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NASA NTRS2001

Evidence for the Widespread Presence of Liquid-Phase Particles During the 1999-2000 Arctic Winter

In-situ Multi-Angle Spectrometer Probe (MASP) particle measurements have been analyzed to determine the typical behaviour of sulphate particles during the SOLVE campaign. The analysis has focussed on variations in the total particle concentration measured by MASP, which is a diagnostic that is primarily sensitive to the growth of small particles (those which are initially smaller than 0.2 micrometers in radius). At all levels of the stratosphere, the total MASP concentration varies continuously with temperature. This behaviour is well-reproduced by assuming that the sulphate aerosols are liquid ternary solutions, but cannot be reproduced if the aerosol is assumed to be frozen. This liquid-like behaviour is apparent for all measurements made during SOLVE, both inside and outside the vortex, and even at the coldest temperatures sampled during the campaign. The only anomalous measurements were made during the flight of January 14th, 2001; however, this midlatitude flight is very unlikely to contain SAT particles based on the recent warm temperatures experienced by the air. At the levels with the coldest measured temperatures, at least 90% of the particles grow as liquids. Therefore, the freezing that occurred during the 1999-2000 Arctic winter was selective, causing most of the particles to remain liquid even in the presence of a small number of frozen particles.

Drdla, K↗

NASA NTRS2002

Dynamics of Planetary Atmospheres

The PI had nineteen papers either published or in press in 1999 through early 2002. Ten of these (Thomas et al. 1999, Geisler et al. 1999, Vasavada et al. 1999, Little et al. t999, Gierasch et al. 2000, Ingersoll et al. 2000, Thomas et al. 2000, Dyudina et al. 2001, Chang et al. 2001, Wang and Ingersoll 2002) were largely supported by the Mars Global Surveyor project and the Galileo project. The other nine papers were largely supported under this grant, and are listed in boldface below. Six of the nine are research papers. Their titles and abstracts are reproduced below. The New Solar System chapter and the Meteorology at the Millennium chapter are review articles, and the World Book Encyclopedia chapter is a popular article. Their title pages and abstracts are also reproduced below.

Ingersoll, Andrew P.↗

NASA NTRS2002

Impacts of PSC Microphysics on Modelled Ozone Loss

Winter-long simulations of the 1999-2000 winter using a coupled microphysical/chemical model have been carried out to explore how PSC microphysics affects ozone loss. Although many models assures that water ice formation leads to denitrification, these simulations show that observed characteristics of the 1999-2000 winter can not be reproduced by such a denitrification mechanism. Instead, denitrification observations are best reproduced by a small number of particles freezing at temperatures near the nitric acid trihydration condensation point. Implications of such a mechanism for assessments of future ozone loss will be discussed. The simulations have also revealed that ozone loss during the 1999-2000 winter was sensitive to chlorine reactivation that occurred during February. Uncertainties in PSC microphysics and heterogeneous reaction rates both influence the modelled chlorine reactivation. For the 1999-2000 winter, these uncertainties have a larger effect on model ozone loss than denitrification. The role of denitrification would have increased if the Arctic vortex had persisted for a longer period.

Drdla, K.↗

NASA NTRS2002

Simulation of High-Latitude Hydrological Processes in the Torne-Kalix Basin: PILPS Phase 2(e): Equivalent Model Representation and Sensitivity Experiments - 3

The Project for Intercomparison of Land Surface Parameterization Schemes (PILPS) Phase 2(e) showed that in cold regions the annual runoff production in Land Surface Schemes (LSSs) is closely related to the maximum snow accumulation, which in turn is controlled in large part by winter sublimation. To help further explain the relationship between snow cover, turbulent exchanges and runoff production, a simple equivalent model-(SEM) was devised to reproduce the seasonal and annual fluxes simulated by 13 LSSs that participated in PILPS Phase 2(e). The design of the SEM relates the annual partitioning of precipitation and energy in the LSSs to three primary parameters: snow albedo, effective aerodynamic resistance and evaporation efficiency. Isolation of each of the parameters showed that the annual runoff production was most sensitive to the aerodynamic resistance. The SEM was somewhat successful in reproducing the observed LSS response to a decrease in shortwave radiation and changes in wind speed forcings. SEM parameters derived from the reduced shortwave forcings suggested that increased winter stability suppressed turbulent heat fluxes over snow. Because winter sensible heat fluxes were largely negative, reductions in winter shortwave radiation imply an increase in annual average sensible heat.

