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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,711 records · Page 95
All sourcesNASA NTRSDOE OSTI
DOE OSTI2013

MAGNESIUM ISOTOPE EVIDENCE FOR SINGLE STAGE FORMATION OF CB CHONDRULES BY COLLIDING PLANETESIMALS

Chondrules are igneous spherical objects preserved in chondritic meteorites and believed to have formed during transient heating events in the solar protoplanetary disk. Chondrules present in the metal-rich CB chondrites show unusual chemical and petrologic features not observed in other chondrite groups, implying a markedly distinct formation mechanism. Here, we report high-precision Mg-isotope data for 10 skeletal olivine chondrules from the Hammadah al Hamra 237 (HH237) chondrite to probe the formation history of CB chondrules. The {sup 27}Al/{sup 24}Mg ratios of individual chondrules are positively correlated to their stable Mg-isotope composition (μ{sup 25}Mg), indicating that the correlated variability was imparted by a volatility-controlled process (evaporation/condensation). The mass-independent {sup 26}Mg composition (μ{sup 26}Mg*) of chondrules is consistent with single stage formation from an initially homogeneous magnesium reservoir if the observed μ{sup 25}Mg variability was generated by non-ideal Rayleigh-type evaporative fractionation characterized by a β value of 0.5142, in agreement with experimental work. The magnitude of the mass-dependent fractionation (∼300 ppm) is significantly lower than that suggested by the increase in {sup 27}Al/{sup 24}Mg values, indicating substantial suppression of isotopic fractionation during evaporative loss of Mg, possibly due to evaporation at high Mg partial pressure. Thus, the Mg-isotope data of skeletal chondrules from HH237 are consistent with their origin as melts produced in the impact-generated plume of colliding planetesimals. The inferred μ{sup 26}Mg* value of –3.87 ± 0.93 ppm for the CB parent body is significantly lower than the bulk solar system value of 4.5 ± 1.1 ppm inferred from CI chondrites, suggesting that CB chondrites accreted material comprising an early formed {sup 26}Al-free component.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2011

Ionization and fragmentation of polycyclic aromatic hydrocarbon clusters in collisions with keV ions

We report on an experimental study of the ionization and fragmentation of clusters of k polycyclic aromatic hydrocarbon (PAH) molecules using anthracene, C{sub 14}H{sub 10}, or coronene, C{sub 24}H{sub 12}. These PAH clusters are moderately charged and strongly heated in small impact parameter collisions with 22.5-keV He{sup 2+} ions, after which they mostly decay in long monomer evaporation sequences with singly charged and comparatively cold monomers as dominating end products. We describe a simple cluster evaporation model and estimate the number of PAH molecules in the clusters that have to be hit by He{sup 2+} projectiles for such complete cluster evaporations to occur. Highly charged and initially cold clusters are efficiently formed in collisions with 360-keV Xe{sup 20+} ions, leading to cluster Coulomb explosions and several hot charged fragments, which again predominantly yield singly charged, but much hotter, monomer ions than the He{sup 2+} collisions. We present a simple formula, based on density-functional-theory calculations, for the ionization energy sequences as functions of coronene cluster size, rationalized in terms of the classic electrostatic expression for the ionization of a charged conducting object. Our analysis indicates that multiple electron removal by highly charged ions from a cluster of PAH molecules rapidly may become more important than single ionization as the cluster size k increases and that this is the main reason for the unexpectedly strong heating in these types of collisions.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2016

Accretion of radiation and rotating primordial black holes

We consider rotating primordial black holes (PBHs) and study the effect of accretion of radiation in the radiation-dominated era. The central part of our analysis deals with the role of the angular momentum parameter on the evolution of PBHs. We find that both the accretion and evaporation rates decrease with an increase in the angular momentum parameter, but the rate of evaporation decreases more rapidly than the rate of accretion. This shows that the evaporation time of PBHs is prolonged with an increase in the angular momentum parameter. We also note that the lifetime of rotating PBHs increases with an increase in the accretion efficiency of radiation as in the case of nonrotating PBHs.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

