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At least 1,711 records · Page 95

A Review of the American Recovery and Reinvestment Act Smart Grid Projects and Their Implications for China

The Chinese government has paid growing attention to renewable energy development and has set ambitious goals for carbon dioxide (CO2) emissions reduction and energy savings. Smart grid (SG) technologies have been regarded as emerging ways to integrate renewable energy and to help achieve these climate and energy goals. This report first reviews completed SG demonstrations under the U.S. American Recovery and Reinvestment Act (ARRA); especially two key programs: the SG Investment Grant (SGIG) and the SG Demonstration Project (SGDP). Under the SGIG, the larger of the two programs, over $3.4 billion was used to help industry deploy existing advanced SG technologies and tools to improve grid performance and reduce costs. Including industry investment, a total of $8 billion was spent on 99 cost-shared projects, which involved more than 200 participating electric utilities and other organizations. These projects aimed to modernize the electric grid, strengthen cyber security, improve interoperability, and collect comprehensive data on SG operations and benefits.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

The FFAG return loop for the CBETA Energy Recovery Linac

The CBETA energy recovery linac uses a single xed eld alternating gradient (FFAG) beam line to return the beam for electron beams with four energies, ranging from 42 MeV to 150 MeV. To keep the beam line compact, the ends of the return line have a small radius of curvature, but the central part of the return line is straight. These are connected by transition lines that adiabatically change from one to the other. We rst describe the design or the arc cell. We then describe how a straight cell is created to be a good match to this arc cell. We then describe the design of the transition line between them. The design process makes use of eld maps for the desired magnets. Because we switch magnet types as we move from the arc, through the transition, and into the straight, there are discrete jumps in the elds that degrade the adiabaticity of the transition, and we describe corrections to manage that.

43 PARTICLE ACCELERATORS↗

Beam dynamics validation of the Halbach Technology FFAG Cell for Cornell-BNL Energy Recovery Linac

The Cornell-BNL Electron Test Accelerator (CBETA), a 150 MeV energy recovery linac (ERL) now in construction at Cornell, employs a fixedfield alternating gradient (FFAG) optics return loop: a single beam line comprised of quadrupole doublet cells, which accepts four recirculated energies. CBETA FFAG cell uses Halbach permanent magnet technology, its design studies have covered an extended period of time supported all the way by extensive particle dynamics simulations using computed 3-D field map models. This approach, which supported the choice of Halbach technology for CBETA FFAG ERL in 2016, is discussed and illustrated here based on the final stage in these beam dynamics studies, namely the validation of a ultimate, optimized design of the cell.

43 PARTICLE ACCELERATORS↗

Low-Energy Water Recovery from Subsurface Brines

A novel non-aqueous phase solvent (NAS) desalination process was proposed and developed in this research project. The NAS desalination process uses less energy than thermal processes, doesn’t require any additional chemicals for precipitation, and can be utilized to treat high TDS brine. In this project, our experimental work determined that water solubility changes and selective absorption are the key characteristics of NAS technology for successful desalination. Three NAS desalination mechanisms were investigated: (1) CO 2 switchable, (2) high-temp absorption to low-temp desorption (thermally switchable), and (3) low-temp absorption to high-temp desorption (thermally switchable). Among these mechanisms, thermally switchable (low-temp absorption to high-temp desorption) showed the highest water recovery and relatively high salt rejection. A test procedure for semi-continuous, bench scale NAS desalination process was also developed and used to assess performance under a range of conditions.

20 FOSSIL-FUELED POWER PLANTS↗

Final Technical Report: Plasma Arc Gasification Based Rare Earth Element Recovery from Coal Fly Ash