Bowling, Laura C.↗

NASA NTRS2002

Tactical Defenses Against Systematic Variation in Wind Tunnel Testing

This paper examines the role of unexplained systematic variation on the reproducibility of wind tunnel test results. Sample means and variances estimated in the presence of systematic variations are shown to be susceptible to bias errors that are generally non-reproducible functions of those variations. Unless certain precautions are taken to defend against the effects of systematic variation, it is shown that experimental results can be difficult to duplicate and of dubious value for predicting system response with the highest precision or accuracy that could otherwise be achieved. Results are reported from an experiment designed to estimate how frequently systematic variations are in play in a representative wind tunnel experiment. These results suggest that significant systematic variation occurs frequently enough to cast doubts on the common assumption that sample observations can be reliably assumed to be independent. The consequences of ignoring correlation among observations induced by systematic variation are considered in some detail. Experimental tactics are described that defend against systematic variation. The effectiveness of these tactics is illustrated through computational experiments and real wind tunnel experimental results. Some tutorial information describes how to analyze experimental results that have been obtained using such quality assurance tactics.

DeLoach, Richard↗

NASA NTRS2003

Deviation of Long-Period Tides from Equilibrium: Kinematics and Geostrophy

New empirical estimates of the long-period fortnightly (Mf) tide obtained from TOPEX/Poseidon (T/P) altimeter data confirm significant basin-scale deviations from equilibrium. Elevations in the low-latitude Pacific have reduced amplitude and lag those in the Atlantic by 30 deg or more. These interbasin amplitude and phase variations are robust features that are reproduced by numerical solutions of the shallow-water equations, even for a constant-depth ocean with schematic interconnected rectangular basins. A simplified analytical model for cooscillating connected basins also reproduces the principal features observed in the empirical solutions. This simple model is largely kinematic. Zonally averaged elevations within a simple closed basin would be nearly in equilibrium with the gravitational potential, except for a constant offset required to conserve mass. With connected basins these offsets are mostly eliminated by interbasin mass flux. Because of rotation, this flux occurs mostly in a narrow boundary layer across the mouth and at the western edge of each basin, and geostrophic balance in this zone supports small residual offsets (and phase shifts) between basins. The simple model predicts that this effect should decrease roughly linearly with frequency, a result that is confirmed by numerical modeling and empirical T/P estimates of the monthly (Mm) tidal constituent. This model also explains some aspects of the anomalous nonisostatic response of the ocean to atmospheric pressure forcing at periods of around 5 days.

Egbert, Gary D.↗

NASA NTRS2002

Challenging Cosmic Ray Propagation with Antiprotons: Evidence for a "Fresh" Nuclei Component?

Recent measurements of the cosmic ray (CR) antiproton flux have been shown to challenge existing CR propagation models. It was shown that the reacceleration models designed to match secondary to primary nuclei ratio (e.g., Boron/Carbon) produce too few antiprotons, while the traditional non-reacceleration models can reproduce the antiproton flux but fall short of explaining the low-energy decrease in the secondary to primary nuclei ratio. Matching both the secondary to primary nuclei ratio and antiproton flux requires artificial breaks in the diffusion coefficient and the primary injection spectrum suggesting the need for other approaches. In the present paper we discuss one possibility to overcome these difficulties. Using the measured antiproton flux to fix the diffusion coefficient, we show that the spectra of primary nuclei as measured in the heliosphere may contain a fresh local unprocessed component at low energies, thus decreasing the measured secondary to primary nuclei ratio. A model reproducing antiprotons, B/C ratio, and abundances up to Ni is presented.