Clusters of primordial black holes and reionization problem

Clusters of primordial black holes may cause the formation of quasars in the early Universe. In turn, radiation from these quasars may lead to the reionization of the Universe. However, the evaporation of primordial black holes via Hawking’s mechanism may also contribute to the ionization of matter. The possibility of matter ionization via the evaporation of primordial black holes with allowance for existing constraints on their density is discussed. The contribution to ionization from the evaporation of primordial black holes characterized by their preset mass spectrum can roughly be estimated at about 10{sup −3}.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

Pulsed microwave discharges in powder mixtures: Status, problems, and prospects

Results of experiments on the excitation of pulsed microwave discharges by gyrotron radiation (λ = 4 mm, P{sub 0} = 100–500 kW, τ = 1–10 ms) in the volumes and on the surfaces of metal-dielectric powder mixtures are presented. It is shown that there are two phases of discharge development: the spark phase, accompanied by a partial evaporation of the powder material, and the phase of a developed discharge, characterized by a plasma density of ∼10{sup 17} cm{sup –3}, high absorption, and high temperatures (∼5–10 kK) in a thin layer (∼0.1–0.2 mm) of plasma and vapor. It is demonstrated that the conductivity induced in the targets by UV radiation play an important role in the microwave absorption by powder grains. It is found that, in the course of the discharge, a conductive metal mesh forms in the powder volume as a result of metal evaporation. Reactions of high-temperature synthesis were initiated in various powder mixtures (Ti + B, Al + Fe{sub 2}O{sub 3}, Mo + B, etc.). It is shown that the reactions of high-temperature synthesis last for up to 0.1 s and are accompanied by the evaporation of powder grains and the formation of an aerosol cloud due to free expansion of reactants from the sample surface. The possibility of experimentally studying the kinetics of reactions of high-temperature synthesis is demonstrated. It is noticed that microwave discharges can be used to initiate plasmachemical reactions on the surfaces of radioparent materials in active gaseous media.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

Modeling Solution Drying by Moving a Liquid-Vapor Interface: Method and Applications

A method of simulating the drying process of a soft matter solution with an implicit solvent model by moving the liquid-vapor interface is applied to various solution films and droplets. For a solution of a polymer and nanoparticles, we observe “polymer-on-top” stratification, similar to that found previously with an explicit solvent model. Furthermore, “polymer-on-top” is found even when the nanoparticle size is smaller than the radius of gyration of the polymer chains. For a suspension droplet of a bidisperse mixture of nanoparticles, we show that core-shell clusters of nanoparticles can be obtained via the “small-on-outside” stratification mechanism at fast evaporation rates. “Large-on-outside” stratification and uniform particle distribution are also observed when the evaporation rate is reduced. Polymeric particles with various morphologies, including Janus spheres, core-shell particles, and patchy particles, are produced from drying droplets of polymer solutions by combining fast evaporation with a controlled interaction between the polymers and the liquid-vapor interface. Our results validate the applicability of the moving interface method to a wide range of drying systems. The limitations of the method are pointed out and cautions are provided to potential practitioners on cases where the method might fail.

36 MATERIALS SCIENCE↗
DOE OSTI2016

THE LAUNCHING OF COLD CLOUDS BY GALAXY OUTFLOWS. II. THE ROLE OF THERMAL CONDUCTION

We explore the impact of electron thermal conduction on the evolution of radiatively cooled cold clouds embedded in flows of hot and fast material as it occurs in outflowing galaxies. Performing a parameter study of three-dimensional adaptive mesh refinement hydrodynamical simulations, we show that electron thermal conduction causes cold clouds to evaporate, but it can also extend their lifetimes by compressing them into dense filaments. We distinguish between low column-density clouds, which are disrupted on very short times, and high-column density clouds with much longer disruption times that are set by a balance between impinging thermal energy and evaporation. We provide fits to the cloud lifetimes and velocities that can be used in galaxy-scale simulations of outflows in which the evolution of individual clouds cannot be modeled with the required resolution. Moreover, we show that the clouds are only accelerated to a small fraction of the ambient velocity because compression by evaporation causes the clouds to present a small cross-section to the ambient flow. This means that either magnetic fields must suppress thermal conduction, or that the cold clouds observed in galaxy outflows are not formed of cold material carried out from the galaxy.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS2009