Southern Research, as the primary awardee, with sub-awardees ArcSec Technologies, LLC (ArcSec) and Reaction Engineering International (REI) have investigated a plasma arc based thermal process intended to concentrate rare earth elements (REE) from coal fly ash. Successful demonstration of the technology would contribute to the effort for realizing a competitive, domestic REE value chain thereby reducing U.S. dependence on foreign supply, maintaining national security interests, and creating opportunities for economic growth. The originally proposed concept included two technology options – 1) a smelting process and 2) a smelting plus vaporization and condensation process. For both options, coal fly ash would be smelted in a plasma arc heated furnace under reducing conditions to separate ash into molten slag and reduced metal (primarily iron) phases. During smelting, it was expected that the REE would also be reduced to metals and partition mostly to the iron phase. During the first year of work, sample coal ash feedstocks were acquired and characterized, feasibility of the smelting process was evaluated in bench-scale experiments, and the vaporization/condensation process was investigated through equilibrium and CFD modeling studies. From the feedstock characterization, REE content for the coal ash samples obtained was measured to be in the range of 302 – 1219 ppm with average at 537 ppm. Though it was successfully demonstrated that ash could be separated into slag and metal phases, the bench-scale experiments were only marginally successful at collecting REE in the metal phase. Producing REE concentrates near the DOE goal of 2%, however, has not been achieved. From the modeling studies, the vaporization/condensation process was predicted to be effective for separating individual REE and producing enriched metal fractions with total REE content higher than 2%, provided the smelting process performed as intended. Supplemental smelting experiments and thermodynamic modeling studies, conducted during the second year of work, indicated a number of technical modifications that could lead to producing higher REE concentrates from coal ash. The strategy shifted to reducing as much of the ash oxides to metals as possible, leaving the REE more concentrated in the remaining slag. Results from later experiments based on the modified approach showed improvements in REE recovery and concentration levels in smelted products. SEM-EDS analyses on product specimens showed agglomerations of reduced metal REE crystals at much larger length-scales as compared to REE content in raw ash.

01 COAL, LIGNITE, AND PEAT↗

Functionalized Porous Organic Polymers as Uranium Nano-Traps for Efficient Recovery of Uranium from Seawater

The long-term use of nuclear power for energy applications relies on the secure and economical supply of nuclear fuel. Among various natural sources of uranium for use in nuclear reactors, seawater is highly appealing given that the oceans contain about 4.5 billion tons of dissolved uranium, almost 1000 times that estimated for mineral reserves. Nonetheless, the concentration of uranium in seawater is extremely low (3-3.3 mg L -1 or 3-3.3 ppb); this, coupled with the presence of a relatively high concentration of other metal ions, makes uranium recovery from seawater a challenge that requires the development of efficient and effective separation processes. Various adsorbent technologies based upon synthetic organic polymers, biopolymers, inorganic materials, mesoporous silica materials, porous carbon-based adsorbents, and ionic liquids have been widely developed for the extraction of uranium from seawater. However, these benchmark sorbent materials suffer from a number of drawbacks such as low adsorption capacity (typically 0.1~3.2 mg-U g -1 adsorbent), poor selectivity, and slow kinetics. Given the extreme complexity and vast volume of seawater, as well as the very low concentration of uranium present, to attain this ambitious task demands the design of adsorbents with high affinity and fast kinetics. The main objective of this project is to develop functional porous organic polymers (POPs) as a new type of adsorbent for mining uranium from seawater. This class of porous materials has quickly moved to the forefront of materials research due to their high internal surface areas, exceptional water/chemical stability, facile chemical tunability, and extraordinary capability to selectively adsorb large quantities of guest species The potential to deploy POPs in uranium extraction is related to the ease with which their internal surfaces can be decorated with high densities of strong binding sites. Beyond introducing postsynthetic modification, the specific functionalities also can be used as building units to be incorporated into porous frameworks. Our approach to fulfill this task involves the custom-design of POP-based uranium “nano-traps” via a “crystal engineering” guided design followed by stepwise post-synthetic modification. Furthermore, to increase the density of chelating groups and to enhance their affinity towards uranyl ions, judiciously designed chelating systems were constructed into porous organic polymers. Moreover, to improve the accessibility of the chelating groups and thereby the utilization efficiency, we assembled the chelating groups into highly crystalline materials where they are aligned in periodic arrays on the open channels.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Comprehensive tracking study for the H-dipoles and common magnets in the splitter sections of the Cornell/Brookhaven Energy-Recovery-Linac Test Accelerator

The Cornell-Brookhaven Energy-Recovery-Linac Test Accelerator will have two splitter sections responsible for and guiding beams of 42, 78, 114, and 150 MeV energies between the Fixed-Field Alternating Gradient return loop and the Main Linac Cryomodule [6], correcting optics, and providing path length adjustments. Modeling of all 36 H-dipole magnets under contract with Elytt Energy has been completed. Four common dipoles, two of which are needed for next year’s Fractional Arc Test, will be added to the order with Elytt. The design of these magnets is underway. This report describes the findings of the tracking studies of the 36 H-dipoles and gives the status of the common dipoles.