Moskalenko, Igor V.↗

NASA NTRS2003

Modelling CLPX IOP3 Radiometric Data by Means of the Dense Media Theory: Preliminary Results for the LSOS Test Site

The capabilities of the Dense Media Radiative Transfer model using the Quasi Crystalline Approximation with Coherent Potential (QCA-CP) to reproduce measured radiometric data were tested using the University of Tokyo Ground Based Microwave Radiometer (GBMR-7) during the third Intensive Observation Period (IOP3) of the NASA Cold-land Processes Field Experiment (CLPX). The data were collected at the Local-Scale Observation Site (LSOS), a 0.8-ha study site consisting of two open meadows separated by trees. Intensive measurements were also made of snow depth and temperature, density, and grain size profiles. A DMRT model is needed to describe radiative transfer in a medium such as snow because the assumption of independent scattering used in classical radiative transfer theory (CRT) is not valid. Validation of the DMRT approach requires a relationship between measured snow grain size and the DMRT approximation of snow grain radius as spherical particles with a mean radius of the log-normal particle-size distribution. This relationship is very important for a better understanding of snow modelling and for practical applications. DMRT simulations were compared with observations of microwave brightnesses at 18.7, 36.5 and 89-GHz (V and H polarizations) collected on February-1 9-25, 2003. Observation angles ranged from 30\deg to 70\deg. Model inputs included measured snow parameters except mean grain size. The average snow temperature, fractional volume and depth were held constant, together with the ice and soil permittivities. The minimum and maximum measured mean grain sizes were used to test the capabilities of the DMRT to reproduce the brightnesses as upper and lower limits. The sensitivity to the largest and smallest measured grain size in the three classes of minimum, medium and maximum observed grain sizes was also investigated. DMRT particle sizes yielding a best-fit to the experimental data for each date were computed. Results show that the measured brightnesses fall within the range of simulated brightnesses using the smallest and largest measured grain size values. The DMRT best-fit radii are comparable to the average radii for the medium observed grain sizes.

Tedesco, Marco↗

NASA NTRS2003

An Earth-Based Equivalent Low Stretch Apparatus to Assess Material Flammability for Microgravity and Extraterrestrial Fire-Safety Applications

The objective of this project is to modify the standard oxygen consumption (cone) calorimeter (described in ASTM E 1354 and NASA STD 6001 Test 2) to provide a reproducible bench-scale test environment that simulates the buoyant or ventilation flow that would be generated by or around a burning surface in a spacecraft or extraterrestrial gravity level. This apparatus will allow us to conduct normal gravity experiments that accurately and quantitatively evaluate a material's flammability characteristics in the real-use environment of spacecraft or extra-terrestrial gravitational acceleration. The Equivalent Low Stretch Apparatus (ELSA) uses an inverted cone geometry with the sample burning in a ceiling fire configuration that provides a reproducible bench-scale test environment that simulates the buoyant or ventilation flow that would be generated by a flame in a spacecraft or extraterrestrial gravity level. Prototype unit testing results are presented in this paper. Ignition delay times and regression rates for PMMA are presented over a range of radiant heat flux levels and equivalent stretch rates which demonstrate the ability of ELSA to simulate key features of microgravity and extraterrestrial fire behavior.

Olson, S. L.↗

NASA NTRS2001

LabHEART: an interactive computer model of rabbit ventricular myocyte ion channels and Ca transport

An interactive computer program, LabHEART, was developed to simulate the action potential (AP), ionic currents, and Ca handling mechanisms in a rabbit ventricular myocyte. User-oriented, its design allows switching between voltage and current clamp and easy on-line manipulation of key parameters to change the original formulation. The model reproduces normal rabbit ventricular myocyte currents, Ca transients, and APs. We also changed parameters to simulate data from heart failure (HF) myocytes, including reduced transient outward (I(to)) and inward rectifying K currents (I(K1)), enhanced Na/Ca exchange expression, and reduced sarcoplasmic reticulum Ca-ATPase function, but unaltered Ca current density. These changes caused reduced Ca transient amplitude and increased AP duration (especially at lower frequency) as observed experimentally. The model shows that the increased Na/Ca exchange current (I(NaCa)) in HF lowers the intracellular [Ca] threshold for a triggered AP from 800 to 540 nM. Similarly, the decrease in I(K1) reduces the threshold to 600 nM. Changes in I(to) have no effect. Combining enhanced Na/Ca exchange with reduced I(K1) (as in HF) lowers the threshold to trigger an AP to 380 nM. These changes reproduce experimental results in HF, where the contributions of different factors are not readily distinguishable. We conclude that the triggered APs that contribute to nonreentrant ventricular tachycardia in HF are due approximately equally (and nearly additively) to alterations in I(NaCa) and I(K1). A free copy of this software can be obtained at http://www.meddean.luc.edu/lumen/DeptWebs/physio/bers.html.