Combined Modeling of Acceleration, Transport, and Hydrodynamic Response in Solar Flares: The Numerical Model - 1

Acceleration and transport of high-energy particles and fluid dynamics of atmospheric plasma are interrelated aspects of solar flares, but for convenience and simplicity they were artificially separated in the past. We present here self consistently combined Fokker-Planck modeling of particles and hydrodynamic simulation of flare plasma. Energetic electrons are modeled with the Stanford unified code of acceleration, transport, and radiation, while plasma is modeled with the Naval Research Laboratory flux tube code. We calculated the collisional heating rate directly from the particle transport code, which is more accurate than those in previous studies based on approximate analytical solutions. We repeated the simulation of Mariska et al. with an injection of power law, downward-beamed electrons using the new heating rate. For this case, a -10% difference was found from their old result. We also used a more realistic spectrum of injected electrons provided by the stochastic acceleration model, which has a smooth transition from a quasi-thermal background at low energies to a non thermal tail at high energies. The inclusion of low-energy electrons results in relatively more heating in the corona (versus chromosphere) and thus a larger downward heat conduction flux. The interplay of electron heating, conduction, and radiative loss leads to stronger chromospheric evaporation than obtained in previous studies, which had a deficit in low-energy electrons due to an arbitrarily assumed low-energy cutoff. The energy and spatial distributions of energetic electrons and bremsstrahlung photons bear signatures of the changing density distribution caused by chromospheric evaporation. In particular, the density jump at the evaporation front gives rise to enhanced emission, which, in principle, can be imaged by X-ray telescopes. This model can be applied to investigate a variety of high-energy processes in solar, space, and astrophysical plasmas.

STOCHASTIC ACCELERATION MODEL↗
NASA NTRS2018

Attribution of Flux Partitioning Variations Between Land Surface Models over the Continental U.S.

Accurate quantification of the terrestrial evapotranspiration (ET) components of plant transpiration (T), soil evaporation (E) and evaporation of the intercepted water (I) is necessary for improving our understanding of the links between the carbon and water cycles. Recent studies have noted that, among the modeled estimates, large disagreements exist in the relative contributions of T, E and I to the total ET. As these models are often used in data assimilation environments for incorporating and extending ET relevant remote sensing measurements, understanding the sources of inter-model differences in ET components is also necessary for improving the utilization of such remote sensing measurements. This study quantifies the contributions of two key factors explaining inter-model disagreements to the uncertainty in total ET: (1) contribution of the local partitioning and (2) regional distribution of ET. The analysis is conducted by using outputs from a suite of land surface models in the North American Land Data Assimilation System (NLDAS) configuration. For most of these models, transpiration is the dominant component of the ET partition. The results indicate that the uncertainty in local partitioning dominates the inter-model spread in modeled soil evaporation E. The inter-model differences in T are dominated by the uncertainty in the distribution of ET over the Eastern U.S. and the local partitioning uncertainty in the Western U.S. The results also indicate that uncertainty in the T estimates is the primary driver of total ET errors. Over the majority of the U.S., the contribution of the two factors of uncertainty to the overall uncertainty is non-trivial.

uncertainty↗
NASA NTRS2018

Attribution of Flux Partitioning Variations Between Land Surface Models Over the Continental U.S.