43 PARTICLE ACCELERATORS↗

Flue Gas Water Vapor Latent Heat Recovery for Pressurized Oxy-Combustion

This final report presents the results of a three-year technology development project carried out by a team of participants sponsored by the Department of Energy (DOE). This is addressing the FOA Area of Interest 2: Enabling Combustion Technology. Specifically, the technology targets for flue gas water vapor latent heat recovery from pressurized oxy-coal combustion power plants. A pilot scale Transport Membrane Condenser (TMC) system has been developed, fabricated, integrated, and performance-tested in a pressurized oxy-coal pilot-scale combustion system to prove its effectiveness. We have evaluated its performance and analyzed the results for application to commercial-scale power plants. We expect the same technology to be also applicable to pressurized chemical looping combustion (CLC) flue gas, which has similar conditions.

01 COAL, LIGNITE, AND PEAT↗

Subject Matter Expert Workshop for the Use of Municipal and Commercial Equipment for Radiological Response and Recovery: National Urban Security Technology Laboratory Workshop Summary Report

This report documents equipment and methods to aid in a wide-area radiological or nuclear response and recovery effort in an urban environment. This report summarizes a workshop held in New York City. The objective of this workshop was to incorporate lessons learned from a prior workshop, close the gaps on some areas that were not discussed in the prior workshop, and include additional subject matter experts from critical infrastructure operations, such as tunnels and bridges, the Port Authority, and mass transit. Various missions were postulated in a hypothetical emergency scenario under five broad support goal categories. Based on the findings and input from a series of such workshops and meetings, we plan to develop “best practices” for use of equipment responding to and recovering from a wide-area radiological incident.

61 RADIATION PROTECTION AND DOSIMETRY↗

Design and Characterization of High Thermal Conductivity Pipes from Roll-to- Roll Processed Hybrid Copper-Polymer Strips for Waste Heat Recovery

Metal based heat exchangers targeting low temperature (<150°C) waste heat recovery (WHR) face high maintenance and material costs [1] that result in long payback periods (>1 year). Low-cost polymer pipes suffer from poor thermal conductivity (~0.2 W/m.K), and thus a low overall heat transfer coefficient. Previous reports demonstrated thermal conductivity enhancement in polymers through systematic molecular alignment [2, 3, 4], or by metal micro-particle inclusions [5]. However, these approaches suffer from scalability issues for WHR heat exchangers in terms of cost [1, 3], and thermomechanical considerations [6, 7]. In this work, we propose hybrid metal-polymer strips that are strategically designed to enhance thermal conductivity by cladding copper around polymer strips. The polymer strips with copper-clad edges are wound helically to form the pipes for a heat exchanger. Through numerical simulations, we optimize the copper-polymer strip layouts to achieve high wall thermal conductivity (k > 1 W/m.K) and also have low volume fraction of copper (<70%) for the composite pipes. In copper-polymer composite heat exchangers, the bottlenecks for heat transfer are the thermal interfacial resistances of copper-copper and copper-polymer joints. We experimentally measured interfacial resistances to be ~1x10 -5 K.m 2 /W and ~4x10 -5 K.m 2 /W for copper-copper and copper-polymer joints, respectively. Using the measured interfacial resistances, we further optimized the design of the hybrid pipes to find high thermal conductivity (> 1 W/m.K) designs. We predict up to ~20 % enhancement in overall heat transfer relative to an all polymer (k = 0.2 W/m.K) heat exchanger system. Using a cohesive zone modelling (CZM) for predicting delamination at the weld joints, we find that our hybrid pipes can have operating internal pressures > 200 psi. The optimized designs of hybrid metal-polymer pipes provide a scalable and cost- effective means for harvesting waste heat from low temperature sources. Thekdi, A., and Nimbalkar, S. Oak Ridge National Lab (2014). Shen, Sheng, et al. Nature nanotechnology 5.4 (2010). Xu, Yanfei, et al. Science advances 4.3 (2018). Smith et al. ACS nano, 9(2), (2015). Sofian, N.M., et al., Journal of Thermoplastic Composite Materials (2001). Aymonier et al. Chemistry of Materials, 15(25), (2003). Tavman, I.H., Journal of Applied Polymer Science, 62(12), (1996).