NASA Discipline Cardiopulmonary↗

NASA NTRS1985

Precision and sensitivity of the measurement of 15N enrichment in D-alanine from bacterial cell walls using positive/negative ion mass spectrometry

Sensitive detection of cellular components from specific groups of microbes can be utilized as 'signatures' in the examination of microbial consortia from soils, sediments or biofilms. Utilizing capillary gas chromatography/mass spectrometry and stereospecific derivatizing agents, D-alanine, a component localized in the prokaryotic (bacterial) cell wall, can be detected reproducibly. Enrichments of D-[15N]alanine determined in E. coli grown with [15N]ammonia can be determined with precision at 1.0 atom%. Chemical ionization with methane gas and the detection of negative ions (M - HF)- and (M - F or M + H - HF)- formed from the heptafluorobutyryl D-2 butanol ester of D-alanine allowed as little as 8 pg (90 fmol) to be detected reproducibly. This method can be utilized to define the metabolic activity in terms of 15N incorporation at the level of 10(3)-10(4) cells, as a function of the 15N-14N ratio.

Non-NASA Center↗

NASA NTRS2004

Validation of an Impedance Education Method in Flow

This paper reports results of a research effort to validate a method for educing the normal incidence impedance of a locally reacting liner, located in a grazing incidence, nonprogressive acoustic wave environment with flow. The results presented in this paper test the ability of the method to reproduce the measured normal incidence impedance of a solid steel plate and two soft test liners in a uniform flow. The test liners are known to be locally react- ing and exhibit no measurable amplitude-dependent impedance nonlinearities or flow effects. Baseline impedance spectra for these liners were therefore established from measurements in a conventional normal incidence impedance tube. A key feature of the method is the expansion of the unknown impedance function as a piecewise continuous polynomial with undetermined coefficients. Stewart's adaptation of the Davidon-Fletcher-Powell optimization algorithm is used to educe the normal incidence impedance at each Mach number by optimizing an objective function. The method is shown to reproduce the measured normal incidence impedance spectrum for each of the test liners, thus validating its usefulness for determining the normal incidence impedance of test liners for a broad range of source frequencies and flow Mach numbers. Nomenclature

Watson, Willie R.↗

NASA NTRS2001

Global Modeling of Tropospheric Chemistry with Assimilated Meteorology: Model Description and Evaluation

We present a first description and evaluation of GEOS-CHEM, a global three-dimensional (3-D) model of tropospheric chemistry driven by assimilated meteorological observations from the Goddard Earth Observing System (GEOS) of the NASA Data Assimilation Office (DAO). The model is applied to a 1-year simulation of tropospheric ozone-NOx-hydrocarbon chemistry for 1994, and is evaluated with observations both for 1994 and for other years. It reproduces usually to within 10 ppb the concentrations of ozone observed from the worldwide ozonesonde data network. It simulates correctly the seasonal phases and amplitudes of ozone concentrations for different regions and altitudes, but tends to underestimate the seasonal amplitude at northern midlatitudes. Observed concentrations of NO and peroxyacetylnitrate (PAN) observed in aircraft campaigns are generally reproduced to within a factor of 2 and often much better. Concentrations of HNO3 in the remote troposphere are overestimated typically by a factor of 2-3, a common problem in global models that may reflect a combination of insufficient precipitation scavenging and gas-aerosol partitioning not resolved by the model. The model yields an atmospheric lifetime of methylchloroform (proxy for global OH) of 5.1 years, as compared to a best estimate from observations of 5.5 plus or minus 0.8 years, and simulates H2O2 concentrations observed from aircraft with significant regional disagreements but no global bias. The OH concentrations are approximately 20% higher than in our previous global 3-D model which included an UV-absorbing aerosol. Concentrations of CO tend to be underestimated by the model, often by 10-30 ppb, which could reflect a combination of excessive OH (a 20% decrease in model OH could be accommodated by the methylchloroform constraint) and an underestimate of CO sources (particularly biogenic). The model underestimates observed acetone concentrations over the South Pacific in fall by a factor of 3; a missing source from the ocean may be implicated.