Accurate quantification of the terrestrial evapotranspiration (ET) components of plant transpiration (T), soil evaporation (E) and evaporation of the intercepted water (I) is necessary for improving our understanding of the links between the carbon and water cycles. Recent studies have noted that, among the modeled estimates, large disagreements exist in the relative contributions of T, E and I to the total ET. As these models are often used in data assimilation environments for incorporating and extending ET relevant remote sensing measurements, understanding the sources of inter-model differences in ET components is also necessary for improving the utilization of such remote sensing measurements. This study quantifies the contributions of two key factors explaining inter-model disagreements to the uncertainty in total ET: (1) contribution of the local partitioning and (2) regional distribution of ET. The analysis is conducted by using outputs from a suite of land surface models in the North American Land Data Assimilation System (NLDAS) configuration. For most of these models, transpiration is the dominant component of the ET partition. The results indicate that the uncertainty in local partitioning dominates the inter-model spread in modeled soil evaporation E. The inter-model differences in T are dominated by the uncertainty in the distribution of ET over the Eastern U.S. and the local partitioning uncertainty in the Western U.S. The results also indicate that uncertainty in the T estimates is the primary driver of total ET errors. Over the majority of the U.S., the contribution of the two factors of uncertainty to the overall uncertainty is non-trivial.

evapotranspiration partitioning; transpiration; so↗
DOE OSTI2015

Control room consolidation at Hanford tank farms for improved conduct of operation - 15345

Washington River Protection Solutions (WRPS) manages the underground waste storage tanks at the Hanford site in Washington State on behalf of the DOE Office of River Protection. There are 177 tanks distributed among 18 tank farms spread across an area of desert scrub covering about 20 square miles. A single evaporator facility supports the tanks to provide waste reduction activities. Farms and associated equipment, including exhausters, have been operated locally since installation. Upgrades over time introduced limited automation, but using inconsistent platforms, and providing isolated control locations around the farms. However, as the Tank Farms move from maintenance operations to production operations, with increased numbers of waste transfers and evaporator campaigns, and also prepare for integration with the adjacent Hanford Waste Treatment Plant, then operational improvements were planned and are being implemented. Infrastructure improvement projects included upgrades of control systems to a common platform, and installation of a fiber optic based local area network to the majority of farms, which together provided a distributed control system supporting tank farms. This new infrastructure provided the basis to propose consolidation of control and monitoring operations to a single location. More than a single location, the new Central Control Room was to increase effectiveness of operations by providing full status of all activities being performed across the Tank Farms and the Evaporator. The recent addition of productivity e-tools also would provide capability for management, supervisors and operators to make informed decisions regarding facility operations, through custom online applications designed to provide real time information derived from operational data. For example, tracking turnover activities between shifts, and maintaining compliance with limited conditions for operations. The Central Control Room would also have a single supervisor able to effectively manage the status of all assets and processes. The expected benefits of this arrangement include increased operator utility, increased situational awareness, improved response time for upset conditions, improvement in operator environment, and reductions in operating costs. The projected ROI for the Central Control Room when fully operational was projected to be about two years based on reduced costs from freeing up operations staff to perform other work plus the time and material savings realized by operations being performed with increased situational awareness. So the Central Control Room would become a hub for monitoring and controlling facility operations while responding to real time information affecting productivity and performance, from a centralized location customized to a fresh working environment. Over a 14-month period, WRPS developed the concept and engineering, procured over 500 items, modified and installed in renovated building, and completed transition and testing of this new Central Control Room, turning over the initial phase to Operations for 24/7 use in April 2014. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2015

Incorporating climate and regional setting into realistic-efficacious end states for contaminated sites - 15386

Data from former uranium milling and processing sites in the arid western United States (US) exemplify a conceptual model in which climate and geomorphology, and the associated geochemical and hydrological conditions, control the fate and transport of contaminants. In arid settings, shallow groundwater is transferred to the vadose zone and atmosphere via evaporation, transpiration and seepage. During these transfers, dissolved constituents accumulate in the vadose zone near the capillary fringe and around the roots of phreatophyte plants. In areas where the water table is shallow, minerals will also accumulate at the surface as a result of capillarity and evaporation. Two western-semiarid former milling sites, Tuba City AZ and Riverton WY, represent deep and shallow water table cases, respectively. At Tuba City, hydrological and geochemical factors limit the size of the groundwater plume and reduce the potential for contaminated water to crop at the locally significant Moenkopi Wash. At both sites, minerals that have formed in the groundwater and vadose zone in the near-field and mid-field areas will sustain elevated groundwater concentrations of anthropogenic contaminants, such as sulfate and uranium, for an extended time frame. The presence of secondary source mineral accumulations in the vadose zone in the mid-field area at Riverton is significant because episodic flooding occurs at this site. The contaminant distributions and plume dynamics observed at arid sites contrast with sites in the eastern US with stronger hydrologic driving forces and weaker evaporative processes. In both arid and non-arid settings, long term contaminant behaviors and concomitant exposure, risk and remediation time frames are controlled by regional conditions and climate and by local modifying factors. As a result, incorporating these conditions and factors into environmental management decisions provides new opportunities to develop more robust, sustainable and technically-defensible end states. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2016

