performance. The same can be said for the angle-of-incidence effects because the reference cells are deployed in the same POA as the PV module. At that point, the main sources of uncertainty are in modeling the temperature effect differences between the reference cells and the PV module and accounting for the difference between the short-circuit current monitored by the reference cells and max power point current and voltage at which the PV module operates. These sources of uncertainty are also associated with typical irradiance measurements made by pyranometers and pyrheliometers; however, typical irradiance measurements also include uncertainties associated with the spectral mismatch between thermopile or photodiode pyranometers and the PV module, which are minimized with the use of reference cells. To enhance the use of reference cells for resource assessment, we identify the necessary data, characteristics, and calibration methodologies of reference cells and how to standardize the use of these data and methods. Further, as we develop this framework, the classification of reference cells will be essential to provide guidance for selecting PV reference cells appropriate for a specific application. As we address the calibration and sources of uncertainties of reference cells, classification schemes and expected limits of performance with respect to certain parameters become important.

14 SOLAR ENERGY↗

A Systems Analysis Approach to Understanding the Physiological Adaptation to Spaceflight

This book is a summary of interdisciplinary research (physiology, space medicine, engineering, computer science, mathematics) that spans two decades (1972-1992). The research was an attempt to use systems analysis, mathematical modeling, computer simulations, and database systems to integrate the biomedical spaceflight data that was being collected during this period. The goal of the effort was to achieve a better understanding of the human physiological response to short-term and long-term space travel. The activity was primarily devoted to analyzing the biomedical results of Skylab (1973-74), a series of three space missions which is still ranked as the most comprehensive of all long-term biomedical space studies to date. This work was begun as a coordinated effort between the National Aeronautics and Space Administration (Johnson Space Center) and the General Electric Company’s Space Division (Houston, TX). It was the intent that this multidisciplined, integrative approach could reveal aspects of the then-new science of microgravity adaptation that were not obvious by adhering to the traditional methodology of examining each organ system in isolation. Some joint work with the Russians, including the Apollo-Soyez test project and a joint bedrest study was also supported during this period. In the 1980’s the systems analysis group’s effort was redirected to support the science management of human and animal experiments on the Space Shuttle. A few examples from this era are also included in the book. Parts of this work have been published elsewhere, presented at technical meetings, and documented in reports with limited distribution. These publications will be referenced throughout the text and the interested reader is advised to use these as resource material where additional details are desired. The intent of this book is not to reproduce these documents but rather to present a coherent view of the integrative analysis under one cover. This volume contains the first detailed publication (other than in internal reports) of an extensive metabolic balance analysis of Skylab data, the development and validation of the “Whole-Body Algorithm,” and simulation studies of diverse hypogravic environments. An analysis of cardiovascular deconditioning and a description of the calcium regulatory model are also new. A long period has passed between the completion of the main body of work represented in this book and its publication in this form. It was inevitable that new research efforts would lead to developments related to the spaceflight problems addressed and thereby make some of our biomedical conclusions obsolete. Although in some cases reference to more recent work have been included, for the most part this book should be considered an historical summary demonstrating the approach and utility of systems analysis and computer modeling in the NASA Life Sciences program at the time the studies were conducted.

Leonard, Joel I.↗

Task 12 PV Sustainability - Mineral Resource Use Footprints of Residential PV Systems

Resource use intensity is often mentioned as one of the main characteristics of PV systems and PV electricity. Recently, the International Energy Agency published a report on the role of critical minerals in clean energy transitions. The Product Environmental Footprint pilot study on PV electricity quantified (among other environmental impacts) its abiotic depletion potential. So far, a comprehensive assessment of resource use impacts highlighting the different facets of its impacts is however lacking. For the first time, the resource use impacts of PV electricity are quantified simultaneously with four impact category indicators recommended or suggested by the Life Cycle Initiative hosted at UN Environment. The indicators cover distinctly different aspects of resource use, namely resource depletion with the Abiotic Depletion Potential, ultimate reserves (ADP UR ), economic resource scarcity with the Abiotic Depletion Potential, economic reserves (ADP ER ), resource quality with the Surplus Ore Potential, Ultimate Recoverable Resources (SOP URR ) and re-source criticality with the ESSENZ method. The resource use impacts caused from the generation of 1 kWh electricity with a residential scale photovoltaic (PV) system installed in Central Europe using mono- and multi-crystalline silicon panels and CdTe panels, respectively are quantified. The product system includes manufacture, use and end of life treatment (take back and recycling) of the PV panels, cabling, inverter and supporting structure, the supply chains of the raw materials and energy used in PV panel and inverter manufacture as well as transport logistics.