Bey, Isabelle↗

NASA NTRS2001

Constraints Pb-210 and Be-7 on Wet Deposition and Transport in a Global Three-Dimensional Chemical Tracer Model Driven by Assimilated Meteorological Fields

The atmospheric distributions of the aerosol tracers Pb-210 and Be-7 are simulated with a global three-dimensional model driven by assimilated meteorological observations for 1991-1996 from the NASA Goddard Earth Observing System (GEOSl). The combination of terrigenic Pb-210 and cosmogenic Be-7 provides a sensitive test of wet deposition and vertical transport in the model. Our simulation of moist transport and removal includes scavenging in wet convective updrafts (40% scavenging efficiency per kilometer of updraft), midlevel entrainment and detrainment, first-order rainout and washout from both convective anvils and large-scale precipitation, and cirrus precipitation. Observations from surface sites in specific years are compared to model results for the corresponding meteorological years, and observations from aircraft missions over the Pacific are compared to model results for the days of the flights. Initial simulation of Be-7 showed that cross-tropopause transport in the GEOSl meteorological fields is too fast by a factor of 3-4. We adjusted the stratospheric Be-7 source to correct the tropospheric simulation. Including this correction, we find that the model gives a good simulation of observed Pb-210 and Be-7 concentrations and deposition fluxes at surface sites worldwide, with no significant global bias and with significant success in reproducing the observed latitudinal and seasonal distributions. We achieve several improvements over previous models; in particular, we reproduce the observed Be-7 minimum in the tropics and show that its simulation is sensitive to rainout from convective anvils. Comparisons with aircraft observations up to 12-km altitude suggest that cirrus precipitation could be important for explaining the low concentrations in the middle and upper troposphere.

Liu, Hong-Yu↗

NASA NTRS1994

Issues on Reproducibility/Reliability of Magnetic NDE Methods

One of the critical elements related to the practicality of any NDE technique is its reproducibility under nominally the same inspection conditions. The results of certain test methodologies, however, are not always repeatable and understanding the origin of the irreproducibility is often as critical as obtaining reproducible results. One example is the characterization of residual stress in structural ferromagnets using the magnetoacoustic (MAC) method. Although it has not been widely publicized, the test results of this method are known to be time-dependent. Two distinct types of time dependencies have been observed during testing. The first type has a clearly definable relaxation time, while no such trend has been observed for the second. The purpose of the present study is to systematically investigate the time dependence of the second type, to find out the range and, if possible, the origin of the variation in the test results. For this, MAC curves were obtained under various stress levels and the tests were repeated over time. Particular attention was given to whether noise in the measuring device or a change in the laboratory environment could have been a contributing factor. The steel samples used for the study were cut from C- and U-class railroad wheels. The MAC behavior of these samples was reported previously. Each steel sample was first machined to be a cylindrical rod of 3.175 cm (1.25 in) in diameter and 26.67 cm (10.5 in) in length. The center portion of the samples were further machined to form a pair of flat and parallel surfaces for the launch and reflection of the ultrasonic pulses. Data acquisition involved two major elements; magnetic and acoustic measurements. Throughout the experiment the net magnetic induction, B, was measured by integrating the induction pickup coil output using an integrating fluxmeter. The acoustic measurements employed the phase-locked technique which will be described in the following.

Namkung, M.↗

NASA NTRS2000

Vascular mechanics of the coronary artery

This paper describes our research into the vascular mechanics of the coronary artery and plaque. The three sections describe the determination of arterial mechanical properties using intravascular ultrasound (IVUS), a constitutive relation for the arterial wall, and finite element method (FEM) models of the arterial wall and atheroma. METHODS: Inflation testing of porcine left anterior descending coronary arteries was conducted. The changes in the vessel geometry were monitored using IVUS, and intracoronary pressure was recorded using a pressure transducer. The creep and quasistatic stress/strain responses were determined. A Standard Linear Solid (SLS) was modified to reproduce the non-linear elastic behavior of the arterial wall. This Standard Non-linear Solid (SNS) was implemented into an axisymetric thick-walled cylinder numerical model. Finite element analysis models were created for five age groups and four levels of stenosis using the Pathobiological Determinants of Atherosclerosis Youth (PDAY) database. RESULTS: The arteries exhibited non-linear elastic behavior. The total tissue creep strain was epsilon creep = 0.082 +/- 0.018 mm/mm. The numerical model could reproduce both the non-linearity of the porcine data and time dependent behavior of the arterial wall found in the literature with a correlation coefficient of 0.985. Increasing age had a strong positive correlation with the shoulder stress level, (r = 0.95). The 30% stenosis had the highest shoulder stress due to the combination of a fully formed lipid pool and a thin cap. CONCLUSIONS: Studying the solid mechanics of the arterial wall and the atheroma provide important insights into the mechanisms involved in plaque rupture.