WOW Technology's Innovative Radioactive Liquid Waste Treatment - 16128

WOW presents its revolutionary technology and equipment for liquid radioactive waste treatment: outperforming ultimate water decontamination and purification process, enhanced sludge concentration, no secondary waste nor consumables, fully automated, remote controlled and self-decontaminating device. The WOW's technology is based upon a never before observed discovery of fluid dynamics science: the possibility of performing a molecular separation between solute and suspended elements and the solvent. The combination of such a molecular separation process with a standard vacuum evaporation improves the abatement performances by thousands of times, with respect to those of the state of the art vacuum evaporators. In addition to this, no secondary waste is produced during the process, as no filters, membranes, resins or additives are used. WOW equipment, automated and remote controlled, self decontaminates after use and can be designed and constructed either tailored to the application needs or with a modular approach for enhanced transportability and application flexibility. After the preliminary verification by CNR, the Italian National Research Center, WOW Technology's decontamination device was tested c/o LENA, the Laboratory of Applied Nuclear Energy of the University of Pavia, Italy with a simulated solution 6000 times more contaminated than the nuclear reactor's cooling water of Fukushima-Daiichi NPP. In addition to that, WOW's technology was also used in a real case at the Radiochemistry laboratory of the Pavia's University Chemistry department. Both the above mentioned contaminated fluids have been successfully decontaminated without production of additional or secondary waste. WOW's technology has already performed on industrial scale c/o the Nuclear Repository of S.S.M. in Saluggia, Italy: 45000 liters of acid radioactive solution have been successfully decontaminated to a Decontamination Factor (DF) of 335000 for Cs-137 by one single evaporation step and without using any additional tool to control steam. [Performances independently certified by: National Physics Laboratory (UK) and Pavia University Radiochemistry Laboratory, Chemistry Department (Italy)]. The high decontamination factors and the high volume reduction of the sludge make this technology suitable for the ultimate treatment of highly contaminated liquid waste such as the Fukushima-Daiichi nuclear reactor's cooling water. The WOW's technology addresses as well to interventions in both, operating and decommissioning nuclear power plants and any other nuclear and radioactive facility whose produced and/or stored radioactive liquid solutions, including acid liquid solutions, can be successfully treated, the waste volume reduced and no secondary waste produced. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2018

Improved Heat Exchanger Performance Achieved Through Improved Condensate Drainage - 18478

Hanford's 242-A Evaporator has had the mission of reducing waste volume in the Hanford Tank Farms since the late 1970's. At the very heart of the 242-A evaporation process is the E-A-1 reboiler, a heat exchanger which adds heat to the waste, and the vacuum condenser system, a three-stage condenser/ejector system which condenses the waste vapors and provides the vacuum at which the evaporation process operates. Over a long period of time, significant degraded performance has been observed in the heat exchangers in both the heating system and in the vacuum condensing system. This degraded performance was indicative of degraded conditions in equipment and/or piping associated with both the heating and vacuum condenser systems. However, in searching for degraded condition in these systems, 242-A engineering also discovered that both systems contained design errors in the condensate drainage associated with all heat exchangers in both systems. By addressing the condensate design errors in addition to correcting the degraded conditions, system performance was restored and even possibly improved. All heat exchangers in the heating and vacuum condensing systems are shell and tube type heat exchangers. Both have liquid on the tube side and vapor on the shell side (in the case of the reboiler the liquid is tank waste and the vapor is 10 lb heating steam, and in the case of the vacuum condensers the liquid is cooling water and the vapor is waste vapor). In both systems, engineering proposed that the vapor condensate was backing up into the heat exchanger, resulting in added poor performance. By focusing on basic heat exchanger system design, projects were initiated to redesign the condensate drainage of these systems and re-plumb the condensate drain lines. Data collected before and after the replumbing provides evidence that the corrected drain lines from the heat exchangers improved the performance of the system as a whole, and in the case of the reboiler, removed a potentially damaging steam condensate water hammer condition. (author)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2014