C Rajagopal, Manjunath↗

CO2 Recovery

Operation of an amine-based CO2 recovery system. To access the model referenced in the report, please visit https://www.netl.doe.gov/energy-analysis/details?id=1B4476B5-320E-400E-8A94-B332CE71454A

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Enhanced Oil Recovery Operations

This unit process models the injection of CO2 and water to produce crude and light hydrocarbons via enhanced oil recovery. To access the model referenced in the report, please visit https://www.netl.doe.gov/energy-analysis/details?id=039E9317-8803-407B-8563-1A31D3D5C33A

02 PETROLEUM↗

Natural Gas CO2 Recovery

Operation of an amine-based CO2 recovery system for production natural gas. To access the model referenced in the report, please visit https://www.netl.doe.gov/energy-analysis/details?id=F70C58A6-97B3-40C5-9405-E33C7C7F3C1E

03 NATURAL GAS↗

Post Membrane CO2 Recovery

Operation of an amine-based CO2 recovery system for post-membrane acid gas removal. To access the model referenced in the report, please visit https://www.netl.doe.gov/energy-analysis/details?id=1572C8E5-9184-4BE3-8437-05BDB24A5188

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Steam injection for oil recovery

Steam injection by a once-through steam generator (OTSG) for thermally enhanced oil recovery. To access the model referenced in the report, please visit https://www.netl.doe.gov/energy-analysis/details?id=2FD3B525-400F-4878-A5C5-218364AF5A3F

02 PETROLEUM↗

Post-Closure Report for Closed Resource Conservation and Recovery Act Corrective Action Units, Nevada National Security Site, Nevada: For Calendar Year 2018 (Revision 0)

This report serves as the combined annual report for post-closure activities for the following closed corrective action units (CAUs): CAU 90, Area 2 Bitcutter Containment; CAU 91, Area 3 U-3fi Injection Well; CAU 92, Area 6 Decon Pond Facility; CAU 110, Area 3 WMD U-3ax/bl Crater; CAU 111, Area 5 WMD Retired Mixed Waste Pits; and CAU 112, Area 23 Hazardous Waste Trenches. The locations of the sites are shown in Figure ES-1. This report covers calender year 2018. The post-closure requirements for these sites are described in Resource Conservation and Recovery Act Permit Number NEV HW0101 and are summarized in each CAU-specific section of this report. The results of the inspections, a summary of maintenance activities, and an evaluation of monitoring data are presented in this report. Site inspections are conducted annually at CAUs 90, 91, and 112; semiannually at CAUs 92 and 110; and quarterly at CAU 111. Additional inspections are conducted at CAUs 92 and 111 if precipitation occurs in excess of 1.0 inch in a 24-hour period. Inspections include an evaluation of the condition of the units, including covers, fences, signs, gates, and locks. At CAUs 110 and 111, soil moisture monitoring and subsidence surveys are conducted in addition to the visual inspections. At CAU 110 the site fence, gate, lock and use restriction signs are evaluated. At CAU 111, an ecological survey, direct radiation monitoring, air monitoring, radon flux monitoring, and groundwater monitoring are also conducted. This report will address all monitoring item notes above except groundwater monitoring. Groundwater monitoring is documented in the Nevada National Security Site Data Report: Groundwater Monitoring Program Area 5 Radioactive Waste Management Site. All required inspections, maintenance, and monitoring were conducted in accordance with the post-closure requirements of the permit. Revision 6 of Permit NEV HW0101 was issued effective December 10, 2015, and remains in effect until December 10, 2020.

54 ENVIRONMENTAL SCIENCES↗

Carbon Dioxide Enhanced Oil Recovery Life Cycle (CELiC) Model

The Carbon Dioxide (CO 2 ) Enhanced Oil Recovery (EOR) Life Cycle (CELiC) Model calculates life cycle greenhouse gas (GHG) emissions for a CO 2 -EOR system, where the user can select one of three sources of the injected CO 2 : (1) extracted from a natural dome, (2) captured from a coal-fired power plant, or (3) captured from a natural gas power plant. The model has several parameters and options to allow the assessment of the system for a wide-array of products—electricity, pipeline CO 2 , crude oil, and refined fuels. The model is also capable of deterministic (i.e., point estimate) and stochastic (i.e., probabilistic) analyses and finally a deterministic time-series analysis that shows the changing GHG emissions for the CO 2 -EOR system over time.

03 NATURAL GAS↗