14 SOLAR ENERGY↗

Additional EIPC Study Analysis: Interim Report on High Priority Topics

Between 2010 and 2012 the Eastern Interconnection Planning Collaborative (EIPC) conducted a major long-term resource and transmission study of the Eastern Interconnection (EI). With guidance from a Stakeholder Steering Committee (SSC) that included representatives from the Eastern Interconnection States Planning Council (EISPC) among others, the project was conducted in two phases. Phase 1 involved a long-term capacity expansion analysis that involved creation of eight major futures plus 72 sensitivities. Three scenarios were selected for more extensive transmission- focused evaluation in Phase 2. Five power flow analyses, nine production cost model runs (including six sensitivities), and three capital cost estimations were developed during this second phase. The results from Phase 1 and 2 provided a wealth of data that could be examined further to address energy-related questions. A list of 13 topics was developed for further analysis; this paper discusses the first five.

Electricity Grid↗

El Paso County Geothermal Project at Fort Bliss. Final Project Report

The El Paso County Geothermal Project at Fort Bliss was an effort to determine the scale and scope of geothermal resources previously identified on Fort Bliss’ McGregor Range in southern Otero County, New Mexico. The project was funded with a $5,000,000 grant to El Paso County from the U.S. Department of Energy (DOE) as part of the American Recovery and Reinvestment Act of 2009 and a $4,812,500 match provided by private sector partners. The project was administered through the DOE Golden Field Office to awardee El Paso County. The primary subcontractor to El Paso County and project Principal Investigator - Ruby Mountain Inc. (RMI) of Salt Lake City, Utah - assembled the project team consisting of Evergreen Clean Energy Management (ECEM) of Provo, Utah, and the Energy & Geoscience Institute at the University of Utah (EGI) in Salt Lake City, UT to complete the final phases of the project. The project formally began in May of 2010 and consisted of two preliminary phases of data collection and evaluation which culminated in the identification of a drilling site for a Resource Confirmation Well on McGregor Range. Well RMI 56-5 was drilled May and June 2013 to a depth of 3,030 ft. below ground level. A string of slotted 7 inch casing was set in 8.75 inch hole on bottom fill at 3,017 ft. to complete the well. The well was drilled using a technique called flooded reverse circulation, which is most common in mineral exploration. This technique produced an exceptionally large and complete cuttings record. An exciting development at the conclusion of drilling was the suspected discovery of a formation that has proven to be of exceptionally high permeability in three desalinization wells six miles to the south. Following drilling and preliminary testing and analysis, the project team has determined that the McGregor Range thermal anomaly is large and can probably support development in the tens of megawatts.

15 GEOTHERMAL ENERGY↗

Final Technical Report: "Achieving Regional Energy Efficiency Potential in the Southeast”

The overall objective of this award was to facilitate sharing of DOE resources and best practices as well as provide technical assistance to key stakeholders to support greater compliance with energy efficiency standards and increased energy savings. The outcomes of this award include greater awareness among key stakeholders on energy efficiency topics, increased deployment and utilization of DOE resources, and effective policies and programs to support energy efficiency in the Southeast.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

The National Solar Radiation Database Final Report: Fiscal Years 2022-2024

The National Solar Radiation Database (NSRDB) is the leading public source of high-resolution solar resource data in the United States, with more than 400,000 users annually. This database represents the state of the art in the satellite-based estimation of solar resource information and uses a unique physics-based modeling approach that enables improvements in accuracy with the deployment of the next-generation geostationary satellites. Making the highest-quality, state-of-the-art, regularly updated datasets available on a timely basis for users reduces costs of solar deployment by providing accurate information for siting studies and system output prediction and thereby reduces project financing costs and risks.

14 SOLAR ENERGY↗

Virtual Inspection of Advanced Manufacturing via Process-Scale Digital Twins (Abbreviated Report)

Inspection and certification comprise the most significant bottlenecks in advanced manufacturing for NNSA applications, often requiring far more time and resources than the fabrication of the parts themselves. Traditional methods, such as manual review and X-ray computed tomography, are not only slow and costly, but also struggle to provide a clear connection between manufacturing instructions and the final performance of critical components. This gap limits both the agility and assurance needed to support the modernization and safety of the United States nuclear stockpile. In response, our Strategic Initiative established a digital twin framework that integrates realtime process monitoring, automated data analysis, and immersive virtual reality collaboration into a unified inspection pipeline. By leveraging data from sensors, machine instructions, and imaging, we created high-fidelity virtual models of manufactured parts that could be rapidly analyzed and certified. This approach was first demonstrated with Direct Ink Write, and then extended to other manufacturing settings, including conventional (or “subtractive”) manufacturing and to predict the end of life performance of parts per the aging and lifetimes programs. The result is a transformational capability: inspection times have been reduced by a factor of 120,000 without loss of accuracy and while simultaneously improving traceability and confidence in part quality. This framework not only streamlines certification for critical applications, but also positions the national security enterprise to respond more flexibly to emerging challenges, supporting agile manufacturing and digital engineering practices across a broad range of mission-relevant domains.

42 ENGINEERING↗