Evaluation of convection‐permitting model simulations of cloud populations associated with the Madden‐Julian Oscillation using data collected during the AMIE/DYNAMO field campaign

Abstract Regional convection‐permitting model simulations of cloud populations observed during the 2011 Atmospheric Radiation Measurement (ARM) Madden‐Julian Oscillation Investigation Experiment/Dynamics of the Madden‐Julian Oscillation Experiment (AMIE/DYNAMO) field campaign are evaluated against ground‐based radar and ship‐based observations. Sensitivity of model simulated reflectivity, surface rain rate, and cold pool statistics to variations of raindrop breakup/self‐collection parameters in four state‐of‐the‐art two‐moment bulk microphysics schemes in the Weather Research and Forecasting (WRF) model is examined. The model simulations generally overestimate reflectivity from large and deep convective cells, and underestimate stratiform rain and the frequency of cold pools. In the sensitivity experiments, introduction of more aggressive raindrop breakup or decreasing the self‐collection efficiency increases the cold pool occurrence frequency in all of the simulations, and slightly reduces the reflectivity and precipitation statistics bias in some schemes but has little effect on the overall mean surface precipitation. Both the radar observations and model simulations of cloud populations show an approximate power law relationship between convective echo‐top height and equivalent convective cell radius.

Hagos, Samson↗
DOE OSTI2015

The origin of water vapor rings in tropical oceanic cold pools

Tropical deep convection over the ocean is found to grow preferentially from thermodynamically preconditioned regions of high specific humidity and, thus, high moist static energy. Because of this, rings of enhanced specific humidity at the leading edges of evaporatively driven cold pools have recently received considerable attention. The prevailing theory explains these rings by the water vapor source from the evaporation of rain drops below cloud base. Their origin is reported on in this letter using large-eddy simulations of individual cumulus clouds that rise into a tropical atmosphere over ocean. It is demonstrated that - in contrast to this theory - water vapor rings are primarily explained by surface latent heat fluxes rather than by the evaporation of rain. This result implies that conceptual models used in subgrid-scale parameterizations of deep convection should consider the formation of rings of increased specific humidity by the cold-pool-induced enhancement of surface fluxes.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

The Role of Convective Gustiness in Reducing Seasonal Precipitation Biases in the Tropical West Pacific

Abstract Precipitation is an important climate quantity that is critically relevant to society. In spite of intense efforts, significant precipitation biases remain in most climate models. One pervasive and persistent bias found in many general circulation models occurs in the Tropical West Pacific where northern hemisphere summer‐time precipitation is often underestimated compared to observations. Using the DOE‐E3SM model, the inclusion of a missing process, convective gustiness, is shown to reduce those biases through a net increase in surface evaporation. Gustiness in surface wind fields is assumed to arise empirically in proportion to the intensity of convective precipitation. The increased evaporation can be treated as an increase in the moist static energy forcing into the atmosphere. A Normalized Gross Moist Stability (NGMS) framework (which characterizes the relationship between convective forcing and convective response) is used to explore the processes responsible for the precipitation bias, and the impact of the gustiness parameterization in reducing that bias. Because the NGMS of the Tropical West Pacific is less than unity in the E3SMv1 model, the increase in energy forcing amplifies the increase in precipitation to exceed that of the evaporative flux. Convective gustiness favors increased precipitation in regions where the resolved surface winds are weak and convection is present.

54 ENVIRONMENTAL SCIENCES↗