NASA Program Biomedical Research and Countermeasur↗

NASA NTRS2004

Sensitivity of a Cloud-Resolving Model to the Bulk and Explicit Bin Microphysical Schemes

A cloud-resolving model is used to study sensitivities of two different microphysical schemes, one is the traditional bulk type, and the other is an explicit bin scheme, in simulating a mid-latitude squall line case (PRE-STORM, June 10-1 1,1985). Simulations using different microphysical schemes are compared with each other and also with the observations. Both the bulk and bin models reproduce the general features during the developing and mature stage of the system. Furthermore, the observations and the well-proven bulk scheme simulation serve as validations for the newly incorporated bin scheme. However, it is also shown that the bulk and bin simulations have distinct differences, most notably in the stratiform region of the squall line system. Weak convective cells exist in the stratiform region in the bulk simulation, but not in the bin simulation. These weak convective cells in the stratiform region simulated in the bulk scheme model are remnants of the stronger convections previously at the leading edge of the system, sustained by horizontal vorticity generated by its own cool pool near the surface. The bin simulation, on the other hand, has a horizontally homogeneous stratiform cloud structure, which agrees better with the observations. Examinations of the downdraft core strength, the potential temperature perturbation, and the evaporative cooling rate show that the differences between the bulk and bin models are due mainly to the stronger low-level evaporative cooling in the convective zone simulated in the bulk microphysical scheme, which is unrealistic because of the assumptions made in raindrop size distribution. Further sensitivity tests that reduce the evaporation rate in bulk scheme artificially produce more upright convective core and less weak cores in stratiform region. However, they produce weaker upper level outflow and consequently less stratiform rain area. The addition of a more realistic raindrop breakup scheme in the bin scheme results more realistic radar reflectivity and stronger surface rainfall. Despite the increase of the rain evaporation and strengthening of the near surface cool pool, bin scheme with rain breakup shows homogeneous stratiform rain. These sensitivity tests prove the robustness of the bin microphysical scheme and the difficulty of tuning the limited parameters in the bulk microphysical scheme to realistically reproduce detail structures in a mid-latitude squall line case study.

Li, Xiao-Wen↗

NASA NTRS2005

Deposition and Characterization of Thin Films on Metallic Substrates

A CVD method was successfully developed to produce conversion coatings on aluminum alloys surfaces with reproducible results with a variety of precursors. A well defined protocol to prepare the precursor solutions formulated in a previous research was extended to other additives. It was demonstrated that solutions prepared following such a protocol could be used to systematically generate protective coatings onto aluminum surfaces. Experiments with a variety of formulations revealed that a refined deposition protocol yields reproducible conversion coatings of controlled composition. A preliminary correlation between solution formulations and successful precursors was derived. Coatings were tested for adhesion properties enhancement for commercial paints. A standard testing method was followed and clear trends were identified. Only one precursors was tested systematically. Anticipated work on other precursors should allow a better characterization of the effect of intermetallics on the production of conversion/protective coatings on metals and ceramics. The significance of this work was the practical demonstration that chemical vapor deposition (CVD) techniques can be used to systematically generate protective/conversion coating on non-ferrous surfaces. In order to become an effective approach to replace chromate-based pre- treatment processes, namely in the aerospace or automobile industry, the process parameters must be defined more precisely. Moreover, the feasibility of scale-up designs necessitates a more comprehensive characterization of the fluid flow, transport phenomena, and chemical kinetics interacting in the process. Kinetic characterization showed a significantly different effect of magnesium-based precursors when compared to iron-based precursors. Future work will concentrate on refining the process through computer simulations and further experimental studies on the effect of other transition metals to induce deposition of conversion/protective films on aluminum and other metallic substrates.

Gatica, Jorge E.↗